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The products from beneficiation present themselves at opposite ends of the spectrum, and yet numerous synergies exist in the preparation of coking coal and hematite iron ore products for their common export markets. Returning to the coal side of the business with Anglo Coal following a five-year sojourn in WA with Hamersley Iron, has provided the opportunity for comparing and contrasting some of the key synergies of the supply chains of both bulk commodities.Comparisons include consideration of things like: resource evaluation (especially quality aspects), run-of-mine handling and preparation, beneficiation, product handling and transportation, quality assurance and customer awareness, value-in-use and impacts on iron and steelmaking, and supply chain environmental aspects.Inherent within these are several other notable contrasts including: æseamsÆ and æorebodiesÆ, rocks and minerals, rejects and tailings, oxidation and weathering, suppliers and users, and marketing and purchasing, to name but a few.This paper covers some of the more interesting of these synergies and raises some potential opportunities for sharing knowledge and innovation between the two areas of activity in the future.

Jan 1, 2005

By E E. Hall, S, E D. Thimons, R J. Timko

The heart of mine ventilation science and technology is the protection of the life and health of the miner. Lung diseases that result from overexposure to various mine aerosols can largely be prevented by maintaining concentrations below prescribed limits. Maintaining safe aerosol concentrations depends, in part, on our ability to know what mine aerosol concentrations are in a timely and accurate way. The Centers for Disease Control and Prevention (CDC), National Institute for Occupational Safety and Health (NIOSH) has been developing several new tools to help miners monitor respirable coal dust, silica and diesel particulate matter. This paper will discuss three main topics. First, the latest results of the person wearable dust monitor (PDM), developed by Rupprecht and Patashnick under CDC contract. The PDM was tested side-by-side with conventional samplers at a number of US coal mines and results indicated that the PDM was comparable to conventional samplers. Second, improvements to the dust dosimeter monitoring technique that includes a new pump with built-in pressure transducer and algorithm to convert differential pressure to dust concentration have shown good precision. Third, advances in the use of the detector tube technique to monitor tailpipe diesel emissions and ambient diesel particulate matter show that strong correlations exist between differential pressure measurement and elemental carbon in the samples.

Jan 1, 2005

By Susan P. Taite, Alain R. Charest, Peter D. Lewis

The El Sauzal deposit is a classic, high sulfidation, epithermal gold system located in the southwestern Chihuahua state of Mexico (Fig. 1). A Francisco Gold geologist discovered the prospect in1995. El Sauzal was encountered as a result of an extensive grassroots exploration program in the rugged, dissected volcanic terrains of the Sierra Madre Occidental, around the historical Batopilas silver camp. At El Sauzal, high grade gold is hosted within a series of more permeable, low-dipping, lithic and fine-grained dacitic rocks of early Tertiaryage. The mineralization appears tobe structurally and lithologically controlled. The alteration characteristics are typical of a high sulfidation system, including kaolinite, illite, alunite, dickite and pyrophyllite.

Jan 1, 2005

By Tiezheng Li

Keywords: Laminate Composites; Mechanical Behavior; Damage Evolution The mechanical performance of Ti-6-4-Al3Ti metal-intermetallic laminate (MIL) composites synthesized by a reactive foil sintering technique was evaluated. Crack morphology of untested Ti-6-4-Al3Ti MIL composites has been characterized by optical microscopy. Mechanical tests were performed on Ti-Al3Ti metal-intermetallic laminate (MIL) composites and pure Al3Ti, and the principal mechanisms of damage initiation and accumulation were identified experimentally. The elastic properties and anisotropy of the laminates were calculated and successfully compared with Resonant Ultrasonic Spectroscopy (RUS) measurements. The effect of residual stress on the fracture toughness of the Ti-6-4-Al3Ti MIL composites was analyzed.

Jan 1, 2005

By P Lamberg, M Lyyr, S Heimala, J Liipo

Since the introduction of froth flotation for industrial practice, the process has long been developed and improved by making cultivated guesses or by using trial and error methods to a varying degree. Fresh possibilities have emerged after development of new surface sensitive analysing methods and in situ electrochemical methods. Having had the possibility to combine different findings between science and everyday plant practice, Outokumpu has been able to develop a catch-all procedure to manage a flotation process taking into account the specific requirements set by different minerals in a slurry. A number of these procedures are available and offered globally to clients as part of a Plant Audit service. The Outokumpu Plant Process Audit (Process ef-X) concept comprises of mineralogical determinations from process samples and plant data analysis together with electrochemical process measurements using mineral electrodes. Automatic control loop analysis can also be included. The objective is to combine the results for a basis of flotation process improvement. Since this methodology has earlier been an in-house practice, it follows that the results are also reflected in the development and design of the OutokumpuÆs processing equipment. An increasing number of ores have a very intimate fine-grained texture and it may be physically impossible to combine high grade with acceptable recovery by a flotation process alone. For such cases, combinations of different hydrometallurgical û mineral separation û pyrometallurgical processes are available. Mineral specific information and chemical expertise of flotation technology can be utilised in development of other processes, as well.

Jan 1, 2005

By M. Duncan

Lightweight, high-pressure cylinders for compressed hydrogen storage are essential components for fuel cell vehicles. Storage volume and mass are two key considerations. Current on-board hydrogen storage systems are based on a maximum pressure of 350 bar. While 350 bar systems are excellent solutions for many applications, some situations require higher storage densities due to space restrictions. As a result, significant research and development work has been expended by cylinder manufacturers, systems providers, testing agencies and automotive manufacturers to develop 700 bar systems with reduced storage volumes. Dynetek Industries Ltd. has proactively developed several 700 bar storage cylinders based on a seamless aluminum liner over wrapped with a carbon fiber composite. This paper presents the challenges and processes involved in the design, testing and certification for Dynetek Industries Ltd. 700 bar cylinders. This paper also provides reasoning for further volume and mass optimization of compressed hydrogen cylinders through the establishment of realistic cylinder usage parameters in standards. In particular, the overly conservative fill life requirement for cylinders is examined.

Jan 1, 2005

By Esher Hsu

Keywords: Recycling, Consumer Battery, Fee rates On November 11, 1999, all types of spent consumer batteries are proclaimed to be collected in Taiwan. Under current recycling system, all producers and importers of consumer batteries have to pay a collection/recycling fee to the Recycling Management Fund (RMF) of EPA based upon the rate approved by EPA. Collectors and recycling plants receive subsidies from RMF according to the collected and treated amounts audited by an independent auditing organization. Collected spent consumer batteries only reached 923 tons in 2002 equivalent to 10% of the total quantity sold at the same year. How to increase the collection efficiency of used batteries becomes an important issue for EPA in Taiwan. The objective of this study is to explore current recycling system of spent consumer battery in increasing collection efficiency. Results provide some suggestions to Taiwan EPA regarding recycling route, recycling system, recycling rates, and recycling subsidies.

Jan 1, 2005

By G. N. Shannon

Keywords: inclusions, slag, modeling, interfacial energy, capillary force, particle flotation, particle separation A previously introduced model of inclusions separating across a steel-slag interface, developed by Nakajima/Okamura and Bouris/Bergeles, is expanded to include different inclusions shapes (octahedral and plate-like, besides spherical) as well as comparison between model ladle-, tundish-, and mold-slags. Investigation of the relation of these shapes with the interfacial capillary force ? which arises due to the dynamic interfacial energy during separation ? has shown that the force has a significant effect on whether the inclusion separates rapidly or settles at the interface. For the slags considered, the most significant physical property is found to be viscosity, which resulted in fast separation times for inclusions in the mold and ladle slags, relative to the more viscous tundish slag. Particle dissolution (using experimental data) is included in separation modeling.

Jan 1, 2005

By Juliana Gutiérrez-Paredes

Keywords: Slag, chromium oxide, recovery, stainless steel Experimental and theoretical work was performed to estimate the effect of slag basicity and amount of reducing agents on the reduction of chromium oxide from the slag which interacted with molten steel at 1600°C. The slag system contained CaO, MgO, SiO2, CaF2 and Cr2O3 together with Fe-alloys (Fe-Si and Fe-Si-Mg). The CaF2 and MgO contents in the slags were 10 mass % each; Cr2O3 was 25%. The amount of the ferroalloys ranged from 12.5 to 50 g per 100 g of slag. The (CaO+MgO)/SiO2 ratio was held at 1 and 2. The Cr yield was determined using both Fe-alloys as reducing agents. Some estimations were made to determine the theoretical effect of temperature, slag basicity, (CaO+MgO)/SiO2, and amount of reducing agents in the slag on the chromium recovery. The FACT (Facility for the Analysis of Chemical Thermodynamics) computational package is used to determine the equilibrium between the slag and molten steel.

Jan 1, 2005

By Magno Rodrigues Ribeiro, Alexandre Cabral Stelzer, Cacio José da Silva, Leonardo Nogueira Ferri, Marcelo Ciminelli Mendes, Christophe Bouché, Marco Aurélio Soares Martins, Evenilson Soprani Lopes, José Xavier da Silva Filho, Sérgio Luiz Dalvi

Since 2001, CVRD is carrying out a modernization project in it’s pelletizing plant’s automation systems, that comprehends instrumentation, control and information systems. In addition, the project includes implementation of advanced control systems, using artificial intelligence techniques, including fuzzy logic, expert systems and dynamic physical models, to increase production, reduce fuel and energy consumption and improve quality. This paper reports CVRD’s experiences in carrying out an optimization project.

Jan 1, 2005

By G. J. Hasenfus

There are no known published methods of estimating the degradation of coal measure rocks by water that are simple and efficient, yet still provide a quantitative, meaningful value for assessing the stability of coal mine floor, roof, and rib. The slake durability test, the standard index method for estimating the durability of rock subject to wetting, can provide misleading results for floor stability assessment. Additionally, slake durability testing is time consuming and requires specialty equipment. Methods based on humidity cycling have been demonstrated to be very effective for assessing coal mine roof, but require specialty equipment and do not address floor stability concerns. Visual observation techniques, such as that developed for the Coal Mine Roof Rating (CMRR) method, adequately qualify rock degradation, but lack quantitative rigor. This paper will describe an alternative method, coined the water sensitivity test, originally developed for floor stability analyses, but also found applicable for roof and rib stability assessment. The test was developed by CONSOL in the early 1990's, and in its current form, has been in use for approximately twelve years. The method is based on the basic slake durability principle of measuring the mass of the rock retained on a screen after submersion in water. The new test employs two screens of different sizes, and also uses modified submersion, drying, and data processing procedures. The method is relatively efficient and can be geared toward batched testing. As with the slake durability test, the resulting index value provides a quantitative measure of the susceptibility of rock to water degradation. In addition to discussing the test method and its development, this paper provides a comparison of results with those fiom standard slake durability tests, and tabulated results for various types of coal measure rocks. Examples of the technique's utility are provided, including assessment of longwall and development floor conditions, roof and rib rock weathering and stability, and drum-bit cutability.

Jan 1, 2005

By A. J. Rigby

Refractory linings in converters or anode furnaces used to over-oxidize the blister copper will suffer rapid deterioration, due to prolonged contact with copper oxide-rich slag. Nitrogen stirring with COP KIN porous plugs and use of SEMTECH OPC in converters and anode refining vessels can considerably reduce both refractory wear and processing times. In addition, careful control of the vessel atmosphere and the use of real-time optical process control minimize both slag volume and contact time with the vessel refractory.

Jan 1, 2005

By V. K. Alves, P. Lacoste-Bouchet

"In order to improve ball milling efficiency in pellet plants, Companhia Vale de Rio Doce (CVRD), experiments new technologies in Santa Luzia (M.G. – Brazil) research center facility. Pilot grinding tests have been conducted with small grinding media, size distributed from 5 to 12 mm (millpebs). Tests have been conducted on an ore from CVRD’s Usina 5 Nibrasco, in Vitória, Brazil. A sample of the regrind circuit feed was obtained and used in comparative grinding tests with two types of grinding charges: 100% balls and a blend of 70% balls and 30% millpebs by weight. According to the balls charge, the grinding media mixture has showed the following benefits: reduction of the power draw, increase of the mill capacity, reduction of the circulating load and a slight increase of the ore blaine. Following the results obtained, CVRD is going to further explore the regrinding potential of millpebs.INTRODUCTIONCompanhnia Vale de Rio Doce (CVRD) is the largest mining company in Brazil. CVRD is involved in iron, base metals, gold and bauxite industries. Moreover, CVRD operates several pelletizing plants in Brazil and in other countries.CVRD’s Center for Mineral Development (CDM) is equipped with a comminution laboratory where studies are carried out that are aimed at the optimization of existing plants at several mining sites as well as the technical and economical feasibility of new projects. The laboratory is equipped with a complete pilot plant with several mills and classifiers, enabling continuous grinding tests in grinding circuits of almost any capacity and characteristics.In January 2004, CVRD undertook to conduct pilot tests at CDM for evaluating the effect of small grinding media on ball milling efficiency. Generally speaking, it is not unusual for operators to add oversize grinding media in a conventional regrind mill. This fact originates mainly from prohibitive prices of grinding media below 25 mm due to a production capacity decrease of grinding media producers. The size of the grinding media is an important variable affecting ball milling efficiency. Use of oversize balls decreases the number of contact surface between which particles can be caught and broken."

Jan 1, 2005

By A. R. Laplante

Gold recovery early in the flowsheet, typically from the primary grinding circuit, has seen significant advances in the past three years. Some of the advances achieved under the auspices of the AMIRA P420B Gold Processing Technology project are reviewed. The areas covered are gravity-recoverable gold (GRG) characterization, GRG behaviour in classification, gravity recovery simulation and the link between gravity recovery and cyanidation.

Jan 1, 2005

By Eung Ha Cho, Wendi Li

Wet desulfurization of Pittsburgh No. 8 coal and Illinois No. 6 coal were conducted with sodium hypochlorite in the laboratory. Pittsburgh No. 8 coal was leached by hypochlorite at high pHs in one step only. The hypochlorite concentration varied from 0.2 to 0.6 molar; sodium hydroxide concentration, from 0.2 to 0.8 molar; and temperature was at the levels of 80 and 90°C. The desulfurization of Illinois No. 6 coal was conducted in three consecutive steps of pretreatment in concentrated ammonia at room temperature, leaching with hypochlorite at room temperature and hydrolysis in sodium hydroxide solution at 90°C. In the leaching step, hypochlorite concentration varied from 0.2 to 0.8 molar. The desulfurization method of Pittsburgh No. 8 coal was found to reduce mainly pyritic sulfur. More than 70% of pyritic sulfur removal was achieved at the optimum conditions of 0.4 molar hypochlorite, 0.4 molar sodium hydroxide and 90°C. The desulfurization method for Illinois No. 6 coal was capable of reducing significant amounts of organic sulfur. The removal of organic sulfur achieved a 37.8% reduction at the optimum operation of leaching at 0.4 molar hypochlorite and room temperature followed by hydrolysis at 0.3 molar sodium hydroxide and 90°C. The chlorine content in the coal produced by the chlorination during leaching was kept below the threshold value of 0.3% at the optimum conditions of the desulfurization method for each coal.

Jan 1, 2005

By M P. Schwarz

In recent years, computational fluid dynamic (CFD) modelling of mechanically stirred flotation cells has been used to study the complexity of the flow within the cells. In CFD modelling, the flotation cell is discretised into individual finite volumes where local values of flow properties are calculated. The flotation effect is studied as three subprocesses including collision, attachment and detachment. In the present work, these subprocesses are modelled in a laboratory flotation cell. The flotation kinetics involving a population balance for particles in a semi-batch process has been developed. From turbulent collision models, the local rates of bubble-particle encounters have been estimated from the local turbulent velocities. The probabilities of collision, adhesion and stabilisation have been calculated at each location in the flotation cell. The net rate of attachment, after accounting for detachments, has been used in the kinetic model involving transient CFD simulations with removal of bubble-particle aggregates to the froth layer. Comparison of the predicted fraction of particles remaining in the cell and the fraction of free particles to the total number of particles remaining in the cell indicates that the particle recovery rate to the pulp-froth interface is much slower than the net attachment rates. For the case studied, the results indicate that the bubbles are loaded with particles quite quickly, and that the bubble surface area flux is the limiting factor in the recovery rate at the froth interface. This explains why the relationship between flotation rate and bubble surface area flux is generally used as a criterion for designing flotation cells. The predicted flotation rate constants also indicate that fine and large particles do not float as well as intermediate sized particles of 120 - 240 ¦m range. This is consistent with the flotation recovery generally observed in flotation practice. The magnitude of the flotation rate constants obtained by CFD modelling indicates that transport rates of the bubble-particle aggregates to the froth layer contribute quite significantly to the overall flotation rate and this is likely to be the case especially in plant-scale equipment.

Jan 1, 2005

By B K. Da, S A. Balaji, G P. Roy, T K. Dutta

The raw material handling complex at the Durgapur steel plant provides iron ore, crushed coke and flux to two sinter plants. Either some facilities were not envisaged or not properly designed before the project stage which caused problems during operation of the plant. The absence of an in situ roll turning facility, used to increase maintenance activities for disassembly, transportation of rolls to central machine shop and assembly of rolls, led to decreased crusher availability and increased activities for the maintenance crew. The provision of a smaller vibro feeder/screen in place of a suitable sized screen caused jamming of the screen deck, adversely affecting screening efficiency and the crushing index of crushed coke. Some design modifications and developmental work was undertaken, such as the development and installation of an in situ roll turning facility in the existing limited space, achieving low feed (0.1 - 0.2 mm/rev), lower cutting speed of 30 - 40 m/minute for 350 BHN hard roll, which was also a difficult engineering challenge to bring within the tolerable limit of vibration. This was successfully achieved. Modifications to the screen deck, introduction of differential speed crushing and modification to the vibro screen and vibro feeder for uniform distribution of feed have been incorporated. These innovative design modifications to the in situ roll turning have led to a drastic decrease in maintenance activities and an improvement in the crushing index. Modifications to the screen have resulted in the elimination of jamming and improved screening. Modifications to the vibro screen before the primary crushers and to the vibro feeder before the secondary crushers have prevented excessive wear in the central portion of rolls, ultimately leading to increased roll life. Incorporation of differential speed crushing has resulted in an increased crushing index and decreased generation of micro fines. All the above modifications have led to distinct improvements in equipment availability, increased roll life and a decrease in maintenance activities and improvement in crushed coke granulametry, ultimately resulting in improved productivity and quality of iron ore agglomeration at the sinter plant. The innovative design modifications mentioned above are discussed in detail in this paper.

Jan 1, 2005

By J. M. Elder, W. S. Kow

Challenges to new heavy mineral deposit developments are presented. These include land use issues, particle fineness, declining grades, and particle coating, amongst others. Industry responses to these are presented as possible solutions.

Jan 1, 2005

By L Neindorf

The development and application of paste fill, cement slurry aggregate fill and shotcrete bulkheads at Mount Isa Mines is described. The progressive changes in filling style in the Mount Isa copper mines from a dry fill based cemented rock fill to tailings based paste fill and slurry fills is explained. The development of shotcrete arched bulkheads and engineered drainage system is described. Details on how Mount Isa Mines has achieved approximately 30 per cent cost reduction in backfill operations through innovations are given. The development of a rocky paste fill is explained.

Jan 1, 2005

By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska's North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005