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By Sam S. Taylor

The disposal of oil-field brines by injection into subsurface formations other than fresh-water-bearing strata is a positive method of eliminating the harmful effects of mineralized water on fresh-water supplies, vegetation, and aquatic and other animal life. The methods used most generally for the disposal of brines produced with oil are (1) impounding in evaporation ponds, (2) controlled diversion into surface streams, and (3) injection into subsurface formations. Various States recognize one or more of the methods as legally authorized procedure. As a general rule, impounding brine in ponds and solar evaporation have not been entirely successful, principally because of the large volumes handled; the porous nature of the soil, and the low rate of evaporation. Likewise, the diversion of brine into freshwater streams by controlled dilution has not proved satisfactory in some areas, especially in parts of Kansas and Oklahoma where the rainfall is relatively low, because it has been impossible to obtain enough fresh water for such dilution.

Jan 1, 1939

By Louis J. Cabri

"Mineralogical evaluation of ores containing platinum-group elements (PGE) is fraught with difficulties because of the low grades (often 1-3 g/t PGE), dispersal of PGE (usually as finegrained platinum-group minerals [PGM]), as well as occurring in solid solution in some base metal sulphides (BMS) such as pentlandite and pyrrhotite. Mineral processors not only need to know how the PGE are distributed, that is, their mineralogical distribution, but the grain sizes of the PGM, and especially the associated minerals.After obtaining a representative ground sample, common approaches include studying a large number of polished or polished thin sections, concentration of the PGM and sulphides by different gravity methods (e.g., heavy liquids, elutriation, micro-panning) and study of the produced concentrates. Unfortunately, these methods often do not produce concentrations that are sufficiently representative of a particular ore. The newly developed patented technology of hydroseparation (Rudashevsky et al., 2002) is especially effective at making concentrations of PGM over a wide range of concentrations (down to <300 ppb Pt+Pd+Au) and size fractions, including <45µm (down to a few micrometres in size), a size range not possible by other techniques. This water-based environmentally friendly laboratory technique provides a large amount of data from samples, which can range from 5 to 1000g, giving confidence to extrapolation of results to bench-scale and larger test work, especially when combined with quantitative image analysis to determine modal percent of major minerals and mineral liberation data, needed to predict the minimum (K80) and optimum (K40) grinds. INTRODUCTIONThe invention of the electron microprobe in the early 1960’s and scanning electron microscopes (SEM) with energy dispersive spectrometers (EDS) in the 1970’s presented mineralogists with powerful tools permitting them to obtain chemical and surface area data on minute amounts of minerals in situ, in a non-destructive manner. An area of process mineralogy that has very much benefited from this new technology was the characterization and understanding of PGM species, resulting in rapid growth of newly characterized species (Figure 1). Recognition of the first PGM may be ascribed to the Spanish explorer Ulloa in 1748, who described native platinum from South America. The second PGM (laurite, RuS2) was only recognised in 1866 by Wöhler in placer samples from Borneo (now Kalimantan) and the third (sperrylite, PtAs2) by Wells in 1889 from the Sudbury Ni-Cu sulphide deposits. The discovery of the important Pt-Pd deposits in the Bushveld Igneous Complex led to the characterization of the important Pt-Pd sulphides (cooperite, PtS2 in 1928 and braggite, (Pt,Pd)S2 in 1932). By the early 1960’s, only about 20 PGM were recognised, and many later proved to be poorly or incompletely characterized. Thus, the introduction of electron probe microanalysis (EPMA) led to a 50% increase of known PGM, as shown in a 1972 review on PGM (Cabri, 1972). At the time of the next review in 1981 (Cabri, 1981) the number of known PGM had grown to 75 and as of 2002, it had increased to 109 (Cabri, 2002). However, it is the author’s experience that less than about 25 PGM may be considered to be “common”, i.e., found in many different deposit types, as shown in Table 1, but usually only some of these occur in any one particular deposit."

Jan 1, 2004

By P. H. Carr, G. G. Marino, K. A. Patel

Extensions to a correctional institution at Wabash Valley, Indiana, required development over abandoned coal-mine workings, at 90 m depth, where subsidence was possible at surface. Backfilling of the flooded mine in critical areas was determined to be the most cost-effective method of limiting the risk of damage to the buildings. Containment grout was first placed in selected entries and cross-cuts of each mine area; the remaining volume was then filled with a readily flowing infill grout. Where a high proportion of an area was taken up by rubble, calcium lignosulphonate was used as a retarder and plasticiser to increase penetration. Grout movement was monitored from adjacent boreholes with an electrical resistivity probe during grouting, while after the work was finished core samples were obtained from verification holes drilled in the backfilled areas

Jun 19, 1905

By Paul C. McWilliams

The U.S. Bureau of Mines has, primarily through its contract program, used large-scale centrifuges to determine design criteria for tailing embankments. The centrifuge runs were made at two installations, the University of Cambridge, Cambridge, England and Sandia National Laboratories, Albuquerque, NM. The major problems considered were as follows: slope stability of embankments, modeling erosion and seepage, use of the phreatic surface level to ascertain the validity of centrifuge modeling, and the effects of compaction and weathering on a tailings embankment. This report summarizes the results of the four test series conducted at University of Cambridge and Sandia National Laboratories. A review of prior centrifuge applications to mining problems is included. Consideration is given to future centrifuge application to mining problems in both soil and rock mechanics.

Jan 1, 1989

By Raymond Philippe

Background ?Hatch Water has worked with most major mining companies in Chile on water supply and optimization projects ?Many(copper) mining projects are located in Northern Chile, which hosts the driest desert on earth Water supply options in Northern Chile ?River ?Availability/Rights ?Well(Brackish) Water ?Availability/Rights ?Municipal Wastewater ?Water rights ?Volume ?(Desalinated) Seawater ?Infinite source ?Cost depends on distance and altitude ?Recycling/Reutilization ?Water losses All these options present water quality issues

May 1, 2009

By H. Verakis, M. J. Sapko

The Pittsburgh Research Laboratory (PRL)1 of the National Institute for Occupational Safety and Health (NIOSH) in collaboration with the Mine Safety and Health Administration (MSHA) Technical Support Center has devised a prototype hand-held instrument which can provide a direct assessment of the potential explosibility of a coal and rock dust mixture. Current Federal regulations require that rock dust be applied in all underground areas of a coal mine to mitigate the propagation of a coal dust explosion. To determine compliance with the Federal regulation, mine inspectors collect dust samples from sections of underground coal mines for an MSHA laboratory analysis of incombustible content. However, the laboratory analysis may not be completed for more than a week or two, during which time the mine area from which samples are taken may be inadequately protected. The operation of the Coal Dust Explosibility Meter (CDEM) is based on the difference in optical reflectance between light rock dust and dark coal dust. For a given coal volatility, the optical reflectance of such mixtures is relatively constant at the limit of explosibility, independent of the coal dust particle size. The CDEM is not intended to replace the current MSHA laboratory analysis of coal mine dust samples for incombustible content, but to serve as a supplemental device for enhancing mine safety through improved rock dusting practices.

Jan 1, 2006

By D. A. Elgillani, M. C. Fuerstenau, J. D. Miller

Adsorption of lead and ferric iron on quartz and alumina is presented as a function of pH. Only the hydrolyzed species of these metal ions, FeOH++ and PbOH+, adsorb significantly on each of these minerals. Zeta potentials of quartz were measured as a function of pH in the presence of various additions of aluminum, lead, and magnesium salts. Sign reversal occurs at the pH values where significant concentrations of hydroxy complexes are formed. Models of adsorption are presented in the absence and presence of collector. The mechanism of adsorption of metal and collector species in the activation of nonmetallic minerals is still the center of considerable discussion in spite of the extensive study given this system. Until recently, the view was widely held that hydrated metal ions were responsible for this phenomenon. This fact is surprising, since it had been shown that the pH range in which flotation is effected corresponds to that in which metal ion hydrolysis occurs.&apos; Additional support of this concept was pro vided by the work of Wolstenholme and Schulman in another system.&apos; Later work has shown that hydroxy complexes of metal ions are the active species. These studies have also indicated that basic aqueous complexes of metal-collector may be necessary for flotation.3-7 Depending on the molecular weight of the collector, formation of these complexes may occur before or after precipitation of the metal-collector salt has occurred. Ion pair formation can occur when low molecular weight collectors are involved because relatively high concentrations of metal hydroxy complex and collector can be present in solution before precipitation occurs. This is not the case when high molecular weight collectors are used. A model of aqueous complex adsorption has been presented6,7 in which it has been assumed that adsorption occurs by the formation of water from adsorbed hydroxyl and hydrogen of the hydroxyl contained in the complex. Other authors8 have suggested that hy-droxy complexes are involved in these systems but that collector adsorption occurs by replacement of the hydroxyl of the adsorbed metal hydroxy complex with a fatty acid anion. All of these investigations have involved mineral surfaces that were negatively charged so that it is not possible to state with certainty whether hydrated metal ions or hydroxy complexes are the active species in this system. Use of a positively charged mineral should be helpful, however, since the hydrated metal ion will be repelled from this surface. On the other hand, if the hydroxy complex adsorbs by splitting out water, surface charge should have no effect because of the free energy decrease that the system will experience when water is formed. In this regard, sapphire is well-suited for study, since its surface is positively charged until approximately pH 9. Electrokinetic studies of quartz in the presence of various metal ions should also be useful in establishing the mechanisms of adsorption in these systems. That is, if the hydroxy complexes adsorb by water formation, drastic changes in the zeta potential should occur in the pH range in which hydrolysis occurs. In this view, adsorption of ions of widely different hydrolysis characteristics on both sapphire and quartz was measured. In addition, zeta potentials of quartz were measured as a function of pH in the presence of various metal ions and compared with flotation responses obtained under similar conditions. Experimental Materials and Techniques Reagent-grade aluminum, ferric and magnesium chlorides, and lead nitrate were used in this investigation. Adjustments in pH were made with reagent-grade HCl or KOH. Conductivity water, made by passing distilled water through an ion exchange column, was used in all of the experiments.

Jan 1, 1971

By William A. Enrico

Umicore acquired the Pirdop Smelter in a privatization offering by the Bulgarian government in September 1997. Since that time, an investment program has been conducted to increase capacity to 225 000 tons per year of anode copper, while improving the environmental performance to meet Bulgarian and European standards. A significant part of this investment program involved reconstruction of the three Peirce-Smith converters and the associated gas handling system. During the period June, 2000 through April, 2002, converter capacity was increased, the existing water-cooled hoods were replaced, the waste heat boiler was replaced by two evaporative coolers, the dry ESP&apos;s were rebuilt and extended, and a Converter Control System (CCS) installed. From 2002 until the present, a continuous improvement of operating and environmental performance has been achieved. This paper will describe the converter reconstruction project, the operational, maintenance, and environmental improvements achieved since then and additional projects presently under consideration.

Jan 1, 2005

By Walter I. Paniagua

A housing complex of 76 buildings is being constructed in the city of Morelia, in western central Mexico; the buildings are 5 levels high, with a shallow concrete slab foundation. Soil conditions include a soft clay stratum, with up to 8 m depth, in a highly seismic area. Pile foundations and micro-piles were considered, but discarded due to economic factors. The alternative of soil improvement with rigid inclusions was used. An FEM (Finite Element Method) analysis was conducted to determine the diameter, spacing, length and arrangement of the inclusions. Construction was implemented with traditional methods: soil boring, and mortar tremied with pipe and the aid of a sock to contain the material (no steel reinforcement was used). So far, 46 buildings have been built, and level measurements for 18 buildings have been recorded since 2006, with resulting good behavior in both total and differential settlements.

Jan 1, 2008

The Research on Application of New Technologies in High Gradient Magnetic Separator with Horizontal Magnetic Line

Sep 13, 2010

By D. Turnbull, H. N. Treaftis

Precipitation of tin from Pb-Sn alloys (lead-rich) occurs by the nucleation and growth of hemispherical cells which consist of tin lomelloe interspersed in the depleted solid solution. Nucleation and growth of these cells and the tin interlamellar spacing at various compositions and temperatures have been investigated. The interlamellar spacing increases approximately as the reciprocal of the logarithm of the supersaturation ratio. For constant initial tin concentration the concentration of cell nuclei increases with decreasing temperature to a limiting temperature-independent value. The kinetic results support the view that the cell growth rote is governed by the diffusion of tin along the cell boundary. In the main, the results confirm the authors&apos; earlier deductions, drawn from resistometric and calorimetric data, about the precipitation mechonism. IT has been shown1, 2 that tin (ß) precipitates from lead-rich (a) PbSn solutions by the nucleation and growth of cells (cellular or discontinuous precipitation). These cells consist of tin lamellae, with a spacing 1, interspersed in a depleted a solution. Reorientation of a also accompanies cell growth. The kinetics of cellular precipitation of tin from lead have been measured by resistometric2, 3 and ca1orimetric1, 3 techniques. The time-transformation isotherms (t equals time; x, volume fraction of specimen transformed) of the initial rapid precipitation, which drains about 60 pet of the tin from solution, have been described by a kinetic law having the form x = 1 —exp (—bt n) [I] where n usually has the value 3.0. It was shown" that this law and the other kinetic facts can be explained satisfactorily if it is assumed that the cells grow at a constant rate and that all the cells nucleate in a time negligible in comparison with the period of cell growth before impingement. Thus, for hemispherical cells b = (2/3)pNG3 [21 where G is the rate of cell growth in cm per sec, and N is the number of cell nuclei per unit volume. The rapid rate of cell growth at low temperatures can be accounted for"&apos; if it is assumed that the dissolved tin drains to the lamellae edges by diffusion along the sweeping cell boundary rather than by diffusion through the a crystal (volume diffusion). For cell growth governed by cell boundary diffusion it was shown, approximately G=2(X° - X° / X° ) DBA / l2 where A equals the thickness of the cell boundary; D R, the coefficient of diffusion of tin atoms within the boundary; and X° and X, are the atom fractions of tin in the supersaturated and saturated solutions, respectively. Zener8 had already shown that, where

Jan 1, 1959

Effect of Matching Relationship Between Bubble Size and Particle Size on Kaolinite Flotation

Sep 13, 2010

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By W. M. Deaton

The formation of gas hydrates in natural-gas pipe lines depends on temperature and pressure conditions in the lines as well as on the presence of condensed water. The operating pressure in a pipe line may be determined easily and usually is available from the records of operation, but the temperature seldom is known. In cooperation with the American Gas Association, the Bureau of Mines, in its investigation of gas hydrates, conducted a pipe-line-temperature survey and studied underground temperatures at depths at which pipe lines ordinarily are buried and the relationship of these temperatures to prevailing atmospheric conditions. A similar but mere limited study of this type was conducted by engineers of the Bureau of Mines a number of yours ago.4/ A summary of the earlier findings was included in a general report by the Bureau on the flew of natural gas through high-pressure transmission lines.5/ In the present study, data on temperature variations were obtained at several places widely separated geographically. This information should assist pipe-line engineers in designing and operating natural-gas pipe lines.

Jan 1, 1941

By P. N. Anyalebechi

The effects of solidification rate (0.4-26.1 K/s) and alloying elements on the cast microstructures of aluminum alloy 5182 have been investigated with directionally cooled laboratory-size ingots. The alloying elements examined included Mg (3.6-4.7 wt.%), Mn (0.35-0.75 wt.%), Fe (0.11- 0.42 wt.%), Cu (0.03-0.25 wt.%), and Si (0.11-0.28 wt.%). These reflect the chemical compositions of AA 5182 end stocks with high recycled used beverage container (UBC) content. For a given chemical composition, the average dendrite cell and constituent phase particle size decreased with increase in average solidification rate. In general, within the level investigated, Mg did not have a significant effect on the types, volume fractions, and average sizes of the constituent phase particles. However, increase in Mn, Si, Fe, and Cu increased average sizes and volume fractions of the constituent phase particles.

Jan 1, 2010

Influence of Grinding Media on the Flotation of Carbonate Using Sodium Oleate as Collector

Sep 13, 2010

By A. Broussaud, J. D. McKay

Benefits analysis of adaptive Expert control systems operating at plants in Africa and the United States are presented. Proper statistical tools and techniques are discussed. Technical and practical pitfalls of strategy comparison are also presented and illustrated with from published data. Advantages and disadvantages of a “Pay for Performance” approach to a project are reviewed.

Jan 1, 2001

In most mines using presplitting the final excavated wall shows a zone of damage just below the crest and well defined presplit half barrels. The crest damage (surface dilation) zone varies and is added to by subsequent adjacent perimeter blasting operations. Keeping the preconditioning to a minimum is possible using the methods described in this paper, developed on several diverse and geographically distant mining operations to control crest dilation and preconditioning by presplitting in advance - not just laterally but vertically in advance. The first documented case (Delbridge, Marton and McSweeney, 2004) in the development of the concept was undertaken at AngloGold Australia Pty Ltd&apos;s Sunrise Dam Gold Mine (SDGM), located beside Lake Carey, some 730 km northeast of Perth, Western Australia. The mine had been developed in a series of cutbacks to a depth of over 300 m and began underground mining during the latter stages of open cut operations. This mine is fairly unique in that it utilised a single pass vertical presplit which initially extended over three bench heights and after the failure mechanisms were understood, over four benches. The presplit drilling for the three stacked benches started on the floor of the second bench so that any dilation was confined to the surface one bench above the crest and modified perimeter blasting was then developed to curtail damage from blasting adjacent to the new crest. The second case is based on a South African coal mine in the Witbank Coal Measures, 140 km northeast of Johannesburg, Republic of South Africa (RSA). It was important that blasting for optimal wall stability and minimal scaling was developed in advance. A dragline is scheduled to excavate the #2 seam midburden which is the lowest of the economically viable coal seams in the five seam Witbank Coal Measures. Mining of the overburden, coal and partings above the dragline midburden pass are by excavator and truck and each mining layer is individually blasted. The results of presplitting the midburden through the overlying coal seams and partings have provided a presplit with no surface dilation of the midburden crest and ensures any subsequent crest loss is solely due to blasting adjacent to the vertical presplit. Typical of all coal mines in South Africa only vertical presplits are used. Wall control is most commonly delivered by presplit blasting and one common sight after the dust clears is a ridge of broken blocks along the presplit row, usually with a main crack running between the presplit blastholes and often parallel cracks either side of the perimeter line. The surface rock strata or block structures have been dilated by the venting gases and shock waves. Decoupled, fully coupled, single or double deck charges are used depending on a variety of factors, anecdotal practices and perceived benefits. Preconditioning of the crest rock by blasting from above may not be visible to the naked eye (or non-existent in overburden in strip coal mines) but the high speed venting of explosives gases (and often the water in the presplits) preferentially follow existing cracks and structures because there is no developed presplit crack near the surface. This nearly always lifts, shifts and separates the surface structures and geological layers. Stopping the dilation by &apos;sacrificial&apos; or &apos;in advance&apos; presplitting has been shown to reduce the crest loss at both metal and coal mines. Drilling and presplit blasting through an upper level of bench or layer provides a degree of restraint to the target layer where the crest must be maintained and any damage caused by the venting gases will not cause concern as it is removed as planned, leaving a stable crest.

May 1, 2010

Flue dust from the sintering of base metal sulphides was leached to remove cadmium and arsenic. Leach liquor contained cadmium, zinc and small amounts of other base metals as chlorides. Results are reported of the use of a cation exchange resin Zeocarb 225 to separate the base metals from the arsenic. The resin was eluted with sodium chloride or sulphate to give a solution of relatively concentrated cadmium suitable for recovery by zinc cementation. The limited solubility of sodium sulphate presented some practical problems which were investigated. Another problem was the precipitation of lead sulphate in the resin during elution.INTRODUCTIONWhen lead-zinc sulphides are sintered prior to smelting, the gases passing to the flue are mainly uncondensable but contain a certain proportion of sublimates and dust particles which deposit in the flue or are carried, after condensation in the gas stream, to some form of dust extraction equipment.The recovered dust is a complex mixture of base metal sulphates, sulphites, sulphides, chlorides and oxides, the composition depending on the original concentrates. A large proportion of the cadmium and some of the arsenic originally in the concentrates finds its way to this flue dust, the treatment of which can be a convenient means of removing these elements and controlling their concentrations in the main lead-zinc smelter circuit. However, disposing of this material represents an appreciable waste of base metals as well as a serious toxicity hazard.Sulphide Corporation Pty. Ltd. was faced with this problem in planning the flow sheet of the new lead-zinc smelter at Cockle Creek, N.S.W. From a test run carried out on a pilot plant at Avonmouth, U.K., using a mixture of lead and zinc concentrates, a sample of dust was obtained for...

Jan 1, 1960

By Edgardo Fogli, Mario Lampiano, Antonio Nicola

The project is located in the northern region of the People’s Republic of China and was awarded to Impregilo, as sponsor of the Wan Long Joint Venture, in September1997. The project consists of four tunnels for a total length of 88,700 m, with an excavation diameter of about 4.9 m. The lining is made of honeycomb pre-cast segments, connected by PVC dowels and the joints are sealed with elastomeric gaskets. The geology is mainly Limestone, Dolomite and Sandstone. Karst cavities are abundant and are often in-filled with plastic red clay. This has adversely affected the TBM’s progress. Four double shield telescopic TBMs were mobilized to cope with the very tight construction schedule and, at the end of November 2000, more than 80% of the tunnel has been bored. The article analyses the TBMs’ productions in the various geological conditions and the results of different technical solutions adopted at the project.

Jan 1, 2001