Search Documents

By M. D. Max, A. H. Johnson

INTRODUCTION Gas hydrates have considerable potential to be a major energy resource owing to their apparent abundance in Arctic regions and along continental margins throughout the world (Kvenvolden, 1988). Yet, the oil and gas industry has been slow to pursue this opportunity. The primary reasons for this are the large conventional reserve base for natural gas worldwide and the perception that gas hydrate will not be a viable resource for another twenty or thirty years. Gas hydrates are thus viewed as a potential resource for the distant future, but not a valid investment for the near term. This paper addresses both global gas markets and gas hydrate technology, and shows that the commercial development of gas hydrate could proceed rapidly enough to constitute a near-term energy resource. GLOBAL GAS MARKETS The proven worldwide reserves of conventional natural gas are truly enormous, totaling over 6,000 TCF according to BP (2004). Moreover, those reserves have nearly doubled during the past two decades and now represent 67 years of consumption at the current production rates of 80 TCF per year (Fig. 1). This reserve increase has occurred even as global production of natural gas has increased by 67% during the same two decades (Fig. 2). While declining conventional gas reserves are a concern in North America, especially in regions where established infrastructure exists to bring gas to consumers, large new discoveries continue to be made elsewhere in the world. Indeed, in many parts of the world (such as the Middle East and parts of West Africa), natural gas has been regarded as an essentially worthless byproduct of oil production or exists in stranded gas fields. Given this situation, pursuing unconventional gas resources that are inherently riskier exploration targets and more expensive to produce would appear to have little rationale from a business standpoint.

Jan 1, 2006

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By Jeong-Hwan Kim

The liquid-liquid reactive process (solution process) is often adopted as a synthetic method for precipitated calcium carbonate (PCC) in laboratory studies for its simplicity in operation or ease in controlling process variables. Still, PCC are produced commercially by passing carbon dioxide through a milk of lime, i.e., by a gas-liquid reacting method (carbonation process). Few studies on the carbonation process have been conducted, since the process variables are interrelated and difficult to control compared to the solution process. In this study, both carbonation and solution processes were employed to study the polymorphs of calcium carbonate and growth rate of PCC crystals. The effects of the characteristics of limestone ores as a raw material in the synthetic system of PCC on the synthetic characteristics of PCC were also investigated. To control the nucleation rate in the synthetic systems, the shape factor was considered most important. Single-phase aragonite PCC could be synthesized under a variety of controlled experimental conditions such as ionic strength, solution composition, concentrations of additive ions, and temperature.

Jan 1, 2006

By O Dahl, I M. Platten, E J. Sides

Many narrow-vein gold deposits are characterised by a high to extreme nugget effect and the presence of coarse gold. They rank amongst the most difficult of deposits to produce an accurate and precise resource estimate. This contribution presents a case study from the Nalunaq Gold Mine in Southern Greenland. The mine commenced operation in May 2004 and is currently operating at a rate of 400 tonnes per day, to produce about 100 000 oz gold per annum from a total resource base of 1.2 Moz. Mineralisation is characterised by quartz veins that are hosted within a shear zone that is continuous over about 1000 m. The principal orebody is the Main Vein structure, which ranges up to 3 m in width, maintains an average dip of 35¦SE, and contains significant gold grades (1000s g/t Au). Gold particles are often visible, with 25 per cent being greater than 250 microns in size. Variography using underground development samples indicates a nugget effect of about 75 per cent. For the 2005 resource estimate, a 2D metal accumulation ordinary kriged block model was used to produce a global grade for the Target and South Blocks of the Main Vein. Grade control chip-channel samples are collected from æshantyÆ drive footwalls, and used as the basis for both the kriged block model and to determine the grade of individual stope blocks by peripheral weighted averages. Geology plays a key role in mining efficiency, given the locally variable nature of the ore zone.

Jan 1, 2006

By Tim O’Neil

The earthmover tire shortage has been a case of bust and boom for the tire industry. Tire producers were unwilling to invest ahead of the mining boom. In their defense, though, the metals sector of the mining industry tends to be cyclic, tire manufacturers are not prescient. Until two years ago, low tire demand depressed prices. The incentive to invest in new, big-tire capacity was almost nonexistent, according to Prashant Prabhu, president of Michelin Earthmover Tire worldwide. “There has been very poor anticipation or a miscaluation of the amplitude of the (tire) demand on the part of just about everybody,” said Prabhu. What a turnaround. The earthmover tire market has grown by 30 percent over the past two years. Now there are not enough earth-mover tires and likely won’t be for the next two years. Goodyear said it was offering customers bias-ply tires when it could not supply enough radial-ply tires. Komatsu said it lost equipment sales because it could not provide the tires that customers requested. Volvo and Caterpillar said they are delivering some vehicles without tires, either promising tires later or leaving the customers – mine operators – to find their own rubber.

Jan 1, 2006

By W. Beres, M. Bielawski

Recent research on the development of erosion resistant coatings has been directed to the finite element modelling of the behavior of coating and substrate, and their interface under the impact of eroding particles. The approach presented in this paper is based on advanced computer simulation techniques using ABAQUS/Explicit to investigate stress and strain at the surface and at the coating/substrate interface of multilayer coatings under single particle impact. It was found previously that solid particle erosion mechanisms are predominantly governed by the kinetic energy of the impacting particles. However, recent modelling efforts revealed that effects of various material models could be also significant. Therefore, different material models representing relevant coating and substrate properties were investigated and the effects of these models on the coating/substrate response were studied. Particularly, differences between elastic, elastic-plastic and brittle cracking model responses were assessed.

Jan 1, 2006

By Xiaowen Liu

The DSC/TG, IR and XRD analysis were used to characterize the heating phase transformation of illite, which came from Ouhai deposit, China. It was discovered that the dehydration and de-hydroxylation of illite carried out stage by stage during heating. The adsorptive water and layer-inter water were dehydrated from room temperature to 500°C; and dehydroxylated in the range 500°C~800°C. In these stages of process, illite?s layer structure kept almost unchanged. After 800°Cillite began to change into disorder structure. At about 1100°C, the layer structure of illite had been destroyed, and amorphous SiO2 and mullite crystallite appeared. At about 1200°C the structure of illite completely destroyed and mullite crystal phase had become perfect..

Jan 1, 2006

By Wenquan Zhang

Based on the mining and geological conditions of Wadong Mine, Longkou City, Shandong Province, China, a viscoelastic model with proper creep parameters was established. The 3-D ANSYS was used to simulate surface subsidence, analyze overburden subsidence characteristics, and propose the rational mining and pillar widths for mining in weak rocks and under special mining conditions, and provide the policy makers scientific data for decision making on mining activities.

Jan 1, 2006

By H. Nan

Using the case of Qianqiu Mine, Yima Coal Mining Administration, theoretical analysis, laboratory physical simulation, and underground observation were performed to study the major parameters for fully mechanized sublevel caving mining method, including drawing spacing, drawing sequence, drawing numbers, and number of shields performing simultaneous drawing. The effects of those parameters on coal recovery and amount of waste rocks were also investigated. The optimal coal drawing technology for this case was obtained.

Jan 1, 2006

By K. Ronald Chapman, Claus Ludwig, Doug Jenevein

"In the spring of 2005 Schnabel Foundation Company completed a $15.2 million Design/Build subcontract to underpin 11 structures, and provide 202,800 square feet of earth retention for the Reno Transportation Rail Access Corridor (ReTRAC) project in Reno, Nevada. Schnabel’s work was part of a Design/Build contract to depress a railroad alignment through downtown Reno. The depressed section was 2.2 miles long, 54 ft wide, and up to 35 ft deep (3.5 km long, 16.5m wide and up to 10.7m deep). The trench structure was required to be watertight. SUBCONTRACT WORK OVERVIEWEleven buildings along the track alignment required underpinning. Three types of underpinning were used, designated Type 1, Type 2 and Type 3.At four buildings the trench retaining walls were to be located directly under the exterior footings. This alignment eliminated traditional underpinning and cut-off wall techniques that could normally be used to support structures. Type 1 underpinning was used at these buildings. This underpinning system consisted of a combination of permeation grouting, hand-dug piers, and permanent tiebacks. This underpinning system became the new watertight trench walls.Five buildings were located a few feet behind the trench walls, and their exterior walls were supported by continuous footings. Type 2 micropile/pile cap underpinning (patent pending) was used to support these buildings.The remaining two buildings were also located a few feet behind the trench walls, but they had column footings along the exterior walls. At these structures traditional micropile underpinning was provided through the existing footings. This is described as Type 3 underpinning.Temporary earth retention was required on both sides of the trench along most of the alignment. This shoring supported frontage roads, private property and surcharge from the temporary railroad shoofly running parallel to one side of the trench.SUBSURFACE CONDITIONSThe soil along the trench alignment consisted of river outwash deposits. The top 2 to 18 feet (0.6m to 5.5m) generally consisted of flood plain silt and sand deposits, or fine-grained fills. These fine-grained soils are underlain by the Tahoe Outwash Formation which consists of interbedded layers of sand; sand and gravel; and sand, gravel, cobbles and boulders. Some of these layers encountered during construction consisted of 30 to 50 percent cobbles and boulders, with some boulders up to eight feet in diameter.A major challenge to the design and construction of the trench structures and the underpinning was the ground water table which was 10 feet (3m) above subgrade in the deepest portions of the trench. Based on specification restrictions, temporary and permanent dewatering was not feasible. As a result, the selected design and construction methods had to consider three water conditions: the anticipated groundwater level during construction (CGW), the groundwater level for permanent design (DGW), and an additional special design condition with water at street grade."

Jan 1, 2006

By Thomas M. Brady

The Spokane Research Laboratory/NIOSH and the University of British Columbia (UBC) geomechanics group are focusing on the development of safe and cost-effective underground design guidelines for weak rock masses having an RMR in the range of 15 to 45. Weak ground conditions, ground support, and mining methods used in several North American underground mines were observed. The RMR values were calculated to update both manned entry span design and non-entry stability graphs, plus a database on underhand mining methods was created to reflect existing North American mining conditions. The immediate rock mass was characterized and analyzed in terms of prevailing type of ground support, potential failure mechanisms, and rock behavior to define how existing design curves must be modified for the existing weak rock mass. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making sound economic decisions that will also ensure a safe working environment.

Jan 1, 2006

By Alex Moyano

At present, the Codelco Norte smelter processes in the Teniente Converter and the Flash smelting Furnace 1,420,000 t/y of its Chuquicamata concentrate with an arsenic content of up to 1.5%. In a near future Codelco-Chile is considering different processing options for a new projected concentrates from the Alejandro Hales mine (former Mansa Mina mine with an arsenic content of up to 6%). The main option is the possibility to process 3,000 t/d of mixing concentrates from the Alejandro Hales and the Chuquicamata mines, in the Teniente Converter. The main feature of this smelting unit will be high volatilization of arsenic when processing high arsenic-bearing concentrates. The CN smelter staff carried out a technical feasibility study to evaluate the processing of high arsenic-bearing concentrates directly in the Teniente Converter, thus the low arsenic-bearing concentrates can be processed in the FSF. Accordingly, laboratory scale tests were carried out at the Tohoku University facilities. The lab-scale results allowed an industrial scale test at the Codelco Norte smelter to smelt 2,300 tpd of high arsenic-bearing concentrates in the TC and evaluate the metallurgical impact in the smelting, converting and refining areas of the smelter. The main industrial-scale result confirmed the stabilization of the arsenic content at 0.5% in the 70% Cu produced white metal at the test condition.

Jan 1, 2006

By Dale Preece

A carefully designed and controlled in-place destruction experiment was performed on a concrete bunker buried in 4.27 m (14 ft.) of soil. The objective was to determine if the explosive charges would collapse the structure in-place without requiring mechanical excavation. Collapse of the buried structure was first attempted by drilling holes in the soil and placing four 13.38 Kg (29.5 lb) Comp B explosive charges at a depth of 2.13 m (6.7 ft.). The configuration of the charges when detonated was 2.13 m (6.7 ft.) off the top of the concrete roof and 3.66 m (12 ft.) apart in a square pattern. Detonation of these charges created a crater ~4.88 m (16 ft.) in diameter and 2.13 m (6.7 ft.) deep, leaving ~2.13 m (6.7 ft.) of soil covering. Very limited spalling occurred on the ceiling of the concrete structure as a result of detonating these four charges. The second attempt to collapse the structure consisted of placing another single 13.38 Kg (29.5 lb) charge, identical to the first four, near the geometrical center of the bunker roof. This charge was detonated in the soil cover 100 to 200 mm (4 to 8 in.) above the reinforced concrete roof, collapsing it. Due to the collapsed roof and remaining soil cover, the structure had been collapsed in place, requiring no further demolition.

Jan 1, 2006

By Kenneth L. Cashdollar

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine and after laboratory explosions in the PRL 20-L chamber and the Fike 1-m3 chamber. The dusts studied included both high and low volatile bituminous coals. Low temperature ashing for 24 hr at 515°C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as or higher than the initial incombustible content. The MSHA alcohol coking test-was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared to the initial dust loadings to determine the transport distance of dust during an explosion. All of these data will be useful in future forensic investigations of accidental dust explosions in coal mines or elsewhere. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health or the Mine Safety and Health Administration.

Jan 1, 2006

By M. H. Attia

The concept of sustainable development has been evolved into a working framework for sustainable manufacturing, in which the environmental requirements are introduced into product development at the design stage. This keynote paper is discussing a number of issues pertaining to the impact of manufacturing on the environment. The conflicting requirements of sustainable development, sustainable manufacturing (SM) and economical growth are presented in the light of successful case studies that were able to convert conflicts into opportunities. Integration of SM into the product life cycle is also presented. A number of concepts that are related to Ecoefficiency, e.g., inverse manufacturing, demanufacturing and re-manufacturing are also discussed. The paper underlines the fact that the positive impact of this new philosophy is equally applicable and beneficial to both; developed and developing countries. The paper concludes with an overview of Global trends in environmentally benign manufacturing (EBM); e.g., product-take back and emerging material and processing technologies. The state-of-the-art approach to Life Cycle Impact Assessment and integration of design for the environment DfE principles are demonstrated through some case study.

Jan 1, 2006

By J. W. Senn

A magnesium alloy modeled after commercial alloy WE54 was thermomechanically processed and characterized to understand the mechanisms by which its texture can be randomized, as reported by Ball and Prangnell [1]. Samples were deformed in plane strain compression to prescribed strain levels at temperatures high enough to prevent cracking and then recrystallized. The deformation texture is very similar to that observed after plane strain compression (e.g., rolling) of other Mg alloys, such as common AZ31. However, the texture can radically evolve during recrystallization. Annealing above the precipitate solvus temperature results in a nearly random recrystallization texture where the initially strong basal texture is completely eliminated. Annealing below the solvus temperature produces a recrystallized texture similar to conventional Mg alloys, i.e., a weakened basal texture. If this same material is then annealed above the solvus to promote grain growth, a randomized texture evolves, which is similar that of samples simply recrystallized above the solvus. It is hypothesized that a sort of preferred growth mechanism, whereby grains with random orientation grow faster than those with the original basal texture, contributes significantly to the texture randomization observed in wrought magnesium alloys containing rare earth elements.

Jan 1, 2006

By Brijes Mishra

This paper presents a correlation of acoustic emission (A.E.) with physical and mechanical properties of different types of rock and coal specimens which were tested under aegis of a consultancy project from a Columbian Mining Company. In this study, three types of rocks which are sandstone (Arneisca), siltstone (Arciolita) and claystone (Limolita) and two different types of coal were tested. The tests were carried out under constant loading rates according to ASTM Standards for determining Young?s Modulus and Poisson?s Ratio. In both cases a MTS electro-hydraulic loading system was used. Mode of failure in each material was characterized by the acoustic emission and the results were substantiated by the deformation characteristics of the materials during failure.

Jan 1, 2006

By Florian Kongoli

While calcium ferrite slags have been successfully used in continuous copper converting for the last 30 years, ferrous calcium silicate slag was proposed about 8 years ago as an additional alternative for copper smelting. Although both slags are normal extensions of each other their phase relations have not been completely clarified. In this paper the liquidus relations of both slags have been quantified at various areas that cover both of them. The existing experimental data have been first reviewed and discussed in relation to the solidification procedure. An original physical model is then used to predict various diagrams of the liquidus surface of both slags. It is shown that the ternary liquidus diagrams normally used for FeOx-SiO2-CaO system are not suitable for industrial slags. The new model diagrams of Fe/CaO versus SiO2 and Fe/SiO2 versus CaO as well as Fe/CaO versus Temperature and Fe/SiO2 versus temperature are proven to be much more convenient for ferrite and ferrous calcium silicate slags. Based on these diagrams the effect of SiO2 and CaO on the melting temperature is quantified. The effect of Cu2O is also quantified through the model. Some Fe/CaO versus Cu2O and Fe/SiO2 versus CaO at various copper contents are predicted and the results show good agreement with the experimental data. It is also shown that in the presence of liquid copper, Cu2O is dissolved in the slag depending on the oxidation degree of the system and might lower the liquidus temperature. Some discussions are also presented taking into account plant observations and important conclusions are drawn for copper smelting and converting

Jan 1, 2006

By A. Bowles

The process of accumulative roll bonding (ARB) has been applied to wrought magnesium alloy AZ31. Accumulative roll bonding results in severe plastic deformation of sheet material. In AZ31, this process leads to the refinement of the microstructure by dynamic recrystallization. The refinement of the microstructure results in an improvement in mechanical properties with potential for producing materials for superplastic forming. In this work AZ31 was bonded with up to 64 layers and the potential of roll cladding with aluminium was also investigated. The development of microstructure and the mechanical properties are reported here.

Jan 1, 2006

By R. M. Jara

This work evaluates and characterizes the impact of the support size and mining dilution of a block model in the operation and selection of equipment at an open pit mine. An exploratory analysis and geostatistical modelling of the grades assayed on a set of drill hole samples is performed, which allows constructing a grade model on a dense grid by means of a conditional simulation. The grades are then averaged to greater selective mining unit supports in order to proceed with the study and methodology. First, the metal-tonnage curves are used to analyse the loss of selectivity on the in situ resources caused by a change of support. Concerning the ore reserves and their mining sequence, defined in the pit optimization and analysis process, the same curves prove that the loss of selectivity is more accentuated. Second, the importance of the block boundary dilution produced during mining operations is assessed. Its value depends on the amount of ore in contact with waste, on the loading error of the equipment and on the ore loss/waste dilution criterion assumed by the planner. The dilution percentage and the differences between waste and ore grades become higher when the block size decreases. For these reasons, considering the dilution in the production plans makes mining a small support more constraining. An adequate delimitation of the orebody can improve the mining selectivity, leading to greater income. Finally, a study of the increase in mining cost that provides a zero difference in NPV between the different block size options is carried out, in order to determine the maximum increase in mining costs for which it remains profitable to mine at a smaller block size. Keywords: Mining selectivity, support effect, block boundary dilution, selective mining unit size, block model.

Jan 1, 2006