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By L. L. Oden

The Bureau of Mines has studied a number of processes to remove Cu from molten steel scrap with the objective of determining if any of the laboratory methods studied warranted in depth research investigations. Experimental approaches included oxidizing Cu from steel containing other metals that form stable mixed oxides with Cu (AI, Cr, Fe, Mn, Mo, and V), injecting the same metals as oxides to simplify the mechanism of complex oxide formation, partitioning Cu into alkali or alkaline earth silicate slags or oxide-moderated sulfides, and coremoving Cu and S by injecting active compounds of Ca and Mg. The most promising tests, producing nearly 0.3 pct Cu in the slag, used Ar injection of K20-moderated Na2S-FeS below the surface of molten steel containing about 0.6 pct Cu and protected by a CaO-SiOz slag; however, in depth research investigations currently are not felt to be warranted.

Jan 1, 1987

By Bill M. Stewart

To decrease the potential for fine coal waste slurry impoundment failures, the Bureau of Mines investigated a new disposal technique. The fine coal waste slurry is rapidly thickened (i.e., dewatered) and deposited on a slightly sloping surface. To accomplish rapid dewatering, a chemical flocculation system using polymers was developed to treat the fine coal waste slurry stream. The fine solids formed flocs, settled from suspension, and rapidly released excess water. During the last 5 days of the field test, slurry flowing at rates from 498 to 675 gal/min with a specific gravity range of 1.15 to 1.33 was successfully treated and dewatered. During this period, untreated slurry had an average moisture content of 227.4 pct (30.7 wt pct solids). The effectiveness of the dewatering system was determined by monitoring the moisture content of the deposited waste with respect to time. Sixty-five hours after ending the field test the average moisture content was 54.9 pct (64.5 wt pct solids); 68 days after the field test the average moisture content was 28.8 pct (78.0 wt pct solids).

Jan 1, 1986

By H. O. Poppleton, F. E. Block

This investigation was made to develop a method of preparing high - purity thorium metal in quantities up to 20 kilograms per batch . Several methods for the preparation , purification , and reduction of thorium tetrachloride are discussed . Thorium tetrachloride was prepared by chlorination of decomposed thorium nitrate or oxalate with carbon tetrachloride or phosgene . tion of the crude tetrachloride was achieved by multiple distillations or by filtration of the molten chloride . It was found that high - purity thorium metal could be prepared by sodium reduction of thorium tetrachloride if chloride of sufficient purity were available . Byproduct salts and excess reductant were removed by vacuum distillation , and the resultant thorium metal sponge was consolidated by consumable - electrode or fixed - electrode arc melting . It was demonstrated that metal prepared by this method could be fabricated into bar , rod , or sheet , at room temperature .

Jan 1, 1964

By F. E. Griffith, C. H. SEELING

Cardox blasting is used widely in coal mines in the United States . A model of a Cardox blasting device was approved by the Bureau of Mines subject to certain conditions and limitations , and the approval was extended to other models from time to time . Certain special hazards are entailed in the use of Cardox as with explosives . One of these is flying shells . In some blasts , the Cardox shell is violently ejected from the borehole and flies like a projectile , frequently ricocheting off solid objects and striking points considerably off the line of its initial flight . Flying shells have been known to pierce the webs of structural - steel beams , to pass through both sides of allsteel mine cars , to be driven through stout hardwood timbers , to knock out timber sets , to damage loading equipment , and to break or short - circuit power lines . A considerable number of shot - firers and other workers have been struck by flying shells and killed or injured . Accidents from this cause , although not as frequent as other types of mine accidents , are usually serious , closely approximating accidents caused by blasting with ordinary explosives . The increasing number of such accidents prompted a Bureau of Mines field investigation of possible methods of preventing dangerously violent ejections of Cardox devices . This report contains pertinent data collected during the investigation and describes methods tested and discarded as well as the development and proof of an apparently satisfactory method .

Jun 1, 1943

By M. M. Tilman

The purpose of this investigation was to determine the effects of small amounts of cobalt in nickel on the tensile properties and hardness of representative types of austenitic stainless steels . Cobalt substitutions for nickel up to 2 weight - percent were made in types 302 and 309 stainless steels . Data were obtained at room temperature for tensile strength , yield strength , percentage elongation , percentage reduction in area , and hardness . In type 302 steels , tensile strength and hardness increased with increased percentages of cobalt , percentage elongation and reduction in area decreased , and yield strength showed little change . Property changes were largely due to the reduction of nickel content rather than to the addition of cobalt . In type 309 steels , only minor variations were observed for the properties investigated ; the effects of the relatively snall cobalt substitutions and nickel reductions were somewhat reduced by the higher total alloy content .

Jan 1, 1964

By A. W. Fahrenwald

The logic leading to the development of the experiments in this paper already has been stated in Part I,3 but is briefly as follows: The results of the batch-grind experiments in which time of "grind" and fineness of finished product were the variables, strongly indicated (1) that batch grinding involving a single grind could not be operated under any condition to give maximum mill efficiency, (2) that the, sieve analysis of the feed charge in the mill materially affected the efficiency of the mill, and (3) that the percentage of finished product in the mill is a vital factor in ball-mill efficiency. A laboratory closed-circuit grind technic designed to simulate present closed-circuit grinding suggested itself, in which: a ball mill and a classifier constitute the grinding unit. The features of the closed-circuit grinding system are: (1) Short large diameter mills, (3) rapid flow of pulp through the mill, (3) continuous automatic removal of finished product from the system, and (4) high circulating loads. The high circulating load is a result if the short length of the Mill - that is, of the time the charge remains in the mill - and the small percentage of finished material produced during each circuit of the feed through the mill.

Jan 1, 1930

By D. B. McGilvra

This paper, describing the mining practices and methods at the Black Rock mine, is one of a series of similar papers on mining methods in the various mines of the United States being prepared by the Bureau of Mines. The Black Rock mine is located in the northeast corner of the Butte district, about 3 miles from the center of the town of Butte, and is owned and operated by the Butte & Superior Mining Co.

Jan 1, 1930

By J. E. Geier

This Bureau of Mines report reviews hypotheses for the mechanism by which water jets reduce the specific energy of cutting for drag bits. Several of these hypotheses are shown to be inconsistent with published evidence and new observations. The notion of a limiting cutting speed, above which water jets would be incapable of rendering assistance, is shown to be improbable. The hypothesis that seems most plausible is that specific energy reductions are mainly due to the erosion of crushed materials from in front of the bit. This hypothesis leads to a prediction that, for a given rock type and jet-bit configuration at a constant depth of cut, the reduction in bit forces should be a function of dM/dx, the jet energy spent per unit length of cut. This dependence upon dW/dx is shown to be consistent with other workers? results.

Jan 1, 1987

By Robert Lundquist

REAM is a unique method of rock breaking using high energy projectile impact. This report-describes the most recent in a series of tests demonstrating mining applications for the REAM method. In an underground limestone mine at Greer, West Virginia, REAM was used to drive a short tunnel and drill a large diameter borehole. Along with breakage data from these tests the goal of the program was to examine environmental problems which might result from the use of cannons under-ground. A total of 103 shots was used to advance a 14-l/2-feet high by 10-feet-wide face a distance of 5-1/2 feet. It is estimated that the 9.3-pound-concrete projectiles launched at 5000 feet per second will break an average of 0.78 tons of limestone or 67 percent of the 1.125 tons of granodiorite broken in previous tests. The 9-inch-diameter borehole was drilled horizontally by repeated axial impact for 7 feet, 2-1/2 inches by 21 shots giving an average of 4.12 inches per shot. Scaling this result to compressible impact energy yields an estimated 5.8 inches per shot for a 12.8-inch-diameter hole compared to 8 inches per ~hot for a 16-inch-diameter hole in granodiorite. Noise measurements indicate that a silenced cannon can be used within a few hundred feet of mine personnel in a room and pillar mine within the legal limit of 140 dB impulse without additional protection. Some fume measurements were made with satisfactory results, even though the military propellants used produce much greater quantities of toxic fumes than the liquid propellant proposed for the future.

Jan 1, 1976

By Catherine C. Kilgore

The Bureau of Mines investigated the availability of manganese from known domestic occurrences. Eight of these deposits were found to have demonstrated resources totaling 420 million metric tons with an average grade of 10 percent contained manganese. They were found to be submarginally subeconomic. Economic evaluations of the eight deposits resulted in incentive prices ranging from $8 to almost $35 per long ton unit (22.4 pounds) of contained manganese. Comparing these prices with the current market value of $1.70 per long ton unit of manganese clearly illustrates the submarginal nature of the domestic ores analyzed. These domestic resources would probably not be developed except in the case of an extreme national emergency. Production from the eight deposits would take 3 to 6 years to develop, and the final product would be manganese ore concentrate, which could be used in the production of ferromanganese. If preproduction development began in 1981, annual production would peak in 1987 with 900,000 metric tons of recoverable manganese. Thereafter, production would see a steady decline unless additional resources were located or technologic improvements were made to allow processing of lower grade material, or unless mining and processing of ocean manganese nodules began to take place.

Jan 1, 1982

By G. R. Palmer

Using a fluidized, countercurrent multiple-compartment ion-exchange (MCIX) column previously developed by the Bureau of Mines, Bureau researchers have successfully extracted uranium from a simulated acidic in situ leach liquor that contained 150 ppm U30s? This successful demonstration of the MCIX system is reported, and the effects of varying the operating conditions on the performance of the system are also examined. Operating the MCIX system with a flow rate of 15 gpm/ft2 and an aqueous-to-resin flow ratio of 200:1, more than 90 percent of the uranium Has extracted, and a resin containing approximately 28 grams U308 per liter was produced. The absorption column used to investigate the operating variables was approximately 18 feet long with a 2-inch ID and was divided into compartments that were 1 foot long.

Jan 1, 1980

By Sara J. Davenport

Hydrogen sulfite has been listed (1)3/ as a possible hazard in 50 occupations, many of which are in the mineral industries. The effects of its occurrence in the petroleum industry made themselves felt more than two decades ago, resulting in a comprehensive study (2) of the toxic gases from Mexican and other high-sulfur petroleum products. The mining industry, likewise, has had cause to guard against this gas. Enough hydrogen sulfide has been found in coal and some noncoal mines during normal operations to cause severe eye irritation, some serious illness, end even fatalities. It is usually a product of the decomposition of sulfur compounds and may be produced by burning explosives containing sulfur; the gas in harmful qauntities is formed by the use of block blasting powder or by the use of dynamite in blasting sulfide ores. Hydrogen sulfide is readily soluble in water, and enough may be released from water streams in coal and noncoal mining to cause fatal poisoning it is found sometimes in stagnant water underground, particularly where ventilation currents are absent, and great care must be exercised when accumulations of such waters are disturbed, as exposure to comparatively low concentrations of the gas evolved therefrom has caused fatal accidents.

Jan 1, 1945

By Constantine C. Popoff

During 1946 several high-grade limestone deposits in western Washington were examined by the Bureau of Mines. This report presents the data obtained from investigation of the Sauk Mountain deposits in east-central Skagit County, Washington, The investigation consisted of transit and topographic surveys and sampling. The areas selected for sampling were first cleaned by blasting; channel samples up to 40 pounds Were cut where practical. Chip samples averaging 30 pounds were taken where channel samples could not be cut. A total of 21 samples in the Sauk Mountain area were taken and analyzed. The locations of the samples are shown in figures 2 and 4, and the analyses are listed in tables 1 and 2. This investigation is a part of a long-range program of general investigation of mineral resources for future industrial development of the Pacific Northwest. The Sauk Mountain deposits were investigated for the purpose of disclosing new sources of high-purity limestone, which could be mined and shipped at low cost to Seattle and other industrial cities in the Pacific Northwest.

Jan 1, 1948

By R. W. Lewis

Spectrochemical procedures were developed using dc arc excitation for the determination, in parts per million, of 18 impurity elements in electrorefined beryllium and high-purity beryllium oxide. The metal samples were dissolved in dilute hydrochloric acid, evaporated to dryness, and converted to the oxide in a muffle furnace at 900° C. Germanium oxide was added as an internal standard for the determination of 15 of the elements, copper oxide for boron and molybdenum, and neodymium oxide for calcium. The average coefficient of variation was 11 percent with the exception of copper, which averaged about 43 percent.

Jan 1, 1962

By Stephen D. Cramer

A nondestructive procedure for measuring electrodeposit porosity has been developed which records the location and number of deposit defects including pores, pits, and voids. The procedure involves the passage of an X-ray beam through the deposit-substrate system onto suitable film. The defects are recorded as images on the film. Variables studied included intensity and spectra of the X-ray beam, composition and thickness of deposit and substrate, film type and developing procedure, and limits for detecting defects. At an X-ray tube voltage of 40 kv, pores several mils thick were easily detected in copper-nickel specimens more than 20 mils thick. To illustrate the utility of the procedure, the effect of substrate oxidation and of current density on electrodeposit porosity was briefly studied.

Jan 1, 1970

By Sidney Katell

This Bureau of Mines study estimates typical capital investments, operating costs, and selling prices for two bituminous coal strip mines in the Eastern and Interior provinces and a subbituminous coal operation in the Northern Great Plains province. The annual productions were based on tonnage required to fuel a 250-million-standard-cubic-foot-per-day, high-Btu gas plant. The annual tonnage for the Eastern province mine is 4.8 million tons; for the Interior province mine, 6.72 million tons; and for the Northern Great Plains province mine, 9.2 million tons. It is assumed that the mines have a 20-year life. Wages and union welfare payments are considered as of December 6, 1974, under the terms of the Bituminous Wage Agreement of 1974, and costs for material and equipment are based on 1975 indexes. Initial capital investment varies: $65,137,900 for the 4.8-million-ton-per-year (MM tpy) mine in the Eastern province, $78,514,600 for the 6.72-MM-tpy mine in the Interior province, and $42,050,100 for the 9.2-MM-tpy mine in the Northern Great Plains province. Total capital investments for the Eastern province mine, the Interior province mine, and the Northern Great Plains province mine are $86,969,900, $109,378,500, and $78,543,500, respectively. Corresponding selling prices for the coal, per ton, are $6.94, $6.03, and $3.39, assuming a 15-percent discounted cash flow rate of return after Federal income taxes. These studies are considered typical for the areas involved. Costs will vary depending on specific locations in these areas.

Jan 1, 1976

By V. A. Nieberlein

An extractive process was developed applicable to submarginal titanium deposits containing valuable minor constituents; such as columbium (niobium) and iron. The process consisted of reducing the mineral concentrate with coke at high temperature to form a carbide-suboxide sinter, chlorination in the 400° -500° C. range, and fractional condensation of the chlorides. The chlorination procedure recovered 97, 83, and 87 percent of the titanium from brookite, rutile, and ilmenite sinters, respectively, while simultaneous columbium recoveries on the same materials were 85, 50, and 87 percent.

Jan 1, 1957

By Laxman S. Sundae

In the vast majority of American coal mines, roof bolt holes are drilled dry, mainly because of mine operator concern with the spent water creating adverse working conditions. Wet drilling, however, can increase drilling rates and the effective lifetime of the drill bits used. This study, carried out as part of an ongoing cooperative research program between the U.S. Bureau of Mines and the University of Missouri-Rolla, shows that the large volumes of water conventionally used in wet drilling are not necessary, and the performance benefits from wet drilling can be achieved with total volume flows on the order of 0.4 L per hole. This conclusion is validated based on the measured respirable dust generated in drilling Berea sandstone. The results are confirmed using a variety of bit shapes, which are also shown to have a significant effect on penetration rate.

Jan 1, 2010

By D. L. Hollis

An arc plasma reactor, constructed and used for studying extractive metallurgical processing, was adapted by the U.S. Bureau of Mines to separate gases of different masses by using the high rate of plasma rotation. With argon and helium as input gases, peripheral reactor outlet ports had a measured average increase of about 10 pet in argon concentration relative to helium with the plasma on compared with plasma off for the same gas inlet concentrations in both cases. Approximately the same average increase in argon concentration occurred from the peripheral outlet port compared with a central outlet probe with the plasma on. There was no difference with the plasma off.

Jan 1, 2010

By W. D. Riley

The U.S. Department of the Interior, Bureau of Mines, has been conducting minerals recovery research in support of the nation's geothermal program since 1974. The Bureau's program of laboratory and field studies has focused on determining the materials of construction for geothermal resource recovery plants and an the recovery of mineral values from the geobrines. An analytical program has been conducted at the Avondale Research Center to determine the chemical constituents of some high- and low-salinity geobrines found in the Imperial, Valley of California. Data are reported for the early stages of brine production of femur geothermal wells--the low-salinity, medium-enthalpy brines from the East Mesa Known Geothermal Resource Area (KGRA), Mesa 6-1 and 6-2, and the high-salinity, high-enthalpy brine from the Salton Sea KGRA, Magmamax 1 and Woolsey 1. The reported results indicate the importance of the operating and engineering history, the operating parameters during sampling, and the method of sampling in order to evaluate the chemical analyses.

Jan 1, 1980