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By C. Pace, D. Darlington, A. Montera, C. Lingren

"A phosphate beneficiation plant in Utah is using isotope-based Prompt Gamma Neutron Activation Analysis (PGNAA) technology to analyze the entire slurry streams of the incoming feed and final product in order to adjust the flotation circuits in near real time and optimize the plant output. The plant has gained greatly improved visibility/control and has reduced product variability for improved profitability and product quality. This paper takes a look at the economics as well as application details and the difference this technology provides in a phosphate application. SIMPLOT PHOSPHATES INTRODUCTION Simplot’s Vernal, Utah Phosphate Mine and Mill are located in the northeast corner of the state in the Uinta Mountains along US Highway 191, eleven miles north of the town of Vernal. The phosphoric acid and fertilizer plant fed by the Vernal mine is located 94 miles Northeast of Simplot Phosphates in Rock Springs, WY.At the Vernal plant, loader and shovel mining to 85 Ton capacity trucks is done at an annual rate of 3.8 Million tons of ore. Run of mine ore is crushed in a mineral sizer to minus 14 inch diameter at the rate 11,500 tons a day and transported to the SAG Mill’s 130,000 ton surge stockpile by overland belt. ORE RESERVES The ore is a Phosphoria Formation of sedimentary rock type dating to the Permian Age. The ore body rests over a 25 mile area on Weber Sandstone from the Pennsylvania and Permian geologic period. Layers of Phosphate Rock can vary in thickness from 0.3 up to 2.1 feet, alternating with layers of Mudstone. The eastern edge of the ore’s body Panel “G” runs 16 feet deep with a feed grade of 21.5% P205 with lower MgO diluents of less than 2.79%."

Jan 1, 2016

By Alejandro Ferrada Vergara

Most blasting techniques that are designed to improve fragmentation and subsequently improve ore work index to downstream comminution processes, apply powder or energy factor increases, either by stretching the drilling pattern (burden/spacing ratio) implementing faster initiation sequences or using more energetic explosives. The new application will move detonation parameters up, making the blasting process riskier for the surrounding boreholes, explosive column or initiation systems functioning.

Jan 1, 2016

By Peter Richards, Alexander Lewis-Gray, Mark Davies, Nicholas Katsikaros

"Gekko Systems developed the Gekko Resin Exchange Column (G-REX) in order to optimise the recovery of gold in complex leach-to-electrowinning processes, as an intermediate step using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin (Lewis-Gray et al, 2015). Operational experience has been gained at the CGT Ballarat Gold Plant in near continuous operation since 2008, treating unclarified concentrate leach solution. The extension of the technology to higher throughputs and more complex chemistry is discussed.Aurix®100 ResinAuRIX®100 resin is a cross-linked polystyrene alkaline resin developed by Henkel (Virnig et al, 1996). The resin beads are off-white in colour, spherical, with a nominal size of 100% +600µm. This resin is highly selective for gold and silver over many metals, by way of extracting precious metal cyanide complexes from leach solutions with a pH less than 11.5. The higher end of the pH scale produces best selectivity according to the order of preference: Au > Ag > Hg > Zn > Ni > Cu > Co > Fe. Purolite produces the resin and Gekko Systems maintains licensing of AuRIX®100 resin for use in its G-REX column as part of its unique suite of gravity gold handling equipment.Significant cost savings over carbon-in-solution (CIS) systems are realised with AURIX®100 resin, of around 4% to 12% in capital savings and 27% to 40% in operating costs (Virnig et al, 2004). Allied to this is that AuRIX®100 resin is not susceptible to fouling, that is, the resin does not load with inorganic salts or organic compounds which would affect the loading and extraction of precious metals. To counter any potential for fouling by inorganic salts, in service a dilute acid wash is carried out periodically on the resin to unblock resin pores."

Jan 1, 2016

By Ulrich Maidl, Marc Comulada, Janosch Stascheit

"INTRODUCTION Cohesive soils are notorious for causing clogging of the cutter head and the excavation chamber of tunnel boring machines (TBMs). While clogging leads to a drastic reduction in excavation performance, it further induces higher wear of tools and other parts of the cutter head and may even prevent a controlled support of the tunnel face and, thus, lead to face collapse and excess settlements or sinkholes. Employing well-balanced soil conditioning techniques, the clogging tendency can be significantly reduced. The monitoring and control of soil conditioning as well as the timely detection of potential clogging tendencies require a close monitoring of all relevant machine parameters and measurements. To this end, a reliable and powerful Process Controlling software that gathers all machine and process-related information is a prerequisite for successful mitigation of clogging-induced problems. The remainder of this contribution is organized as follows: First, a brief introduction to the Process Controlling system PROCON is given. Afterwards, the mechanisms and mitigation techniques of clogging are discussed. Finally, an example is given how Process Controlling has been employed to soil conditioning in a tunneling project with highly clogging soils.PROCESS CONTROLLING Being both the active part and a huge measuring device, the shield machine represents the core component in mechanized tunneling. This machine comprises a manifold of complex components and devices that require constant supervision and control and, thus, is equipped with a manifold of different sensors that provide a continuous monitoring of the state and condition of the machine (Maidl & Stascheit, 2014). If these data are put into the whole context of the tunneling process, they can provide insight to the assessment and optimization of the performance and to the prediction of potential risks and hazards such as, for example, the tendency of clogging of the cutter head."

Jan 1, 2016

By J. N. Van der Merwe, M. Mathey

"The South African squat coal pillar strength formula, developed by researchers from the Chamber of Mines Research Organization in the 1980s, predicts an exponential increase in coal pillar strength once a critical width-to-height ratio of 5 is exceeded. The arguments that have been proposed in favour of this formula are discussed critically in this paper.Field experience with squat pillars in the USA and evidence from published physical, analytical, and numerical model pillar studies corroborate the fact that a squat effect is unlikely to occur in coal pillars at width-to-height ratios less than 10. Furthermore, an exponential increase in peak strength of coal pillars does not exist. An alternative design criterion for squat pillars in South Africa is therefore suggested. IntroductionFive decades of coal pillar research in South Africa have produced a wealth of information on the mechanisms contributing to the strength and failure of in-situ coal pillars and accompanying phenomena. The relevant knowledge was sourced from, and for, a South African coal mining environment that remained largely unchanged in the second half of the 20th century. The depth of mining seldom exceeded 250 m, with mined seam thicknesses averaging 3 m and typical pillar width-to-height ratios (w/h) of 3–4.It is therefore not surprising that comparatively little research has been directed at the prediction of coal pillar performance in deeper deposits, where squat pillars of larger width-to-height ratios will be required to support the overlying strata. However, a thorough understanding of squat pillar performance will be necessary should the remaining deep coal deposits of the country be extracted in future, for instance in the Waterberg or Ermelo coalfields.A squat coal pillar strength formula has already been proposed in South Africa. The origin of this formula will be discussed in some detail in the following sections and its appropriateness will be critically reviewed against a great amount of evidence from relevant squat coal pillar research conducted internationally."

Jan 1, 2016

By Emilio Cordero Cordero

En los proyectos de excavaciones subterráneas, túneles de obra civil y galerías mineras es necesaria la realización de cálculos para el sostenimiento adecuado para cada situación y comprobar que este cumple los parámetros de seguridad indispensables para garantizar la estabilidad de la excavación en el tiempo. En este sentido, el texto señala el uso de SDT(software) como aplicación informática decuada para el cálculo de sostenimiento en túneles y galerías mineras que suministra una respuesta a las necesidades de proyectistas e ingenieros mineros. Dicho software se basa en cerchas metálicas con capacidad de deslizamiento (perfiles THN), cerchas de perfil HEB, pernos de anclaje y hormigón proyectado en túneles y galerías mineras que utiliza el método “Convergencia – Confinamiento”, procedimiento de referencia en el cálculo y diseño de sostenimiento en excavaciones subterráneas, con las premisas de sección circular, presión sobre el sostenimiento uniforme y el campo de presiones hidrostático.

Jan 1, 2016

By Jiang Su, Michal Uhrin

"The use of composite linings, consisting of permanent sprayed primary and secondary linings with a sandwiched spray applied waterproofing membrane is expected to improve efficiency and reduce lining thickness, but it also brings complex primary-secondary lining interaction. This issue is further complicated by the uncertainty regarding the long-term behavior and parameters of the sprayed concrete–sprayed membrane interface.This paper aims to address this issue by presentation of a series of numerical analyses of a typical shallow SCL tunnel in soft ground with a range of design assumptions on the interface behavior: (1) compression only; (2) compression and tension; and (3) compression, tension, and shear.The results demonstrate that the assumed interface behavior has a significant impact on the primary-secondary lining interactions. A design approach of ignoring the tension and shear bond at the interface may not be conservative particularly for serviceability. This paper explains the rationale behind these conclusions and discusses the implications for design.INTRODUCTIONSprayed Concrete Tunnel Lining SystemsSprayed concrete linings (SCL) have been used in conventional tunneling for decades. However, details of SCL systems may differ to a large extent depending on ground conditions and specific tunneling methodologies.In hard rock conditions, for example, drill and blast excavation is typically supported by rock bolts and sprayed concrete (NGI 2014). Such tunnels are usually designed fully drained and the above-mentioned support elements considered permanent without the need for a further inner liner. Therefore, there is no structural interaction between separate lining shells to consider.In conventional tunneling in the European Alps, a double shell lining is typically utilized, consisting of an outer (primary) sprayed concrete lining and an inner (secondary) cast-in-place concrete lining, separated by a waterproofing system. The primary lining normally includes rock bolts and may include other support elements. The waterproofing system is usually based on a plastic membrane and a geotextile fleece. The tunnel may be designed fully or partially drained or fully undrained. Although there are two structural lining shells interacting, investigation of such interaction is generally irrelevant to designers because the primary lining is considered only temporary (fully sacrificial in the long term). An overview of reasons for this assumption is given, for example, by Lemke (2014). The secondary lining is designed to resist all foreseeable loads on the tunnel. The primary lining may, in reality, interact structurally with the secondary lining during the life span of the tunnel. However, since the secondary lining design must cover all possible (extreme) scenarios, investigation of such interaction does not bring any value to the design."

Jan 1, 2016

By Britta Schoesser, Zdenek Zizka, Markus Thewes

"The support pressure of a slurry shield corresponds to the in situ earth and groundwater pressure to ensure the stability of the tunnel face. The support fluid (bentonite suspension) penetrates from the excavation chamber into the pore space and transfers the support pressure to the granular structure of the soil within this zone. At the same time, the cutting tools rotate periodically with the cutting wheel and remove the penetrated soil up to a certain cutting depth at the face. Shortly after the tool passing, the penetration process starts again. Both, the support pressure and the soil excavation, act in the same direction at the tunnel face, but they are subject to different cyclic intervals. This relationship between the time needed for the transient penetration process and the interval of the cyclic passage of the cutting tools at a local point at the face is examined and the impact onto the global face stability is discussed. INTRODUCTION Slurry shields are usually deployed for excavations in soft ground. The main application range is in non-cohesive soils (DAUB Recommendations 2010). In non-cohesive granular soils, the tunnel face stability is one of the key design issues. The slurry shields make use of pressurized bentonite suspension (slurry) to support the unstable tunnel face. To support the tunnel face effectively, the slurry pressure has not only to counter the groundwater pressure, but also has to be transferred into an effective stress to support the soil grains. In general, the pressure transfer can be achieved in two ways: (1) with a thin flexible membrane or (2) a penetration zone. The membrane (1), called filter cake, creates a thin impermeable layer from bentonite particles directly on the tunnel face, and enables a transformation of excess slurry pressure into effective stress. In case of penetration zone formation (2), the excess slurry pressure is transferred onto the soil skeleton along the entire penetration depth by shear stresses between slurry and soil grains. These theories, presently applied to assess the pressure transfer on the grains within slurry shield tunnelling, are originating from diaphragm wall technology, e.g. Müller-Kirchenbauer (1977), Kilchert and Karstedt (1984). They assume that the support pressure transfer mechanism is built-up instantaneously on the whole tunnel face and is not damaged or influenced by the interaction with excavation tools. These assumptions are valid for conditions during the excavation of diaphragm wall trenches whose bottom is excavated and the walls of the trench are supported. At the tunnel face of a slurry shield, the support suspension acts on the same area as the soil excavation. Hence, the conditions on the tunnel face are transient (time dependent) due to the time period needed for the penetration process of the slurry and the periodical damage of the pressure transfer mechanism by excavation tools (Fig. 1a)."

Jan 1, 2016

By Narasimha Mangadoddy, Balraju Vadlakonda

"Bubble size distribution, bubble rise velocity and gas and solids hold-up are the key major hydrodynamic parameters that are extensively used for column flotation design and performance evaluation. The distribution characteristics of mean gas hold-up is studied using electrical resistance tomography (ERT) coupled with pressure transducers (PT) in column flotation. The ERT technique facilitates non-invasive and nonintrusive visualization of different flow regimes even in the presence of particles in a column flotation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas hold-up and its radial distribution has been analysed for both two-phase and three phase flows. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the three-phase flow hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, are employed to explore the influence of parameters in two phase flow in column flotation. Mean gas and solids hold-up values extracted from ERT have been critically analysed for the column operating in various flow regimes. Gas hold-ups and solid hold-ups results using ERT are in very good agreement with conventional estimation and correlations obtained using pressure transmitter methods. Meanwhile, the results show that the gas hold-ups in the centre region increase constantly with an increase in the superficial gas velocity, whereas solid hold-ups distribution is very heterogeneous for high gas velocity. Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the 'inside' flow behaviour of gas –liquid–solid three phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is perhaps the most significant technological innovation in flotation machinery and its successful introduction in mineral processing plants. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker & Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena, Biswal, Das, & Reddy, 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on performance of column flotation (Finch, J.A.;Dobby, 1991). Many techniques have been developed that could be used to experimentally analyse the hydrodynamics of column flotation. Tomography techniques are well sound to investigate the hydrodynamics for process equipment. Among that, Electrical resistance tomography (ERT) has been used in various industrial investigations for visualization of the concentration profiles and characteristics of the fluid dynamics in gas–liquid two-phase systems (Wang, Dickin, & Mann, 1999; Williams, R.A; Wang, 2000). ERT is an imaging technique to analyse the internal flow behavior non-intrusively. ERT provide very useful tools for measuring and monitoring of column flotation process on line. Due to its high speed capability, low cost measurement, robust sensors, ERT is considered to be the most powerful tool among other tomography techniques such as positron emission tomography (PET), magnetic resonance imaging (MRI), optical and infrared tomography. Application of ERT has extended in process systems due to its improved speed of data acquisition, sensitivity, flexibility and noise immunity. In multiphase flow of bubble columns, gas hold-up and solid hold-up are explored by using the coupling of ERT and difference pressure method (Jin, Han, Yang, & He, 2010)."

Jan 1, 2016

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

"The Industrial Comminution Efficiency (ICE) working group, part of the Global Mining Standards and Guidelines Group (GMSG) has engaged a large number of industry professionals representing mining companies, equipment vendors, consultants and metallurgical laboratories with interests and capabilities in the comminution field. These participants have collaborated to develop three guidelines for the assessment of the efficiency of mineral comminution circuits. Two of these guidelines deal specifically with power based modelling techniques to quantify energy efficiency using widely practiced techniques, those developed by Bond (1961), Rowland and McIvor (2009), and Morrell (2009). The third guideline deals with the sampling and surveying of grinding circuits as is required to provide the necessary information, at appropriate quality, to furnish the efficiency analysis promoted by the first two guidelines. This preprint will focus on the Guideline on Methods to Survey and Sample Grinding Circuits, which is currently in the final stages of peer review and finalization by the GMSG. INTRODUCTION It is important to make a clear distinction on the scope of work of the GMSG guideline for sampling grinding circuits. Many mineral processing practitioners are familiar with the sampling and surveying of comminution circuits, in particular grinding circuits, for performance diagnosis and the identification of optimization potential. These surveys often provide information for population balance modelling of individual comminution and classification unit processes, and as a result require a large amount of information to calibrate and validate the unit models. As a result these surveys are labour intensive, somewhat expensive depending on internal capabilities of the mine site or company, and have a long time span from initial planning to final reporting. They also require a high level of expertise to process the survey data, simulate the circuit and make sensible recommendations on follow up actions. As a result of these factors full grinding circuit surveys are not a common occurrence at a large number of facilities, and several years may pass before follow up surveys are conducted. In the ensuing gap between surveys, the efficiency of the grinding circuit must often be taken on faith, and this is considered an unacceptable lapse in an environment of strained natural resources and low commodity prices. To support the rapid and productive energy efficiency analysis being promoted by the ICE working group, a much simplified survey and analysis process is required. The process reflected in the GMSG guideline is indeed more conducive to frequent analysis, at a skill level that is well within the capabilities of the average plant metallurgist. As a result it becomes feasible to conduct mini-surveys of plant performance, which can be used to quickly and precisely diagnose the high level impact of process changes. It can also be manipulated by experienced practitioner to provide sufficient information for modelling of the circuit to estimate the impact of process changes, supporting an initial rate and rank exercise to focus plant optimization efforts."

Jan 1, 2016

By M. Soleymani Shishvan

"Continuous mining systems containing multiple excavators producing multiple products of raw materials are highly complex, exhibiting strong interdependency between constituents. Furthermore, random variables govern the system, which causes uncertainty in the supply of raw materials: uncertainty in knowledge about the reserve, the quantity demanded by the customers, and the breakdown of equipment. This paper presents a stochastic-based mine process simulator capturing different sources of uncertainties. It aims to quantify the effect of geological uncertainty and its impacts on the ability to deliver contractually defined quantities and qualities of coal, and on the system efficiency in terms of utilization of major equipment. Two different areas of research are combined: geostatistical simulation for capturing geological uncertainty, and stochastic process simulation to predict the performance and reliability of a large continuous mining system.The process of modelling and simulation in this specific production environment is discussed in detail. Problem specification and a new integrated simulation approach are presented. A case study in a large coal mine is used to demonstrate the impacts and evaluate the results in terms of reaching optimal production control decisions to increase average equipment utilization and control coal quality and quantity. The new approach is expected to lead to more robust decisions, improved efficiencies, and better coal quality management.IntroductionContinuous coal mining systems containing multiple excavators producing multiple products of raw materials are highly complex and exhibit strong interdependencies between constituents. A network of conveyor belts is used for transportation of the extracted materials to different waste dumps or the coal stockpile.Optimal decision-making in short-term planning and production control are impacted mainly by geological uncertainty associated with incomplete knowledge of the coal deposit represented in the reserve block model. These uncertainties cause deviations from expected process performance. For more robust decision-making, understanding the impacts of these stochastic elements plays a key role."

Jan 1, 2016

By H. Bouzahzah

The field of quantitative mineralogy has evolved significantly through the development of image analysis techniques and information technology. Quantitative mineralogical characterization can now be routinely conducted for determining ore compositions and understanding the behaviour of minerals within mineral separation processes. The characterization of mine tailings is another important application of quantitative mineralogy. The estimation of acid and neutralization potential as well as the interpretation of kinetic leaching test results are often based on quantitative mineralogical knowledge (mineral abundance, texture, metal distribution amongst minerals, etc.). The objective of this paper is to determine and compare the accuracy of four mineralogical characterization techniques that are often used for environmental sample analysis: (1) X-ray diffraction, (2) normal analysis from chemistry analyses, (3) normal analysis from specific gravity measurements and (4) SEM-EDS image analysis. For this purpose, three artificial samples were assembled by mixing pure minerals in proportions often observed in mineral processing plant tailings. BILMAT, a statistical data reconciliation software, was applied to reconcile the chemical analyses with the results of other mineralogical analysis techniques and to estimate the acid and neutralization potential of actual mine tailings samples. The acid mine drainage was qualified from the acid potential and neutralization potential equilibrium as determined through quantitative mineralogical analysis. The statistically reconciled data made it possible to predict the metal deportment as a function of their bearing minerals and therefore, in the case of neutral contaminated drainage, to assess metal leaching potential.

Jan 1, 2016

By Niels Verbaan, Ernesto Bourricaudy, Ronald Molnar, James Brown, Sunil Jayasekera

"SGS Minerals commissioned an internal R&D program to develop in-house expertise to design, set up and operate REE separation pilot campaigns at its Lakefield, Canada site. A team approach was used that included expert consultants in the field of REE separation as well as in-house expertise supported by the on-site Analytical Laboratories.A mini pilot scale SX circuit was designed and constructed consisting of several modular banks of 30 stages each. About 80 stages of mixer-settlers were used to separate Pr and Nd from La and Ce contained in a synthetic REE chloride stream simulating the raffinate from an initial La-Nd|Sm-Lu+Y separation.Two pilot campaigns were operated totalling 25 days of 24/7 operation with 99.4% plant availability in the final 20 day campaign. Purities of > 99.9% in the Pr-Nd strip liquor and > 99% in the La- Ce raffinate were achieved and simultaneously sustained in the second campaign for prolonged operating periods. Key to controlling and adjusting the circuit was the rapid assay turnaround (as low as 2 hours) provided by the on-site SGS analytical lab. This permitted the operating team to modify conditions and observe the effect of changes relatively quickly considering the large number of stages. A portable XRF analyser was also used to track evolving assay trends in the circuit. The small physical size of the circuit enabled longer operation with a limited amount of sample.This paper discusses the design of the circuit, operating conditions, some of the key operating factors and controls and results obtained.INTRODUCTIONSGS Minerals commissioned the design of and built a solvent extraction (SX) pilot plant for the separation of rare earth elements (REE). The plant consists of a battery of 120 mixer-settlers set up in a dedicated piloting facility.The purpose of the programme was to develop capabilities and in-house expertise in REE SX separation technology. The program aimed to establish operating procedures, sampling regimes, and analytical methodologies and protocols for this type of process/plant. A team comprised of SGS personnel and several external consultants with prior industrial and REE separation piloting experience was assembled to achieve these objectives."

Jan 1, 2016

By Yann Sivry, S. Subramanian, Divyasree C. Prabhakaran, Jean Riotte

The potential of a bacterial strain isolated from water samples collected from a chromite mine in Odisha, India has been assessed for the bioremediation of hexavalent chromium, a toxic environmental pollutant. The isolate was identified as Sphingopyxis sp., a Gram negative bacterium, adopting molecular biological protocols and biochemical characterization techniques. Detailed investigations on the bioremoval of Cr(VI) were carried out using Sphingopyxis sp. cells and the various parameters affecting the biosorption process were evaluated. About 55 % biosorption of Cr(VI) was obtained using Sphingopyxis sp. bacterial cells and the residual chromium in solution was found to be bio-reduced to the trivalent form, namely Cr(III). Thus, complete bioremediation of Cr(VI) could be achieved using the mine isolate, with contributions from both biosorption and bioreduction mechanisms. The Cr(VI) biosorption isotherm obtained for the isolate was found to follow a typical Langmuirian behavior and the free energy value of biosorption was determined to be ~-25 kJ/mol, indicative of involvement of chemical binding forces in the bioremediation process. The chromium biosorption kinetics by the isolate followed a pseudo second order reaction. The FTIR spectral studies revealed that carboxyl, hydroxyl, amino and phosphate groups were involved in the biosorption process. X-ray photoelectron spectroscopic studies on the bacterial cells interacted with Cr(VI) confirmed the presence of both Cr(VI) and Cr(III) on the cell surface. The electrokinetic studies revealed that the surface potential of the bacterial cells were less electronegative subsequent to interaction with Cr(VI), compared to the cells alone, which further testified to the binding of positively charged Cr(III) ions, formed by bioreduction of Cr(VI), to the bacterial cell surface. A marginal shift in the iso-electric point obtained for the bacterial cells interacted with Cr(VI), corroborated the involvement of chemical binding forces in the bioremediation process.

Jan 1, 2016

By Jun Yang, Zongshan Zou, Mei Qu, Jianjun Zuo

For technical renovation of the thermal plant, one frame structure workshop of 50,000 m2 (59,800 yd2) construction area and one reinforcement concrete chimney of 150m (492 ft) height shall be demolished by blasting at same time. The engineering environment of which is complicated and the accommodation space is limited. Therefore, the collapse sequence, direction, scope of the dismantled building must be accurately controlled to ensure the safe operation of the adjacent generator unit and transformer station. By taking technical measures of theoretical analysis and numerical simulation etc., as well as research on structures collapse method and detailed delay interval, it puts forward the technology of bidirectional folded collapse of the workshop and it uniquely adopts the initiation system that combined with “half-second delay inside drilling” and “millisecond delay outside drilling”. Additionally, by using of the integrated vibration reduction technology in combination of the blasting ruins, buffer ditch and damping ditch, it has safely accomplished the demolition blasting work in high efficiency. Besides the demolition blasting vibration signal is collected and analyzed. The success of the demolition blasting will become valuable reference to other similar works.

Jan 1, 2016

By M. Gunter, M. Buzon

"Talc formed by hydrothermal alteration of preexisting carbonate rocks is known to be nearly monomineralic, and lacking in amphiboles. In southwest Montana, talc formed from hydrothermally altered dolomitic marbles, and is still actively mined. These talc deposits are typically in contact with quartzofeldspathic gneiss and marble. Accessory minerals vary between these rocks and the ore producing body; the identification and characterization of such minerals requires carefully selected analytical methods. Recent litigation and ensuing confusion over the petrology and asbestos content of these deposits challenges the talc mining industry in Montana, and elsewhere in the world. INTRODUCTION Commercial talc has been mined from the deposits in southwest Montana since the 1940s, and by 1956 the region had output 200,000 tons of talc ore (Chidester et al., 1964). Commercial talc refers to rocks containing more than 20% of the mineral talc (McCarthy et al., 2006); the ores from Montana typically contain upwards of 90% talc. This region remains the leading domestic source of talc in the U.S. partly due to the reserves in the area, and partly due to the diagnostic purity of the ore compared to that of other regions, some of which are no longer actively mined. The mineral talc, a sheet silicate, is expressed by the formula Mg3Si4O10(OH)2, and therefore can form in geologic environments that are rich in Mg, Si, O and water. The protolith for the talc deposits in southwest Montana is a dolomitic marble, but other common protoliths include ultramafic igneous, mafic igneous, and siliceous dolomites (McCarthy et al., 2006). Physical properties such as hardness of 1 on Mohs hardness scale, white streak and slippery feel are among some of the reasons why talc is so widely used as fillers in a number of industries. In decreasing order, ceramics, paper, paint, roofing, plastics, rubber, and cosmetics are the leading domestic industries that use talc despite the decreasing trend in U.S. talc use and production since 1994 (Virta, 2015). The purpose of this paper is to describe the mechanism of talc formation in southwest Montana by focusing on talc deposits and surrounding rocks in the Ruby, Greenhorn, and the Gravelly Ranges, and to relate the mechanism of formation to the composition of talc ores. The compositional data show mineral content of selected ores, and the major and trace element content of those minerals, specifically talc. Our electron microprobe (EPMA), powder x-ray diffraction (XRD) and x-ray fluorescence data for samples from five mines in these three ranges provide continued evidence of the purity of these ores despite claims made during recent litigation that these ores contain asbestos. The five mines that we discuss include the Beaverhead, Treasure, Regal, Willow Creek, and Yellowstone Mines (Figure 1.)"

Jan 1, 2016

By E. McCullough

"Fostering positive community relations is a principal tenet of sustainable development, but conflict can test even the strongest of relationships. While conflict surrounding resource development projects has the potential to be destructive, it may actually pose opportunities for partnership and collaboration when managed effectively. It is therefore not only important for mineral resource professionals to recognize the financial and social costs associated with legal disputes among project stakeholders, but also for them to prioritize resolving social conflict using alternative channels that allow for win-win outcomes. A variety of dispute prevention and resolution techniques do exist, but successful practice is not yet the norm. Here we review the sources and consequences of social conflict in the context of mining projects, and discuss typical and alternative approaches to conflict management in light of their respective benefits and drawbacks. We also suggest implementation of conflict resolution lessons into resource-related university curricula as a critical step in the continued shift of the mining industry towards sustainable development. INTRODUCTION Social conflict is a recurring phenomenon in the human experience and serves as a critical mechanism for change [1-5]. It occurs when two or more parties perceive that their needs and interests are in direct competition with each other and believe they cannot be reasonably accommodated. Conflict over mineral resource activities, particularly the distribution of benefit and risk, has become an omnipresent issue throughout the world [6-7]. Contrary to common perception, however, conflict can be a positive, transformative encounter in some instances [2, 8-11]. For this to be possible, society and its acting agents must reconsider how to address conflict. What if conflict were only a challenge to try something different? It is well-understood that the mineral industries must manage an increasingly significant volume of social conflict [12-13], which can be a costly externality impacting all of whom are involved. We commonly consider conflict in a two-party sense, but this deeply over-simplifies the true number of stakeholders. Besides mining companies and community members, government policymakers and regulators, public interest groups, and judicial systems, to name a few, bear the social expenses of poorly-managed conflict [4, 6, 12, 14-22]. It is desirable for interested parties to participate actively in a constructive way to pursue their needs rather than contributing to adversarial relationships, operational problems, and legal costs [1, 4, 12]. Some mining companies are of course already working to develop more productive relationships with their stakeholders, but there is undoubtedly still a gap between ideal and common practices. This gap can inhibit collaboration and threaten the potential for mutually-beneficial resolutions to complex social issues [12]."

Jan 1, 2016

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By P. Mageau-Béland, È. -M. Proulx, M. -C. Patoine

Over the past six decades, Hatch has helped several industrial processing facilities in debottlenecking their operations, allowing them to produce more with the same equipment, to reduce and even eliminate expenditure investments, or to increase the return value of their expansion projects. These successes result from the application of a proven analysis approach that can be applied to any industrial facility. A five-stage methodology is discussed and demonstrated with a specific example of a nickel concentrator optimization study. The first stage is an observation stage which allows to meet key actors at the plant, develop mutual understanding of problems, understand operating philosophy, and efficiently collect large amounts of operating and maintenance data. Following is a data compilation stage during which data is analyzed over a representative time period to identify parameters that significantly affect the production, to evaluate data reliability and to define the focus of the upcoming analysis. Quantitative metrics are defined using statistical tools such as pivot tables, histograms, percentiles and MDR (Maximum demonstrated production rate during 3 to 7 consecutive days). Then, the production bottlenecks are identified by a thorough analysis of the facility’s control philosophy, process throughput, equipment capacity, availability, downtime causes, and interaction between components of each circuit. Understanding the maintenance practices and frequency of planned shutdown is also critical to this analysis. Opportunities for improvement are identified in collaboration with the operation, maintenance and engineering teams, ranked as a function of their impact on the bottlenecks and prioritized. The final and most critical stage involves engagement with the plant stakeholders, namely the operators and the maintenance staff members, to present the results of the analysis and obtain their participation in the implementation of the solutions. The benefits of the case study translated into: 10% production capacity gain, improved maintenance planning and avoidance of several million dollars of investment.

Jan 1, 2016