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By F. P. Haver

A method to recover copper and elemental sulfur from chalcopyrite concen¬trate, using a ferric chloride leach, CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S, was reported by the Federal Bureau of Mines in 1971 (Report of Investigations 7474). Since that time, additional work has been done to improve certain steps in the procedure; that is, the recovery of sulfur from the leach residue, the recovery of copper and iron from the leach solution, and the regeneration of the leach solution. It was determined that over 99 pct of the elemental sulfur in the leach residue could be extracted at ambient temperature with an ammonium sulfide solution. Heating the pregnant solution precipitated crystals of rhombic sulfur (99.5 pct purity) and liberated ammonia and hydrogen sulfide for recycle. Copper with a purity in excess of 99 pct was obtained from the leach solution by electrolysis, using a diaphragm cell, with an energy requirement of less than 0.7 kW-hr/lb. Metal was deposited as a weakly adherent powder that could be easily dislodged from the cathode and withdrawn continuously from the cell in the form of a slurry. During electrolysis, part of the Fe(II) was oxidized to Fe (III) at the anode so there was no chlorine evolution. The leach solution was regenerated by direct oxidation of the spent electrolyte with air or oxygen in a turboaerator at 80° C. This precipitated the iron dissolved during leaching in an easily filterable form, Fe203.xH20, and converted the remaining Fe(II) to Fe(III).

Jan 1, 1975

By D. E. Wolfson

As part of its overall program of coal-carbonization research, the Bureau of Mines is studying the coking properties of coals from various fields of this country. Few of the coals included in this survey are used for the manufacture of metallurgical coke, although some well-known coking coals necessarily are tested to provide comparative data, particularly on blending properties. The overall objectives of the study were given in detail in a previous report.3/ The inherent suitability of coal for metallurgical purposes, as distinguished from economic considerations, depends primarily on (1) the available reserves, (2) chemical composition, (3) preparation characteristics, and (4) carbonization behavior. These items are considered in selecting coal for carbonization tests.

Jan 1, 1956

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By Charles Prasky

The Bureau of Mines investigated the conversion of nonmagnetic iron minerals to magnetic form through reduction Toasting operations. The primary objective was to obtain a concentrate that could be used as a direct shipping material for blast furnace consumption. Crude iron materials from the Steep Rock Lakes, Ontario, area were prepared into a blend of 8 parts siliceous ore, 3 parts pyritic ore, and 1 part tailings. Experimental work included laboratory reduction roasting tests, two continuous 10-day campaigns, and one 12-hour test all in a 34-inch by 36¬-foot rotary kiln. The objective of the project was achieved in producing an iron concentrate containing about 66 percent iron with over 90 percent iron recovery. Desirable operating conditions were developed in the kiln but optimum process variables were not completely established.

Jan 1, 1969

By Jack E. Fraley

Because of their noncombustibility, silicate and magnesium oxycements are desirable for sealing shale in underground coal mines. In this Bureau of Mines investigation, cement samples were cured and tested (nonstandard tests) for submersion to note resistance to dissolution (breaking into parts), which is an important property for a coating. Nonappreciable dissolution during 1 week of submersion was set for passing the test. Over half of the coatings passed the test.

Jan 1, 1977

By Agnes Y. Lee

The Bureau of Mines has developed an effective hydrometallurgical method to recover high-purity Pb metal and elemental S from concentrates. This low-temperature process eliminates S gases and Pb emissions, in contrast to the current high-temperature smelting technology. The method consists of (1) oxidative leaching with H202, Pb02, and waste fluosilicic acid at 95° C to produce a solution of PbSiF6 and a residue containing elemental S, (2) electrowinning the PbSiF6 solution at 35° C to produce 99.99 pct Pb metal and H2SiF6, and (3) solvent extraction to recover S, leaving a residue containing Cu, Ag, and other metal values. Spent electrolyte was recycled repeatedly, with impurity buildup controlled by controlling the leach parameters.

Jan 1, 1986

By V. H. Gottschalk

Among the procedures developed by the Germans for providing the tonnage of iron powder needed to make rotating bands for artillery shells is the use of a ceramic tunnel kiln, not only for finishing the reduction of centrifugal powders but also for making so-called "brickyard sponge iron," which, after crushing and grinding, seems to yield a product suitable for powder-metallur- gical purposes. The final report issued jointly by the German Powder-Metallurgical Society (DPG) and the Chemical-Metallurgical Branch of the Research Depart- ment of the Metallgesellschaft, Inc. (ZFC of MG) gives the available details of this procedure, which may be regarded as a further development of the process in commercial use since 1911 at a ceramic plant in Hoeganaes, Sweden. The Bureau of Mines' wartime development of the Hoeganaes process also cul- minated in the adaptation of ceramic tunnel kilns for carrying out the solid- carbon reduction of iron ores, and comparison with the German technique should further advance the art. This information circular is issued as a supplement to Bureau of Mines reports of investigations Nos. 3819,2 3822, 3841,2 and 4271, on brick- yard sponge iron and is based on four German reports entitled "Making Iron. Powder in the Tunnel Kiln," translated from FIAT microfilm reel H-46, frames 9190-9209, 9280-9299, 9339-9357, and 9377-9384 (PB L 70042), which represent the four original research reports, Nos. 2005, 2008, 2010, and 2012, respec- tively, of the Metallgesellschaft, Inc.

Aug 1, 1948

By W. W. Adams, T. D. Lawrence

The National Safety Competition , a safety contest conducted annually by the Bureau of Mines , United States Department of the Interior , to promote safety at mines and quarries , has just resulted in the award of safety trophies , known as the " Sentinels of Safety" , for 1939. Awards were made to a bituminous- coal mine in Wyoming , an anthracite mine in Pennsylvania , a metal mine in Michigan , and a nonmetallic -mineral mine in Alabama ( all being underground mines ) and to anopen-cut mine in Minnesota and a stone quarry in Michigan. The awards signify that the recipients won first place in their respective groups in an accident-prevention contest by operating during 1939 with the smallest loss of time in proportion to the total number of man-hours worked at the mine or quarry . Each of the trophy-winning companies for 1939 operated his property without a disabling injury to an employee , except at the anthracite mine , whose record , while not free of accidents , was better than that of any other mine in the anthracite group . The " Sentinels of Safety" trophy is a bronze statue of a mother and infant welcoming the father safely home after his day's work in the mine . Six trophies were provided by THE EXPLOSIVES ENGINEER magazine to be awarded annually by the Bureau of Mines . These trophies remain in the custody of the mining companies for 1 year , after which the trophies are transferred to the winners of the succeeding year's contest . A replica of the trophy is provided for permanent retention by the company surrendering the bronze trophy . In addition to the award of the safety trophies for 1939 , each man employed at a winning mine or quarry receives from the Bureau of Mines a certificate of honor in recognition of his part in helping his company to win the trophy . Companies ranking second , third , fourth , or fifth in their respective groups , and all mines and quarries whose records were free of disabling ( losttime) injuries and showed at least 30,000 man-hours worked during the contest year were awarded certificates of honorable mention . Mines and quarries that won the " Sentinels of Safety" trophies for 1939 and those that were awarded certificates of honorable mention are indicated in the following paragraphs .

Jun 1, 1940

By John C. Feeley

The methods used and the funds available for the development and oper- ation of shall mines and the reopening of small abandoned mines frequently present problems that tax the ingenuity and resourcefulness of the mining engineer far beyond that required in the mass production from large deposits. The objective of this paper is to describe in considerable detail the means whereby engineers have solved local problems in reopening an abandoned mine at which equipment, facilities, and funds were limited... The Etowah Coal & Iron Co. Gadsden red-iron-ore mine at Gadsden, Ala., 18 of interest in this category since it is the only independent red-ore mine under active development in the State. All other red-ore mines in Alabama are owned or controlled by the large iron or steel companies. The The mine, located on the southwest end of Shinbone Ridge in the outskirts of Gadsden lies in an ares once productive. but now idle, for many years. ore is relatively highgrade compared with that in the Birmingham area, but the bed is thin and somewhat lenticular. The presence of a large blast furnace at Alabama City, 3 miles from Gadsden, and the growing scarcity of red-iron ore supplies for it offered inducements for reopening the mine in 1946. Up to the time this circular was prepared (1947) only a small quantity of ore (about 1,500 tons) has been produced and shipped to the furnace. A force of 14 men was employed in sinking the main slope and developing a third "lift" (a local term for level) 100 feet below the old mine workings.

May 1, 1949

By J. B. Zadra

During the investigations of the occurrence of manganese in the western United States, the Bureau of Mines received a 100-pound sample of manganese ore from the Doyle-Smith property, Yuma County, Ariz. Laboratory tests were made to determine the amenability of this ore to standard ore-dressing methods of concentration to produce a marketable-grade product. The Doyle-Smith claims are in northern Yuma County, within 15 miles of the Artillery Peak deposit. The lot of ore used in the test work was taken from the outcrop of a large, massive, irregular bed of oxide manganese ore found on the claims.

Jan 1, 1952

By J. O. Merritt

The primary objective of this research program was to recommend ranges of minimum luminance for safety in underground metal and nonmetal mining. Visual tasks critical to safety were identified and rank-ordered. Realistic, full-scale, dynamic task simulations encompassing the most important visual components of the critical tasks were installed in a large simulated workspace. Five trained observers performed the six simulated mining tasks under varying levels of luminance. Over 13,000 measurements of visual task performance were used in developing minimum luminance recommendations for the on-foot underground worker and the mobile equipment operator.

Jan 1, 1983

By Ellis S. Hertzog

The material published in this report is part of a special study of some of the chemical and physical properties of Alabama coals. The complete study included friability and grindability determinations, high and low temperature assay distillation tests, and ash fusion-temperature determinations. Proximate and ultimate analyses and. calorific values of the coal samples also were obtained. This paper is concerned only with grindabilities, although proximate analyses have been included to give a better picture of the problem as a whole. The growing interest in grindabilities of coals is a result of the increase in use of pulverized fuel in rescent years. The tenative ball-mill grindability method D408-35T4/ was used in making all the determinations. The method of sampling and the technic of the testing procedure is described in Considerable detail in this report because the procedure was established quite recently. The ball-mill grindability index is a measure of the ease with which coal may be ground, which may be an important factor in estimating pulverizing costs. Up to the present time few data on the grindability of Alabama coals have been published. The data in this paper show that the Warrior and Cahaba fields exhibit a wide range of grindability in their coals. The mines tested are well distributed throughout the productive areas of these fields, and it is possible to make rough estimates of the grindabilities of coals not listed in this report from the data given for mines situated in the same vicinity.

Jan 1, 1938

By F. R. Cattoir

The Federal Bureau of Mines refined chromium from an aqueous electrolytic process in molten sodium chloride-chromium chloride electrolytes. Oxygen and nitrogen contents were reduced by a factor of 10 to 40, but most other impurities were little changed. The product usually contained a little more iron than the feed. Since iron was entering the bath from the iron pot and the graphite liner at a nearly constant rate, contamination of the chromium deposits by it was more serious at low currents and deposition rates. A few runs in an iron cell with a nickel liner yielded chromium containing one half as much iron as the feed, but up to 1.5 pct. nickel. In all cases the anode feed lay in the bottom of the container, which itself was used as the anode connection. With a 12-in. cell, variations in applied voltage from 0.05 to 1.5, in current from less than 10 to over 100 a., and in initial cathode current densities from less than 100 to over 2,000 a./sq.ft. had little or no effect upon the analysis of the metal produced) except for iron content. Changes in bath analysis from 3 to 11 pct. chromium were also without effect. These changes did bring about large differences in the physical forms of the crystals obtained. The thick heavy crystals produced at low voltage and current contained voids which made them difficult to leach free of chlorides. Easiest to leach were the thin leaf-like crystals obtained at around 1 v.

Jan 1, 1960

The Anaconda Copper Company reportedly reached an exclusive agreement with Cook Inlet Region, Inc., to explore 24 million acres in south-central Alaska and to share equally with Cook the proceeds of any mineral discovery. According to an Anaconda geologist, "the company is anticipating, based on geologic testing, that it will find significant deposits of copper, lead, and zinc. There is also evidence of the presence of precious metals such as silver and gold, and also strong evidence of strategic minerals such as chrome, platinum, tin, and nickel." Cook Inlet Region, Inc., is owned by 6,500 Alaskan natives. Chile, which has a growing, free-market economy under President Pinochet, reportedly will no longer require companies to obtain prior governmental approval for the exploration and development of new mines.

Jan 1, 1981

By Susan M. White

Increased coal production, wider use of indiscriminate mining techniques, improved cleaning methods, and greater emphasis on clean fuels is increasing the rate at which wastes accumulate Over the next several years, Colorado Plateau underground coal production is predicted to increase. Currently, mine refuse is deposited in canyons or lowland areas near mines. This study presents information on the nature of coal refuse and disposal practices on the Colorado Plateau. Samples were collected and analyzed to provide information to help formulate alternative methods for reclaiming refuse piles. The analyses were based on determining the capability of unmodified refuse to provide a suitable medium for plant growth. Local topsoils which would be used in reclamation were used as standards. Potential environmental hazards were assessed also. A general cost analysis was done for both surface and underground disposal and the advantages and disadvantages of each were assessed. Several problems were identified which, if solved, would increase the effectiveness of state regulatory programs.

Jan 1, 1982

By J. H. Soulé

"The Copper King copper-gold-silver deposit was discovered about 1880. Various individuals and companies have been interested in the deposit and considerable work has been done, although production, if any, has been small. The deposit is located in the western part of Laramie County Wyo., and is favorably nituated with respect to rail and truck transportation and high-tension power facilities.Mild summers and cold winters characterize the climate. Precipitation averages between 16 and 17 inches annually, with considerable snowfall in the winter. Permanent streams are small and most available water in being stored for use by Cheyenne, Wyo. Range grasses comprise the bulk of the vegetation, with small treed and shrubs common in the most rugged areas.The deposits lie upon land owned by Wyoming, now leased by a group of Wyoming and Colorado businessman constituting the Copper King Mining Co.Primary copper-gold mineralization seems largely confined to an equigranular, relatively fine grained gneiss that is part of a pre-Cambrian complex of metamorphic rocks ranging from schists to pegmatites. The copper minerals are oxidized to a depth of from 100 to 150 feet, with the occasional occurrence of secondary minerals at greater depths. The copper minerals chalcopyrite, malachite, chalcocite, bornite, cuprite(?), and some native copper were observed in Le deposit.In addition to the 4,030 feet of diamond-core drilling in 11 holes done on the deposit by private companies, the Bureau of Mines drilled 3 holes for a total of 2,630 feet. The sample results of this drilling plus available data from previous drilling and sampling are appended to this report."

Jun 1, 1955

By A. J. Forney

Recent experiments used catalysts of plate assemblies in synthesizing high-Btu gas and gasoline indirectly from coal. A gas with a heating value of 925 to 943 Bt-: per cubic foot has been prod u la the hot-gas-recycle pilot plant from synthesis gas (3H2+100) with lathe turnings used as catalyst in the first reactor, and assemblies of parallel sprayed plats of nickel in the second. Solid plates made of Raney nickel, and steel and aluminum plates sprayed with Raney nickel or nickel oxide were tested. Those catalysts had very low resistance to gas flow; 90 percent lower than nickel granules used in previous experiments. In a single stage of synthesis thee nickel plates were only partially successful. Although the heating values of the product gas ranged from 856 to 941 Btu per cubic foot, the carbon monoxide content of he gas was above 0.1 percent. Both steel and wrought turnings were tested in single-stage synthesis, but the conversion of hydrogen and carbon monoxide was too low to attain the desired heating value of 900 Btu per cubic foot in the product gas. Assemblies of plates thermally sprayed with fusel iron were tried in an experiment to make gasoline. A gasoline yield of 52 percent (of the hydro¬carbons produced) was obtained using a 1H2-10O feed These sprayed assemblies were in service for 1,500 hours, the longest that this type of catalyst has been used. When a second reactor containing Raney nickel catalyst was added in series with the first reactor, complete utilization of the feed gas was obtained because in addition to the liquid product, a high-Btu gas with a heating value of 800 Btu per cubic foot was made.

Jan 1, 1965

By M. J. Kovalik

Lower Sunnyside seam coal from Utah was blended with various proportions of char and high-temperature coke to improve the quality of the coke obtained from carbonizing this coal. The Hanson 5-pound carbonizer was used as a "screening test" for the larger scale Bureau of Mines-American Gas Association (BM-AGA) tests, which were correlated with industrial production. Eighteen carbonization tests were made in the BM-AGA 13-inch retort, with a coal charge of about 90 pounds; the cokes were evaluated by the standard ASTM tumbler test. Carbonization of blends containing char and coke breeze yielded less fissured and blockier cokes of significantly higher ASTM I-inch tumbler indices as compared with the value for the straight Sunnyside coal. It was found that the simultaneous addition of char and coke breeze yielded stronger cokes than that obtained by the addition of either one of these additives. Addition of a small proportion of Pocahontas No. 3 or Sewell coal to an optimum blend improved the resulting coke strength further.

Jan 1, 1969

By Walter Kawa

In connection with its research in producing synthetic liquid fuels from coal, the Federal Bureau of Mines studied reactions of iron and iron compounds with hydrogen and hydrogen sulfide in batch autoclaves. The Bureau hoped to gain indirect evidence regarding the chemical changes that iron catalysts undergo when they are used in the hydrogenation of coal. The information obtained may be helpful in identifying the active form or forms of iron catalysts. At 450° C., with hydrogen at hundreds of atmospheres and hydrogen sulfide at 1 or 2 atmospheres, the thermodynamically stable form of iron is ferrous sulfide in the case of the metal, magnetite, ferric oxide, ferrous sulfate, ferrous oxalate, or the chlorides of iron. However, complete conversion to ferrous sulfide was not achieved at temperatures of 400° to 500° C. for kinetic reasons. Extensive sulfiding of iron, magnetite, ferric oxide, and ferrous oxalate occurred below 400° C., and some conversion of ferrous sulfate to ferrous sulfide occurred at 400° C. In the hydrogenation of coal, ferrous sulfide is the form of iron likely to be available for heterogeneous catalysis when starting with the metal, oxide, sulfate, or oxalate.

Jan 1, 1960

By Vernon C. Davis

"INTRODUCTION This report describes the work done and presents the data obtained from limited diamond drilling at the lead-zinc deposits cf the Belle Eldridge Gold Mines, Inc., in Lawrence County, S. Dak. during the summer and fall of 1943. The work was undertaken in an effort to increase reserves and step-up production of zinc and lead so vitally important to the war program.The geology, topography and existing mine workings were mapped and studied. Subsequently, six vertical core-drill holes were put down from surface sites.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our natural resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests, if such are necessary.Special acknowledgment is made to John Paul Gries, geologist, South Dakota School of Mines, for mapping and interpretation of geology and topography, logging of cores obtained, and his assistance in guiding the drilling."

Mar 1, 1948