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In this paper, response surface methodology was applied to optimize the experimental conditions for the wet grinding of synthetic rutile. The effects of parameters such as rotation speed, solids concentration and duration of grinding on grinding efficiency were systematically investigated and the process conditions were optimized, using a nonlinear regression model based on central composite design. The statistical analysis of the results showed that in the range studied, the grinding efficiency of synthetic rutile was significantly affected by the rotation speed of the conical ball mill. According to results from analysis of variance, the value of the determination coefficient (R2=0.9989) indicates that the predicted values are found to be in good agreement with experimental values. The optimized experimental conditions were as follows: a rotation speed of 350 rpm, a solids concentration of 27.31% and a grinding time of 50.31 min, respectively. Under optimum conditions, the predicted grinding efficiency of 94.79% is obtained. The experimental values from the validation experiments were well within the predicted value of the model.

Jan 1, 2011

Refractory copper ores (CROs) in central Africa contain copper minerals that are locked up in a micacious solid matrix or associated with carbonate, sulfide and phosphate minerals. Several researchers have reported that the recovery of copper from CRO material by an acid-leaching process is not economically feasible, due to the presence of excess gangue-acid-consuming minerals such as calcites, dolomite, asbolane and iron oxides. Since the proportion of acid-insoluble copper (CuS) is about 28% of total copper and total free sulfur is extremely small, sulfide flotation was considered unfavorable. Consequently, hundreds of millions of tons of CRO material have been stockpiled specifically at the Nchanga Mine of Zambia. In terms of copper distribution in CRO material, a significant portion of total copper exists as carbonates (39%) and oxides (17%), while 28% of the copper is acid-insoluble (CuS). The rest of the copper is in the form of carbonates (16%) and (hydr) oxides (17%). This means that only about 72% of total copper is recoverable through the non-oxidative acid-leaching process. In this study, batch leach tests were performed on CRO solids (d95 = 95%) to establish the gangue acid consumption values at different feed pH values and to evaluate the leaching characteristics of copper, manganese and iron within the CRO material. Subsequently, continuous leach tests were performed on CRO solids (106 um, 80% passing) using optimum leach conditions derived from batch tests. This paper aims to show that sustainable copper recovery can be achieved by selecting leaching conditions whereby gangue acid consumption (GAC) values become significantly small and the final concentration of manganese and iron in the leach solution are appreciably low.

Jan 1, 2011

By G. J. Joy

Although rates of pneumoconiosis in coal miners have declined substantially in the United States since the passage of the Federal Coal Mine Health and Safety Act of 1969, new cases continue to occur, including cases of rapidly progressive disease. In contrast, Australia?s underground coal mining industry has reported few new cases of pneumoconiosis for over twenty years. Mortality from Coal Workers? Pneumoconiosis in official health statistics and the prevalence of pneumoconiosis among miners screened in x-ray surveillance programs are also lower in Australia. To understand this disparity, the National Institute for Occupational Safety and Health was requested by both industry and labor stakeholders to examine this issue, with the ultimate aim of reducing the rate of pneumoconiosis among United States coal miners. A number of factors, including coal dust exposure, silica exposure, and coal rank were examined as potential contributors to the above observed differences. Comparison of coal rank data from each country did not show any significant differences. Air sample data from the coal mining industries in both countries show that coal dust levels in Australian mines are somewhat higher than those reported in similar U.S. mines; however, quartz exposure for Australian miners is lower than for many U.S. miners. Assuming that quartz is contributing to the greater number of cases of advanced pneumoconiosis in the U.S., more effective dust control measures, as well an independent exposure standard for respirable quartz in coal mining, need to be implemented to prevent this potentially disabling condition.

Jan 1, 2011

Traditionally within the mining industry, single models for both grade and geology of orebodies are created upon which all mine development decisions are based. These models provide a single interpretation of the extent and continuity of the mineralization envelope based on solids and sections interpreted from relatively wide spaced drilling i.e. the models infer behaviour of grade and geology at smaller/local scales based on data available at wider scales. The variable behaviour of grade and geology cannot be derived from single kriged resource models. In recognition of this, Newmont Mining Corporation typically uses Sequential Gaussian Simulation (SGS) to quantify grade variability and to determine its effect on some of these mine development decisions. In most of these studies the mineralized envelope remains fixed and grade simulations are generated within a fixed volume. To account for uncertainty in the geology/ mineralization envelope Newmont Mining Corporation has been experimenting with Multiple Point Statistics (MPS). Multiple-Point Statistics is an emerging technique, which can be used to generate multiple, geologically realistic, realizations of data that displays complex non-linear features. MPS uses a conceptual model of the geology, called a Training Image (TI), to infer these high-order spatial relationships. The multiple realizations allow for an assessment of the geologic uncertainty, which can be further combined with grade simulations to generate a more complete picture of the true uncertainty of a mineral deposit.

Jan 1, 2011

By Svatopluk Zeman, Zbynek Akstein, Jiri Pachman, Ahmed Elbeih, Marcela Jungova

BCHMX (cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole or Bicyclo-HMX) was studied as an energetic component of three different plastic explosives based on three matrices: C4 matrix, semtex10 matrix and silicone matrix. The original plastic explosives, Composition C4 - based on RDX (1,3,5-trinitro-1,3,5-triazinane), Semtex 10 explosive based on PETN (pentaerythritoltetranitrate) and plastic RDX-silicone, were included for comparison. Sensitivity and performance parameters were studied.

Jan 1, 2011

By Jesse R. Jacobson

A large casino complex in Cherokee, North Carolina recently underwent a $633 million expansion that involved substantial foundation challenges. The site is located in a valley on the southern edge of the Great Smoky Mountains National Park, where subsurface conditions typically consist of varying thicknesses of fill overlying alluvium, residuum, partially weathered rock and rock. The fill and alluvium contain cobbles and boulders as large as several feet in diameter. The residuum and partially weathered rock are very thick in some areas, and the depth at which consistently high quality rock is encountered is highly variable. To reduce the foundation costs for the expansion, continuous flight auger (CFA) piles were proposed in lieu of micropiles. CFA piles are not generally used in this geologic environment and concerns regarding their selection included: (1) an uncertainty that CFA piles could be successfully constructed given the difficult conditions and (2) a lack of regional data regarding unit resistance values and load transfer characteristics. To address these concerns, a design-phase test program was undertaken to evaluate pile constructability, develop an understanding of the load transfer behavior, and establish the required pile lengths. The program included soil test borings, shear wave velocity measurements, timed auger probes, instrumented pile load tests and observation of exhumed piles. It was demonstrated that CFA piles could be advanced through the fill, cobble/boulder-laden alluvium, residuum and into the partially weathered rock, albeit with some limitations. Under axial loading, the pile response was very stiff and relatively high unit resistance values were measured. Pile instrumentation allowed for the evaluation and use of design pile lengths shorter than that tested, and the overall reduction in pile lengths yielded a 40 percent reduction in foundation cost. In general, CFA piles were determined to be a suitable, economical foundation alternative.

Jan 1, 2011

By D. Küster, G. Franken, P. Schütte, J. Vasters

The CTC (Certified Trading Chains) mineral certification system has been piloted in Rwanda since late 2008. CTC project implementation is jointly driven by the Federal Institute for Geosciences and Natural Resources (BGR) and the Rwanda Geology and Mines Authority (OGMR), in cooperation with other national stakeholders. Five Rwandan mineral producers participate in the CTC project with their flagship mining concessions. Based on independent third-party audits, CTC certifies supply chain due diligence measures of these companies engaged in the artisanal mining sector through on-the-ground assessments of mining conditions, transparency, as well as mineral origin and traceability. The CTC system thus allows responsible mineral producers and their clients to verifiably demonstrate supply chain due diligence and good governance in conflict-affected and high-risk areas.

Jan 1, 2011

By R. Gensemer

A number of state and federal agencies are calling for development of aquatic life criteria for conductivity. These aquatic life criteria or ?benchmarks? are based on observed correlations between conductivity and benthic macroinvertebrate community composition, generally measured by composite metrics or indices. However, development of an aquatic life criterion for a composite variable like conductivity is made difficult by a number of factors. Based on a database from West Virginia, observed patterns of invertebrate community composition versus conductivity may instead be related to a combination of abiotic (e.g., ionic composition, habitat) and biotic (e.g., life history, colonization potential) factors. Many benthic invertebrate taxa also do not respond to increasing conductivity in a consistent relationship. Many states have determined that a composite variable, like conductivity or TDS, is not appropriate for criteria development, as many studies have shown that toxicity varies as a function of ion composition and can be mitigated by elevated hardness. We conclude that the relationships between conductivity and changes in benthic macroinvertebrate community composition are neither strong nor reliable enough to warrant derivation of a criterion based solely on conductivity.

Jan 1, 2011

By K. R. Griffin

Explosions in underground coal mines have been a serious safety concern since the advent of mining; despite significant technological advances, they are still occurring. Parameters such as barometric pressure, geological changes, and changes in ventilation can contribute to an explosion. These factors can be monitored with available and developing technologies to create algorithms that predict when explosions are more likely to occur. This paper reviews current underground atmospheric monitoring systems and related regulations around the world. In addition, suggestions for improvement and implications for explosion prevention are discussed.

Jan 1, 2011

By Jacob Chacko

The Izmit Bay bridge, a 3-km-long suspension bridge crossing of Izmit Bay, Turkey is planned to be constructed in one of the most seismically active places in the world. The site, which has the potential to experience significant earthquakes associated with the relative motion accommodated on the North Anatolian Fault, is underlain by deep deposits of soft soils, and areas of unstable and liquefiable soils. Characterizing the seismotectonic setting, foundation soil conditions, potential fault locations, as well as other geohazards was a critical component for the project concessionaire to finance the project and obtain meaningful bids for bridge design and construction. Given the Build Operate Transfer (BOT) funding mechanism, executing this work in the least possible time was critical to the concessionaire?s financing scheme. Fugro was retained to provide geotechnical, geological, and seismological evaluations for the project region, and to generate data for contractors to develop reliable designs and bids. The uncertainties in these data made it difficult for the BOT concessionaire to finance the project and tender Bridge design and construction. The investment in an early and comprehensive site characterization program to evaluate and quantify those uncertainties allowed the concessionaire to save schedule, provide a robust bid basis to bridge contractors, and persuade banks to finance what was perceived to be a relatively high risk project.

Jan 1, 2011

By J. J. Swanepoel

Titanium nitride in upgraded nitrided ilmenite (bulk of iron removed) can selectively be chlorinated to produce titanium tetrachloride. Except for iron, most other components present during this low temperature (ca. 200°C) chlorination reaction will not react with chlorine. It is therefore necessary to remove as much iron as possible from the nitrided ilmenite. Hydrochloric acid leaching is a possible process route to remove metallic iron from nitrided ilmenite without excessive dissolution of species like titanium nitride and calcium oxide. Calcium oxide dissolution results in unrecoverable acid consumption. The leachability of nitrided ilmenite in hydrochloric acid was evaluated by determining the dissolution of species like aluminium, calcium, titanium and magnesium in a batch leach reactor for 60 minutes at 90°C under reflux conditions. The hydrochloric acid concentration (11%, 18% and 25%), initial acid-to-iron mole ratio (2:1, 2.5:1 and 3.3:1), and solid-to-liquid mass ratio (1:8.33 to 1:2.13) were varied. The results indicate that a hydrochloric acid concentration of 25 wt% supplied in a 2:1 acid-to-iron mole ratio would produce the most favourable upgraded nitrided ilmenite product. The dissolution of iron in this solution reached 97 per cent after only 60 minutes. The total dissolution of calcium and titanium species was 0.01 and 0.11 wt% respectively. Hydrochloric acid can therefore be used as lixiviant to remove metallic iron from nitrided ilmenite. Keywords Titanium nitride, upgraded nitrided ilmenite, hydrochloric acid leaching, metallic iron dissolution.

Jan 1, 2011

By M. Massinaei, M. R. Yarahmadi, S. Zeidabadi, M. Oliazadeh

"Although the majority of new flotation column installations continue to be for cleaning or recleaning, an increasing number of flotation projects are specifying columns for roughing or scavenging duties. NICICO has recently installed flotation columns operating in rougher, cleaner and re-cleaner circuits at three new copper concentrators; Miduk, Sungun and Sarcheshmeh. Miduk is probably one of the unique operations that use flotation columns in a rougher circuit. The Miduk rougher circuit comprises five CISA parallel columns. The rougher concentrate constitutes 88% of final concentrate and reports to concentrate thickener. The rougher tailings are scavenged with ten 50 m3 mechanical cells. The scavenger concentrate is then reground and cleaned in three 3.2 m columns in parallel. The cleaner tailings are scavenged in six 50 m37mechanical cells. The cleaner tailings along with the rougher scavenger constitute final tailings.In Sarcheshmeh, the cleaner concentrate is re-cleaned in a column. The column tailings are sent back to the cleaning circuit and the concentrate is reported to the concentrate thickener.This paper reviews performance details of the flotation columns utilized in rougher circuits at Miduk and compares their metallurgical performances in an industrial scale with columns at cleaning circuits for copper flotation. Practical limitations for applying the flotation columns in rougher circuits will be discussed in details.INTRODUCTIONThe use of flotation columns has grown rapidly since the first successful commercial application at Mines Gaspe, where columns were used in a cleaning circuit to float molybdenite. Early applications of columns were restricted to replacing or adding final cleaning stages in existing circuits. Columns can achieve superior cleaning as compared to conventional cells due to their ability to support a large froth depth and the use of water for washing froth. Wash water travels down through the froth and crosses the pulp/froth interface, replaces the entrained particles reporting to the froth from pulp and improve the concentrate grade."

Jan 1, 2011

By R. A. Harris

In this study Pt-Al thin films were prepared via electron beam physical vapour deposition (EB-PVD) with an atomic concentration ratio of Pt25:Al75. These films were heat treated at temperatures ranging from 150°C to 650°C for annealing times from 4 to 60 minutes. The resulting microstructure of these thin films were obtained via secondary electron imaging used in conjunction with depth profiling with the aid of scanning auger microscopy (PHI 700).Elemental maps of the micrographs were obtained. Simulations, based on a chemical potential Monte Carlo method1, were run for various interaction parameters. From these simulations theoretical depth-profiles and proposed microstructures were obtained. These were compared to the experimentally measured depth profiles and elemental maps. Keywords Monte Carlo, chemical potential, depth profile, Pt-Al thin films.

Jan 1, 2011

By D. Preece

The mining and oil industry employs techniques such as geologic mapping, core drilling and electromagnetic and potential field techniques to explore for new deposits. Since new discoveries of major near-surface ore bodies are becoming progressively rare and since traditional exploration methods are unable to resolve ore bodies deeper than about 500m, high-resolution seismic reflection techniques show great potential for exploration to much greater depths down to almost 3km.

Jan 1, 2011

By Xueyi Guo

The total production of nonferrous metals in China is 31.35 million tons in 2010, which ranks first in the world for the past ten years. Large quantities of solid wastes including slag, residue, ash, and dust are produced every year in the production of nonferrous metals. These secondary resources are renewable, not only contain abundant valuable metals which can be recycled by metallurgical processing, but also could eliminate the pollution to the environment. In this paper, the status quo of the main nonferrous metals recycling in metallurgical industries in China was summarized, and the future development of waste processing and resource recycling was prospected.

Jan 1, 2011

By Bill Dershowitz

Consider a deep gold orebody with grade of 4 g/t (0.11 oz/st). At the time of this writing, with gold prices at historic highs, it could be a good, but not great, prospect. But if it is a vein deposit, and those veins are 200 g/t (5.8 oz/st), it would be significantly more attractive if there was a way to produce directly from those veins, leaving the rest of the rock in place. [Figure 1 The red around each of the four injector wells shows areas of high pressure, where the lixiviant fluid is pumped into the rock mass, with orange and yellow indicating dissipated pressure. The black lines indicate some of the fracture pathways through which the lixiviant, with absorbed metal, flows toward the central recovery well where low pressure is indicated in blue. Lixiviant is pumped out through the recovery well. Image courtesy of Golder Associates.] There is a way to do this, in situ leach (ISL) or solution mining. It has been a viable commercial technology for more than five decades.

Jan 1, 2011

By Wayne Bell, Matthew Andriese, Shuqian Xie, Jiann-Yang Hwang, Zhiwei Peng

"Pyrolyzed carbons are generally known as good microwave absorbers and their dielectric properties still remain to be fully explored. In the present study the dielectric properties and dielectric polarization-relaxation phenomenon of a typical activated carbon was investigated. The experimental results indicate the complex permittivity is highly dependent on temperature and frequency. The decrease of permittivity with increasing temperature from room temperature to ~100 °C is probably ascribed to the release of the water vapor adsorbed on the surface of activated carbon, and the variations of permittivity with temperatures between 100 °C and 450 °C in the frequency range of 300 MHz to 3000 MHz are mainly attributed to the decreased relaxation time of dielectric polarization.IntroductionPyrolyzed carbons have been identified as excellent microwave absorbers owing to their high dielectric and electrical loss under microwave irradiations. Among them, activated carbon continues to attract more and more attention from researchers. Due to its special physical properties, the production, modification and regeneration of activated carbon with the assistance of microwave have been widely studied over the last few decades [1-6]. However, only few attempts have been applied to explore the dielectric properties of such materials due to the complexity and variability of their organic precursors and activation processes [7,8]. In order to shed a light on this problem, a typical sample, Norit® A Supra USP powdered activated carbon, was adopted to perform dielectric characterization, which may provide useful information for its wide application in the fields of purification, energy (hydrogen) storage and so on."

Jan 1, 2011

By Kuwauchi. Y., M. Barati

Recycling of dust using a rotary hearth furnace (RHF) has gained considerable attention in the past two decades for the sustainable production of steel with less environmental impact. In order to further promote the recycling of electric arc furnace dust and carbonaceous wastes using the RHF process, a mathematical model was developed to predict the reaction behaviour of dust-reductant composites. The reduction kinetics of zinc and iron oxides as well as the volatilization behaviour of volatile matter in the reluctant were considered. The modeling approach and some preliminary results are presented in this article.

Jan 1, 2011

By Bern Klein, Randy Blaskovich, Reem Roufail

"Morphology is a tool that is rarely used for mineral breakage mechanism evaluation. Ground particles are typically assessed for their size distribution. They are also visually analyzed using image analysis. However, image analysis is not a comprehensive evaluation of the particle surface texture. It evaluates particle’s size parameters such as area, diameter, and perimeter amongst other features. On the other hand, morphology analysis takes the particle assessment to another level of detail. Morphology analysis evaluates particles’ roundness, elongation and angularity that would indicate the degree of roughness of the particle. According to Roufail and Klein (2009), rougher surfaces are generated due to breakage along grain boundaries – intergranular breakage. Mill operation, particularly mill speed, dictates the dynamics in the mill. Stirred mills are known to break the particles via abrasion under standard operation. However, if the dynamics of the grinding media in the mill are changed, the particles could be more exposed to impact and compression loading that would lead to a different mode of breakage.In this paper, the effect of material properties and mill operating conditions on particle morphology will be studied. Hard non-sulfide versus soft sulfide minerals are compared, namely quartz and galena, respectively. Extreme mill speeds are tested covering the range of 1000 to 2000 rpm for a 4-litre Netzsch (ISA) mill. In addition to particle size distribution, micro-analysis is executed in the form of morphological analysis using a tested manual roughness point counting technique.INTRODUCTIONGrinding in general and stirred milling in particular are processes that are used to break particles to liberate metal-bearing minerals for further separation downstream. The energy required to achieve the target particle size versus maximum possible liberation has been studied intensively and it is usually the breaking point for the grinding system chosen in a process flowsheet. Operating conditions are dictated by the energy consumption. Becker et al. (2001) related different forms of energy such as input, specific, volume/mass specific energies to stress intensities and final product fineness. Other research studies focused on energy input in a stirred mill (Zheng, Harris and Somasundaran, 1996)."

Jan 1, 2011

By Christopher Laughton

A new underground laboratory is under construction at the recently closed Homestake Gold Mine, Lead South Dakota, United States of America. The Deep Underground Science and Engineering Laboratory is designed to meet the needs of an international group of scientists and engineers interested in conducting fundamental and applied research at depth in the Earth’s crust.

Jan 1, 2011