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By C. K. C. K. Gupta

The rare earths in elemental form are required for a variety of scientific and technological purposes. They are not easily obtained in this form, due to the great chemical stability of the rare-earth compounds and the strong tendency of elemental metals to react with everything they come in to contact with, especially at high temperatures. Beginning in the 1950s, when sufficient quantities of separated rare earths became available, as the result of intense research and development, three processing routes were developed to accomplish the preparation of all 16 naturally occurring rare-earth elements. They are chemical reduction of the halide intermediates, the oxides and electrochemical reduction of chlorides and oxide-fluoride mixtures. Not all the processes are effective with all the rare earths. In spite of the celebrated similarity of trivalent rare earths, the physical properties of individual rare-earth elements are sufficiently different that a variety of techniques are required for their preparation. The development of reduction processes for the rare-earth metals are covered in this paper, with focus on the oxide reduction routes. The strong reliance of effective reduction processes on the fundamental science of reduction reactions is highlighted.

By M. P. Corriveau

This is the case history of how two nearby plants in Southwest Virginia solved their water clarification problems. While the solutions should not be considered applicable industry-wide, the methods used in arriving at the answers deserve consideration. When Clinchfield's Moss No. 2 Preparation Plant, the first ever built in Tiller Seam coal, was started in the fall of 1956, the clays in the raw coal soon posed a flocculation problem, Laboratory sedimentation tests were initiated; and as a result, lime was adopted as the flocculant for the clays, With lime, a pH of 11.2 was required. As the plant tonnage increased, it became evident that the amount of coal fines produced in the mining and preparation was greater than had been estimated and that the 90-foot thickener was inadequate in providing sufficient settling time to effect a clarified overflow for reuse. Testing showed that Separan 26105 (NP10)1/, when used with lime, was the most satisfactory coal flocculant available,

Jan 1, 1960

By Joseph D. Martinez

Salt, because of its plasticity, exerts a major influence in deformation. Resulting salt structures are common world-wide. A special type, salt domes, are associated with thick sequences of sediments deposited over salt. Their upward intrusion is generally thought to be in response to buoyancy. Mines in salt domes reveal an internal pattern compatible with large amounts of vertical flowage. Caprock, the end product of accumulation of anhydrite from salt dissolution, attests to long continued upward growth and concomitant truncation by moving underground waters. Concepts of modes of growth are evaluated and related to problems in utilization.

Jan 1, 1979

By John M. Karpinski

A method and equipment have been developed Tor measuring the impact strength of grains of brittle materials. It is shown that brittle materials develop a characteristic particle size distribution when fractured by impact. A simple mathematical model has been found to describe this distribution, and one of the parameters of the model has been designated the r value. The r value is directly proportional .to impact energy and, for fixed impact energy, it becomes a useful criterion of grain strength. Data are presented on the variation of the r value as a function of sample history, initial size, energy input and number of impacts, The results are interpreted in terms of the flaw theory of brittle fracture.

Jan 1, 1964

By M. F. Corcoran

Rapid advances have been made in the past few years in the application of automatic controls and instrumentation to iron ore pelletizing plants. Present practice in applying instrumentation and control to the Grate-Kiln system of iron ore pelletizing is described. Major control points and loops are tabulated. Future trends in the application of digital control including computer data logging systems are described.

Jan 1, 1965

By C. D. Harrison

This paper presents the results of 18 high-G centrifuge tests performed at the Electric Power Research Institute's Coal Cleaning Test Facility in January 1985. These tests, using -28 mesh (0.6mm) froth flotation product, show that the high-G, solid-bowl centrifuge can produce clean-coal moistures of less than 12 percent at solids recovery rates exceeding 98 percent. The high-G centrifuge achieved these low moistures by applying centrifugal forces up to 2,000 times gravity. Because these forces are two to three times the forces used in a screen-bowl centrifuge, the high-G centrifuge can use a solid bowl and still produce a low-moisture product. The solid bowl captures ultrafines that would pass through a screen bowl, and thus obtains higher recovery rates than a screen-bowl centrifuge.

Jan 1, 1985

By J. G. Nalven

On July 1, 1999, most domestic metal mines will have to report releases of toxic chemicals into the environment for the first time as required by SARA Title 313. Some of these reportable releases will appear huge in relation to reports by other industries. The reasons for the potentially large reportable releases, special considerations for mining operations, and strategies for dealing with the reports are described. Data composited from experience with several mining companies is presented in the context of a typical gold mine.

Jan 1, 1999

By Douglas D. Donald

The financial analyst's job is to make an objective appraisal of the investment opportunities which exist within the various industries under his supervision within the context of the economic model provided by his firm and the a climate of investor sentiments. Industry analysis is critical. When a major investment trend develops, usually the stock of all companies within the specific industry react in the same direction. I should emphasize here, however, that an investment trend is influenced by the economic outlook, but economics is not the only determinant - investor psychology and arbitrary political factors may be of equal or greater importance. Part of our job is to recognize trends early and determine whether they are valid. Following industry analysis, the analyst must examine the specific companies within that industry since some companies usually react more violently than others to industry trends, whether they be favorable or adverse. To simplify the process of evaluating an investment opportunity, it is convenient to isolate three types of factors which have a bearing on every sort of business although the degree of influence of each factor may vary from industry to industry. These categories are, 1) independent or external factors insofar as they are beyond the control of corporate management, 2) interdependent factors insofar as influence may be exerted by industry-wide action, and 3) dependent factors covering the area of internal decisions which are basically under the control of the individual corporate managers. Although the title of this paper, "The Corporate Use of Cash Flow," is only one segment of the third category, it may be useful to continent on the first two categories as well. The independent factors may be either economic or governmental. The economic factors include cyclicality which may be very high in the case of the basic commodity industries or relatively low as in the case of utilities. Underlying growth rates, another independent factor, may range from the business equipment industry with an annual growth rate of 14% through the electric utility industry with a growth rate of about 7% per year to the

Jan 1, 1970

By X. Cheng

The mechanism of cathodic decomposition of pyrrhotite was studied in deoxygenated solutions at natural, near neutral pH using potential and cyclic voltammetric measurements. Reaction products on pyrrhotite surfaces were examined by AES and XPS, and by analyzing the voltammograms for the electron balance of the reactions. Surface properties of the pyrrhotite/solution interface were characterized using ac impedance technique. The parameters of an equivalent circuit were determined by the nonlinear least squares fit (NLLSF) technique. The effect of cathodic polarization on floatability was investigated by micro-flotation tests. Possible implications to the flotation separation of chalcopyrite-pyrrhotite ores are discussed.

Jan 1, 1993

By B. N. Everett

The growing role of Colombia as a major supplier of internationally traded steam coal has been widely discussed in the industry. Although Colombian coal has been produced and exported in small quantities for a number of years, Colombia's position as a major coal exporter began in earnest in 1985 with the first commercial exports from the Cerrejon North Block Project. By way of background: ? The mine is located on the Guajira peninsula in Northeast Colombia, about 90 miles from the coast, as shown in Figure 1. ? In addition to the mine itself, the project involves construction of a dedicated railroad and port, which form a modern, efficient and integrated system. ? The Project is embodied in a 50/50 Association Contract between International Colombia Resources (Intercor), a wholly owned subsidiary of Exxon, and Carbocol, the Colombian state coal company. Intercor and Carbocol share investment and operating expenses equally and Intercor has the additional responsibility of managing operations on behalf of both partners. Each partner is entitled to 50% of the coal produced, and each markets its share separately. ? The project is a multi-seam, truck and shovel operation, based on large reserves (2-3 billion tonnes') of high quality bituminous coal. ? Exports began in the first quarter of 1985 at modest levels through what we call Early Coal Facilities, designed and constructed apart from the permanent coal handling system. ? Production will increase rapidly in each of the next few years, reaching the design capacity of 15 Mt per year in 1939. Based on available resources, however, the resource will support expansion, and continued growth n production into the 1990s appears feasible.

Jan 1, 1986

By Wayne A. McCurdy

I welcome the opportunity to meet with you and discuss the work and program of the Office of Coal Research. Our programs are oriented to serve the conservation objectives of the Johnson Administration and of the Nation by seeking out the most efficient and best uses for coal. We believe that even if only a portion of our program is successful, the coal industry and the Nation will benefit far out of proportion to our expenditures. Operating with a budget of $7,220,000 in Fiscal Year 1966, OCR sponsors contract research which offers potential for achieving benefits to the coal industry in the form of new production and new markets. This directs us into many areas of research activity: in coal combustion, in advancements in mining methods and coal preparation, in new uses for coal, and in associated economic and marketing research.

Jan 1, 1966

By David D. Eyer

In today's world coal market, coal quality is becoming increasingly important. Often the coal quality parameters are one of the crucial considerations in the development of a coal mine. Because of the user's tighter specifications and because of strict environmental regulations, coal producers are being called on to predict with increasing accuracy, not only the quality of their product but also the variability of that quality. This area of reserve evaluation is naturally receiving a great deal of scrutiny. Consolidation Coal Company has developed reliable and sophisticated methods for predicting coal quality, but the company's efforts continue to search for even better techniques. The following is a step-wise summary of The methods currently used by consolidation coal company, with A recent project used as an example. Two of the newer, and as yet experimental techniques will be briefly discussed.

Jan 1, 1980

By C. Y. Chen

In order to put an end to the uneven environmental standards and enforcement established by various coal mining States in the United States, the Congress passed and the President signed the Surface Mining Control and Reclamation Act (Public Law 95-87 or the Act) on August 3, 1977. Within one year after passage, the Secretary of the Interior was directed to promulgate permanent program regulations implementing Title V provisions of the Act. These regulations were to form the basis for State regulatory programs under the Act and to allow States to assume primary regulatory responsibility. In order to implement the underground mining provision of the Act, the Secretary is directed in section 516(a) of the Act to promulgate rules, but ones which take into consideration the distinct differences between surface coal mining and underground coal mining. The regulations developed by the Secretary and promulgated on March 13, 1979, with respect to subsidence control, included (1) a subsidence control plan as part of the permitting process, (2) substantive provisions establishing performance standards for subsidence control, and (3) provisions providing for the prohibition of mining under perennial streams, impoundments larger than 20 acre feet, and certain public facilities and urban areas.

Jan 1, 1985

By R. S. Austin

One third of the world's and most US kaolin is produced from Late Cretaceous and Early Tertiary sedimentary strata in Georgia and South Carolina. The kaolin is part of a belt extending to Arkansas of aluminous lateritic deposits, including bauxite. Original sediments were profoundly altered by chemical weathering during Early Tertiary time. Mining exploits those uncommon deposits where extreme leaching and chemical recombination have produced a clay of nearly pure mineral kaolinite. . Its whiteness, brightness, fine particle size, platelet shape, surface chemistry, and chemical composition make kaolin an important pigment, filler, extender and chemical compound in the paper, paint, plastics, ceramics and catalyst industries.

Jan 1, 1998

By J. C. Irvine

Meramec Mining Company is a joint venture by Bethlehem Steel Corp. and St. Joe Minerals Corp. which mines and pelletizes iron ore at the Pea Ridge Mine. The Pea Ridge property is located near Sullivan, Missouri, about 70 miles southwest of St. Louis. The orebody was delineated in the mid-1950's by St. Joe during a lead exploration program. The first test holes drilled on the Pea Ridge magnetic anomaly revealed the presence of a large magnetite deposit; further drilling in 1956 and 1957 confirmed that the orebody was mineable, Meramec Mining Co. was incorporated in 1957 and shaft sinking began late in the year. Production commenced in April 1964. The orebody is overlain by about 1300 feet of flat-bedded sediments. It is tabular, about 2600 feet long and up to 600 feet thick. It dips about 80° and is of unknown depth. The ore is mainly high grade magnetite with small zones of specular hematite. The wall rock is a Precambrian rhyolite porphyry. The mine was initially started with five major levels on 150 foot intervals. Crosscuts were driven across the orebody on 190 foot centers. Banks of scopes were mined between the crosscuts by a modified shrinkage stoping method. This was done by undercutting a 40 foot wide by 150 foot long block and blasting horizontal "lifts" drilled on 5 foot intervals. A 65 foot still was left between levels which contained the slushing drift, fingers, crown pillar, and adequate thickness for support. By 1971 a ?lattice? of pillars had been left and mining had progressed to the point that an orderly pillar recovery program was necessary.

Jan 1, 1976

By John C. Brower

Bolivia is nor a major gold producer but has produced continuously since pre Inca times. Production reached a peak in 1964 of about 4,000,000 grams and is currently about 1,000,000 grams. Production is mainly from the Tipuani River valley north of La Paz and is derived from Pleistocene basin fill: the Cangalli conglomerate and overlying terraces. Abandoned Pleistocene lake terraces south of La Paz in the Oruro area are another source of gold whose potential have not been realized. In both the Tipuani and Oruro areas, primitive hand methods are the principal means of production, with the exception of a single modern dredge. In spite of a long history of production, probably very little of the gold potential has been mined.

Jan 1, 1979

By Geoffrey Purcell

Improvements which have been made in commericial flotation systems during the past fifty years have resulted more from trial and error methods in the mill than from research in the laboratory. Research has often provided explanations of why mill changes have improved the metallurgical process. Hopefully, in the next fifty years, changes in mill flowsheets will come about, primarily, as a result of research work. However, since minerals, in their infinite variety, cannot be reduced to a standard state, research on commercial ores will have only a local utility, and research on pure minerals will have little commercial application. What will emerge from research on pure systems are mechanisms of adsorption, and this in turn may throw some light on the very much more complex adsorption processes taking place in the pulps of commercial ores. Quartz, without a doubt, has been the subject of more research effort than any other mineral, but we are still a long way from completely understanding its behavior in flo¬tation. Hematite and calcite have received considerably less attention. Ores containing a mixture of all three minerals, however, are commercially important, and the iron deposits in Alabama have been extensively studied by the United States Bureau of Mines (1). The literature reveals no reports of research on synthetic mixtures of all three.

Jan 1, 1967

By P. D. Lafleur

A concerted effort to determine the quantities and effects of trace elements in the environment requires the application of a number of different analytical techniques in the same or in different laboratories. The interpretation of analytical data is often difficult because of differing results between analysts or even by the same analyst at different times. Standard Reference Materials (SRM), which are certified for their trace element content and are in a matrix similar to the one of interest, can greatly increase the accuracy of analysis and the reproducibility between laboratories. The United States National Bureau of Standards (NBS) has developed a number of SRMs applicable to the determination of trace elements in environmental materials. Two of these, SRM-1571, Orchard Leaves, and SRM-1577. Bovine Liver, are excellent for biological tissue analyses. Several new standards are of value for fossil-fuel analyses. These are: SRM-1632. Trace Elements in Coal; SM-1633, Trace Elements in Fly Ash; SM-1634, Trace Elements in Residual Fuel Oil: and SRM-1635, Trace Elements in Gasoline. In cooperation with the US Environmental Protection Agency, the NBS has recently concluded an interlaboratory comparison involving analyses by more than 60 laboratories on these fossil-fuel materials. The resulu of this intercomparison and the broad range experience with the biological materials will be presented showing both intratechnique and intertechnique variations, and the sensitivities and comparisons with the values certified by NBS.

Jan 1, 1975

By Fouad Faraj, Julian M. Ortiz

Within the natural resource industries, there is an increasing amount of data and number of variables being recorded when sampling a site. This has made multivariate geospatial datasets more difficult to analyze, in particular the definition of estimation or simulation domains used in geostatistical analysis. Establishing these domains is typically the first step for any subsequent geostatistical workflows or modeling. Domains are traditionally established using categorical data such as lithology, mineralization, or alteration from geological logging and are aimed at identifying distinct populations with particular geological, spatial, and statistical features. The manual logging process is time-consuming and costly but is required because defining geologically homogenous volumes is crucial for the planning, extraction, and processing of natural resources. Classical clustering methods have aided in analyzing the multivariate datasets, but the resulting clusters from these methods do not correlate well with geological logging and do not allow practitioners to input their knowledge of the domain in the clustering process. In this work, a simple unsupervised classification workflow is presented which allows the practitioner to input domain knowledge by selecting relevant variables to cluster reasonable geological domains. This can be used as a tool to aid the manual logging procedure or as a tool to establish domains for different uses such as defining zones with different rock hardness distributions which allows the corresponding volumes to be sent to appropriate mills for efficient mineral processing. The performance of the workflow is assessed on a mining dataset using the geochemical information and validated with the geological logging.

Apr 16, 2021

By Gamal Rashed, Tim Miller, Nicole Evanek

High horizontal stress has been identified as a critical factor affecting roof stability in underground mines, particularly when the immediate roof consists of weak or laminated rock. Numerical models were employed to better understand the influence of caprock thickness, cutting sequences, and the orientation of driving direction relative to maximum horizontal stress on roof stability in underground stone mines. These models were calibrated based on field observations of roof falls from the study mine. The findings of this study enhance our understanding of roof stability under high horizontal stress and contribute to reducing the risk of roof falls in underground stone mines.

Feb 1, 2025