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OPENING SESSION Session Chairpersons: Dr. P.P. Jourdan & Dr. L.A. Cramer Transformation to Tackle the Challenges Facing the Ferro Alloy Industry in the Next Decade R.J. Linnell Electricity Supply in SA ? A 10-Year View T.S. Gcabashe IDC as the Catalyst for Growth in the South African Ferroalloys Industry J. Kriek Development in the Global Stainless Steel Industry V. Muñoz CLOSING SESSION Session Chairpersons: Mr. R.J. Linnell & Dr. O.F.R.A. Damm The Health of Vanadium T.E. Jones Steel Raw Materials - Nickel, Chrome, Stainless Steel Scrap and Manganese H.H. Pariser

Jan 1, 2004

By Hans-Peter Rossmanith

Fracture mechanics (Atkinson 1987, Broek 1988, Rossmanith 1978-2002, 1983, 1997, Kanninen & Popelar 1985) and wave propagation (Graf 1975, Rinehart 1975) form the main ingredients in the new electronic detonator based blasting technology. The full potential of using short delay initiation timing in bench and underground blasting can only be exploited if the underlying physical processes are properly understood. From a structural geology point of view, in many open pit mine operations, blasting is performed in incompetent and/or loose rock. Under such conditions the stress waves produced by blasting very quickly dissipate in the rock mass and often their energy cannot effectively be put to work. This contribution shows the effect of open and closed joints – and to some degree also faulting – on the blast wave field and shows the influence of structural geology on the blasting result. A simple engineering method which combines wave propagation and impact mechanics is developed in order to assist the non-scientifically trained blaster in understanding blasting in blocky rock formations. Extensive use will be made of the so-called Lagrange diagram which was introduced in detail in the author’s previous lecture at ISEE 2003 (Rossmanith 2003). This presentation can be considered a continuation of the 2003 presentation.

Jan 1, 2004

By G. Velarde

Agglomeration has as main objective to form a uniform and highly permeable heap for leaching. An inaccurate dosage of moisture during agglomeration leads directly to poor agglomerate quality and segregation of particle sizes during stacking. This causes a heterogeneous distribution of the leach solution inside the heap which invisibly and practically permanently affects the recovery. Unfortunately, only when this becomes serious and the mineral contains an excess amount of fine particles and/or clays then the poor permeability of the pile becomes obvious. This paper is based on the experience of Minera Cerro Verde in the development and application of a quantitative method to control moisture during agglomeration. As the amount of fine particles/clays varies, the quantity of moisture has to be altered in real time. The measurement of agglomerate electrical conductivity is used for it. This concept is based on the sharp change seen in conductivity when the mineral passes its absorption limit. A liquid conductive film then begins to form over the surface of the particles, which leads to the formation of agglomerates through liquid bridges, which are also electrical bridges. Moisture is adjusted to reproduce a value of conductivity established previously and is the guiding parameter. Moreover, moisture amount added to reach this conductivity parameter provides information about the fines/clays relative content for best leaching management.

Jan 1, 2004

By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By Frank J. Arland

Augered-Cast-in-Place piles have been used successfully for many deep foundation applications. The four case studies discussed herein describe ACIP pile projects where problems developed during ACIP pile installation requiring changes to the method or sequence of installation. The case studies illustrate the importance of understanding existing subsurface conditions and project constraints when considering the use of this pile type. Ground loosening and over-excavation of soil during the augering process, a significant concern for fine to medium sands and non-plastic silts below the water table, can significantly impact adjacent structures. This risk needs to be evaluated during the pile selection process and generally can be mitigated, but not eliminated, by requiring the use of piling equipment with high torque and slow auger rotation speed to advance the auger with minimum amount of rotation. In some applications where high lateral stresses in the soil are present such as at the base of retaining structures, the use of ACIP piles may not be appropriate if structure movement is unacceptable. On the other hand, ACIP piles have been successfully used to support deep foundations in preconsolidated varved deposits where the new structure was designed to accommodate recompression settlement.

Jan 1, 2004

By J. H. Potgieter

This paper describes two cases of corrosion that occurred in dry-process, rotary, cement-clinker kilns. In the case of the kiln with five pre-heater stages, the attack occurred primarily from sulphates that probably originated in the raw feed and fuel being used in the plant and that penetrated the refractory lining. The corrosion was similar to ash-deposit corrosion often observed in steam boilers. In the second case the plant consisted of a long dry kiln with a single pre-heater fitted to the feed-end. In this case the corrosion could be ascribed to alkali chloride penetration through the refractory-brick lining and subsequent hot corrosion of the kiln shell.

Jan 1, 2004

By A. V. Pavlov, V. A. Grygorian, Kossyrev, A. E. Semin, A. Korostylev

A new way of producing low-silicon ferrosilicon from iron-ore materials in a new type of aggregate-oxygen reactor is presented. The oxygen reactor process is based on using the calorific combustibility and reducibility of carbon materials inside the aggregate. The key to the process is successful post-combustion of carbon monoxide above a layer of a solid coke bed. Initially the possibility of production of grades of ferrosilicon containing 20 to 25% Si (FeSi20-FeSi25) was studied on a laboratory model of the oxygen reactor. Quartz sand and iron ore concentrates (from Russia and India) were used in the laboratory tests. This test work demonstrated that a ferrosilicon grade FeSi15 could be obtained directly from raw iron ore (containing 75.9 % Fe2O3 and a maximum of 23.8 % SiO2) without using rich iron-ore concentrates. The process was successfully tested on a pilot furnace at Serovsky metallurgical plant. Very promising results and efficiency parameters were achieved. The consumption of materials for 1t of ferrosilicon (15 % Si) production was as follows: 1567 kg raw iron ore, 591 kg of coal (in a composition of ore-coal briquettes), 299 kg of coke (for coke bed formation), and 815 m3 of oxygen.

Jan 1, 2004

By Craig Wilbour, John Stimberis, Rob Gibson, Lee Redden

An avalanche is a snow slide. A simple explanation is that the snow on a slope will slide (avalanche) when the snow strength can no longer support its own weight. Snow avalanches happen when the load from snowfall or ram on a snow slope increases faster than the stre n g t h of the bonds between snow crystals. Avalanches can also happen when the strength of a buried layer decre a s e s . Active avalanche control is the intentional triggering of slides. Washington State Department of Tr a n s p o r t a t i o n (WSDOT), does avalanche control to minimize the chance of natural avalanches into traffic. Avalanche control work is done all over the world by: highway departments, ski resorts, railroads, mining operations, utility companies, and other activities threatened by avalanches. The majority of active avalanche control is done with skis, by explosives, or exploding projectiles. Blasting techniques and practices have evolved to fit the specific needs of avalanche contro l . Passive avalanche control is the use of engineered s t r u c t u res such as snow sheds, bridges, or snow supporting devices, to permanently protect a specific location from avalanches. The problem is that these struct u res are extremely expensive. There are a variety of passive avalanche control measures as well as the active m e a s u res used to protect the highway over Snoqualmie Pass. As traffic volume and use expectations incre a s e , m o re extensive passive measures will be needed to keep avalanches from affecting the highway.

Jan 1, 2004

By John Stubbles

Data are presented on the global warming issue to reinforce the decision by the U.S to reject the Kyoto protocol. The evidence that CO2 is a problem rather than a benefit is inconclusive and will be discussed in this paper. Nevertheless, for economic reasons alone, the US steel industry will continue to minimize CO2 emissions (and the release of real pollutants) per ton of steel through energy reduction programs. However, relative to inevitable increases in absolute CO2 emissions from the utility industry and the transportation sector, future reductions by the steel industry will be inconsequential in the "big picture."

Jan 1, 2004

By G. Avramovic-Cingara

Grain boundary characteristics and microstructural evolution are analyzed in a comparative study using orientation imaging microscopy (OIM/SEM) and transmission electron microscopy (TEM/SAD). The subgrain sizes and misorientations were determined by the OIM for aluminum deformed in torsion to equivalent strains between 0.2 and 4 over the temperature ranges of300-600°C and strain rates 0.01-1 s". The OIM gives clearer evidence of boundaries with high misorientation than does TEM, but it overestimates their frequency b y missing boundaries less than 1 0. T EM more clearly reveals low-angle arrays of widely spaced dislocations resulting in finer subgrain sizes than those indicated by OIM. The evidence supports a mechanism combining dynamic recovery (DRY), deformation band formation with permanent boundaries and geometric dynamic recrystallization (gDRX) in contrast to the hypothesis known as continuous dynamic recrystallization (cDRX).

Jan 1, 2004

By L B. Sukla, V N. Misra

Microbial desulfurisation of coal has significant advantages over physicochemical desulfurisation processes since the former process selectively removes the inorganic sulfur compounds and heavy metals without significant carbon loss. The purpose of this study was to improve the desulfurisation yield of a coal sample from northeastern coalfields, Assam, India using microbial technique. The coal sample contained 2.13 per cent of total sulfur and 2.59 per cent of ash. Stirred tank reactors of 40 L capacity were operated in batch mode. Initially, the reactor was fed with 40 L of slurry containing ten per cent (w/v) coal, ten per cent (v/v) inoculum of mixed culture of mesophilic acidophiles, native to coal itself and the requisite amounts of constituents for 9K medium without added ferrous sulfate. The percolate of the reactor was then used to seed the medium for the next experiment. The purpose was to obtain a better adapted and more active biomass which would give a better desulfurisation yield for coal. Further studies were conducted in the bioreactor, fed with 40 L of slurry containing ten per cent (w/v) pulp density of coal, ten per cent inoculum (derived from previous studies) and the medium, supplemented with ferrous sulfate. Results showed an increased total desulfurisation yield of 43 per cent in the latter treatment in comparison to the previous one, where the desulfurisation yield was only 23 per cent. The findings also demonstrated the convenience of using inocula derived from coal, where 50 - 60 per cent of pyritic sulfur was removed, while chemical desulfurisation is of little significance with the majority of coal types. The ash content was also reduced to 1.74 per cent as the low pH of the process caused dissolution of a number of common minerals present in the coal.

Jan 1, 2004

The effect of composition on electrical conductivity (resistivity), viscosity and liquidus temperature of the slags encountered in electric smelting of PGM containing suphide concentrates is reviewed, along with the relationsip between slag composition, slag-matte separation and metal losses to slag. Optimization of slag composition at furnace temperature is attempted on the basis of opposite and parabolic trends of the viscosity-conductivity relationships of the slags. The importance of surface tension of slags is emphasized using available and estimated information which are grouped into a useful correlation. These values are coupled with or incorporated into slag viscosity plots to illustrate the correlation between the two factors, which influence slag-matte separation as well as refractory attack. The electrode in the slag-resistance furnace is the central factor in the design and operation of the furnace by its role of conveying the smelting power. The obvious parameters are the size and positioning in the slag bath, which are defined by slag resistively, furnace resistance, cell constant and power input. The flow of heat generated by the electrode current determines the energy distribution and furnace dimensions creating viscosity profiles, which in turn affect flow conditions. Thus the flow of slag and matte are discussed in conjunction with the furnace geometry, stirring action of the electrodes, buoyancy and electromagnetic effects. The action of the electric furnace as a settler is discussed. The rectangular furnace is considered as a channel reactor in this analysis, and the action of the electrodes is described to indicate a balanced settling rate in the area of electrode action. Discussion of the design and production capacity of the electric furnace, with reference too perating current, power input, furnace dimensions and electrode size, are based on considerations derived mainly from slag properties such as its resistively, viscosity and liquidus temperature.

Jan 1, 2004

By Hae-Moon Choi, Sang-Don Lee, Hee Soon Shin, Choon Sunwo, Chang-Ha Ryu, Hyun-Koo Lee

Building tunnels means dealing with what rock is encountered. Relocation of the site of the underground structure is rarely possible. Tunneling engineers and miners have to cope with the quality of the rock mass as it is. Different tunneling philosophies and different rock classification methods have been developed in various countries. Most of the rock classification methods are based on the response of the rock mass to the excavation. Tunnel support requirements could be assessed analytically, supplemented by rock mass classification predictions, and verified by measurements during construction. Rock mass classifications on their own should only be used for preliminary, planning purposes and not for final tunnel support. Design of blast pattern in tunneling projects in Korea is also for the most part prepared according to the general rock classification methods such as RMR or Q. It, however, does not take into account the blast performance, and as a consequence, produce poor blasting results. In this paper, the methods of general rock classification and blast design for tunnel excavation in Korea are reviewed, and efforts to develop a new classification method, reflecting the blasting performance, are presented. Copyright ©

Jan 1, 2004

"After the non-destructive testing is completed, the data must be compiled, evaluated, and interpreted. During this process, the data may indicate that there is an anomaly warranting further investigation, which may eventually be determined to be a flaw or defect. The definitions of an anomaly, flaw, and defect can be described as follows (after Amir, 2002):Anomaly - Any irregular feature identified in the NDT graphic results. An anomaly may be due to the testing instrumentation (such as noise), to the means used to perform the test (e.g. access tube debonding in CSL) or to the shaft itself. It is the responsibility of the NDT practitioner to gather and analyze all relevant data and try to resolve every anomaly before it is declared a flaw or defect.Flaw - Any deviation from the planned shape, size and/or material of the shaft.Defect - A flaw that, because of either size or location, may detract from the shaft’s intended performance or durability. The geotechnical engineer and the structural engineer are jointly responsible to decide which flaw comprises a defect.This section describes the process of evaluating the data, determining if an anomaly exists, and if so, deciding whether the anomaly is actually a flaw or a defect. If the anomaly is determined to be a defect, its effect on the performance of the shaft must be evaluated, and if necessary, the can be re-engineered, repaired, or replaced."

Jan 1, 2004

By Detnet Solutions

1. “Daisy-Chain” concept The term “daisy-chain” stems from the fact that when the HotShot? detonators are connected there is a chain or electrical path for electrical current to flow from detonator A to detonator B, detonator B to detonator C etc until the path is terminated by an electrical means. The “daisy-chain” concept has long been used in electronic detonator systems, historically used in Expert Explosives’ ExEx 1000 5/6 wire system and currently in use in African Explosives Limited (AEL’s) Electrodet? electronic detonator system and has been adopted as the basis upon which the “auto-programmability” of the HotShot? electronic detonator system functions. HotShot? Detonators are connected to each other in a string, completing a “daisy chain”, and during the auto-detection mode of the control equipment, it is possible for the equipment to determine the order of hookup of the detonators as well as map the entire blast layout. The auxiliary components (Row Controllers & Branch Controllers) assist the control equipment in mapping the entire blast by indicating different points on the blast, i.e. The inflection point of a row of blast holes on a closed chevron timing pattern, the beginning of row of blast holes on open chevron timing pattern and extra blast holes or extra blast rows.

Jan 1, 2004

Despite the wealth of information available on phase equilibria of oxide systems there remainmany gaps and inconsistencies in our knowledge base. From an industry perspective there is anongoing need to adequately describe the phase chemistry of slag systems in order to optimizeprocess performance and improve productivity. Since this chemical behaviour cannot be predictedfrom first principles it follows there is also an ongoing need for accurate experimental data. The advances made in recent years in the capabilities of sophisticated analytical and measurement equipment have made it possible to develop new experimental techniques for the direct determination of phase equilibria in low order and complex multi-component slag systems. In addition the development of powerful computer modelling tools makes it possible to provide more comprehensive descriptions of the phase chemistry, to present the information in a range of perspectives, and to critically analyse the various types of related thermodynamic and structural information available. This review provides an overview of the types of information that can be used to determine phase equilibria in slags systems, analyses the influence of uncertainty and the relative importance of these types of data, and describes the advantages and limitations of the various experimental techniques that can be employed to obtain this information. Examples of recent studies are provided that demonstrate how an integrated approach to the determination of phase equilibria in complex systems, involving the use of targeted experimental studies and systematic thermodynamic model development, can lead to a better utilization of our current research capabilities and resources and more accurate descriptions of these systems. Keywords: slags, phase equilibria, experimental techniques

Jan 1, 2004

Splashing and wave formation has been studied experimentally by using one-seventh water model of CLU (Creusot-Loire Uddeholm) reactor with two different tuyere configurations by using paraffin and water as simulated slag and simulated metal respectively. Experimental results have been discussed in terms of total splash volume, relative slag volume in splash (dispersed-slag phase holdup in splash), wave frequency and wave amplitude with respect to gas injection rate and tuyere configuration at bath heights between 0.25m and 0.38m. Gas flow rates ranged from 0.00599m3/s to 0.01312 m3/s. The results of splash measurements showed that splash volume increased with increasing gas flow rate and decreasing bath heights for both tuyere arrangements. However, off-centre configuration resulted in relatively higher amounts of splash. The slag volume in splash (Dph in splash) was also found to increase with decreasing bath heights and increasing gas injection rates. The high speed photography revealed that the frequency and wave amplitude increased with gas injection rate. The experimental results also showed that the frequency and vertical displacement of the rotating wave increased when the tuyere orientation became off-centered. This might be used to explain why off-center configuration resulted in generating higher splash volumes than the center configuration.

Jan 1, 2004

By K. S. Coley, G. A. Irons, T. Kaneyasu

"It is very important to reveal the lime dissolution mechanism in steelmaking slag, to promote its dissolution without calcium fluoride, which is now almost forbidden for use in most industrialized countries. In this research, the purpose was focused on the development of an experimental method to measure the mutual diffusivity of Ca2+ under the condition of lime dissolution into slag. By forming diffusion couples using a ""vacuum slag aspirating technique"", the method was established. The following mutual diffusivities of Ca2+, in CaO-SiO2-FeO slag systems, imitating oxygen steelmaking slag, were determined using this method:4.1*10-10 m2/s at 1400°C for 27wt.%CaO-53wt.%SiO2-20wt.%FeO slag,4.3* 10-10 m2/s and at 1400°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag, and 1.3*10-10 m2/s at 1250°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag.It was also verified that, if the basicity and ferrite content of the bulk slag are low, then a calcium silicate film forms on the lime surface, and drastically deters the lime dissolution."

Jan 1, 2004

Delivery of effective plant shutdowns is primary to the business success of mining and processing plant operations. This paper sets out a methodology that starts with understanding the business objectives of the shutdown and promotes rigorous detailed planning, effective communication, appropriate governance and effective participation of plant operations personnel. The result is delivery of business effective outcomes.

Jan 1, 2004