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By T. A. Johnson

Recovering from low demand in 1975, raw mineral production in the United States maintained a steady climb in value and quantity throughout 1976, keeping pace with the gross national product (GNP), which increased 11.5% compared with that of 1975. The minerals industry, in the past, has met ever-increasing demand while keeping production costs to a minimum. To maintain this capability, technological research and development of more efficient processing methods must continue. The role of Government and its increasing involvement in minerals industry actions received unfavorable comment from various segments of the industry in 1976. Government pricing controls were of concern to most industrial firms marketing like products. Public land withdrawals in large blocks were of concern to the mineral industry.

Jan 1, 1978

By J. Schlocker

The present emergency has greatly stimulated interest in the light metals - aluminum and magnesium - owing to their extensive use in airplane construction. The $63,000,000 plant being erected in the Las Vegas Valley by Basic Magnesium, Inc., under the auspices of the Defense Plant Corporation,

Jan 1, 1942

By Earl L. Phillips

The Bureau of Mines conducted laboratory tests on samples of pozzolanic-cement concrete to develop a low-strength backfill. Results show that support costs can be lowered by replacing a portion of the portland cement in mine backfill with pozzolan (fly ash) and lime. Unconfined compression tests on various ratios of fly ash to cement in 84 samples produced compressive-strength curves that can be used to estimate the best backfill mix for any mine.

Jan 1, 1981

By K. P. V. Lei

An electrochemical process was developed for the preparation of vanadium from vanadium carbide. Commercially available vanadium carbide (V2C) was used as the starting material. Vanadium was obtained by electrolysis of the V2C in a BaCl2-KCl-NaCI-VCl2 electrolyte at 670° C using a helium-atmosphere, molten-salt electrolytic cell. Vanadium products were recovered with purities high as 99.6 percent. Current efficiencies of 87 percent and vanadium recoveries of 84 percent were attained. The cathode products were amenable to electrorefining to high-purity vanadium of 99.96-percent purity.

Jan 1, 1971

By D. D. Dornenburg

The effect of changes of atmospheric pressure on methane emissions from extensive worked-out areas of coal mines in several Midwestern States has lone caused concern to State and Federal mining departments, as well as to the operating companies involved. Common mining and ventilation methods employed in mines in these States have resulted in large sealed and unsealed worked-out areas in which considerable quantities of methane are emitted alone both intake-and return-air courses. The common practice is to watch barometric changes very closely and take special precautionary measurer during periods of low barometric pressure. Although the hazard is recognized, mining officials have different opinions concerning the effect of barometric pressure variations on the emission of mine gases. These opinions are based upon scattered personal observations, as no records exist of actual studies to establish such effects.

Jan 1, 1955

By Raymond P. Maloney

The Rhyolite mercury prospect is on the south flank of Juninggulra Mountain--a large rhyolite intrusive in the Kuskokwim River region about 36 airline miles northwest of Red Devil, Alaska. Bulldozer trenching by the Bureau of Mines exposed bedrock at intervals in a 2,000-by 3,000-foot area where previous prospecting by the owners had disclosed abundant float and several in-place stringers containing cinnabar in widely varying amounts. The additional trenching indicated that the mercury mineralization in the limited area investigated was confined to erratically distributed short stringers and to small lenses, occurring in discontinuous zones in numerous silica-carbonate dikes and sills or along their altered contacts with sedimentary rocks. The geologic relationship of the mercury-bearing silica-carbonate dikes and the nearby rhyolite intrusive is similar to that existing at several other mercury mines and prospects in the. Kuskokwim region. The depth of over-burden and the presence of permafrost were serious obstacles to bulldozer trenching, and only a comparatively small part of the mineralized area was thus investigated.

Jan 1, 1962

By G. L. Finfinger, J. Cervik, L. J. Prosser

The Bureau of Mines has completed an underground degasification project in which an underground piping system was used to transport methane from the coalbed to the surface. In a 10-month period four horizontal holes were drilled to an average depth of 1,450 feet. All four holes were surveyed vertically and azimuthally. In 991 days of degasification, 255 MMcf of gas was drained from the coalbed. The underground piping system proved to be a safe and effective means of transporting methane from the coalbed to the surface.

Jan 1, 1981

By Stephen Utter

This report summarizes the procedure and results of an investigation to determine the stresses in the rock around an underground opening in the Climax molybdenum mine, Climax, Colo. This study is part of an overall investigation conducted by the Bureau of Mines to determine the stresses induced by block-caving mining. The purpose of this study is to obtain estimates of the magnitudes and directions of the principal stresses, the location of the maximum stress concentrations, and the effect of topography on the stresses.

Jan 1, 1962

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of the Ohio coalfield. Washability analyses were made on 39 coalbed samples collected from a 14-county area. None of the samples were of metallurgical quality as received. Nine of the samples could be sufficiently upgraded to produce metallurgical-grade products, and the remaining 30 samples could not be upgraded to this quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, 10 of the samples were of medium sulfur content as received and one could be upgraded to a low sulfur content. Of the 29 samples having a high sulfur content as received, 18 could be upgraded to a medium sulfur content. The original sulfur content of the other 11 samples having a high sulfur content as received can be appreciably reduced by removal of the sink 1.58 specific gravity material; however, these coals would be classified as high sulfur coals both before and after removal of the sink 1.58 specific gravity material.

Jan 1, 1972

By Gertrude N. Greenspoon

Legislation and Government Programs.-The Occupational Safety and Health Administration (OSHA) held public hearings in early 1975 on proposed standards for exposure to inorganic arsenic. The findings obtained at the hearings will be considered to promulgate emission standards. Domestic Production.-Arsenic trioxide (As203) was produced domestically only at the Tacoma, Wash. copper smelter of ASARCO Incorporated. Production data cannot be published. Output rose 9% over that of 1974, shipments were less than half those of 1974, and stocks rose 31 %. Production of arsenic metal, begun by ASARCO in August 1974, continued in 1975.

Jan 1, 1977

By John S. Berber

Bureau of Mines research on the production of phthalic anhydride by vapor phase oxidation of hydrocarbons began at Morgantown, W. Va., in October 1960. For these preliminary studies, a known solution containing naphthalene and 1-methylnaphthalene was used. In another series of tests, pure naphthalene was dissolved in different solvents. A series of investigations was conducted with the neutral oil fraction (210° to 270° C) of a low-temperature tar obtained from the Texas Power and Light Company's low-temperature carbonization unit. The neutral oil fraction was first dealkylated, and then the product was distilled into 210° to 250° C and 250° to 270° C fractions. These two fractions were then subjected to catalytic vapor phase oxidation. Although a number of catalysts was tested, most of the experiments were made using 9 percent vanadium pentoxide on inert alumina. The activity of this catalyst did not decrease after 162 hours at 1,030° F. Studies were conducted over a temperature range from 610° to 1,180° F. An operating temperature of 1,030° F yielded 47.50 percent of phthalic anhydride from a synthetic mixture of naphthalene and 1-methylnaphthalene. The highest yield (84.40 percent phthalic anhydride) was obtained with naphthalene dissolved in toluene and also with naphthalene dissolved in methyl ethyl ketone. With a 210° to 250° C fraction the highest yield of phthalic anhydride obtained was 12.32 percent at a temperature of 900° F, and, with a 250° to 270° C fraction, it was 15.80 percent at a temperature of 875° F.

Jan 1, 1963

By D. L. Paulson

The Bureau of Mines studied the feasibility of producing copper matte in an electric furnace from blends of copper concentrate similar to those currently smelted in a gas-fired reverberatory system at an installation in Tacoma, Wash. A 800-kva electric-arc furnace was used to determine the distribution of constituents when arseniferous concentrates are being smelted in an electric-arc furnace. Test results from smelting 40 tons of materials indicated that electric smelting is more like a conventional gas-fired system than originally expected. Although gas composition over the molten bath is much different in an electric furnace, the secondary constituents such as arsenic, lead, zinc, and antimony behaved the same as in a reverberatory furnace. The results established that an electric furnace would be compatible with sulfur and particulate recovery facilities that are being used.

Jan 1, 1976

By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 961 Bcf as of January 1, 1983. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas re- serves, 271 Bcf, (2) helium in probable natural gas resources, estimated at 202 Bcf, (3) helium in possible natural gas resources, estimated to be 351 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 137 Bcf. These helium resources are further divided into depleting, nondepleting, and stored classifications. The depleting resources are those associated with natural gas fields that are, or will be, produced for the natural gas they contain. All of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 789 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gas fields, are estimated to total 134 Bcf. There is 38 Bcf of helium in storage in the Federal Government- owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1985

By J. J. Demeter

A tube-wall reactor with a Raney nickel catalyst deposited on the outer wall of the tube by flame spraying is effective in the practically complete conversion of 3H2+1CO synthesis gas to a high-Btu gas (methane) at an hourly space velocity of 7,000 volumes of gas (NTP) per hour per volume of annular volume. Partially reacted synthesis gas containing an appreciable amount of methane can also be treated in this reactor to increase the heating value to over 900 Btu per cubic foot. Excellent heat removal through the metal wall to a coolant and temperature control were obtained. The heat transfer co-efficient from the catalyst to the coolant was about 275 Btu per hour per square foot per ° F. Synthesis tests were conducted with tubes 1.2 inches in ad by 6 inches long, and 1.3 inches in od by 36 inches long. When operating at a synthesis gas rate of 100 to 120 scfh per square foot of catalyst-coated tube, catalyst life was long enough to realize a catalyst cost for the raw Raney nickel alloy of about 0.3 cent per 1,000 cubic feet of pipeline gas (900 to 950 Btu per scf). Gas recycling at ratios of 1:1 to 3:1 was effective in increasing conversion and in extending the life of the catalyst to about 16 weeks. In cost and in operating characteristics the tube-wall reactor compares favorably with the fluidized-bed and hot-gas-recycle reactor systems for the synthesis of high-Btu gas from H2+CO.

Jan 1, 1967

By C. E. Augustine, P. Nicholls

"INTRODUCTION A layer of soot on the heating surface of a boiler decreases efficiency because it increases resistance to the flow of heat, with the result that the heat transfer to the water is lower and the temperature of the flue higher than they would be if the surface remained clean. The percentage of reduction in heat transfer depends on the position and area of the sooted. The percentage of reduction in heat transfer depends on the position and area of the sooted surfaces, the thickness of the most, until the percentage of the total heat absorbed by those surfaces when clean; thus it will vary with the type of boiler and in particular with the ratio of the area of the convection heating surface to the total area. Medium-size and large boilers usually are equipped with soot blowers, and tests have been published giving the increase in efficiency resulting from removal of the soot. Fuel savings up to,8 percent have been reported, but 4 to 5 percent is probably more conservatives. However, these savings may not be due wholly to a reduction the thermal resistance of the surfaces but may be due partly to improvement in the combustion because of better draft or more uniform flow of the gases. In addition, the deposits on the surface of boilers include as a clinker, and as the size of the boiler and the rate of burning increase very little or none will be soot.There are no corresponding test data on small boilers operated at low rates of burning. In stall boilers, deposits are much thicker, and it might be expected that the reduction in efficiency would be greater; in fact, statements have appeared suggesting that the decrease may be as high as 50 percent. This investigation was undertaken because the Bureau frequently receives requests for authoritative information on the effect of soot in small and other heating boilers."

Feb 1, 1935

By W. P. Haynes

The Bureau of Mines has been studying a modified steam-iron process using coal-derived producer gas for making either hydrogen plus carbon monoxide or methane. To provide a guide for this experimental study, compositions of equilibrium product gases for the reaction of steam plus carbon dioxide with iron were calculated and are discussed in this report. The calculations, which are described in this report, are based on thermodynamic data in the literature and cover temperatures from 800° to 1,300° K., pressures from 1 to 30 atmospheres, and hydrogen-to-carbon atomic ratios in the gas of 4 to 12. The equilibrium gas compositions are discussed in regard to making hydro-gen, carbon monoxide, and methane in the oxidation step of the modified steam-iron process. From the viewpoint of thermodynamics alone, assuming the reactions reach equilibrium, the discussion considers the effects of temperature, pressure, and composition of feed gas upon the composition of the product gas, the degree of oxidation of the iron, and the possible deposition of carbon. The results indicated the following: (1) Nearly all the carbon can be converted to methane at low temperatures (800° to 900° K.) and high pressures (over 20 atmospheres); (2) to obtain high yields of synthesis gas, high temperatures are required. For example, at 30 atmospheres, a temperature over 1,200° K. is required to convert 60 percent of the steam plus carbon dioxide to hydrogen plus carbon monoxide. Lower temperatures may be used at lower pressures) (3) oxidation of the iron increases with increasing pressure and decreases with increasing temperature; and (4) process conditions favoring carbon deposition were found within the range of variables studied, but it is thermodynamically possible to operate the oxidation process with steam and carbon dioxide outside this range of carbon deposition.

Jan 1, 1961

By W. P. Diamond, B. M. Bench, C. M. McCulloch

This Bureau of Mines report describes photolineaments obtained from stereoscopic examination of vertical aerial photographs and by the Ronchi grating study of aerial photoindex sheets. The photolineaments are compared with the trends of oriented fracture systems procured by measuring the compass direction of joints in bedrock. The relative reliability of the methods is shown, and the results are presented in graphical, tabular, and written form. Analyses of field measurements of strikes of bedrock joints in the project area indicate for the most part two intersecting sets of major joints oriented N 76° W - N 15° E, and N 57° W - N 27° E. The analyses of lineaments determined by stereoscopic examination of aerial photographs show dominant trends of lineament zones of weakness to be an average of N 65° W - N 20°E. Analysis of lineaments found by Ronchi grid viewing of aerial photoindex sheets indicate dominant trends of N 70° W - N 27° E. The three methods give similar findings and verify the work of previous authors. The Ronchi grid method is a useful guide, but it cannot be substituted for the two more painstaking methods.

Jan 1, 1977

By M. Kanda, W. D. Bensema, J. W. Adams

Two different techniques were used to make measurements of the absolute value of electromagnetic noise in an operating hardrock mine, Grace Mine, located near Morgantown, Pennsylvania. Diesel-powered haulage equipment is used in this mine, and the electromagnetic noise environment it creates was measured to see how it differs from the environment created by electric-powered haulage equipment. One technique measures noise over the entire electromagnetic spectrum of interest for brief time periods. Data are recorded using broadband analog magnetic tape and are later transformed to give spectral plots. The other technique records noise amplitudes at several discrete frequencies for a sufficient amount of time to provide amplitude probability distributions. The specific measured results are given in a number of spectral plots and in amplitude probability distribution plots.

Jan 6, 1974

By D. Harrington

The occurrence of dusts in underground workings creates many difficult and, in some instances, contradictory and conflicting problems for workers, operators, and all others interested in health and safety in mining and tunneling. Moreover, there are many misconceptions both as to the actual effect of most dusts which may be encountered in underground work and as to remedial or alleviating measures. Although the harmfulness of mine dusts to health of miners has been mentioned by man; writers in ancient times, much of our really authentic knowledge of the effect of underground dusts upon health or safety in both coal and metal mines has been pained during the past 30 or 35 years. There has been, however, a considerable amount of generalizing from some local condition or occurrence or theory rather than arriving at conclusions after extended studies and observations made not only in mines and tunnels but also in town, camps, and plants, and comprising date on as many different mining and tunneling localities, conditions, etc., as could be secured with reasonable expenditure of time or money. This paper dives sortie observations based on the writer's 30 odd years of experience in and around both coal and metal mines, including approximately 20 years? close study of dust disease with detailed surveys and reports on dust occurrence and effects in considerably more than 100 mines in probably 20 States of the Union. The observatio are those of an engineer and in many respects conflict the with "going" ideas of doctors, pathologists, and others who have written on dust disease. Were the word dust is used in this p: per in connection with respiratory disease, it refers to solid particles which float or can float in the air breathed by workers. Although these particles are usually dry, they may be wet; in general, their dimensions are so small as to be invisible to the nailed eye. Dusts in coal mines which may be involved in the initiation or extension of explosions, are generally thought to be those which are smaller than 20-mesh in size but chiefly finer than 20-mesh; coal-mine dusts which are harmful to health of workers have essentially the same general physical characteristics as other dusts, but usually consist of smaller particles.

Jan 1, 1936

By N. Kyriazi, W. Duerr, J. Shubilla, J. G. Kovac, J. Kravitz

A joint effort by the Bureau of Mines and the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, was undertaken to determine how well self-contained self-rescuers, deployed in accordance with Federal Regulations (30 CFK 75.1714), held up in the underground environment. This report presents findings regarding laboratory-tested breathing apparatus from the first year of a 5-yr program as well as other related findings. The SCSR's were tested on human subjects and on a breathing and metabolic simulator. These results indicate that the apparatus, if well-treated, perform as expected except for manufacturing defects or quality control problems, which are identified. However, when the apparatus are carried in and out of the mine every day and stored at the working section, they may suffer abuse that can be extreme. Physical signs of abuse, unless extremely obvious, frequently are not detected by the miners or the mine operators; this poses a danger to a potential user in case of emergency. Recommendations include improved training in inspection procedures.

Jan 1, 1986