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By A. Porvali, V. Agarwal, M. Lundström

Hydrometallurgical recovery of rare earth elements (REE) from NiMH battery waste can be performed using sulfuric acid leaching followed by selective precipitation as double salt (REENa(SO4)2•H2O) by adding Na2SO4 as a precipitating agent. The formed double salts can be treated further with NaOH solution to form REE hydroxides. This study focuses on metamodeling of a simulated flowsheet with design of experiments (DOE). Based on literature survey, a process flowsheet was developed using HSC Sim software. The created flowsheet focuses on circulation of solution containing Na+, K+, SO42- ions and impurities liberated in the NaOH treatment of double salt precipitate. The effect of seven parameters (P1-P7) on seven responses (R1-R7) were modeled using central composite design (CCD). INTRODUCTION Nickel metal hydride (NiMH) battery waste can be considered as an urban mineral due to the presence of valuable metals like: Ni, Co and rare earth elements (REE) (Larsson et al., 2013). In NiMH battery waste leaching experiments, sulfuric acid has often been employed as a lixiviant (Pietrelli et al., 2002,Zhang et al., 1999,Rodrigues and Mansur, 2010,Porvali et al., 2018). The key advantages of sulfuric acid are its stability and cost-effectiveness compared to other mineral acids such as HCl and HNO3. However, the usage of sulfuric acid in NiMH battery waste leaching poses simultaneous challenges and advantages. Limited REE solubility can be taken as benefit when recovering REEs double sulfates after solid-liquid separation. However, sodium and potassium hydroxide, present in electrolyte residues in the battery waste, can cause in-situ precipitation already during leaching due to limited solubility, thus decreasing the total REE recovery (Porvali et al., 2018). However, this problem can be circumvented by washing the electrolyte residues off the raw materials. Subsequently, the REEs may be precipitated in bulk as a mixed double salt out from the solution at very low pH with minimal co-precipitation of Ni and other metals. This relatively easy separation method can be extremely advantageous in the case of such a complex solution matrix with relatively high REE concentrations (conc.). Once REEs have been precipitated as double sulfates as per eq. (1) (Porvali et al., 2018), the resulting double salt precipitate lacks applications without further treatment. Direct thermal treatment would generate sulfur dioxide emissions and likely require high temperatures in order to transform double sulfates into REE oxides. Furthermore, the precipitate contains Na ions, which would need to be removed by chemical treatment from the calcined REE product. In the context of circularity of raw materials, it can be taken of a remarkable benefit if the sodium and sulfur present in the double salt could be reused instead of wasting them into the side streams. To that end, in this simulation study, the double salts are converted by dissolution and precipitation to hydroxides which are readily treatable, e.g. with total dissolution and solvent extraction, for further purification (Abreu and Morais, 2010):

Jan 1, 2019

By Wallace Macgregor

The direct investment role of Middle Eastern oil producing countries in future world-wide mineral development probably will be a limited one for the next five years. Their needs and their longer range economic objectives substantially preclude any such risk taking ventures. There is, of course, the possibility of political in- vestment. One hears many rumors and doomsday calculations of what the Arabs might do with the rising accumulation of surplus funds. Up to now, this kind of investment has been more in rhetoric than in money. For the most part, oil producing countries of the Middle East have been, and will be, investing surplus funds with strong emphasis on the preservation of capital. They will seek security first and yield second just like any other prudent investor. In several respects, this is regrettable. A direct infusion of risk capital into mineral development, especially in the Third World countries, is a constructive way of enhancing their earning power which many desperately need just to stave off starvation. It would also be a good way of eliminating material shortages in the industrialized world. Most important of all, it would help to ultimately reduce inflation without imposing the hardship of recession. So why isn't it done?

Jan 1, 1975

By Z. Jin, D. DePaoli, P. Zhang

"Phosphogypsum is a byproduct created during the production of industrial wet-process phosphoric acid. This study focused on recovering rare earth elements (REEs) from a Florida phosphogypsum sample and investigated the effects of removing detrimental impurities such as phosphorus pentoxide (P2O5 ), uranium (U) and fluorine (F) during the leaching process. Experimental results indicated that REE leaching efficiency increased rapidly, reached a maximum and then began to decrease with sulfuric acid concentrations ranging from 0 to 10 percent and temperatures ranging from 20 to 70 °C. At a sulfuric acid concentration of 5 percent and leaching temperature of 50 °C, REE leaching efficiency obtained a maximum value of approximately 43 percent. Increasing the leaching time or liquid/solid ratio increased the leaching efficiency. The leaching efficiencies of P2O5, U and F consistently increased with sulfuric acid concentration, temperature, leaching time and liquid/solid ratio within the testing ranges. A fine-grain gypsum concentrate, sized smaller than 40 µm, was separated from leached phosphogypsum through elutriation, in which the P2O5, U and F content levels were reduced by 99, 70 and 83 percent, respectively, from their content levels in fresh phosphogypsum. IntroductionPhosphogypsum is a byproduct generated during the industrial wet process of phosphoric acid production, in which sulfuric acid is used to digest phosphate rock. Gypsum (CaSO4·2H2O), the main component of phosphogypsum, usually accounts for 65 to 95 percent of phosphogypsum by weight.There are small quantities of impurities in phosphogypsum, such as phosphates (H3PO4, Ca(H2PO4)2·H2O, CaHPO4·2H2O and Ca3(PO4)2), fluorides (NaF, Na2SiF6, Na3AlF6, Na3FeF6 and CaF), sulfates, trace metals and radioactive elements (Rutherford, Dudas and Arocena, 1996). Global phosphogypsum generation is estimated at 200 Mt/a (Parreira, Kobayashi and Silvestre, 2003; Yang et al., 2009), but only about 15 percent is recycled as building materials, agricultural fertilizers or soil stabilization amendments (Tayibi Choura and Lopez, 2009)."

Jan 1, 2017

By Terry A. Rightnour

Multiple seam mining is predominant throughout the central Pennsylvania Appalachian coal fields. Wide ranges in individual seam thickness, coal quality, and overburden characteristics are common throughout the region. On typical mining permits, ranging from 404 x 103 to 2023 x 103 m2 (100 to 500 acres), often as many as eight seams are concurrently mined, with each interburden requiring unique economic and environmental consideration in the mine plan. Specifically, this paper presents several planning tools and operational guidelines developed in response to current regulations for the special handling of potentially acid-forming materials as they are related to development and operation of multiple seam mines.

Jan 1, 1984

By P. Somasundaran, J. T. Kunjappu

Spectroscopic techniques are becoming increasingly popular for characterizing the interior of adsorbed layers of surfactants and polymers at solid- liquid interface as well as in the identification of com- pounds on mineral surfaces. This review encompasses the application of fluorescence and ESR spectroscopic techniques to reveal the microscopic environment of the adsorbed layers of surfactants and polymers on minerals with a special reference to the adsorption of anionic surfactants (e.g., sodium dodecyl sulfate) and polyelectrolytes (e.g., polyacrylic acid) at positively charged mineral (e.g., alumina) - water interfaces. Finally, the utility of XPS and auger techniques to identify the surface elemental composition of different mineral species has been related to their flotation efficiency.

Jan 1, 1987

By Peter Kreisman

This paper and four other papers on the MEQB Regional Copper-Nickel Study, presented today at the 1980 SME-AIME Fall Meeting are based on four years of extensive inter-disciplinary research and impact analysis supported largely by the Legislative Commission on Minnesota Resources. This study produced over 180 technical reports, the results of which are summarized in an Executive Summary available from the Minnesota State Planning Agency, St. Paul, Minnesota. Those wishing to examine the many scientific, engineering, environmental, social or economic issues addressed by the study are encouraged to obtain a copy of the executive summary. The executive summary includes a bibliography of all technical reports produced by the Regional Copper-Nickel Study and describes the five-volume, 26 chapter Regional Copper-Nickel Study Report.

Jan 1, 1980

By B. Mishra, K. Savage, T. Evans, A. Noble

"Recent government initiatives and commercial activities have targeted asteroids for in-situ characterization, manipulation, and possible resource extraction. Though emergent technologies may be effective for such undertakings, uncertainties remain concerning the effects a space environment may have on the mechanical behavior of rocks. Various non-destructive rock characterization techniques can empirically predict in-situ rock strength on Earth; however, these techniques must be adapted to account for unique space conditions. In order to mimic one element of a space environment, various rock samples were evaluated after prolonged exposure to low temperatures ranging from -75°C to 0°C. Tests included uniaxial compressive strength, Schmidt hammer, and ultrasonic pulse velocity, while rock types included shale, limestone, and chalk. This data was used to generate a temperature correction for the non-destructive methods and evaluate the accuracy of these methods in predicting strength values. Overall, these results provide insight on the mechanical behavior of rocks at low temperatures and may be used to design robust systems needed for asteroid rock characterization INTRODUCTION NASA and various commercial entities have recently targeted near-Earth asteroids for exploration and scientific investigation to better understand their in-situ properties, mechanical characteristics, and formative processes. In particular, NASA’s Asteroid Initiative encompasses several studies and mission plans that will enable future investigations while vetting technologies that can be applied to deep space exploration. One component of the Asteroid Initiative is the Asteroid Redirect Mission (ARM). This multi-stage space mission proposes to rendezvous a robotic spacecraft with a large near-Earth asteroid. Upon approach and after landing, the spacecraft will prospect the surface and identify a multi-ton boulder (up to 5 m in its largest dimension) suitable for capture. The robotic spacecraft will engage the boulder, remove it from the parent asteroid, and return the sample to a controlled lunar orbit. Once the asteroid mass is in stable orbit around the moon, astronauts aboard the Orion spacecraft will engage with the retrieved asteroid for manned exploration that will include sample collection and geologic prospecting. Launch plans for the ARM robotic craft are expected as early as 2020, and manned explorations of the asteroid mass in lunar orbit are expected to follow sometime in the mid-2020s (NASA, 2015). Overall this mission will demonstrate NASA’s ability to intersect, manipulate, and redirect an extraterrestrial body, while supplying scientific information that is relevant for planetary defense and in-situ resource utilization (ISRU) applications."

Jan 1, 2016

By H. Habenicht

Requirements for full extraction in underground coal mining call for inexpensive, safe, techniques to be competitive with conventional methods. Longwall and shortwall systems are to some extent employed for this purpose. Another method would be rib pillar extraction (and pillar extraction). These methods are compared with each other with respect to procedure, equipment, safety, roof control, investment, output, performance, costs The advantages of r.p.e. show this method very attractive. Number and cost of equipment are lowest. Safety and roof control becomes improved by a mobile roof support recently developed in Austria. Its successful use in the R.S.A. is being explained.

Jan 1, 1986

By William Gleason

The numbers tell the story of this one. More than 50,000 people and 1,890 exhibitors took over the Las Vegas Convention Center Sept. 24-26 for the largest mining trade show in the world ? MINExpo. Inside the convention center, some of the largest machines used in mining were on display. Caterpillar, Liebherr, Komatsu and Hitachi displayed ultraclass offroad mining trucks and shovels. Atlas Copco and Schramm were among companies that rolled in mining drills and Bridgestone, Goodyear and Michelin were among the companies showing off the massive tires used by the trucks. Throughout the three halls and an outdoor display area, just about every kind of product, gadget or service used in the mining industry could be found on display somewhere.

Jan 1, 2012

By C. Dale Elifrits

Observations made from laboratory analysis of samples of fine-grained argillaceous materials (shales) subjected to various changes in moisture content have been correlated to loss of strength in the rock material. This reaction to a change in in-situ conditions (subsequent to mining) at a mine site combined with the observed relationships of surface-disturbing subsidence features at locations where the predominant overburden material is fine-grained, provides a predictive tool for the subsidence engineer.

Jan 1, 1983

By Edward A. Vitunac

The emerging importance of pneumatic conveying systems for bulk materials is becoming recognized by more persons responsible for materials management as consultants, at the corporate level and at the plant level. They have learned that the economic advantages of a pneumatic system are frequently decisive when compared to alternate methods. Included in these advantages are relative simplicity, ease of installation, flexibility, ease of maintenance, cleanliness, safety and ease of automation to the degree desired. In general, installed costs favor a pneumatic system when compared to competing mechanical systems if the transporting distances are long or to and from many points. In addition, supplemental use such as cooling, heating, or drying may supply the incremental value required to justify its selection. (1). The main disadvantages of a pneumatic system is the greater horsepower required per unit weight of material conveyed and material limits in abrasiveness and density. In addition, there is a tendency to increase material breakage at changes of direction and at any obstruction such as the imperfect butting of one, piece of pipe to another in the conveying line. Classification of the material at the discharge may also cause problems in dusting and segregation. Materials weighing less than 4 pounds per cubic foot tend to cause feeding and collecting problems although they can be conveyed easily. Material between 4 and 20 pounds per cubic foot can be handled with less problems but flow rate is hard to predict. The 20 to 60 pounds per cubic foot range offers best results; whereas, over 60 pounds per cubic foot, materials tend to drop out of the air stream and settle in the pipe line unless careful provisions are made to prevent it. (2).

Jan 1, 1967

By M. J. Richards

Spontaneous combustion caused by the movement of air through the waste is a major problem. Combat methods attempt to exclude oxygen rich air, but little is known about airflow through the waste. The use of a tracer gas technique to monitor the flow of nitrogen from an injection hole during inertisation is described. Correlations are drawn between barometric pressure changes and the nitrogen entering the waste. As no information was obtained about airflow and oxidation zones, a second experiment was conducted to sample from the waste, but the results were inconclusive. A finite element method developed to model the pressure and airflow distribution, under steady state and nitrogen injection conditions is outlined

Jan 1, 1987

By G. L. Smit

The Buffelsfontein Gold Mining Company is situated in the Klerks-dorp district of the Province of the Transvaal in the Republic of South Africa, approximately 100 miles west of Johannesburg. Gold production commenced in January 1957 and Uranium treatment of residue slimes as a by-product started in July 1957. The mining property is 5435 mining claims in extent, the equivalent of 7,988 acres or 12.5 square miles. The mine was initially exploited by the Pioneer Twin Shaft System, consisting of a 26 feet diameter down-cast shaft and a 22 feet diameter up-cast shaft, sunk in the north-west area of the mine to cater for the hoisting and ventilation requirements for a milling rate of 150,000 tons per month.

Jan 1, 1964

By A. R. Negele

Kaolin-based pigments are the most widely used pigments in the paper industry. Several types are available and include standard hydrous, delaminated, calcined, chemically-structured, and most recently, composite pigments. Within each category, a spectrum of products is available to satisfy the application requirements of paper producers. The paper industry has a broad range of applications including fillers in woodfree and groundwood-containing papers, pigmented size press applications, ultra-lightweight and lightweight coated papers, coated merchant papers, cast coated papers and coated paperboard. Each application has its own set of performance criteria and suppliers must work with mills to identify appropriate product(s) to fulfill these requirements.

Jan 1, 1993

The General Purpose Simulation System (GPSS) is a computer simulation language that has been used for simulations of open pit haulage operations since the 60's. It is easy to learn, simple to use, and has a block-diagram structure that is amenable to load-haul systems. However, due to its lack of flexibility, there are situations where another language should be chosen. This paper reviews the characteristics and capabilities of both GPSS and FORTFAN with regard to open pit shovel and truck simulation. The relative advantages and disadvantages are highlighted and a case study presented along with comparative results from two computer models (one written in GPSS and the other written in FORTRAN).

Jan 1, 1986

By H. R. Bullis

Lupin is located on the shores of Contwoyto Lake at lat. 65° 48'N, Long. 111° 15'W and lies about 80 kilometers south of the Arctic Circle. Since start up in 1982 the mine has produced over 2.15 million ounces of gold from 6.66 million tonnes of ore grading 10.63 gm/tonne. Total remaining reserves at 1993 year end were 5.1 million tonnes at a grade of 9.11 gm/tonne (1.65 million ounces). This is sufficient for 7 -8 years at the present annual production rate of about 200,000 ounces. The Centre and West Zones of the deposit are open to depth. The deposit is in an Archean metaturbidite sequence of the Contwoyto Formation, which has been mapped as part of the Yellowknife Supergroup of supracrustal metasedimentary and metavolcanic rocks making up part of the Slave Geologic Province. These rocks have been subjected to regionar and contact metamorphism and to several phases of deformation. Six stages of Archean plutonism have been identified and all Archean rocks have been cut by Proterozoic diabase dyke swarms. Gold mineralization in the Lupin deposit is commonly fine grained and associated with pyrrhotite and arsenopyrite in amphibolitic banded iron formation. The gold-bearing portions of the host iron formations are characterized by the presence of multiple quartz veins and the pervasive replacement of grunerite by hornblende. In sparsely mineralized portions of the host iron formation, zoning of sulfides about quartz veins is clearly seen with the arsenopyrite halo being more restricted around the veins than the pyrrhotite halo. In well mineralized portions, quartz vein densities approach one vein per metre along strike. In these areas pyrrhotite distribution in the iron formation is more pervasive and the rock takes on the appearance of a banded sulphide rock.

Jan 1, 1995

By H. Majima

In spite of the importance of the presence of pyrite in the flotation of sulphide ores, not many studies have been made from the electrochemical point of view. It is generally recognized that the oxidation of sulphide minerals is one of the most Important factors among those which affect the floatability of sulphide minerals. The concept that the presence of oxygen is essential to the flotation of sulphide minerals is supported by numerous experimental results (1). The presence of oxygen in sulphide minerals- aqueous solution systems would affect the electrochemical behaviour of sulphide minerals and subsequently lead to more complicated reactions on the surface of sulphides. Actually some of the phenomena observed in sulphide flotation are deemed to be more appropriately explained from the electrochemical point of view. The author and co-workers have studied extensively the electrode reactions of pyrite and its significance in sulphide flotation. The results have been partly published elsewhere (2-7). In this paper, the author discusses the electrochemical nature of pyrite, and the three different phenomena observed in pyrite flotation: (1) Xanthate¬dixanthogen system on pyrite, (2) Flotation of complex sulphide ores containing pyrite and (3) Depressive mechanisms of pyrite with cyanide. The phenomenon which has been known as an iron contamination effect due to steel grinding media on sulphide flotation is also explained from the electrochemical aspect. However, this problem is not directly concerned with pyrite, and it will be discussed elsewhere (8).

Jan 1, 1971

By M. E. Rossi, J. A. Bassan, J. B. Novillo

Sampling and geological models are the basis of recoverable resources models. They are pillars of mineral resources and reserves estimation, and what geostatistical methods for grade estimation should rely upon. The resource model is best estimated if geostatistical methods make good use of sound geologic models. Data collection from the original drill holes, including field procedures and the quality assurance and quality control (QA/QC) of those samples are pillar one of a resource model. The second pillar of the model is the good use of the logged geological information, resulting robust geological interpretations, and the corresponding three-dimensional models of those interpretations. These models are partly subjective and mostly conditioned by the quality of logging and the geologist’s experience. They are also conditioned by the quality of the three-dimensional models built, regardless of the modeling method employed, traditional or implicit. Grade estimation is more commonly done by applying some geostatistical method and using the two basic sources of information, data and geologic model. Multiple stages are involved in this process, and in all of them there are uncertainties and risks that have to be dealt with. Knowledge, understanding, interpretation, and management of the model’s fundamentals are critical, given that they directly affect its accuracy and predictive quality. The mitigation of related risks allows for the creation of opportunities, generating value and reducing the project’s uncertainty. This paper discusses some of the key variables, uncertainties, and risks involved in the resource modeling process, illustrating with specific examples; discusses possible risk mitigation alternatives, and proposes best practices to avoid or mitigate those uncertainties. Emphasis is placed on taking advantage of technological advances without ignoring fundamentals. INTRODUCTION In the area of mineral resource estimation, one alarming trend that these authors have observed in the past 20 years or so is that the care and diligence in checking the work as it progresses has generally diminished. This is, perhaps, an unintended consequence of the availability of new technologies and tools that attempt simplify and speed up the work involved. This has led to a more casual attitude towards checks and balances that have to be in place at any given stage of the process before proceeding to subsequent stages, as best practices dictate. To some extent, some of these aspects are covered in international standards for resource estimates reporting (JORC, 2012; CIM, 2010). But these are broad, and do not specifically recommend best practices to a level of detail that would have an impact on certain aspects of the process. There are numerous references in the geology and mining journals and conferences that discuss the consequences of poor recoverable resource models (Baker and Giacomo, 1998; Vaughan, 1997).

Jan 1, 2019

By Zhe Wang, Tichang Sun, Yongqiang Zhao, Zhengyao Li

Coal-based reduction followed by magnetic separation is a promising technology for processing refractory iron ores. Analysis of the size distribution of metallic iron particles is an effective approach for exploring the mechanisms of coal-based reduction. As metallic iron particles exhibit very complex shapes compared with nature ores, approaches for measuring and characterising metallic iron particles still remain unclear. In this study, the size of metallic iron particles was measured and characterised using manual point-counting by optical microscopy technics and image analysis. The effects of CaF2 as an additive on behaviour of the particle size distribution (i.e. mean size and cumulative frequency distribution) were also determined. Results indicate that CaF2 had a significant effect on the growth of metallic iron particles. When the CaF2 dosage increased from 0 to 8%, the mean size according to the area method increased from 9.03 to 16.28 μm, while the promotion effect gradually weakened and generated many fine metallic iron particles when the CaF2 dosage exceeded 8%. An increase in CaF2 dosage also led to cumulative distribution curves gradually shifting to the right mainly because F− can break the crystal structure of each phase during the carbothermic reduction of titanomagnetite and reduce the stability of the lattice structure, thus reducing the melting point and accelerating the growth of metallic iron grains. Compared to different measuring methods, the area method is a more suitable approach for measuring and characterising the size of metallic iron particles.

Sep 18, 2020

By J. J. Kollé

A compressed-water hydraulic pulse generator (HPG) for nonexplosive blasting of rock and con¬crete is described Energy is stored in the HPG by compressing water to ultrahigh pressure. A large, fastopening valve discharges the com¬pressed water, resulting in a high-energy impulse. The HPG can be used for small-scale bench blasting by discharging the water through a nozzle that is closely fitted into a borehole. A bench blasting system requires an HPG, a drill and an indexing mechanism to allow insertion of the HPG nozzle into a drilled borehole. Systems with discharge energies ranging from 40 to 250 kJ have been used to excavate hard rock, including andesite, granite and quartzite. The largest system can excavate 15 t/h (16.5 stph) of massive quartzite based on a 2-min cycle time for hole drilling. Blasting with an ultrahigh-pressure hydraulic pulse generator was demonstrated as an effective means of excavating hard massive rock under the confined conditions of a tunnel opening or underground sloping panel. Hydraulic blasting provides a continuous mechanized mining capability that is well suited for deep-level mining and urban excavation sites where explosives are prohibited

Jan 1, 1997