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By Rak-lun Choi

Plasma-induced damage of InGaN/GaN multiple quantum well (MQW) light-emitting diodes (LEDs) has been studied in terms of forward turn-on and reverse breakdown voltages, together with etch rate and surface morphology. The physical degradation of sidewall along with rough surface morphology of n-GaN caused by increased ion scattering induced the deterioration of the forward and reverse voltages. It was found that the turn-on voltage is sensitive to the surface roughness of the etched n-GaN and the breakdown voltage is strongly affected by the sidewall contamination. Annealing under nitrogen after the mesa etching improved the electrical properties of the InGaN/GaN MQW LEDs. Efficient blue light-emitting diodes (LEDs) were fabricated using InGaN/GaN triangular MQWs. The LEDs with triangular QWs showed a lower operation voltage and 2.4 times higher light output power than those with the rectangular MQW LEDs at 20 mA and 20 °C. The intensity of electroluminescence (EL) at 20 mA was almost independent of ambient temperature in the triangular QW LED, but decreased substantially in the rectangular one.

Jan 1, 2003

By A. Pellegrino, F. Collin, C. Guiducci, R. Charlier

A numerical approach for modeling coupled Hydro-Mechanical fracture behavior in 2D is presented in this paper. This approach accounts for the strong dependence of the flow characteristics on fracture apertures and offers an anisotropic description of the flow propagation in the fracture. An interface finite element and a constitutive model are developed . In order to validate the applicability of the model to general geomechanic problems, 2D simulations were performed. Results show the good application of the mathematical model and the fundamental hydraulic role played by the fractures. In diesem Beitrag wird ein Stoffgesetz vorgeschlagen um hydromechanisches Kluftverhalten numerisch zu Modellieren. Dieser Vorgang nimmt die starke Abhängigkeit der Fliesseigenschaften von der Kluftöffnung mit in Anbetracht. Ein Interfaceelement und ein Stoffgesetz wurden entwickelt. Zum validieren der Anwendbarkeit dieses Modells wurden 2D Simulationen durchgeführt. Ergebnisse haben gezeigt dass das mathematische Model anwendbar ist und dass Klüfte eine fundamentale hydraulische Rolle spielen. Une approche numérique pour la modélisation du comportement couplé hydro-mécanique des fractures en 2D est présentée dans ce papier. Cette approche prend en compte la forte dépendance des caractéristiques du flux de fluide sur les ouvertures des fractures et présente une description anisotrope de la propagation du flux dans la fracture. Un élément fini d'interface et un modèle constitutif sont développés. Dans le but de valider l'applicabilité du modèle à des problèmes généraux de géomécanique, des simulations 2D ont été réalisées. Les résultats montrent la bonne application du modèle mathématique et le rôle hydraulique fondamental joué par les fractures.

Jan 1, 2003

By N. Powell, P. Hunt, A. Wetherelt

This paper considers the current methods of analysis employed, the validity of assumptions made and the reliability of results and predictions derived; where appropriate, alternative methods are proposed which are more accurate and can be applied with greater confidence. In regard to data collection, new local blasting data has been analysed and conclusions drawn but, due to the restricted amount of space available, reference to data set A only has been made in the text. The problem of mathematical model choice is considered and results for two and three parameter power laws are compared. The very important matter of parameter determination is discussed fully, with major emphasis being placed on the comparative merits of log-log linear, log-log planar and direct power law regression. Supporting data analysis examples are included. Assumptions regarding the normality of ‘best-fit’ regression model residual distributions are questioned and the reliability of associated safety limit determinations is discussed.

Jan 1, 2003

By Michael Zinigrad

The quality of metallic materials depends on their composition and structure and these are determined by various physico-chemical and technological factors. To effectively prepare materials with required composition, structure and properties it is necessary to carry out a research in two parallel directions: Comprehensive analysis of thermodynamics, kinetics and mechanisms of the processes taking place at the solid-liquid-gaseous phase interface during welding processes and development of mathematical models of the specific welding technologies. We have developed unique method of mathematical modeling of phase interaction at high temperatures. This method allows us to build models taking into account the thermodynamic characteristics of the processes, the influence of the initial composition and temperature on the equilibrium state of the reactions, the kinetics of heterogeneous processes, the influence of the temperature, composition, hydrodynamic and thermal factors on the velocity of the chemical and diffusion processes. The model can be implemented in the optimization of various technological processes in welding, surfacing, casting as well as in manufacturing of steels and non-ferrous alloys, materials refining, alloying with special additives, removing of non-metallic inclusions.

Jan 1, 2003

By V. Jovicic, J. Likar

The knowledge of the geological sequence and hydrological conditions in the area of portals was the basis for the design of the entry of the highway into tunnel Trojane. Mudstone, claystone and sandstone dominate the rock layering, which is tectonically reworked and contains structural anomalies. The complexity of the sequence makes it impossible to survey all the relevant features along the full 3km length of the tunnel. Sudden and frequent transitions between litological sequences impose potential instabilities and make the excavation of the tunnel particularly difficult. The initial survey established the zones of potential failures. These were monitored using topographic survey and inclinometers with an aim to make further geotechnical analyses more reliable and adjusted to the ground conditions. The analyses of the wall construction and the results of the monitoring showed that the design of the retaining wall was adequate. La connaissance de la séquence géologique et des conditions hydrologiques dans l'aire des portails a été la base pour la planification de l'entrée de l'autoroute dans le tunnel Trojane. Le schiste, l'argilite et le grès dominent la couche rocheuse qui est tectoniquement transformée et contient les anomalies structurales. A cause de la complexité de la séquence, il est impossible de revoir toutes les particularités le long des 3 kilomètres de la toute longueur du tunnel. Les transitions soudaines et fréquentes entre les séquences lithologiques imposent l'instabilité potentielle et font l'excavation du tunnel particulièrement difficile. La revue initiale a été établie sur les zones où il existe l'éboulement potential. Elles étaient contrôlées à l'aide de la revue topographique et de l'inclinomètre pour que les analyses géotechniques suivantes soient plus sûres et adaptées aux conditions du sol. Les analyses de la construction des murs et des résultats du contrôle ont montré que la planification du mur réteneur était correspondante. Der Autobahneingang in den Trojane Tunnel war projektiert auf Basis von der Kenntnis der geologischen und hydrogeologischen Bedingungen in dem Portalgebiet. Das Gebiet besteht aus dem Tonstein und dem Sandstein. Die Schichten sind tektonisch verformt und sind deswegen sehr heterogen. Die anfaenglichen Untersuchungen haben die Zonen von den potentiellen Bruechen definiert. Weitere geotechnische Analysen waren fitted an reale geologische Bedingungen durch das Monitoring der potentiellen Bruchzonen, welches aus den topographyschen Messungen und Inklinometerdaten entstand. Die Analyse des Wandbaues und die Resultate von dem Monitoring haben erwiesen, dass die Wandprojektierung entsprechend war.

Jan 1, 2003

By A E. McElnea, M A. Martens

An 18-month project was undertaken to test the effectiveness of controlled daily tidal exchange augmented with hydrated lime treatment of surface waters as an approach for remediating a severe acid sulfate soil disturbance at East Trinity, Cairns, north Queensland. Actual acid sulfate soils were producing hazardous levels of acid and heavy metal contaminants and degrading approximately 720 of the 940 ha East Trinity property and the adjacent foreshores. A government-led research team established a series of research projects with the aim of characterising the site (soils, water, terrain) and testing the effect of the lime-assisted tidal exchange management strategy on soils, water, sediments and biota.

Jan 1, 2003

By A. Sissing

Paper written on project work carried out in partial fulfilment of M.Sc. (Chemical Engineering) degree Thermophilic bioleaching, conducted at temperatures in excess of 65°C, provides considerable benefit over mesophilic bioleaching, particularly through extending the extent of leaching of base metal minerals such as chalcopyrite. Thermophilic bioleaching is facilitated through a group of micro-organisms known as the Archae, well adapted to extreme environment. In order to maximize the space time utilization of the stirred tank reactor in the thermophilic bioleaching process, it is desirable to maximize the loading of the finely divided mineral phase present while not adversely affecting the microbial performance. In this paper, the effect of the loading of the solid particulate phase on the bioleaching performance of Sulfolobus metallicus was studied in a stirred tank reactor. Emphasis was placed on the effect of the concentration of the finely divided solid phase (35 ? 75 µm). A model system comprised of 3% (w/v) pyrite in the presence of varying quantities of quartzite in the range 0 to 24% (w/v) was used to obtain the different solids concentrations. The bioleaching experiments revealed similar bioleaching performance in the presence of 3 to 18% (w/v) total solids. Above 18% (w/v) total solids (15% quartzite loading), bioleaching was impaired progressively with increasing solids concentration. At the highest solids loading studied of 27% (w/v), bioleaching was still observed. In terms of mass transfer, oxygen transfer potential was not significantly influenced in the bioleaching process over the range of solids investigated.

Jan 1, 2003

By Mike O’Brien, Rob Croll

The Evolution of AngloGold -Incorporated in 1944 under the name of Vaal Reefs Exploration and Mining Company Limited -Name changed to AngloGold Limited in 1998 as the vehicle consolidating the gold interests of Anglo American Corporation -Diversification (geographic and orebody) through the sale of low-margin, deep level, short-life assets and the acquisition of higher margin, open-pit and shallow underground operations

Jan 1, 2003

By M. Nakamura, T. Akamatsu

Embankment dams are often constructed on soft rock foundations in Japan, so it is important to precisely predict deformation of the foundations due to fill placement at the design stage. In order to accurately evaluate the settlement and the strain of the rock foundation surface during construction, the influence of the scattering of the deformability of foundations on the deformation behaviour should be investigated. In this paper, a method of evaluating the settlement and the strain of the rock foundation surface during construction was studied with stochastic deformation analysis considering the scattering of the deformability of the dam foundation. Based on the analytical results, a dam foundation design using the deterministic method considering the scattering of its deformability was discussed. Da in Japan Uferdämme of auf weichen Felsfundamenten gebaut werden, ist es wichtig, die Verformung der Fundamente auf Grund der Platzierung der Aufschüttungen bereits in der Planungsphase genau vorherzusagen. Im Zusammenhang mit einer genauen Beurteilung der Senkung sowie der Belastung der Felsfundamentoberfläche während der Bauarbeiten sollte auch der Einfluss der Streuung der Verformbarkeit der Fundamente auf das Verformverhalten untersucht werden. In der vorliegenden Studie wurde die Bewertungsmethode zur der Senkung sowie der Belastung der Felsfundamentoberfläche während der Bauarbeiten mit Hilfe von Wahrscheinlichkeitsanalysen der Verformung unter besonderer Berücksichtigung der Streuung der Verformbarkeit der Dammfundamente untersucht. An Hand dieser analystischen Ergebnisse wurde das Design der Dammfundamente dann enthusiastisch mittels deterministischer Methoden hinsichtlich der Streuung der Verformbarkeit diskutiert. Comme les barrages en remblai sont souvent construits sur des fondations rocheuses tendres au Japon, il est essentiel de prévoir précisément les déformations des fondations causées par la mise en place du remblayage durant la phase de conception. Afin d’évaluer avec exactitude le tassement et la déformation de la surface du rocher de fondation durant la construction, l’effet de la dispersion de la déformabilité des fondations sur le comportement de déformation doit être étudié. Dans cette étude, l’auteur a étudié la méthode d’évaluation du tassement et de la déformation de la surface du rocher de fondation durant la construction en procédant à une analyse aléatoire/stochastique de la déformation et en prenant en considération la dispersion de la déformation des fondations du barrage. En se basant sur les résultats de l’analyse, la conception des fondations de barrage avec la méthode déterministe considérant la dispersion de sa déformabilité a été activement discutée.

Jan 1, 2003

By Thomas Mucho, Anthony Iannacchione

This marks the 100th year that the aggregate industry has been served by a national association. Of all the accomplishments this longstanding relationship has achieved, there is probably none greater than the progress made, in worker safety. Perhaps the best way to measure this success is to examine injury trends in the aggregate miner population. For example, in the first half of the 20th [ ] century, 16 quarry mining disasters (a "disaster" is an incident with five or more fatalities) claimed 157 miners between 1909 and 1952. The largest of these was the disaster at the Sandts Eddy Limestone Quarry near Allentown, Pa., on March 26, 1942, where 31 miners died of asphyxiation by fumes/explosion. Thankfully, no mining disasters have occurred in the aggregate industry since 1952. It is these kinds of information that help us characterize improvements in aggregate worker safety over the last 100 years.

Jan 1, 2003

By S. Kahraman

The correlations between the modulus ratio and penetration rate of rotary and percussive drills were statistically investigated using the raw data obtained from the experimental works of different researchers. An inverse power law was found between the modulus ratio and the penetration rate of rotary and diamond drills. The penetration rate of rotary drills and diamond drills decrease with an increasing modulus ratio. The penetration rates of percussive drills increase with an increasing modulus ratio. There are significant linear correlations between the penetration rates of percussive drills and the modulus ratio. In one of the cases of percussive drilling, a strong correlation between the penetration rate and the modulus ratio was found for the rocks having a porosity value lower 1.23 %. It can be concluded that the modulus ratio might be a representative measure of rock drilling efficiency. However, further study is necessary to check the validity of the derived equations for other rock types. The effect of porosity on the correlations between the modulus ratio and penetration rate needs to be further investigated.

Jan 1, 2003

By Mikula Adolf

Lead-tin solders are commonly used in electronic packaging due to their unique combination of electrical, chemical, physical, thermal and mechanical properties. Since it is known that lead and lead containing alloys cause great environmental concern and health hazards it is necessary to replace lead in solder materials. Besides the environmental concerns new technologies in electronic packaging require new and improved solders. In most cases the new solders will consist of temary or quarternary alloy systems, the main component will be tin or indium and the second element could be bismuth. silver, copper and gold and to improve certain properties a third element will be added. For a third element zinc, nickel, antimony and aluminum can be considered. This report will concentrate on solders containing zinc as an environmental safe. element.

Jan 1, 2003

Cospidie (3CaO*2SiO2*CaFe2) is one of the most important compounds crystallized in mold flux films during casting in the continuous casting process of steel, The primary crystallization field of cuspidine has been experimentally developed in the CaO-SiO2-CaF2-SiF4 system. The cuspidine-NaF binary and cuspidine-CaF2-NaF ternary systems have been also experimentally determined to study effects of addition of NaF on the primary field of cuspidine. In order to discuss its thermodynamic stability the standard Gibbs energy of formation of cuspidine has been deterimed by an electromotive force methods using CaF2 as solid electrolyte and a transpiration method as follows: ^fG° (cuspidine) /kjmol-1 = 5198 + 0.825T (+12) (1313<T/K<1329): EMF method ^fG° (cuspidine) /kjmol-1 = 5178 + 0.813T (+8) (1221<T/K<1469): Transpiration method The chemical potential diagram and constituent activities for the CaO-SiO2-CaF2 System have been evaluated based on the obtained thermodynamic data.

Jan 1, 2003

By J. N. Van der Merwe

The data base of failed pillar cases as used by Salamon and Munro (1967) in their original analysis to determine the strength of coal pillars empirically, has been updated for this study. It is shown that the Vaal Basin and Klip River coal fields exhibit similar behaviour that differs from the failures in other areas, i.e. failure at high safety factors within a short period of time. Those collapse cases have been omitted from the new data base. Failures in the other areas that occurred after 1967 have been added. Using a technique to minimize the area of overlap between the populations of safety factors of failed and intact pillar cases, the new data base was re-analysed in conjunction with the original Salamon-Munro data base of intact pillar cases, from which the cases in the areas of weak coal were likewise eliminated. It was found that a linear formula reduced the overlap area by22%. The new formula predicts higher strength for pillars with a width-to-height ratio greater than approximately 2.0 to 3.0 and a lower strength for smaller pillars. It was also found that in order to obtain the same relative measure of stability as with the Salamon-Munro formula, the strength constant in the new formula should be within a range of 2.8 to 3.5 MPa. For most current South African coal mining conditions, using the new formula for pillar strength will result in leaving smaller pillars without sacrificing stability. The reason for this is that the Salamon-Munro formula under-estimated the strength of larger pillars and over-estimated the strength of smaller pillars. The new formula will thus result in improved reserve utilization without sacrificing stability.

Jan 1, 2003

By C. Erichsen

ABSTRACT: The Berg Bock Freeway Tunnel represents the southernmost link of the "Thuringian tunnel chain" of the new freeway A71 located in the eastern part of Germany. It comprises two tubes each 2700 m in length. From north to south, it passes through the Suhl granite, the base sediments and the porphyrite of the New Red as well as the layers of the Middle Bunter. The two tunnel tubes were driven by the shotcrete method within appr. 10 months. With four tunnel faces, maximum performances totalling appr. 30 m/d were attained. Additional, supplementary demands on the safety conception, resulting from the findings from and the analysis of fire accidents in tunnels in recent years, had to be fulfilled in the execution planning at short notice. The inner lining is largely constructed using non-reinforced concrete. Reinforcement is only installed in the portal zones, in tunnel sections in less stable rock and in areas with a special cross-section as for instance cross connections and niches. ZUSAMMENFASSUNG: Der Autobahntunnel Berg Bock stellt das südlichste Glied der "Thüringer Tunnelkette" auf der Autobahn A71 dar, die im Osten von Deutschland liegt. Er besteht aus zwei Röhren von je 2700 m Länge. Vom Norden nach Süden durchörtert er den Suhler Granit, die Basissedimente und den Porphyrit des Rotliegenden, sowie die Schichten des Mittleren Buntsandsteins. Die beiden Tunnelröhren wurden in Spritzbetonbauweise in einer Bauzeit von etwa zehn Monaten aufgefahren. An vier Vortriebsorten wurden Spitzenleistungen von insgesamt etwa 30 m/d erzielt. Ergänzende Anforderungen an das Sicherheitskonzept, die sich auf der Grundlage der Auswertung der in den letzten Jahren aufgetretenen Brandunfälle in Tunneln ergeben haben, wurden im Rahmen der Ausführungsplanung kurzfristig berücksichtigt. Die Tunnelinnenschale wurde weitgehend aus nicht bewehrtem Beton hergestellt. Nur in den Portalzonen, in Tunnelabschnitten mit weniger standsicherem Fels und in Bereichen mit speziellen Querschnitten, wie beispielsweise im Bereich von Querstollen und Nischen, wurde bewehrter Beton ausgeführt. RÉSUMÉ: Le tunnel d&apos;autoroute de Berg Bock représente le plus méridional maillon de la "chaîne thuringienne de tunnels" sur l&apos;autoroute A71 dans l&apos;est de l&apos;Allemagne. Il se compose de deux tubes d&apos;une longueur de 2700 m chacun. Du nord vers le sud, il traverse le granit de Suhl, les sédiments de base et le porphyrite du Rotliegendes, aussi que les strates du grès bigarré intermédiaire. Les deux tubes étaient creusés en méthode de construction de béton projeté dans une période de construction d&apos;environ dix mois. À quatre fronts de taille rendements maximaux collectifs d&apos;environ 30 m par jour étaient obtenus. On a eu égard à court terme dans la conception d&apos;exécution à des demandes supplémentaires vers la conception de sécurité, qui ont résulté sur la base de l&apos;interprétation des accidents d&apos;incendie dans des tunnels dans les années dernières. La paroi intérieure était construite largement de béton non armé.

Jan 1, 2003

By H. Castillo

This paper describes the computer simulation of thermal stress fields generated in the quenching of the ns 415 H Steel automotive parts (Valve Lifters), running the ANSYS Multiphysics software of finite element (FEM). Simulation was performed introducing residual stress measurements on specific values areas, like internal pressure condition in the material. The stress condition effect in the material and the properties as temperature function data, were introduced to the FEM software. The thermal stress simulation was made on the 2D system. The parts were austenized to 850 900 °C and then oil quenched, tempered at 150 -200°C, and air cooled. The X-Ray diffraction technique was made to take measurements from residual stresses on valve lifters surfaces. The results analysis showed the ideal stress condition necessary in raw material to reduce the scrap percent in grind operations after hardening heat treating process. Keywords: Thermal Stresses, Temperature profile, Computer Simulation, Finite element analysis, Quenching of steel, Residual Stresses

Jan 1, 2003

By K. S. Rao, R. P. Tiwari, V. K. Shrivastava

ABSRACT: In this paper numerical simulation of jointed block mass behaviour obtained in an experimental study has been presented. Singh et al. (2002) conducted extensive tests on the jointed model materials with several joint configurations. The results of this experimental study were used to validate the strength behaviour of numerical block mass model developed using professionally available software. This software basically contains different kinds of material models. From the results of numerical simulation the existence of strength anisotropy was observed. The strength anisotropy so obtained has been compared with the experimental values reported by Singh et al. (2002). The anisotropic curves in both cases are U-shaped with flat base. They show good agreement in sliding mode of failure zone in which inclination ß (= 90° - ?) of joint set-I lie between 20° to 40° for all cases of interlocking. ZUSAMMENFASSUNG: In dieser numerischen Papiersimulation des verbundenen Blockmasse Verhaltens, das in einer experimentellen Studie erhalten wird, ist dargestellt worden. Singh et al. (2002) leiteten umfangreiche Tests auf den verbundenen vorbildlichen Materialien mit einigen gemeinsamen Konfigurationen. Die Resultate dieser experimentellen Studie wurden verwendet, um das Stärke Verhalten des numerischen Blockmasse Modells zu validieren, das mit professionell vorhandener Software entwickelt wurde. Diese Software enthält im Allgemeinen unterschiedliche Arten der materiellen Modelle. Von den Resultaten der numerischen Simulation wurde das Bestehen von Stärke Anisotrophie beobachtet. Die Stärke Anisotrophie also erreicht ist mit den experimentellen Werten verglichen worden, die von Singh et al. (2002) berichtet werden. Die anisotropen Kurven in beiden Fällen sind mit flacher Unterseite u-förmig. Sie zeigen gute Vereinbarung in gleitender Erscheinungsform des Ausfalls Zone, in der Neigung ß (= 90° - ?) von der Verbindung stellenSie Lüge zwischen 20° auf 40° für alle Fälle vom Ineinandergreifen ein. RESUME: Dans cette simulation numérique de papier du comportement joint de la masse de bloc obtenu en étude expérimentale a été présenté. Singh et autres (2002) ont effectué les essais étendus sur les matériaux modèles joints avec plusieurs configurations communes. Les résultats de cette étude expérimentale ont été employés pour valider le comportement de résistance du modèle numérique de la masse de bloc développé en utilisant le logiciel professionnellement disponible. Ce logiciel contient fondamentalement différents genres de modèles matériels. Des résultats de la simulation numérique on a observé l&apos;existence de l&apos;anisotropie de force. L&apos;anisotropie de force ainsi obtenu a été comparée aux valeurs expérimentales rapportées par Singh et autres (2002). Les courbes anisotropes dans les deux cas sont en U avec la base plate. Elles montrent la bonne concordance dans le mode coulissant de la zone d&apos;échec en lequel la inclination ß (= 90° - ?) du joint placez-Je le mensonge entre 20° à 40° pour tous les cas d&apos;enclencher.

Jan 1, 2003

By Elzbieta Mielczarski, Jerzy Mielczarski, Jan Drzymala, Yann Duval

"The monoalkyl ethers of polyethylene glycols are universal flotation reagents because they can be used as collectors, frothers, surfactants, and depressants. Their collecting power was demonstrated for different minerals including coal and quartz.It was confirmed in this work that monoalkyl ethers of polyethylene glycols could be used as collector in flotation of quartz in a monobubble Hallimond cell. Since feldspar does not float in the same cell, it was also shown that selective separation of quartz and feldspar in the Hallimond tube is possible. However, a trail to use the monoalkyl ethers of polyethylene glycols compounds for separation of quartz and feldspar by flotation of mixture of these minerals in a Mechanobr laboratory flotation machine was futile, indicating that these reagents required special environment for flotation.Most probable parameter responsible for a decrease in quartz flotation in the flotation machine is the hydrodynamics of process, and different adsorption/desorption conditions. To prove this, another series of experiments was carried out to separate quartz and feldspar, in which a laboratory flotation column was utilized. The performance of the flotation column was in between that of in the Hallimond tube and flotation machine. These experiments confirmed that the hydrodynamics of flotation plays a vital role in flotation of quartz with monoalkyl ethers of polyethylene glycol compounds."

Jan 1, 2003

By H Kundapen, B R. Bolton, H Davies

The Ok Tedi porphyry copper-gold mine is located in the Star Mountains of Western Province, Papua New Guinea. Open-cut mine commenced in 1984 and is due to cease around 2010. The mine produces a total of 88 Mt of waste annually including 58 Mt overburden and 30 Mt tailings, which are discharged directly in to the Ok Tedi River. Mine derived wastes are transported downstream and deposited within the river channel in a variety of bar forms. The prevailing hydrogeological conditions including, velocity, competency, capacity, gradient, grain size and specific gravity, control the deposition and segregation of these sediments. Periodic exposure of the reactive sulfides to oxygen during fluctuations in the river discharge may result in oxidation, localised acid generation and liberation of metals into solution. To evaluate the significance of this issue, Ok Tedi Mining Limited initiated an investigation of the sediments deposited in the upper Ok Tedi River as part of its overall ARD Management Program. The specific objectives were to: evaluate the acid-forming characteristics of identified high sulfide river deposited sediments; characterise geochemically the waters in contact with sulfide-bearing river deposited sediments; map and monitor exposure areas and oxidation depth of deposited potentially acid forming (PAF) sediments; determine the depositional processes controlling sulfide distribution; and assess lag period, oxidation and metal release rates for the sediments. This work included the analysis of sediment and water samples collected on a 50 + 50 metre grid at six gravel/sand bars. The sediment samples were analysed for total sulfur, ANC, NAG, total sulfur and total copper. Water samples were tested for general water quality parameters, sulfate and a suite of dissolved metals including; Al, Ca, Cd, Cu, Fe-sol, K, Mg, Mn, Na, S and Zn. This paper presents the results of these investigations with particular emphasis on the geochemistry of the river sediments and associated contact waters.

Jan 1, 2003

By Graeme Heyes, Warren J. Bruckard, Michael A. Somerville

"A limited series of laboratory batch flotation tests was conducted on a suite of calcium-ferrite-based slags made in laboratory smelting trials. The smelting tests were conducted as part of a wider CSIRO Minerals’ research project aimed at developing a single-stage continuous copper-making process. The objective of the flotation work was to maximise copper recovery and iron rejection from slags made in the process.The slags treated included a reduced low copper slag, an oxidised high copper slag composite, and a very reduced low copper self-pulverising slag. The copper content of the slags varied from 2.9% to 14% Cu. The copper was present as metallic copper, oxide copper and copper-calcium ferrite phases with the phase mix related to smelting conditions. The slags were crushed, ground, wet-screened at 355 or 210 µm to remove coarse metallic particles of copper, and floated at natural pH (about pH 11) using reagents and conditions appropriate for the selective recovery of the copper phases.In rougher/scavenger tests on the reduced low copper and self-pulverising slags copper recoveries above 92% were obtained with copper enrichment ratios varying between 2.3 and 2.9. For the oxidised high copper slag copper recoveries were poorer - only 47% of the copper was recovered with an enrichment ratio of 3.3. The presence of the slow floating copper-ferrite phases in the slags limited further (selective) copper recovery. Ageing of the high copper slag, that is, a significant delay between grinding and flotation, resulted in a deterioration of the copper flotation response.The critical parameter affecting the flotation of copper from direct converting slags was found to be the form of the copper in the slag. Slags containing a higher proportion of the more desirable form of copper for flotation will provide the best opportunity for high copper recoveries to be consistently obtained, allowing improvements in the economics of the overall copper-making process."

Jan 1, 2003