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By C. J. Allen, L. Battiston

"Introduction It has long been recognized by the hot-dip galvanizing industry that the characteristics of the galvanized coating can be influenced significantly by steel and pro cessing variables. Probably the variable of most concern to galvan izers today is steel chemistry. More specifically, the problem is the excessive reactivity of continuously-cast, silicon-bearing steels. In the past, structural steels processed by general galvanizers were in the low-to-medium ca rbon category and contained silicon at either low impurity levels (as with rimmed steels), or less than approximately 0.10% (as with semi-killed steels). The structures of the coatings produced on such steels are characterized by dense, compact layers of delta and zeta iron-zinc alloy phases and a distinct outer layer of eta zinc, which usually imparts a bright shiny appearance to the coating. The presence of silicon in steel, above the so-called semi-killed levels, is known to cause marked stru ctural changes in galvanized coatings. Such coatings are characterized by a relatively thin delta layer, a thick , coarse zeta layer and frequently an absence of the eta layer. The eta phase, comprising zinc which is carried out of the bath during withdrawal of the work, can be consumed by the continuation of the coating reactions until its temperature drops to the solidification point. This results in a dull grey and often mottled surface instead of the usually bright metallic appearance. These galvanized coatings are usually much thicker than coating specifications requ ire and they are usually more brittle and have poor adhesion to the steel. In service, these coatings tend to develop a rust-like discolouration. With the wider use of continuous casting by the steel producers and the associated additions of silicon in this process, the problem is becoming more important and receiving greater attention from the galvanizing industry ."

Jan 1, 1987

By Thomas L. Hurst, Joseph M. Hans

INTRODUCTION The former Shiprock uranium mill site is located in the community of Shiprock, New Mexico on a bench overlooking the San Juan River (Figure 1). Both Shiprock and the mill site are located on the Navajo Indian Reservation. The millsite was built on a 230 acre tract leased by Kerr-McGee Oil Industries Inc., and was operated from 1954 to 1963. The Vanadium Corporation of America and its successor, the Foote Mineral Company, operated the mill from 1963 to 1968. During its entire operation, 1.5 million tons of uranium ore was milled producing 3711 tons of U308 concentrate. The concentrate was sold to the former U.S. Atomic Energy Commission. During milling, the ore was crushed to less than 35 mesh and acid leached to remove the uranium. The [ ] uranium was removed from the leach solution by solvent extraction and the uranium-barren solution discharged into raffinate ponds for disposal by evaporation and seepage. The spent solids (tailings) were pulped with waste process fluids and water and discharged to form tailings piles. The piles (ponds or dams) were formed with earth starter dikes. The dike walls were then raised using the separated sand fraction of the tailings. The slime fraction of the tailings were discharged into the diked impoundment. Since only a small fraction (0.25 percent) of the ore was U308 by weight, most of the ore bulk ended up as wastes. The wastes contain nearly all of the uranium decay chain radionuclides present in the ore except uranium. The mill was shut down and partially dismantled before the lease expired in 1973, and the remainder of the mill and wastes reverted back to the Navajo Tribe which was the lessor. Portions of the millsite were then occupied by the Navajo Engineering and Construction Authority (NECA), a Tribal enterprise. In order to provide skilled personnel to operate earth moving equipment, a heavy equipment operator's training school was also established on the mill site and was administered and operated by NECA. The U.S. Public Health Service (PHS) and the Environmental Protection Agency (EPA) staff conducted radiation surveys at four inactive uranium millsites on the Navajo Reservation in April 1974. During the survey of the Shiprock millsite, it was noted that the training activities were degrading its radiological condition. Both the PHS and EPA staff recommended that the training activities be directed towards the decontamination of the millsite area and interim stabilization of the tailings piles. Preparation for the decontami-nation work commenced in April 1974. In order to facilitate the decontamination activities, the mill site and its contaminated environs were divided into major areas labeled A through F (Figure 2). Areas A, B, and C are defined as "perimeter" areas and contained surface contamination ranging from 5 to 30 cm deep. Area D defined the mill yard and contained contamination ranging from 0.6 to 5.5 m deep. Area E contained several raffinate ponds which were removed to line up the northwest boundary of the tailings pile and to move the contaminants away from the vicinity of the occupied on-site buildings. The contaminants in Area E ranged from 0.05 to 5.5 m in depth. Area F encompassed the ore storage yard. Contaminants in this area ranged from 0.18 to 1.2 m deep. Washes, however, had contamination exceeding 7.6 m deep.

Jan 1, 1981

By E. A. Wieselmann

In 1970 Texasgulf (Australia) introduced natural gamma radiation logging of drill holes for exploration in the Hamersley Iron Province of Western Australia. Drill hole logs have allowed positive stratigraphic and structural correlations within complexly folded secondary hematite ore deposits and between individual iron ore deposits separated by distances in excess of seventy-five miles. A Neltronics model KPD logging system and gamma-ray sonde are being used to measure the natural gamma radiation of the enriched Brockman and Marra Mamba banded iron formations. The parent banded iron formations are composed of thick, chemically precipitated iron oxide, chert, iron silicate, and carbonate with thin intro-formational clastic horizons. These clastic horizons give a greater natural gamma radiation than the banded iron horizon, and each clastic horizon has a characteristic radiation profile related to its composition and thickness. Because the natural gamma-radiation profile is unchanged during secondary enrichment of the iron formation, the present stratigraphic position of each drill hole can be established and complex folding can be accurately traced in the sub-surface. Gamma ray logging of percussion drill holes has made feasible a significant reduction in diamond core drilling without loss of accuracy. At the same time, it has provided a means of rapid evaluation of complexly folded iron ore deposits.

Jan 1, 1975

By Elizabeth Carvalho L. Cardoso, Ademar B. Lugão, Sandra R. Scagliusi

This research investigated how gamma-radiation affected PP/HMSPP structural foams filled with biodegradable synthetic polyester PLA in terms of thermal properties, biodegradability and infrared spectrum. Polymers are used in various applications providing enormous quantities of wastes in environment and contributing with 20–30% of total volume of solid residues. Besides, shortage of plastics resins obtained from fossil base is addressing research and development toward alternative materials; environmental concerning in litter reduction is being directed to renewable polymers for manufacturing of polymeric foams. Biodegradable polymers, a new generation of polymers produced from various natural resources, environmentally safe and friendly, can contribute for pollution reduction. PLA (poly(lactic) acid)) was chosen to be blended with PP/HMSPP. Blends thereof were subjected to gamma radiation at 50, 100, 150, 200 and 500 kGydoses.Soilburialtestpointedtowardapartialbiodegradationofirradiated PLA-PP/HMSPP foams; other characterizations involved TG/DTG technique and FTIR assessments.

Mar 1, 2017

By J. G. Conaway, P. G. Killeen

"Gamma-ray spectral logging, a useful technique for uranium exploration and evaluation, has generally been underutilized by the Canadian mining industry. Provided that the technique is properly applied, it is capable of yielding reliable quantitative information regarding the distribution of uranium and other radioelements along the borehole under most conditions.In practice. there are numerous factors which potentially can degrade the quality of the log and thus any quantitative interpretation based on it. Fortunately, the appropriate choice of logging equipment and technique can avoid many such problems, and corrections can be applied to the data to compensate for most of the others."

Jan 1, 1980

By P. Khattri

At Tata Steel, Coal is washed in gravity and froth flotation circuit at 13-15 mm size and below. Being coal is high in ash (~35%) and difficult washability characteristics (having high (~40 %) NGM at desired ash levels) needs more and timely quality data of ROM for effective optimization and process control. Conventional approach of supplying quality data takes 4-5 hours time. This means during this period, it is assumed that coal is having similar characteristics as of previous set and it is not possible to fine tune during this time which resulted in yield loss. Hence producing clean coal on agreed ash value consistently is a challenging task because of high NGM and variation in input quality. To overcome the problem of collection of representative sample and timely result a new technology was adopted Prompt Gamma Neutron Activation Analysis (PGNAA) technology which is basically an online analyser using Gamma rays as the source to measure the ash content in coal running on a conveyor which gives real time ash analysis. The details of this technological intervention are discussed in details in this paper. Keywords: near gravity material, PGNAA

Sep 1, 2012

By N. Ahmed

This paper is concerned with the drainage behaviour of gangue mineral in the froth phase. Experiments were carried out in a continuous laboratory flotation cell in which froth depth and bubble size could be changed independently. The fraction of solids returning from the froth to the pulp zone was expressed using a rate constant. A mixture of hydrophilic solids (silica) and floatable particles (glass ballotini) was used as a flotation feed. Samples of glass ballotini of different hydrophobicities were obtained, using controlled silanation. Three samples, with contact angles of 50, 66, 82 degrees, were used. The effect of the initial bubble size (pulp bubble size), concentration of gangue mineral in the froth zone, and froth depth on the drainage of silica, were investigated. The drainage rate of the entrained solids increases with an increase in the degree of hydrophobicity of the floatable particles. Concerning the effect of pulp bubble size on the drainage rate of entrained solids, larger bubbles always give higher drainage rates due to formation of relatively loose froth structures which allow gangue particles to easily move down to the pulp zone. Conversely, smaller bubbles exhibit lower drainage rate constants, in particular at shallow froth depths.

Jan 1, 2003

By Marcelo Marchesi Martinelli, Caio Henrique Vidigal

Gasômetros são equipamentos de grande valia para aumento da eficiência energética e ambiental de empresas siderúrgicas integradas, sendo estes equipamentos responsáveis pelo controle da pressão do gás resultante das transformações dos processos siderúrgicos, controle este realizado através das variações de volume abaixo dos pistões. Quando não há disponibilidade de operação dos gasômetros faz-se necessário o uso de torres de queima para controle das pressões das redes de gases. Em dezembro de dois mil e dezoito fora realizada a troca da selagem do gasômetro de gás de Coqueria da ArcelorMittal Tubarão, que utiliza a tecnologia M.A.N. (Selo a óleo). Utilizando técnicas da metodologia Lean, modificando o mindset e alterando antigos paradigmas foi possível realizar a manutenção, de forma eficaz, em 32 dias, 28 a menos que o último trabalho similar realizado e 13 dias a menos que a meta proposta para a parada, aumentando a recuperação de gás de Coqueria, maximizando ganhos de geração elétrica e minimizando a exposição a riscos ambientais associados a parada. As ideias apresentadas neste artigo são de grande valia para a evolução do pensamento crítico e sistêmico sobre a manutenção, não só em gasômetros, mas em todo o contexto de realização de atividades já consolidadas.

Aug 1, 2019

By Marcelo Macedo Fialho

No processo produtivo de aço, as empresas buscam continuamente a redução do custo de produção. Isto pode ocorrer através de diversas formas, tendo como as principais, o ganho de rendimento, o aumento de produtividade, a redução do homem hora aplicado e a redução do custo de matéria prima. Objetivando reduzir o custo de produção integrado placa bobina, a ArcelorMittal Tubarão busca aumentar o percentual de placas enviadas diretamente do Lingotamento Contínuo de Placas para o Laminador de Tiras a Quente. Os ganhos se dão, em primeiro plano, através da redução da intervenção nas placas aumentando o rendimento de placa e exigindo menos mão de obra para o corte e escarfagem de placa e, em segundo plano, através do aumento da temperatura média de enfornamento, propiciando maior produtividade no laminador de tiras a quente e menor consumo de energia para realizar o pré-aquecimento da placa antes do processo de laminação. Somado a isto, a maior disponibilidade de placas no pátio do LTQ, aumenta a chance de laminação exigindo menos paradas do LTQ e aumentando a produção. Os ganhos estimados com o projeto, apenas no que diz respeito a redução de custo de condicionamento são de 6MUSD/ano.

Jul 30, 2018

By Sueli Aguiar Barros

A água utilizada para refrigerar grandes equipamentos de produção, tais como Alto fornos, Fornos do Laminador de Tiras a Quente, Trocadores de Calor das Laminações de Tiras a Frio é originada de diversas torres de resfriamento da Usina, denominadas CBR´s (Casas de Bomba de Refrigeração). A água refrigerada necessita de tratamento químico para proteger os equipamentos de corrosão, deposição e crescimento microbiológico. Este tratamento químico usualmente na CSN é obtido por uma empresa contratada fornecedora de produtos químicos e serviços nestes sistemas. Dentre os serviços destacam-se as análises físico químicas, monitoramento automático das dosagens, avaliação diária dos tratamentos, etc. Recentemente, em Agosto de 2014 houve o início do novo contrato deste tratamento nas nossas CBR´s, mudando-se o fornecedor, os produtos e a equipe de atuação nestes sistemas. Este trabalho visa descrever como foi realizada esta mudança, as dificuldades enfrentadas inicialmente e os ganhos obtidos com esta alteração do tratamento. Destacamos os ganhos no monitoramento em certos sistemas que anteriormente não era realizado, como nos Staves do Alto Forno 3 e os ganhos financeiros em relação ao tratamento.

Aug 17, 2017

By Enrique Albarrán, Julian Hernández

"In 1942 The “Presa Mixcoac” dam was built, along with 15 other dams, to control the rain fall waterin the mountains west of Mexico City. Mexico City’s population at that time was around 1.5 millionpeople, and the dam was way out of the city."

Jan 1, 2016

By Gordon T. Austin

Garnet is the general name for a family of complex silicate minerals having similar physical properties and crystallizing in the isometric (cubic) system. All garnets have the same general chemical formula but vary greatly in chemical composition. The name garnet is derived from the Latin word granatus, meaning like a grain, which refers to the mode of occurrence wherein crystals resemble grains or seeds embedded in the matrix. GEOLOGY Mineralogy Chemical Properties: The general formula for garnet is A3B2(SiO4)3, whereas A can be calcium, magnesium, ferrous iron, or manganese, and B can be aluminum. ferric iron, or chromium, or rarely titanium. The formulas and names of common garnet species are: [ ] Almandite and almandite-pyrope solid solution garnets are the best abrasive types, but andradite, grossularite, and pyrope also are used. All species of garnet have been used as gemstones. The structure of garnet consists essentially of isolated SiO, tetrahedra connected by oxygen-cation-oxygen bonds through the distinct A and B group cation sites. Within this structure magnesium, ferrous iron, and manganese easily interchange and substitute for each other in the A cation position, and calcium does so less readily. Additionally, aluminum, femc iron, and chromium substitute for each other to a limited extent in the B cation position. This ability to substitute or exchange ions without changing the crystal structure is called isomorphism, and garnet is one of the finest examples of a isomorphous series. Because of this isomorphism there is complete solid solution between certain garnet species but not between others. Fig. 1 illustrates these solid solution relationships. Some rare species of garnet are known that illustrate the wide range of cation substitution that the garnet crystal structure can accommodate. They include: [ ] These rare species are not of interest for industrial applications, but can be of interest to mineralogists and the gem industry. Physical Properties: Garnet displays the greatest variety of color of any industrial mineral. Garnets have been found in all colors except blue. For example, grossularite can be colorless, white, gray, yellow, yellowish green, various shades of green, brown, pink, reddish, or black. Andradite garnet can be yellow- green, green, greenish brown, orangy yellow, brown, grayish black or black. Pyrope is commonly purplish red, pinkish red, orangy red, crimson, or dark red; and almandite is deep red, brownish red, brownish black or violet-red. Spessartite garnet can be red, reddish orange, orange, yellow-brown, reddish brown, or blackish brown. A few garnets exhibit a color-change phenomenon. They are one color when viewed in natural light and another color when viewed in incandescent light. Because of the great variation in color of garnet within each species and similarities in color between garnets of different species it is recommended that garnet identification not be based on color alone. The Mohs hardness of garnet varies from 6.5 to 9.0. Grossularite and uvarovite have a hardness of 6.5 to 7.5; andradite is 6.5 to 7.0; and pyrope, almandite, and spessartite are 7.0 to 7.5 in hardness. There are reports of almandite having a hardness of between 8.0 and 9.0. As with hardness, the specific gravity of garnet varies considerably. The specific gravity may be as low as 3.2 or as high as 4.3 depending on chemical composition. Garnet crystallizes in the isometric system with rhombic dodecahedra and trapezohedra the most common forms. Crystals also form in combinations of dodecahedra and trapezohedra or either of these in combination with hexoctahedra. Crystals can have cubic or octahedral faces, but these are rare. Under favorable conditions of formation garnet will crystalize in nearly perfect forms that rival study models. Garnet also forms as irregular blebs, grains, knots, or masses, with or without distinguishable crystal faces, and as coarse- or fine-grained granular masses that appear to be totally lacking in crystal form. The fracture of garnet also shows great variation. In some garnets, particularly those that are well crystallized and glassy in appearance, the fracture is subconchoidal to conchoidal. Other, more poorly crystallized garnets exhibit a fracture that can only be described as uneven. Garnet occasionally has an indistinct dodecahedral cleavage. Certain species of garnet from specific locations have a pronounced laminated structure consisting of planes of weakness along which parting takes place. This parting may resemble cleavage, but since it is mechanical and not related to crystal structure it is not true cleavage. The optical properties of garnet are sensitive to even small changes in chemical composition or strain in the crystal structure. For this reason each species does not have a single index of re- fraction (IR) but has a range of 1Rs. Uvarovite in its pure form should have an IR of 1.870, but in nature samples vary from 1.74

Jan 1, 1994

By E. H. Erwin Gartner

The Rhenish lignite deposit in the Nordrhein-Westphalia province of the German Federal Republic covers an area on the left bank of the Rhine River of about 970 sq miles (Fig. 1). Here, in the Miocene era, some 20 million years ago a lignite seam was formed and later broken, through tectonic movements into several blocks, some thrown down into depths of over 1,500 ft. This deposit consists of a single seam, in places up to 300 ft thick, but averaging about 150 ft. In a few areas, it is split into as many as five seams, separated by barren strata. It contains about 60 billion tons (2000 lb/short ton) of lignite which, however, being relatively young geologically, has, because of approximately 60% moisture, 2 to 8% ash, and low sulfur, a net calorific value of 3,340 Btu. That calorific value increases, however, with rising thickness of the cap rock. About one-third of the yearly production of 90 to 100 million tons of raw lignites is converted into briquets. Raw lignite is pulverized and dried to about 18% water content and then pressed without binder into briquets under a pressure of about 14,000 psi. The briquets are being used primarily for residential heating; their sales, however, have been declining sharply since 1963. On the other hand, the volume of raw lignite used in steam power plants has been rising steadily and amounts at present (1968) to about two-thirds of the total production. Huge steam power plants, such as Frimmersdorf, shown in Fig. 2 (which, with an installed capacity of 2,600 MW [megawatt], represents the world's largest steam power plant) with a generating capacity of up to 300 MW per unit and a total installed capacity of over 6,000 MW, contribute about 26% of the total electric power production of the German Federal Republic.

Jan 1, 1969

By Jaco van den Berg, Dr. Todor Petrov, Dr. Josh Calnan, Dr. Jhon Silva

This paper shows and reviews the similitudes and differences in explosions generated by high explosives and gas explosions, the reasons why gas explosions are difficult to replicate using high explosives, and the considerations when performing explosive testing using methane gases and coal dust.

Feb 1, 2020

By Barry Hunsaker

I cannot help but be reminded, as I stand here today, of my boyhood years and heritage, both of which are inextricably tied to this very valley and are, in a: bay, apropos of the theme of this Keynote Session. I remember the scarcity of people. For example, 48, 000 in Phoenix and 436, 000 in the State in 1930 and 65,000 in Phoenix and 499, 000 in the State in 1940. Today Phoenix boasts a population of over 500, 000 and the State a population of 1, 500,000. I remember the' lack of facilities, goods and services, including gas and electric power. I recall stories of my grandfather who had the freighting or teaming contract to haul all the supplies and generating equipment, by wagon mind you, up the old Apache Trail to Roosevelt Dam. . .a three day trip from the nearest railhead which, by the way, was not Phoenix, for it did not merit a railhead on those days, but the village of Maricopa approximately 25 miles south of Phoenix. I remember chopping firewood, heating wash water on an open fire in a No. 3 wash tub at the rear of the house and doing my school homework by the light of a kerosene lamp just 25 to 35 years ago within what is now a large metropolitan area

Jan 1, 1965

Natural gas from the south west Queensland gas fields is now available in north west Queensland to fuel the development of many Carpentaria Mineral Province projects. Like these projects, the south west Queensland gas project, developed under the operatorship of Santos Ltd, has its own æMining CycleÆ. While the project is entering its third expansion phase, it is at the same time actively extending its discovery phase, with large programs of gas exploration and reserves definition. This paper outlines the history of the south west Queensland gas project, with particular emphasis on the relationship of the project to north west Queensland.

Jan 1, 1998

By K. C. Sclater

GAS as a factor in the efficiency of oil production, might be a better title for this paper as it deals in general with the significance of the gas-oil ratio as an index of the efficiency of oil production and briefly discusses oil production methods with reference to the gas-oil ratio in wells, particularly during the early life of a field. In the recent hearings held at Washington before the Federal Oil Conservation Board the fuller utilization of the energy contained in the gas occluded in or associated with the oil underground was stressed by some of the speakers when referring to greater ultimate recovery of oil. One speaker commenting on this point said in part, "There is ample evidence indicative that if the gas associated with the petroleum in our fields were conserved and elevated gas pressure maintained in the oil sands during their productive life, the ultimate production of oil could be greatly increased."

Jan 1, 1926

By Italo Onederra, Miguel Araos

Most of the current explosives for mining blasting activities rely on voids to become sensitive to initiation, then detonating and finally, sustaining that detonation. The use of voids is known as hot spot sensitisation. Various forms of voids serve as hot spots – gas bubbles (predominantly in bulk explosives), glass (or plastic microballoons, for packaged products), or expanded polystyrene (bulk explosives). Gas bubble sensitisation uses the decomposition of sodium nitrite to produce nitrogen gas bubbles, which are dispersed throughout the bulk explosion. These gas bubbles, when hit by a shock wave (such as from a booster), compress and heat up, subsequently decomposing the explosive and releasing energy to sustain the detonation. It has been suggested that the use of different types of gases to create voids in non-ideal explosives could offer some alternatives to the sensitisation process, which could be reflected in the change of the detonation properties of the explosive. The reason would be that each gas has a different ratio of specific heats (=/), and when these gas bubbles are compressed, they will heat up to different temperature, affecting the decomposition of the explosive and thus, the VOD.

Jan 26, 2026

By C. A. C. Sequeira, G. N. Anastassakis

Electrochemical processes occur on nano-, micro- and macro- scale in numerous applications such as fuel cells, batteries, hydrogen production, mineral extraction, water treatment, electrotherapy, sensors and many others. In most of these applications, gases evolve either at one or both electrodes due to electrolysis. These gases form bubbles play a crucial role in electrochemical systems. For example, in electrowinning (EW) that is used to extract and refine metals such as Cu, Zn, Ni, Mn, and Cd from their solutions, in most cases the solution is acidic and oxidation of water molecules at the anode is the common counter reaction, which results in the liberation of oxygen bubbles. This generally requires a high overpotential and accounts for a considerable percentage of the energy consumed in metal EW electrolytic cells, apart from producing acid mist that is very corrosive for other cell equipment and building structures. The behaviour of bubbles in electrochemical systems is still a complex challenging topic which requires a better understanding of gas bubbles hydrodynamics and their interactions with electrode surface and bulk liquid, as well as between the bubbles themselves. The objective of the current paper is to briefly review the fundamental hydrodynamics of both gas bubbles on the electrode surface and gas bubbles interaction with the liquid bulk solution. The current work also investigates the impact of gas bubbling and some operating parameters in copper EW, such as current density (100-500 A/m2), temperature (25-75ºC), acidity (50-300 g/L) and a typical chemical mist suppressant (<50 ppm). The results clearly show that both suppressant and temperature reduced the overall surface tension of the solution. Also, chloride concentration and applied current improved electrolyte flow and copper quality at higher current densities. The current paper contributes to the development of mineral processing (specifically to copper hydrometallurgy), as it deals with fundamental hydrodynamics and interactions of gas bubbles that formed during copper EW and play a crucial role in copper electrochemical systems.

Jan 1, 2018

By T P. Fischer, S N. Williams, N C. Sturchio

Chemical and isotopic analyses of fumarole gases from Galeras Volcano, Colombia provide significant insights into the origin of volatile components in the magma. Water comprises a mixture of magmatic (rock-equilibrated at high temperature) and meteoric, with the relative proportions varying through time. Carbon isotopes are most consistent with a mantle source, although other contributions to the system cannot be ruled out. Nitrogen most likely originated from organic matter in subducted oceanic sediments. All of these &apos;primary&apos; components have been modified somewhat by interaction or exchange with other reservoirs during ascent to the surface. In addition to information on the origin of the gases, these data show significant temporal variations precursory to eruptive events. Chemical ratios change and water becomes more meteoric in character prior to eruptions.

Jan 1, 1995