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By Yanxu Shen, Cheng Liu, Zhijie Chen, Hao Chen, Huimin Gao, Zijie Ren

Fluorite, a kind of critical non-metallic minerals, is the primary source of industrial fluorine. Sodium oleate (SO) is commonly used as the collector of fluorite ores. However, because of its some features (such as the low solubility, high solidifying point, and poor dispersion of SO) at low temperatures, it profoundly inhibits its collecting ability as well as the flotation performance. Herein, we have developed a low-temperature-resistant collector for the efficient flotation separation of fluorite from quartz. The advantages and disadvantages of the SO and sodium petroleum sulfonate (SPS) were analyzed by comparing the performance under different temperature conditions. The results of flotation tests suggest that SPS exhibited much better collecting performance than SO under low temperature. The flotation mechanism of the two collecting agents were further analyzed by contact angle measurements, zeta potential measurements, Fourier-transform infrared spectroscopy (FT-IR), and flotation kinetics. The results indicated that both collectors can selectively undergo electrostatic and chemical adsorption with fluorite, with no adsorption on quartz surface. The sulfonic acid group in SPS is a hydrophilic functional group, which has a relatively higher solubility in water. Therefore, the water solubility of SPS is better at low temperatures.

Sep 30, 2021

By E. Minnaar, P. J. Cilliers, M. Bellino, L. M. Roux, R. Dye

The classic technique to remove impurities in a cobalt stream is selective precipitation. This is usually followed by re-leaching to produce an advanced electrolyte for cobalt electrowinning. Although this technique ensures an adequate cobalt concentration in the electrowinning circuit, some of the consequences include unwanted losses through the numerous selective precipitation steps resulting in lower recoveries. One plant that currently utilizes selective precipitation is the Luilu Metallurgical Plant (Luilu) in the Democratic Republic of the Congo. This paper evaluates the benefits of using solvent extraction technology as a purification step in the Luilu Process with the aim of further increasing the overall cobalt recovery and to ensure that a suitable cobalt concentration in the advanced electrolyte is achieved. The implementation of a solvent extraction-electrowinning process is found to be beneficial in terms of achieving improved recoveries and cobalt cathode quality, however there are many other factors that impact the success of converting from the classic precipitation process used at Luilu.

Jan 1, 2007

By Matthias Baeßler, Markus Herten, Ernst Niederleithinger, Steven Georgi

"Abstract: BAW and BAM have performed a large scale comparison and calibration test on static and dynamic load capacity evaluation of bored piles in glacial sandy soil. The test was performed using eight piles at the BAM test site for technical safety at Horstwalde 50 km south of Berlin. The test area has been prepared and investigated in great detail using boreholes, cone penetration tests, pore pressure sensors and geophysical methods to assure controlled conditions for all piles and tests. The piles (10 m length, 0.9 m diameter) are mainly friction piles (low toe resistance) and have been checked by integrity testing. Five piles have been tested by five contractors using the dynamic method in a blind experiment, the other ones piles by static load and/or later on by the dynamic method. Some piles have been equipped with additional fibre optic instrumentation which proved to be robust and helpful in interpreting the results of static, dynamic and integrity tests. We have experienced a deviation of the dynamic load test results gathered in the blind experiment from the static values of up to 20% in most cases, sometimes even up to 30%. This can be related to the known soil inhomogeneities, interpretation and modelling in CAPWAP and method inherent uncertainties. In cases where the static values were known by the testers for calibration, the deviations were significantly smaller. It has to be taken into account, that the two static load tests showed different results as well. Due to the low toe resistance, use of a big drop weight (11 tons) and large drop heights most piles suffered from cracking, which was clearly seen in follow up integrity tests and confirmed by excavation. The piles are available for further research.IntroductionBored piles are used in many construction projects of the German waterways authorities, e. g. bridges, piers or locks. Their load carrying capacity varies with pile type and geometry as well as soil type, parameters and structure and is thus not easy to calculate in advance. Dynamic pile testing as a cost effective addition or replacement for expensive load tests is accepted in many places (Beim and Likins 2008) but still doubted in others. Inspired by the international prediction event for piles in residual soil carried out in the frame of ISC’2 (Viana de Fonseca and Santos 2008), governmental research institutes have designed an experiment in a geological setting typical for glacial and post-glacial areas in northern Germany. Some results have already been presented by Niederleithinger et al. (2012), Herten et al. (2013) and Baeßler et al. (2013). It was intended to perform a blind test for load capacity estimation using dynamic pile testing on six drilled shafts involving five test crews. Two other piles would have to be tested thereafter using static and dynamic methods."

Jan 1, 2014

By Ahmad F. Souri, Murad Abu-Farsakh

"In this study, the static lateral resistance of vertical and battered pile groups was analyzed using 3D finite element analysis. The battered pile group finite element model was verified using the results from a case study performed on the M19 pier foundation of the I-10 twin span bridge in Louisiana. The vertical pile group model was created by adjusting pile inclinations of the verified battered pile group model. The finite element models utilized nonlinear constitutive models for materials behavior and a soil-pile interface model. The results showed that the battered pile group had greater lateral resistance than the vertical pile group with 60-70% lower pile cap displacement. The largest lateral load share was found in the middle rows in the battered pile group, while it was in the leading row for the vertical. The soil resistance profiles showed that the vertical pile group mobilized greater soil resistance compared to the battered pile group.INTRODUCTIONThe lateral resistance of a pile-soil system depends on both pile stiffness and soil reaction. The soil reaction is a nonlinear function of deflection, depth, pile stiffness, and soil stiffness and strength. The lateral capacity of single piles is evaluated at the maximum deflection limit, and can be predicted using established methods such as the p-y curve method (e.g., Matlock 1970, Reese et al. 1974), elastic solution by Poulos and Davis (1980), the strain wedge model (Ashour et al. 2004), and the finite element method (e.g., Yang and Jeremic 2002, Comodromos and Pitilakis 2005, Isenhower et al. 2014). For pile groups, the lateral capacity of a pile-in-group is less than the isolated single pile case because the soil in front of the pile-in-group is weakened by the overlap of stress zones from surrounding piles. The latter is referred to as the shadowing or group effect (Fig. 1). Prediction of the lateral capacity for pile groups is based on the p-y curve method for single piles with the use of empirical factors called “p-multipliers”. The p-multipliers accounts for the shadowing effect, and are a function of pile-pile spacing and soil type (e.g., Brown et al. 1987, 1988, McVay et al. 1995). Moreover, the lateral capacity of pile groups is also influenced by vertical load, piles arrangement, and slenderness ratio (e.g., Rao et al. 1998, Patra and Pise 2001, Ilyas et al. 2004, Hussien et al. 2012).Battered piles refer to piles installed at an angle with respect to the vertical to increase their lateral capacity. The greater lateral resistance is achieved by the additional axial reaction in the pile. Battered piles are called “negative battered” when inclined in the load direction, and “positive battered” when inclined opposite to the load direction (Fig. 1). Previous studies concluded that the lateral resistance is highest in positive battered piles followed by negative battered and vertical piles, respectively (Murthy 1964, Meyerhof and Yalcin 1993, Zhang et al. 1999)."

Jan 1, 2017

By Patrick J. Hannigan

A comparison of 40 statically and dynamically load tested piles was performed to evaluate the variation between testing methods. This evaluation indicated an agreement of 10% to 15% could be obtained when the available static resistance is fully mobilized by both methods and when time dependent capacity changes are minimized. Dynamic pile testing recommendations for minimum induced impact force, ram weight to pile weight ratio, and considerations for time dependent capacity changes are presented.

Jan 1, 1987

By Alan B. Wagner

Data from seven instrumented pile load tests in Milwaukee, Wisconsin and two other instrumented load tests reported in the literature, one in Evanston, Illinois and one in Houston, Texas were reviewed. The data were for pipe piles having diameters from 9-5/8 inches to 18 inches, driven to depths between 36 and 96 feet. These data were used to develop a relationship between effective vertical stress and unit side friction and unit end bearing. These relationships were based on readily measured soil parameters, undrained shear strength, Cu, and Standard Penetration Test (SPT) values. This Beta (ß) and Nt approach and four other methods were then used to calculate the bearing capacity of the nine cases analyzed. The results from each of the methods are compared with the measured results.

Jan 1, 1991

By J. A. Finch, D. Lin

The robustness of the large-sections correction procedure, Hill's fast approximation, Barbery's correction and the PARGEN correction was examined by comparing their ability to reconstruct the true liberation distribution using sectioning data from computer-generated spheres. The results indicate that the flexibility of a correction procedure is related to the assumptions it makes about the continuity of the liberation distribution, locked-particle characteristics and ore texture. Overall, the large-sections procedure appeared to be the most generally applicable. The Hill fast approximation performed well, but this was probably because it partially incorporates the sphere model; the performance of the PARGEN and Barbery corrections varied from case to case.

Dec 1, 1995

By R Lastra, J. A. Finch

An artificial standard material has been developed and used to examine the robustness of some of the procedures for correcting stereological bias. Different mineral liberation distributions were constructed from the standard material. The particles were mounted, sectioned and the sectioning data measured with an electron microscope interfaced to an image analyser. Four correction procedures were used and the corrected and true liberation distributions compared. It was found that the large-sections correction provided a simple, uncorrupted correction. Hill's fast approximation performed well except in cases of narrow liberation distributions; the sectioning data appeared to support the assumption that the locked section and locked particle distributions are identical. Barbery's correction performed well in most cases, having difficulty only with the very irregular liberation distribution. The PARGEN correction was able to provide a good estimate of the true amount of free material, but had difficulty in predicting the locked particle distribution

Jun 21, 1905

By C. L. Schneider, C. O. Gomes, R. P. King, J. A. Finch, D. Lin

Discussion is presented by Prof. King and Dr. Schneider of the paper by Lin, Gomez and Finch published in Trans.IMM C, vol.104, 1995, p.C155-C161. They conclude that the correction procedures used for simulated observations of simulated capped spheres are not reliable when applied to mineralogical data and that their relative ranking should not be extrapolated to other situations. Properly regularised solutions obtained with the use of appropriate kernels can be safely used for routine mineral liberation work and can be calibrated accurately against real mineralogical samples in the laboratory

Jun 19, 1905

By D. Bois, F. P. Hassani, M. Hossein

"A growing environmental awareness hos prompted the mineral industry to seek innovations in waste management and technology. It is estimated that over 500 million metric tonnes of solid waste each year are rejected by the Canadian mineral industry. This waste hos to be disposed of in the most environmentally and economically acceptable manner.An extensive study has been conducted to estimate the cost of implementing total tailings fill from a waste disposal point-of-view as an alternative to large-scale surface disposal of tailings. The cost of waste disposal at the surface (tailings pond), and underground (total tailings fill) for three Canadian mines which have taken part in Quebec Mine Survey conducted in 1992 are analyzed. Surface disposal is the most economical and common method of mine waste disposal in Canada. Total tailings backfill as a method of waste disposal is technically feasible but cannot be regarded as more economic than surface disposal in all . It is important to remember that while surface disposal costs are rising, due to tighter legislation and more environmental pressure on governments; the costs of preparing and placing total tailings backfill is still falling as the technology improves."

Jan 1, 1994

By A. Casuge, D. Lee, J. A. Finch, C. C. Sui

The adsorption of copper and lead und their subsequent xanthate uptake were compared at pH 3.0, 6.0 and 9.2 on both fresh and oxidized sphalerite. The extent of adsorption and the rate of adsorption were strongly dependent on pH, with the highest adsorption of Cu and Pb being at pH 9.2. In the presence of both Cu and Pb, Cu adsorption was enhanced and Pb adsorption was suppressed. The adsorption kinetics of Cu and Pb were characterized by two- and three-stage adsorption processes, respectively. The exchange ratio of Cu to Zn was about one and that of Ph to Zn was greater than one and varied with pH. The uptake of xarlthate on "activated" sphalerite was dependent on pH. The rnaximum uptake was found to be at pH 6.0 for Cu-activated sphalerite artd at pH 9.2 for Pb-activated sphalerite. A measure of "activation strength" based on inetal ion adsorption and xanthate uptake was introduced. The activation strength of Cu to Pb was about one at acidic pH, but it was higher at neutral (pH -6) and alkaline (pH -3) conditions. The oxidation of sphalerite decreased Pb and, especially, Cu adsorption and decreased xanthate uptake.

Jan 1, 2000

By Serdar Aktaş, Özgün Küçükoğlu, Burcu Nilgün Çetiner, Mehmet Hakan Morcalı

This study compares the cementation performance of metallic iron, metallic aluminum, and metallic tin in terms of the reaction conditions and parameters in synthetic antimony chloride solutions. The effects on the antimony recovery (%) caused by the cementators’ types, stirring speed, reaction time, and temperatures were explored thoroughly. The cementation kinetics of antimony were also explored for each cementator. The activation energies were determined to be 10.99, 9.09, and 13.58 kJ mol– 1 for Al, Fe, and Sn, respectively. The results reveal that the reaction is diffusion controlled, and comparable results were obtained for each cementator. At 25 °C, 40 mg of iron powder was found to reduce all antimony ions (i.e., approx. 99% recovery), but even when 100 mg of Al and Sn cementators were used, the antimony recovery did not reach 100%. This result shows that iron is the best candidate to cement antimony out of the solution.

Jan 28, 2022

By Hiroaki Sakurai

Using batch reactors equipped with CO and CO2 gas sensor, CO oxidation over Au catalysts in room air has been investigated and compared with Pt catalysts. For both Au and Pt catalysts, the logarithm plot of CO concentration data during initial 10 min are well fitted by straight line, which mean the first order dependence on the CO concentration between 10 and 10,000ppm. The rate constant value (k) over Au and Pt catalyst generally decrease with increasing initial CO concentration above 100ppm. The value decrease especially rapidly between 100ppm and 1,000ppm over Pt catalysts, which should be due to the strong adsorption of CO on Pt. The k value over Au catalyst has become ten times or more as large as the Pt catalysts at 1,000ppm. Already for the initial concentration of 100ppm CO, the strongly adsorbed CO on Pt metal has been clearly observed by FT-IR during the reaction over Pt/Al2O3. A part of the strongly adsorbed CO has been remained on Pt after the disappearance of gas phase CO, and has gradually changed to gas phase CO2. Such strongly adsorbed species on Au has never been observed on Au/TiO2 under the same reaction conditions. These features of Au catalysts are favorable for indoor air purification.

Oct 1, 2003

By C. Musingwini, G. Njowa, M. Burnett, C. C. Birch

From 2022 to 2040, the global demand for mineral commodities is projected to increase by fourfold to six-fold, largely due to traditional drivers such as population growth and urbanisation compounded by the adoption of decarbonisation technologies that are more mineral intensive than fossil fuel technologies. To meet this projected demand, companies operating in the minerals industry should accelerate the development of mineral projects. Since most of the companies generally operate in multiple geographical, regulatory or legislative jurisdictions, it is critical that the information on Mineral Resources and Mineral Reserves they report on in the public domain should be comparable and consistent across different jurisdictions. The Committee for Mineral Reserves International Reporting Standards fosters alignment of national and regional mineral reporting codes through an internationally accepted template that creates common technical understanding of definitions, classification, estimation processes and the Public Reporting of Exploration Results, Mineral Resources, and Mineral Reserves. The Committee for Mineral Reserves International Reporting Standards Template-based codes guide reporting at respective national and regional levels. Since mine planning is critical in the conversion of mineral resources to mineral reserves, a shared technical understanding should aid comparability of mine planning results. However, differences persist in the way mine planning results are reported. Unlike most previous studies, which have primarily focused on comparing mineral reporting codes, this paper updates and extends such comparisons by exploring how similarities or differences in reporting should influence the mine planning process. It also recommends some principle and process changes to assist mine planning professionals to improve consistency and comparability in reporting mine planning results.

Mar 30, 2026

By Priscila Tavares de Paula, Márcia Mika Saito, Henrique Gonçalves Teixeira, Felicio de Freitas Simoões

In this paper a sample of the apatite flotation from Cajati-SP was studied. Four alternatives of depressants were analyzed: corn starch, cassava starch, sodium hexametaphosphate with corn starch and sodium silicate with corn starch. The cassava starch had a gain of 7.5% in the metallurgical recovery and a collector consumption 13.8% greater than corn starch. Alternatives with hexametaphosphate and silicate sodium had a loss of 6.7% and 7.8% in recovery respectively in comparison with corn starch.

Oct 3, 2019

By Barnes E. L S

With the introduction of diesel powered loading and hauling equipment, a number of Australian mines producing less than one million tonnes per year from shallow orebodies have been dev- eloped by decline. This method of entry has the advantage of providing both flexible access and early prod uction. However, as the depth of mining increases so does the operating cost of haulage, due to the need for more trucks. This cost, together with increased capital requirements for both equipment and infrastructure, leads to the point where the alternat- ive of shaft hoisting must be con- sidered. With an established decline it is possible to provide an ore hoisting shaft using a drilled raise with subsequent stripping to a suitable size. Using DCF techniques and known equipment operating and capital costs, an economic comparison of the two systems is made to determine the limit- ing depth to which truck haulage can be used.

Jan 1, 1973

By C. Liu, G. Zhu, Y. Liao

"The effect of particle size on the flotation kinetics of a low-rank coal was compared using air bubbles and oily bubbles. Five kinetic models were applied to the data from the tests to derive the relationships between the flotation rate constant, the ultimate recovery, and the particle size fraction. The results show that oily bubble flotation (OBF) resulted in a lower ash content and higher combustible recovery than air bubble flotation (ABF), especially for the -125 ??m size fraction. It was found that the flotation of a low-rank coal in individual size fractions using air bubbles and oily bubbles can be best described by a first-order model with rectangular distribution of tendency to float and the classical first-order model respectively. OBF yielded higher ultimate combustible and ultimate ash recoveries. The flotation rate constants for OBF were higher in all the models except for the fully mixed reactor model. The ultimate recovery values and modified rate constants first increased and then decreased as the size fraction decreased. The trend of the flotation rate constants as a function of the size fraction was similar in all the models except for the fully mixed reactor model. IntroductionFroth flotation is a physical-chemical separation method that is widely used in coal beneficiation for the separation of fine coal particles from associated minerals in water slurries. Since the cumulative recovery of a component in the concentrate is proportional to flotation time, the flotation process can be considered as a time-rate recovery process (Emad, Mohammad, and Bahram, 2010). Therefore, the general mathematical flotation models that incorporate both a recovery and a rate function can describe flotation time recovery profiles.The kinetics of coal flotation, as a measure of coal recovery as a function of time, have been studied in detail by many researchers. Different kinetic models have been proposed and published in the literature. The order and the rate constant are strongly dependent on the flotation conditions, such as the particle size and size distribution, the bubble concentration, the reagent concentrations, and the operating parameters (Zhang et al., 2013). The particle size has been reported to affect the flotation kinetics to a great extent (Yoon, Luttrell, and Asmatulu, 2002; Ntengwe and Witika, 2011). Numerous researchers have studied the aspects of flotation kinetics while paying special attention to particle size (Meftuni and Ibrahim, 1997; Rubinstein and Samygin, 1998; Graeme, 2012). However, the effect of particle size on the flotation kinetics of a low-rank coal has been relatively little discussed."

Jan 1, 2017

By Tchingis Lekhatinov, Lev Filippov, Vyacheslav Severov, Alexandre Matinin, Victor Samyguin, Inna Filippova

"Comparison of flotation efficiency of the new multi-zone flotation cell (MZFC) and different conventional cells was carried out at lab and pilot scales on the various samples: high contrast pyrite tailings and old copper containing tailings. MZFC is a cell of intensive flotation, which provides optimal hydrodynamic conditions for all flotation sub processes. Enhancing of particle attachment, creation of conditions for coalescent flotation, selection of spatially separated zones according to optimal hydrodynamic conditions for flotation sub-processes are proposed as main principles to design an MZFC. The bubbles/pulp stratification was pointed out as a limiting step in the existing intensive flotation machines. Two strategies to improve bubbles/pulp stratification in the MZFC were studied: (a) impact of pulp-bubble jet to the surface of a prismatic insert inside of cell, which provides the detachment of low hydrophobic particles from bubbles, and (b) profiling the pulp/bubbles jet from the reactors due to a specific geometry of cell walls. The new continuous MZFC devices were demonstrated similar or higher efficiency in comparison with laboratory batch flotation cells for pyrite flotation. Higher flotation efficiency (82%) with pure pyrite concentrate (51.2% of sulfur) and a recovery level of 92% was obtained in MZFC when the cell with stratification by impact was used. Similar results were obtained with old Cu-containing tailings. Although MZFC had 1.5 times greater yields of concentrate than a batch flotation cell, it provided the increase of chalcopyrite recovery by 29.4% and concentrate grade by 4.8%. An original organization of pulp/bubbles stratification in the separator part of the new intensive flotation machine using variable geometry inserts allowed the best flotation selectivity with a bubble mineral loading coefficient 1.5 fold higher than the laboratory mechanical or pilot cells."

Jan 1, 2014

By H. Cevizci

"Numerical simulation of the plaster stemming method (PSM) was performed and compared with the conventional drill cuttings stemming method (DCSM). Many earlier in situ tests have proved that PSM can use the blast energy more efficiently than DCSM. Despite PSM generating more blast vibrations, it has advantages over DCSM such as better fragmentation and lower cost per unit volume of rock blasted. In this study, numerical simulation with Autodyn software using a 2D tool was employed to prove the efficiency of plaster stemming by comparing parameters such as pressure, Y-velocity, Y-force, internal energy, acceleration-Y, and compression. For example, the maximum pressure attained at the top of explosive column was 7 395 MPa for DCSM whereas it was as high as 11 945 MPa for PSM. Most of the computed parameters were significantly higher in PSM than those obtained for DCSM. This paper is the first study elucidating the efficiency of PSM by numerical simulation. It is concluded that PSM can save substantial amounts of money and effort. IntroductionThe stemming of blast-hole collars in surface mines with an inert material redirects blasting energy to the rock more efficiently, thus the blast-induced energy is utilized more effectively in breaking rock. With proper stemming, the gases should not escape due to loose stemming material. More efficient stemming with better confinement therefore increases the blast fragmentation. In addition, the distance of scatter is increased, giving rise to a looser rock pile that can be more easily loaded and transported. In order to improve the performance of a blast, stemming is used to help maintain the gas pressure over time (Konya and Konya, 2018). Proper stemming has been shown to increase the explosive efficiency by over 41% (Snelling and Hall, 1912).The most common stemming material in open pits and quarries is drill cuttings because of their ready availability at blast sites and the drill cuttings stemming method (DCSM) is a low-cost method. However, it has a major disadvantage in that dry drill cuttings eject very easily from blast-holes during an explosion, thus a great percentage of the blast energy is wasted and lost to the atmosphere. Cevizci (2012, 2014, 2013, 2017) studied blasting parameters in open pits and obtained better results with the plaster stemming method (PSM) in many limestone, basalt, and clay quarries. Moulding plaster is preferred for stemming because of the fast hardening time of 25–30 minutes."

May 1, 2019

By L. Gutierrez, R. Yepsen, F. Alarcón

Chile is the world's largest copper producer which is mostly in the form of sulfides for which froth flotation is the most efficient concentration process. As a result a concentrate that contains high concentrations of copper sulfides such as chalcopyrite, chalcocite and enargite is obtained. In the last decades processing of ores containing high concentrations of enargite (Cu3AsS4) has continuously increased in Chile, which is related to the fact that ore deposits nawadays are more heterogeneous and complex. Enargite is a mineral that contains arsenic and its presence in the copper concentrates implies severe penalties. In addition, the shortage of fresh water has driven the search for new alternative sources of water, among which seawater has proved to be one of the most attractive. The objective of this research is to study the behavior of the enargite in the process of flotation using seawater, and at the same time to compare its behavior with the results obtained using conventional water. The study was carried thorugh micro-flotation tests using pure samples of enargite, at pH values ranging from 4 to 11, both in fresh and seawater. PAX and MIBC were used as collector and frother respectively. Micro-flotation tests were also done at different redox potential conditions so that the effect of the surface oxidation of enargite was evaluated in seawater. The results indicate that the recovery of copper from enargite is reduced in seawater compared to fresh water, in particular at the pH values close to those of the formation of the first hydroxy complexes of Mg and Ca. In general, the experimental data indicate that the floatability of enargite is strongly affected when seawater is used, in particular at oxidizing conditions. These results suggest that Mg2+ and Ca2+ ions contained in seawater interact with the surface of enargite forming hydrophilic species.

Jan 1, 2018