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By V. G. Papangelakis, G. A. Moldoveanu

The use of anhydrite (AH) seed, control of acidity levels and ageing were assessed as means to promote the conversion of freshly produced metastable gypsum generated in-situ to the less soluble anhydrite phase and force deposition of calcium sulphate on seed as opposed to on equipment as scale, while achieving lower terminal aqueous calcium concentration as well. It was found that moderate sulphuric acid levels (0.25M) and ageing in the presence of AH seed accelerated the gypsum-AH conversion, achieving 100% transformation of the metastable gypsum generated in situ to the more stable, less soluble AH in 6-7 days, while lower/nil acidity did not promote more than 30% AH conversion for 10 days, even in the presence of AH seed. These findings indicate that anhydrite seeding, ageing and incomplete neutralization are beneficial for scale control as well as achieving lower calcium levels, thus rendering the resulting solution more amenable for recycling.

Jan 1, 2015

By Frank C. Aplleyard

The two calcium sulfate minerals-gypsum and anhydrite-occur in many parts of the world, and gypsum has long been of economic importance in the family of industrial minerals. Gypsum, the dihydrate form of calcium sulfate (CaSO4•2H2O) and anhydrite, the anhydrous form (CaSO4) are frequently found in close association, and it is seldom that a calcium sulfate deposit will consist exclusively of one mineral or the other. Although known gypsum deposits are extensive, anhydrite makes up the largest part of total calcium sulfate reserves. However, it has very minor economic use, and most of the following discussion will be devoted to gypsum. Calcium sulfate is one of the principal constituents of evaporite deposits, and when pure, has the following composition: [Sulfur Combined Lime Trioxide Water (CaO) (SO,) (H2O) Gypsum 32.6% 46.5% 20.9% Anhydrite 41.2% 58.8% -] Deposits of pure gypsum or of pure anhydrite which are large enough to be considered commercial have never been found because of both the metastable relationship between the two minerals, and the presence of impurities such as calcium or magnesium carbonates, chlorides, other sulfate minerals, clay minerals, or silica. As a result most mine production of gypsum will range between 85 and 95% pure. Often it is used as mined, although in certain cases, one or more forms of mineral beneficiation are employed to upgrade the product. End Uses The largest use for gypsum is based upon the unique property which calcium sulfate has of readily giving up, or taking on, water of crystallization. With the application of a moderate amount of heat in a process known as calcining, gypsum is converted to plaster of paris (the hemihydrate of calcium sulfate, CaSO4 ½ H2O) which when mixed with water will set or harden as the calcium sulfate returns to the dihydrate form. This semifinished product, usually called stucco, is then manufactured into a large variety of plasters, wallboard, and block for construction use, or into plasters for industrial applications. About 75% of the gypsum used in the United States is calcined for these purposes. Uncalcined uses of gypsum are principally as a retarder for portland cement, as a soil conditioner, as a mineral filler, and other minor industrial applications. About 25% of the gypsum mined in the United States goes into these markets; however, in less developed countries where construction and other industrial uses may be quite limited, the use of uncalcined gypsum for portland cement retarder may well be the dominant-if not the only-market for the mineral. It has often been noted that calcium sulfate constitutes the world's largest reserve of sulfur, and minor use of both anhydrite and gypsum has been made to produce sulfuric acid or other sulfur compounds such as ammonium sulfate. However, because sulfur is readily available at lower cost from other sources, use of calcium sulfate has been limited to only a few locations where it could compete economically. No such use is reported in the United States at this time. Mineralogy Anhydrite, CaSO4 because of its geologically rapid conversion to gypsum, and relatively high solubility (about 0.2 g per 100 g H2O) is not often found outcropping in climates wet enough to support abundant vegetation except on steeply dipping slopes or other places where hydrated material is continuously removed. Anhydrite rock is most often light to bluish gray in color, and under the microscope, varies

Jan 1, 1983

By Kenneth S. Johnson

Large reserves of high-purity Permian gypsum crop out and are at shallow depth in three regions of western Oklahoma, Gypsum beds in the Blaine Formation are 10 to 30 feet thick and are generally 95 to 99 percent pure, whereas the massive Cloud Chief Gypsum is 20 to 100 feet thick and is 92 to 97 percent pure. Reserves are estimated at 48 billion short tons. Eight companies in the State currently mine about 1 million tons of gypsum each year for wall- board, for plaster, as a retarder in portland cement, and as a soil conditioner. Future uses, under more favorable market conditions, may be in the chemical industries, largely because of gypsum's potential as a source of sulfur. Three thick sequences of Permian rock salt underlie most of western Oklahoma at depths of 30 to 3,000 feet. Individual salt beds 5 to 30 feet thick are interbedded with thinner layers of shale and anhydrite. Five large salt plains, fed by natural springs of saturated brine constitute additional resources of salt. Reserves, estimated at 20 trillion short tons, are virtually untapped, and, ironically, about 90 percent of the salt used in Oklahoma is imported. Chemical data on the rock salt are lacking, but evaporated salt produced from brines is generally 97 to 99 percent pure. Current production from three solar-evaporation plants is used mainly for stockfeed, recharging water softeners, and deicing roads. Potential uses are in the chemical industries, where salt or brine is a necessary raw material.

Jan 1, 1973

By D. M. Baird

ABSTRACT A revised stratigraphic section of Carboniferous rocks which occupy about 700 square miles in southwestern Newfoundland is presented. Gypsum, which outcrops at thirty-five different localities, is found to belong to four principal zones in the section. The newly mapped structure of the region makes the otherwise random occurrences of gypsum appear as systematic outcroppings of the four zones which follow the regional structure. Details of several occurrences are given and those most advantageous for exploitation are pointed out. INTRODUCTION ROCKS of Carboniferous age occupy an area of about 700 square miles in southwestern Newfoundland. They occur in a belt, from 5 to 15 miles wide, which extends from the head of St. Georges bay southwestward for 65 miles to the mouth of Little Codroy river (see Figure 1). Several hundred feet of Pennsylvanian rocks overlie rocks of Mississippian age, which are at least 12,000 feet thick. The rocks of the Carboniferous section of Newfoundland are very similar to those of Nova Scotia and represent a northeastward continuation of the same palaeophysiographic conditions. Mississippian measures of Windsor equivalence include thick gypsum deposits which outcrop at many places and which extend under large areas as indicated by sink-holes and by structural considerations.

Jan 1, 1951

By J. E. Shearer

The state of Arizona produced 253,276.2 metric tons (279,000 st) of crude gypsum during 1986. This represents approximately 1.7% of the total U.S. production. Four mines provided Arizona's gypsum, three of these mines are in the San Pedro Valley. The uses of the gypsum produced in Arizona are for manufacture of cement, agricultural uses, and wallboard manufacture. The gypsum is used as a retarder in the manufacture of Portland cement. The use in agriculture is treatment of alkali soils to allow water penetration. Other deposits in the San Pedro Valley have production potential, providing there is sufficient market for additional wallboard. The author completed an evaluation of one property earlier this year.

Jan 1, 1988

By J. R. CAMERON

Gypsum is mined in all Atlantic Provinces except Prince Edward Island. It is generally thought to have been derived from the hydration of anhydrite in areas of minimal drainage. Late Devonian downwarping and crustal oscillation east of the Appalachian fold belt allowed the Windsor Sea to advance and retreat in a depositional trough and deposit about 1,000 m of sediments in Mississippian time, much of which were evaporites. The best areas for further gypsum development are lowland basins such as the Cape Breton Lowlands, the Hillsborough area of New Brunswick and the St. George's Lowlands in Newfoundland, all of which are already sites of gypsum quarries. Nova Scotia's gypsum is mined from the Lower Windsor Group, which is divided into subzones 'A' and 'B'; 'B' provides most of the province's gypsum production. The Atlantic Provinces gypsum industry has markets from the St. Lawrence waterway to the mouth of the Mississippi River.

Jan 1, 1984

By J. H. Fowler

Canada's gypsum industry began over two hundred years ago in the Maritime Provinces when farmers attempted to supplement their incomes by selling "land plaster" to traders bound for the United States. Rising from such humble beginnings, gypsum now contributes significantly to the economies of nine of Canada's ten provinces. Thirteen open-pit and three underground mines produced a total of 8.38 million tonnes of crude gypsum and seventeen processing plants manufactured 2.49 million tonnes of finished products in 1985. Recent economic growth in North America has resulted in steady increases in gypsum production, however, competition from foreign producers and by-product gypsum poses a growing threat to Canada's gypsum mining industry.

Jan 1, 1987

By George E. Cole

"It is a truism that the metals, and particularly the precious metals tend to monopolize the attention of those interested £n the mineral industry. This is a tendency to be mildly, but actively and continuously combatted if we are to have a well-rounded mineral development." There are in the province of Ontario a number of industries centred about the non-metallic minerals. Too little is heard of the part these play in our industrial life. It is with the intention of showing what the gypsum industry is doing in Ontario that this paper is written. The writer lays no claim to any originality in the discussion and merely offers some material in an endeavour to assist in bringing about that 'well-rounded mineral development' sought for Ontario. M. Y. Williams in his "The Silurian Geology and Faunas of Ontario Peninsula and Manitoulin and Adjacent Islands"1 in discussing the industries dependent on the Silurian rocks of south-western Ontario points out that "the splendidly ordered gypsum mine at Caledonia, formerly owned by the Alabastine Company of Paris, and now owned by the Ontario Gypsum Company, is a revelation to the average man, who disconnects mining entirely with this part of Ontario". This region is better known as one of the richest and most thickly settled agricultural areas in Canada.

Jan 1, 1925

By Albert A. Mathews

OUTCROPS of gypsum rock near the present site of the city of Gland Rapids, Mich., were known to fur traders early in the nineteenth century. However, the deposits seemed without value and were not worked for some time. So far as cat1 be learned, Michigan gyp- sum was first used by a plasterer who settled in Grand Rapids in 1834 as a member of its fourteenth white family. In building a house for one of the early traders, be used some otnamental stucco mouldings manufactured from the local gypsum deposits for decorations in the gables and around some circular windows. The gypsum was broken out with a hammer, ground in an Indian corn mill, and burlled in a caulclron kettle,. After two attempts, the ornaments were successfully set, and remained on the house until it was destroyed by fire in 1850.

Jan 1, 1936

By I. Spector, A. J. Smith

In 1967, BACM Industries Limited started producing walboard at Saskatchewan's first gypsum products plant, located in Saskatoon, using, as a basic raw material, gyp-sum rock supplied from the company's mine near Amaranth, Manitoba. This paper describes the geology of the Amaranth gypsum deposit, the method of mining the rock and the manufacturing facilities used to produce wall-board.

Jan 1, 1970

By T. M. Chagwedera, A. E. Lewis, J. Chivavava

Eutectic freeze crystallisation is a novel separation technique that can be applied to treat brine solutions such as reverse osmosis retentates, which are often a mixture of different inorganic salts. The treatment of calcium sulphate-rich brine solutions through eutectic freeze crystallisation has resulted in gypsum scale formation on the walls of the crystallisers and ancillary equipment. In order to prevent gypsum scaling on equipment surfaces, it is essential to understand the mechanism of gypsum scaling on cold surfaces. This paper focused on the interaction between gypsum crystallisation in the bulk solution and scaling on the crystalliser walls in the presence of gypsum seeds. A cooled, U-shaped stainless-steel tube suspended in the saturated solution was employed as the scaling surface. Preliminary results showed that the scale layer was predominantly composed of needle-type and hexagonal prismatic crystals. The rate of scale deposition was highest during the first 24 hours, thereafter it decreased. A thin scale layer was observed to have coated the tube within the first hour of the experiment. Seeding, using reagent grade gypsum crystals, was effective in reducing scale layer formation through providing a surface for growth. The highest scale reduction, 81%, was realised at a seed loading of 0.50 g/L. At a high seed loading of 4.01 g/L, the seed material adhered to the tube. Keywords: Gypsum, eutectic freeze crystallization, seeding, scaling, cooling crystallisation

Jan 1, 2020

By R. Pothina

The objective of this research was to develop a mathematical model for gyratory crushers to help in the prediction of energy consumption and to analyze dominant parameters that affect this energy consumption. The development of a gyratory crusher model was achieved in the following three main stages: mathematical representation and coding of the crushing process; building an amperage constant model to derive an energy-scaling formula; and modifying the amperage constant model to represent a full-scale model. Due to their significant influence on feed-size distributions, two blasting parameters, i.e., burden and spacing, were considered. The crusher parameters that affect energy consumption were also identified. A case study of an operating dolomite mine was performed. The results indicated that by changing the burden, spacing and crusher closed-side setting, the overall (blasting and crushing) costs could be reduced by 4.7% to 7.9% annually. It can also be concluded that burden and spacing values have a linear positive relationship with the crusher energy consumption, while closed-side setting values have an inverse linear relationship with the energy consumption.

Jan 1, 2007

By Persio P. Rosario

Crushing has proven to be of fundamental importance in mine mill integration at Highland Valley Copper (HVC). Highland Valley Copper has achieved large throughput and good quality control through the gyratory crushers by proper blast design and better gap control. The next step, in optimizing the mine mill relationship, is evaluating the crusher liner wear and its shape influence on performance and product size reduction. To do this a laser measurement device has been developed and data is being recorded on the concave and mantle liner wear. This paper will outline the work to date and indicate specific objectives of the work.

May 1, 2002

By Mirian Mamani

Estudio sobre los diferentes tipos de depósitos de zinc ubicables en los Andes Centrales. Tras destacar el extraordinario potencial que ofrece Perú, la autora precisa que debido a que los magmas son fértiles, se formaron yacimientos en columnas corticales favorables para incrementar las concentraciones de zinc en las rocas intrusivas y rocas sedimentarias (calizas y dolomitas); se tienen las mejores estructuras (e.g., fajas corridas y plegadas) que favorecieron el emplazamiento de los fluidos y excitación térmica en el tiempo geológico por radiactividad de los depósitos; y lo más importante, que se encuentran en su mayoría preservados debido a que las tasas de erosión donde afloran son mínimas.

May 31, 2019

By Jean-Marc Simard, Richard Genest

"La mine Agnico-Eagle, localisée près de Joutel, a été découverte en 1962 par le forage d'anomalies électromagnétiques. Exploitée à partir de 1974, elle a déjà produit près de 30 tonnes d’or à partir de 2 puits, le puits Eagle et le puits Telbel, distants de 1,3 km.Le gisement est situé entre le sommet du complexe volcanique de Joutel, à dominante felsique, et la base de l'ensemble sédimentaire de la rivière Harricana. Ces deux unités ont une extension régionale; elles sont orientées NW-SE avec une polarité NE et des pendages subverticaux. Une faille majeure, la faille Harricana, passe de façon subconcordante au contact de ces deux ensembles.La minéralisation aurifère, de 2 à 5 m d’épaisseur moyenne, est liée a une zone carbonatée, comprise entre des tufs felsiques, argilites et sédiments chimiques (éponte inferieure) et des argilites carbonatées (éponte supérieure). Le minerai est constitué habituellement de 20% de fine pyrite disséminée. L’or est en fines particules associées directement à ces grains de pyrite de texture cataclastique.Deux modelés ont été for mules jusqu' a présent pour expliquer la genèse du gisement: une thèse syngenetique (Barnett et a/.1982) et une thèse épigénétique (Wyman et al. 1986). Cette dernière apparalt comme la plus probable du fait de la présence de la minéralisation dans les zones cisaillées a carbonates secondaires et pyrite cataclastique."

Jan 1, 1990

By Pierre Sauvé, Guy Perrault, Armand Savoie, Pierre Trudel

"La Mine Doyon est une entreprise détenue à parts égales par Cambior Inc. et par Minerais Lac Ltée qui en est l'opérateur. Les statistiques de production au 1"" janvier 1990 indiquent que, depuis le début de son exploitation (1980), 10.3 Mt de minerai d'une teneur moyenne de 5,9 g Au/t ont été usinées. Les réserves sont estimées a 10,4 Mt à une teneur moyenne de 6,6 g Au/t jusqu' à une profondeur de-450m.Trois zones minéralisées sont présentement en exploitation. Ces zones sont caractérisées par la présence de veines de quartz-pyrite accompagnées localement de chalcopyrite. Les roches encaissantes sont les schistes a séricite (zone# 1), les roches volcaniclastiques de composition felsique (zone #2) et intermédiaire (zone #2, zone ouest) ainsi que les roches intrusives appartenant au pluton de Mooshla (zone ouest). Toutes ces roches ont subi un métamorphisme régional dont l'intensité correspond à la limite supérieure du facies schiste vert ( -425°C}.Les zones minéralisées sont situées à I' intérieur des zones de déformation et d'altération les plus intenses. L'étude des structures mineures nous indique que la région a subi plusieurs épisodes de déformation ductile a fragile qui sont antérieurs, contemporains et postérieurs al a minéralisation. L'analyse structurale indique également que la déformation majeure est associée à une importante phase de compression orientée N-S a NNE-SSW.L’ensemble des observations suggère que la minéralisation et I' altération associée sont de type épigénétique. La mise en place du minerai se serait effectuée à la fin de l'épisode principal de métamorphisme et de la déformation."

Jan 1, 1990

By A. Proulx

Durant les années 1955 à 1961, plusieurs campagnes d?exploration ont été menées sur la zone Bond dans la partie sud-ouest de l?anneau nord de la carbonatite d?Oka (propriété de Niocan, figure 1). Les zones minéralisées HWM1 et HWM2 sont découvertes à l?ouest de la propriété. Un des forages, le S-60, avait intercepté 80 mètres de minéralisation à 0.71% Nb2O5 à l?est des zones HWM1 et HWM2 mais aucun autres travaux d?exploration n?avaient été réalisés sur cette interception minéralisée. En 1995, Niocan réalise une campagne de forage pour mieux définir la zone minéralisée recoupée par le forage S-60. En 1997, une seconde campagne de forage détermine un tonnage de 14.37 Mt avec une teneur de 0.66 % Nb2O5 pour la zone S-60 (Marcotte et Gagnon, 1997). Le complexe carbonatitique d'Oka se situe à environ 35 km à l?ouest de Montréal sur la rive nord du lac des Deux-Montagnes. Sa formation remonte au Crétacé précoce (entre 117 à 123 Ma). La carbonatite d?Oka fait partie de la suite d'intrusions alcalines que constituent les collines Montérégiennes. Le complexe a une forme allongée (7.2 km par 2.4 km) orientée NO-SE (figure 1). Il est intrusif dans des roches précambriennes constituées d?anorthosites au nord et de gneiss charnokitique au sud (Gold, 1963) appartenant à la Formation de la colline d?Oka. Les gneiss au contact du complexe sont fénitisés sur une épaisseur qui peut atteindre jusqu?à 60 mètres. Les roches carbonatitiques forment la série dominante du complexe et elles sont composées principalement de calcite (> 50 %) à gros grain et parfois rubanées. Les minéraux accessoires les plus communs sont la biotite, le pyroxène, la monticellite, la magnétite, l?apatite, la forstérite, la mélilite, le pyrochlore, la pérovskite, la niocalite, la pyrite et la pyrrhotite (Gold, 1963).

May 1, 2003

By Gilles Bonin

Structures and serpentinization patterns in the Thetford Mines peridotites are important characteristics indicating the necessary geological conditions which led to the development of chrysotile orebodies in Early Ordovician limes. These structures and serpentinization patterns are reviewed in this paper using the geology of LAB Chrysotile orebodies as a model. Structural aspects include parallel and transverse faults, parallel and transverse granite slabs, and orebodies, some of which trend clearly north-westward parallel to the accretionarymovement. Serpentinization patterns in the peridotite belt, particularly in the harzburgite, include primary pervasive mass serpentinization and secondary complete serpentinization. Listwaenites layers appeared along some faults and along some granite slabs as a result of hydrothermal alteration of the serpentine, following the emplacement of the devonian plutons to the south. These plutons as we/1 as other important lineaments, align with the structural pattern of Thetford Mines ophiolites. It is believed that these plutons are part of a heavy magma tic corridor resembling the Pilote-Mont-Louis corridor in the Gaspe (Doyon and Berger, 1997), and the Buchans' structure in Newfoundland (Hutchinson, 1984), both intersecting the Brompton-Baie Verte line.

Jan 1, 2001

By Paul Bedard, Réal Daigneault, Guy Perrault

"La mine Lamaque est située a Val d'Or, Québec; les roches hônes appartiennent au groupe de Malartic, partie supérieure, et sont des andésites et des pyroclastites. On y retrouve deux formes d'intrusifs; des petites cheminées (ca. 150 m D) et des dykes (ca. 10 m d'epaisseur). Les petit es cheminées contiennent:1 - des diorites et des tonalites (cheminées principale, est et ouest) d'affinité calco-alcaline: Zr 140 ppm, Sr 761 ppm, P2O5 0.31% et (La/Sm)n 3.0;2 - des diorites (cheminée 4) d'affinités tholéiitique: Zr 32 ppm, Sr 181 ppm, P2O5 0.27% et (La/SM)n 1.5.La diorite de la cheminée no 5 contient deux fractions, une de chacune de ces deux affinités. Les dykes tant de porphyre feldspathique quartzifére que ceux de prophyre feldspathique sont d'affinité calco-alcaline: Zr 83 ppm, Sr 500 ppm et P2O5j 0.10%.Le gisement de 10 mine 2 est filonien: veines subhorizontales (""flats "") surtout et veines sub-verticales dans des zones de cisaillement. Le dernier réajustement structural de direction de compression nord-sud a broyé le quartz des veines existant es et rendu possible leur minéralisation. Les veines minéralisées contiennent du quartz, de la tourmaline, de la calcite avec des traces de scheelite, de pyrite et d'or; elles sont bordées par de minces (2 à 20 cm) bordures d'altération où l'on retrouve un enrichissement en carbonate, paragonite, apatite, rutile, saphène et zircon et où les phases ferromagnésiennes sont disparues. On a documenté le migrations géochimiques suivantes:I - de la bordure d'altération vers l'éponte, K2O, Rb et MgO;2 - de l'éponte vers la bordure d'altération, Na2O;3 - de l'éponte vers la veine, SiO2.P2O5, TiO2, Zr, Y, Nb et CaO sont enrichis dans la bordure d'altération."

Jan 1, 1983

By Jean-Jacques Bouillon, Michel Jébrak, Stephane Faure

"Le gisement polymétallique (Cu-Zn-Au-Ag) des Mines Selbaie est forme par un réseau de filons encaisses dans une séquence de pyroclastites felsiques du sill on Harricana-Turgeon. Les minéralisations sont encaissées dans le tuf de Selbaie, situe sous une épaisse séquence d'ignimbrites Iitées. Ce gisement se distingue des autres gites archéens par une chronologie atypique des minéralisations: les veines de chalcopyrite, de sphalérite et de galène recoupent un amas exhalatifpyriteux stérile. Un vaste halo d'altération hydrothermale a chlorite et mica blanc est associe à cette minéralisation.La mise en place des veines minéralisées est associée à une phase d'extension NNW-SSE. Le complexe volcanique subit, par la suite, trois phases de déformation. Une compression, orienté N-S, développe une schistosité à peine pénétrative et un réseau de fentes de tension. Une réorientation des contraintes locales selon une direction WNW-ESE conduit au chevauchement de I' écaille d'andésite et de tonalite de Brouillan. Un réseau conjugue de failles normales cassantes est associe au relâchement des contraintes."

Jan 1, 1990