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By E. G. King

Thermodynamic calculations involving the oxides of tungsten and molybdenum have been hampered by lack of accurate entropies and high temperature heat contents. This paper presents work by the Federal Bureau of Mines on new low-temperature heat-capacity data leading to the evaluation of the 298.15° K. entropies of tungsten dioxide and tungsten trioxide, as well as high-temperature heat contents (above 298.15° K.) of molybdenum dioxide, molybdenum tri-oxide, tungsten dioxide, and tungsten trioxide. Included are heats of fusion of the two trioxides. The heats of formation at 298.15° K. of these four oxides are tabulated as measured by Mah4 5/ of this laboratory. Included also are the 298.15° K. entropy of Mo02 measured by Kin 6/ of this laboratory, and that for Mo03 according to Kelley and King.7/ These basic data provide a consistent compilation from which to perform accurate thermodynamic calculations involving these compounds. No previous low-temperature- heat-capacity measurements have been reported for tungsten dioxide. Seltz, Dunkerley, and DeWitt8/ measured the low-temperature heat capacity of tungsten trioxide. The only previously-reported high-temperature heat-content measurements for any of the oxides were conducted by Cosgrove and Snyder,9/ who measured molybdenum trioxide to 1,300° K.

Jan 1, 1960

By William C. McBee

Specialized sulfur concretes were developed by the Federal Bureau of Mines as a result of research for the beneficial utilization of sulfur in construction materials. Materials were developed for use in acid and salt corrosive environments where portland cement concrete has been found to deteriorate. Because the mineral aggregates also come into contact with the corrosive media, concretes were developed utilizing both limestone and quartz aggregates. The sulfur binder used with both aggregates was modified by reaction with 5 pct dicyclopentadiene to improve product durability. Sulfur quartz aggregate concrete was found to have moderately high strength characteristics (6,000 psi compressive) and was extremely resistant to chemical attack by both acid and salt solutions. Sulfur limestone aggregate concrete exhibited very high strength characteristics (9,000 psi compressive) and was extremely resistant to chemical attack of salt solutions. Both types of concretes maintained their strength and integrity after long-term testing in acid and salt solutions and exhibited considerable resistance to damage by the action of freezing and thawing. Potential uses include leach tanks, electrolytic cells, thickeners, bridge decking, industrial flooring, pipe, and tile.

Jan 1, 1979

This list is part of the long-range conservation program of the Bureau of Mines and is intended for use by those interested in the Bureau's publications dealing with oil shale and shale oil. The items included represent 51 years of research by Bureau of Mines employees on oil shale and shale oil and are available at any U.S. depository library. DISTRIBUTION U.S. Bureau of Mines report series contain both free and sales publications. An asterisk (*) designates publications for sale. Such publications can be obtained from Superintendent of Documents U.S. Government Printing Office Washington, D.C. 20402

Jan 1, 1969

By J. Douglas Causey

No mines are active in the Hunter Mountain Wilderness Study Area (WSA), and no mineral resources have been identified in the WSA. However, the Monarch Mine has low potential for silver, copper, tungsten, and gold resources in quartz veins; the Shirley Ann Group and Sal Group have moderate and low potential, respectively, for silver, lead, and copper resources in skarn; claims overlying the Eureka Quartzite have low potential for silica resources; and the Tourmaline N1-4 Prospect has low potential for tourmaline resources in quartz monzonite. Copper, lead, silver, tungsten, molybdenum, wollastonite and garnet occur in skarn zones between monzonitic and carbonate units. Silver, tungsten, and copper also occur in quartz veins within monzonite. Known metallic mineral deposits are small, erratic and discontinuous. The J. 0. Mine, adjacent to the northeast corner of the WSA, may contain as much as 26 million tons of subeconomic wollastonite resources. The crest of an open pit to produce that resource would extend into the WSA. No information exists on geothermal potential because no exploration has been done in the area. No occurrences of energy minerals are known within the WSA.

Jan 1, 1983

By T. E. Bernard

The CO2-absorbent canisters used in four approved rescue breathing apparatus were investigated. A breathing machine was used to simulate human expiration with gas flow rates of 26, 37, and 48 1/min of 3.5% CO2 in air. The exit gas CO2 concentration, the pressure drop across the canister, and the exit-gas temperature were monitored. The absorbent capacities of the packed-bed canister designs were found to be dependent on flow rate within the range studied, while the capacities of the other designs were less affected. The radial canister had the least resistance to breathing while the complex bed design proved to be the most effective in utilization of the chemical. The overall results indicated that LiOH (lithium hydroxide) has the highest capacity for CO2 absorption among the absorbents tested. It can be used in a simple packed-bed design while maintaining acceptable levels of resistance and exit-gas temperature. Examination of oxygen supply with respect to CO2-absorption capacity suggested that it is desirable to closely match CO2-absorption capacity with the avail-able O2 supply to minimize the size and weight of rescue breathing apparatus.

Jan 1, 1979

By W. M. Dressel

A simple, reliable field test for beryllium in rocks has been developed by the Rolla Metallurgy Research Center of the Federal Bureau of Minas. A small portion of the pulverized rock is fused with a sodium carbonate-sodium hydroxide flux in a wire loop. The fused mass is dissolved in water, a few drops of quinizarin solution are added, and the solution is viewed under ultraviolet light. A pink-to-orange fluorescence reveals the presence of beryllium in a sample containing as little as 0.013 percent beryllium (0.26 percent beryl). INTRODUCTION New and potential uses for beryllium make necessary a more intensive search for this metal, which is so similar to aluminum in its chemical reactions that it is not separated from aluminum in ordinary chemical analyses. The principal ore mineral of beryllium is beryl, a beryllium-aluminum silicate, which contains only 5 percent beryllium. This mineral is so similar to quartz in appearance that it is not always possible to distinguish one from the other in the field. While the distinction may be made easily with a petrographic microscope, few prospectors have access to such an instrument, and fewer still know how to use it.

Jan 1, 1960

By Michael T. Nigbor

This Bureau of Mines publication identifies the significant environmental issues associated with the potential development of strategic and critical minerals in the Stillwater Complex, MT. The Stillwater Complex contains deposits of Cr, platinum-group metals (PGM), and Ni. Issues that must be addressed prior to minerals development include the effects mining, milling, and smelting will have on the land, water, and air, and methods of minimizing the environmental impacts.

Jan 1, 1985

By John O. Atkins

[Experiments were conducted by the Bureau of Mines on five types of simuated lunar rock (dacite, tholeiitic basalt, vesicular basalt, pumice, and uluth Gabbro) to study the effects of various simulated lunar environments n their strength and deformational properties. Specimens were tested in an ltrahigh vacuum (UHV) system at pressures ranging from atmospheric down to 0-11 torr and at temperatures of -130°, 20°, and 135° C. All tests were onducted with a servocontrolled testing machine. Rock specimens tested at 0° C in UHV exhibited significantly higher compressive strength and Young's odulus than those tested at 20° C in atmospheric pressure. The magnitudes f increase are related to the porosities and permeabilities of the rock pecimens; high porosity and permeability allow better outgassing and thus nprove surface cleanliness in UHV. The compressive strength generally ncreases but Young's modulus decreases as test environments change from 20° C i UHV to 135° C in UHV. No significant difference was observed in the iysical properties measured at 20° C in LTV and -130° C in UHV. Anisotropy i strength and Young's modulus exist both in UHV and at atmospheric condi¬'.ons with the same symmetry pattern. The orientations of the principal axes iy, however, change from the atmospheric to UHV condition. The results idicate that rock fragmentation in lunar environment will require more ergy than that at 20° C in atomospheric pressure.]

Jan 1, 1974

By David A. Monaghan

This report describes instrumentation which is part of a system for extinguishing mine fires by pumping material through surface boreholes in order to seal off all underground passageways leading to the fire area. Major instrumentation systems include a closed circuit television probing system and an acoustic seal checking system. The latter consists of a speaker probe, a receiver probe and related signal processing equipment. All probes can be winch-deployed down a 6-inch diameter borehole. The CCTV unit can be rotated 360 degrees in the horizontal plane, and contains sufficient lighting to reliably assay conditions for sealing or rescue within a 200 foot radius. The acoustic seal checker monitors the completion of a seal as it progresses by use of probes lowered through boreholes on either side of the seal.

Jan 1, 1977

By Jon C. Volkwein

Dust concentrations inside and outside enclosed cabs on several types of mining machinery were measured by the Bureau of Mines. Results indicated that properly enclosed cabs can offer significant dust protection for machine operators. Recommendations for improvements in cab technologies were discussed.

Jan 1, 1979

By J. E. Fraley

This report describes the preliminary results of a Bureau program to develop and test an inexpensive grout for full-column support of roof bolts. Various inorganic grouts were tested in both cartridge and slurry form. Tests were also performed on methods of water packaging and on the effect of fillers on the grout strength. Results showed that some grouts had poor early strength and exceptional mid-to long-term strength. Laboratory tests have shown that rapid-setting inorganic grout could be an economical replacement for resin bolts if the short-term strength could be increased. Further development to improve its early strength would need to be tested in the laboratory and underground to prove its potential for the mining industry.

Jan 1, 1987

By R. Vernon Helm

Four tables listing values for the various physical properties of those sulfur compounds most likely to occur in petroleum and petroleum products are given herein. The data necessary to bring the first compilation2/ in this subject up to date are given in table I -Revised and Additional Data, which includes boiling points, refractive indices, densities, and freezing points. Tables 11-, III, and IV are published for the first time and include refractive indices for the F, C, and G' lines of hydrogen and the helium D:3 line; surface tensions and viscosities, and refractivity intercepts, specific dispersions, specific refractions, and parachors. The need for information concerning the sulfur compounds in petroleum is becoming-more urgent because of the necessity of refining larger quantities of high-sulfur crude oil to meet the rising demand for petroleum products. For a number of years the Bureau of Mines has been engaged in research to make available more information concerning the properties of the sulfur compounds in petroleum. The petroleum industry has recognized the value of such studies, and as a result the American Petroleum Institute has established Research Project 48A to study sulfur compounds. The investigations under this Project are to be done in Bureau of Mines laboratories as a cooperative project in connection with the work already started.

Jan 1, 1949

By John Nagy

Dust explosion data obtained in laboratory tests by the Bureau of Mines are presented for 181 miscellaneous materials that present an explosion hazard. Data are given also for 50 dusts that present primarily a fire hazard and for 88 dusts that did not present an explosion hazard.

Jan 1, 1968

By Fred C. Turin, Jasinder S. Jaspal, Alan G. Mayton, William J. Wiehagen

Dump site injuries occur in all major mineral industries. Working in elevated areas near an edge is a common hazard for operators of off-highway mobile mining equipment. In this Information Circular (IC), serious injuries involving haulage trucks working at dump sites are examined for the period 1988 to 1997. Data were acquired from injury reports gathered by the Mine Safety and Health Administration (MSHA). The IC is organized into three sections. The first presents an overview of the frequency and severity of injuries. The second analyzes injury characteristics using MSHA-defined data fields and author-defined injury classifications. Key findings are discussed in the third section. In summary, 370 serious injuries were identified that involved trucks at dump sites, of which 26 were fatalities. Although haulage truck activities at dump sites resulted in a small proportion of the total number of injuries at surface mines, these injuries were much more likely to result in death or significant amounts of lost time than most other surface mine injuries. These findings support the belief that haulage truck activities at dump sites are worthy of continued study by those interested in improving the health and safety of workers at surface mines.

Jan 3, 2001

By J. Drew Potts

The U.S. Bureau of Mines identified respirable dust sources and controls on four continuous auger mining sections, two with relatively low dust levels and two with high levels. Factors adversely affecting dust levels included auger equipment design, continuous haulage, and low seam height. Dust controls included ventilation practices and spray systems. Maximizing airflow seemed to reduce dust levels most. Air leakage and shock loss can be reduced by constructing stoppings with brushed-on mortar containing fiberglass and by keeping areas between curtains and ribs free from obstructions and storing equipment not essential for face activities in outby crosscuts. Curtain configuration, setback distance, and installation can also affect dust levels. Use of both blowing and exhausting curtains is the most effective configuration. Setbacks from the face should not exceed 15 ft. Installing brattice curtains at least 5.5 ft from ribs, when entries are 26 ft wide, minimizes velocity head. Installing curtains tightly against the mine roof and floor helps maintain a forward airflow movement in the center of the mine heading; curtain overlap can create a tighter seal. The wet-auger spray system also effectively controls dust, provided the mine is already exercising good ventilation practices.

Jan 1, 1989

By J. M. Kuchta

The chemical and thermal criteria used for predicting the spontaneous combustion hazard are briefly reviewed and data are presented to characterize the gas desorptions and self-heating tendencies of 29 U.S. coals. Closed vessel desorption experiments showed that CO, CO2, and CH4 are the main gases evolved and that the CO, CO/?O2 index, and 02 absorption rate increase with decreasing rank and increasing oxygen content of the coal. In this Bureau of Mines report, the effects of temperature, moisture, and other variables are discussed together with the application of the data to the complex conditions encountered in a mining environment. An important finding is that the presence of CO alone in a mine is not necessarily an indication of a self-heating reaction of the coal. Based upon experiments conducted in an adiabatic-type calorimeter, the self-heating temperatures of lignite and subbituminous coals can be as low as 30° C, whereas the bituminous coals require a temperature of about 60° C or more. The self-heating hazard is greatest when the coals are dried and exposed to a high humidity condition, apparently as a result of the "heat-of-wetting." Generally, the hazard is greatest with the western coals of the United States.

Jan 1, 1980

By Frank E. Cash

Data on the occident experience of the pebble-phosphate industry in Florida for 1937 and 1938 are combined in this report with statistics for the 7-year period 1930-36, inclusive, which were published in Information Circulars 69174/ and 69685/. The periodic publication of such data enables the pebble-phosphate industry, as well as other industries, to consider relative hazards, compare experience, and thereby help to prevent accidents. ACKNOWLEDGMENTS Accident data ere furnished by the following; operating companies: Amalgamated Phosphate Co., Brewster; American Agricultural Chemical Co., Pierce; Coronet Phosphate Co., Plant City; International Agricultural Corporation, Mulberry; Phosphate Mining Co., Nichols; Southern Phosphate Corporation, Bartow; and Swift & Co. Fertilizer Works, Bartow.

Jan 1, 1940

By E. Chin

The production of crude mineral commodities in Bangladesh was limited to natural gas, a small amount of construction materials, and clay for ceramics and bricks. No metallic minerals were mined. The only mineral commodity of economic significance was natural gas. Natural gas production has 'been climbing steadily and becoming an increasingly important source of energy for the country. Proved gas reserves were over 4.5 trillion cubic feet, but the amount has been increasing as exploration discovers large new deposits. Some sources quote reserves at over 10 trillion cubic feet.

Jan 1, 1984

By R. W. Stahl

One of the broad purposes of the Bureau of' Mines since its establishment has been conservation of mineral resources. As some of the coal beds approach depletion, especially those coals suitable for making metallurgical coke, more and more attention is being given to means of recovering a larger percentage of coal in place. The customary system of mining in the United States is by room and pillar, or some variation thereof, which leaves pillars of coal to support, the roof. In many operations, where the pillars are not systematically recovered, the loss of coal often amounts to 50 percent or more of the original deposit. In many instances in developing new mines, It is planned to recover chain and barrier pillars on retreat when the mine has reached established boundaries. Too often, however, mines are abandoned for some unforeseen reason before completion of mining without recovering any pillars. Usually, these pillars are lost forever. With this in mind, the Mining Division, Region VIII, of the Bureau; of Mines is encouraging mining by longwall methods. It is a generally known fact that almost all of the European coal is mined by longwall methods, which are conducive to a high percentage recovery of coal. A comparison between mining systems usually is on the basis of tons per man per shift. Unless all operating conditions are similar, such a comparison could be misleading. Generally, the output per man shift in European longwall mines is less than that obtained in room-and-pillar mining in the United States. In European mining, maximum recovery of coal is not only mandatory but it must be accomplished without major damage to surface by subsidence. These restrictions necessitate packing or stowing with consequential increases In manpower and decreases in output per man shift.

Jan 1, 1954

By E. M. Kawenski, J. K. Richmond, M. J. Sapko, G. C. Price

This Bureau of Mines publication presents investigators' reports of all major coal mine explosion disasters that occurred in the United States from 1959 through November 1981, along with a brief analysis of common factors in these disasters, The report reviews the Federal mine health and safety acts of 1969 and 1977, and discusses how implementation of these acts has reduced the number of both fatalities and disasters, Current Bureau health and safety research is summarized, and an appendix lists most of the ignitions and explosions in the period of record,

Jan 1, 1983