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By R. August Heindl

A process for recovering manganese from open-hearth steel-plant slags was investigated. The proposed method of accomplishing this is indicated by the flow diagram in figure 1. Mixtures of open-hearth, steel-plant flush slags and limestone, so proportioned as to have molar [CaO -3P205] ratios of approximately 2, were fired at approximately 2,400° F. in an oxidizing atmosphere and then cooled slowly. This treatment produced a clinker consisting principally of two solid phases comprised of (1) various combinations of the oxides of manganese, iron, aluminum, and magnesium, probably in spinel complexes, and (2) a dicalcium silicate phase, which contains the phosphorus. Reduction of these clinkers with hydrogen or with gaseous mixtures containing CO, CH4, and other hydrocarbons at about 1,300° F. formed manganous oxide as well as varying amounts of ferrous oxide and iron. Carbon monoxide and mixtures of hydrogen and carbon monoxide effectively reduced the clinkers but also gave higher proportions of soluble iron when the manganese was extracted from the reduced clinkers by leaching at about 80° F. with ammonium carbonate solutions containing 26 to 28 percent ammonia and 15 to 26 percent carbon dioxide. It is believed that the manganese is in solution as an ammonia-manganese complex. Concentrations of about 90 grams of manganese per liter were obtained by batch countercurrent procedures. By distilling 50 percent of the ammonia, the ammonia-manganese complex was decomposed, and approximately 90 percent of the manganese was precipitated as the carbonate with the simultaneous precipitation of 15 to 30 percent of the iron, the larger amounts of iron precipitating in the continuous tests. The manganese-iron ratio in the product could be increased either by recycling more manganese from the distillation to the extraction or by aerating the liquor to purge it of iron before, rather than after, the distillation step. Calcination of the pelletized manganese carbonate in an oxidizing stmosphere at 2,000° F. or above gave a final product, Mn304, resistant to crushing and apparently possessing the other physical properties essential in a ferromanganese blast-furnace feed.

Jan 1, 1955

By John D. Foulkes, David A. Curtis, Robert L. Lagace, John L. Rothery

An investigation is made of the feasibility of developing compact transmit antennas and/or other means to efficiently couple VLF to MF band radio energy between portable wireless communication units in coal mines. The completely wireless communication ranges between two portable radios equipped with practically-sized reference loop antennas in representative coal mine environments are estimated. Antenna technology is assessed with respect to transmit moment, range, intrinsic safety, battery and wearability requirements to deter- mine the most suitable antenna types for use by miners. It is concluded that air-core bandolier loop antennas, and perhaps ferrite-loaded loop antennas, having peak transmit moments of about 2.5 ampere-m5 will be the most effective antenna choices for portable units. This choice, however, will not allow the range goal of 1350 feet to be attained in mines having unfavorable signal attenuation and noise environments. Rectangular air-core loops are compared with grounded horizontal-wire and vertical-wire mode exciters for fixed station applications. The potential for significantly increasing the wireless communication range by inductively coupling to communications and power lines in a mine is evaluated and found to be considerable based on theoretical coupling equations. Lastly, the theoretical performance of a hybrid noise cancelling diversity receiving technique that utilizes both the electric and magnetic field components of the ambient noise to improve the receiver output signal-to-noise ratio under certain adverse conditions is estimated and shown to be favorable when the magnetic and electric field noise components are highly correlated.

Jan 1, 1977

By Arno C. Fieldner

In view of the widespread interest in the production of synthetic liquid fuels from solid and gaseous fuels to supplement declining reserves of petroleum, and the many requests that are now being received for information on the subject, this bibliography of Bureau of Mines contributions has been compiled. In addition to the publications issued by the Government in printed or mimeographed form, references are included to articles written by the Bureau staff for the technical press and to cooperative reports of work done jointly with States, colleges, and industries. References are given under each section in chronological order. Bureau of Mines bulletins, technical papers, and Minerals Yearbooks are printed and are obtainable at the prices indicated from the Superintendent of Documents, Government Printing Office, Washington 25, D. C. If no price is given, the publication is out of print. The price of entire volumes of the Minerals Yearbook or of reprints of certain chanters may be obtained upon request. Any orders or remittances in payment for these publications should be cent directly to the Superintendent of Documents and not

Jan 1, 1945

By D. Harrington

The occurrence of dust in mines has always been a source of trouble, but for any years, and virtually up to the beginning of the present century, relatively little of a definite nature was known as to the numerous ill effects of dust in mining operations. Even today, with the west amount of time given and attention paid (for at least 40 years in various, countries) to research and observation en dust in mining, and in spite of the experience with it, much information remains to be obtained, before definite, well-authenticated statements can be made as to numerous features connected with the occurrence of dust in Dines an of its effect upon the health and safety of the worker. One statement that can be made with relatively good assurance of being uncontradicted in that dust is a real menace to the well-being of mine workers, and this includes both health and safety. In addition, dust in and around mines and mining plants is one cause of large financial losses to mine owners and operators. FORMATION OF DUST IN COAL MINES IN THE UNITED STATES One definition of mining is "the processes by which useful materials are obtained from the earth's crust; " since virtually all of the useful materials of or in the earth's crust either are solids or must be reached by penetrating through solids, the materials that are moved in mining must necessarily be broken or disrupted, so that almost every phase of the work of loosening the material and transporting it is likely to produce dust.

Jan 1, 1939

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as 1892, at Point Albino, Canada.4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence urea by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle, the production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is mane of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety end health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide

Jan 1, 1931

By Leonard Obert

THIS REPORT presents methods and principles useful in designing underground mine openings and pillars in competent rock formations. Two types of formations are considered: (1) Massive formations, in which openings are generally mined with an arched roof, and (2) bedded formations, in which openings are generally mined with a flat roof. Design principles for openings and pillars in massive formations are obtained by considering the maximum tangential stresses developed around single and multiple openings for stress fields of various types. Design principles for openings and pillars in bedded formations are obtained by considering the average stress in pillars and the maximum stresses in roof layers. Experimental procedures for making stress, strain, and in situ physical-property measurements in underground mines to check design calculations are outlined and the results discussed.

Jan 1, 1960

By D. N. Nilsen

A mathematical modeling method was developed by the Bureau of Mines for the prediction of the principal equilibrium species in the solvent extraction of copper. The use of models for predicting the amount of metal extracted can reduce the amount of experimental work required to characterize a system for purposes such as optimization studies. Models were developed for the extraction of copper from ammoniacal sulfate and carbonate solutions with commercially available extract ants commonly used by industry. Results from laboratory shakeout tests compared well with predictions of the equilibrium concentrations of copper and pH values. For example, the loading of copper onto the solvent was predicted for most cases within ±S pct of the measured values, and the pH to with-in ±O.l pH unit in sulfate systems and ±O.2 pH unit in carbonate systems. Both mechanistic and empirical extraction equations were developed from laboratory data for copper and ammonia. The empirical-based models were slightly more accurate than were the mechanistic-based mod-els. Industrial level concentrations of the aqueous and organic constituents were used in this work. Independent variables included copper concentration, ionic strength, and initial pH of the aqueous phase; extractants, diluents, and their concentration in the organic phase; and temperature.

Jan 1, 1988

By Erle C. Donaldson

Bureau of Mines engineers examined the chemical and biological treatment of sewage water designed in one case for reuse and in another for subsurface injection. In the first case discussed, approximately 6 million gallons per day of sewage are treated by the activated sludge process followed by tertiary treatment that includes ion exchange. The renovated water is used in the industrial complex. Liquid industrial waste is sent to a waste disposal facility where it is treated for injection into a deep subsurface formation. In the second case, a community of 3,000 people is using a lagoon sewage treatment system followed by subsurface injection of t- treated effluent. Subsurface disposal is used to avoid growth of algae and weeds in a nearby lake to which the treated effluent was originally discharged. The renovation of municipal water for reuse provides a source of water for industries in a semiarid region and may also provide a source for domestic use in densely populated regions where domestic water requirements have priority over industry needs. In addition both waste treatment systems provide examples of the use of subsurface waste disposal to avoid pollution of surface streams.

Jan 1, 1971

By S. J. Broderick

[The discovery in 1934 that carbonaceous materials, such as coal, peat, and lignite, when treated with concentrated sulfuric acid, were given cation or bate-exchange properties opened up a field of new materials with many interesting possibilities. These hydrogen exchangers, as they were called, were so superior to the impractical hydrogen exchangers made from natural and synthetic zeolites tat they were accepted immediately by the water-conditioning industry. A noteworthy advantage of the carbonaceous exchangers is that they are nonsiliceous, hence they do not give up silica to the water as do the natural and synthetic zeolites, especially if the hard water is corrosive. For this reason the new exchangers found immediate favor in boiler-feed-water conditioning.]

Jan 1, 1941

By Ivette E. Torres

The final 26 tables of this chapter, tables 24-49, extend and expand the statistical series on production that was started in the 1963 edition of the Area Reports: International volume of the Minerals Yearbook and that was subsequently updated and expanded in the 1965 and 1967-90 editions. Mainly because of the separation of the countries that formed the U.S.S.R., the column that provided a 5-year average, was deleted. The listing order of major producers, however, continued to be, as in past years, in descending order of rank in the year of review, 1992. This group of tables now includes each of the top 19 crude minerals in 1983 in terms of value of their output plus 3 others of lesser rank. These 22 crude mineral commodities accounted for more than 98 % of the estimated value of world crude mineral production in 1983. Coal production, included in the 1983 value of production table as two separated entries, is combined in one table in this chapter. World output of five key downstream products-aluminum, steel, cement, nitrogen in ammonia, and refined oil-is included because of their significance as products.

Jan 1, 1994

By P. S. Haury, Thomas C. Denton

"INTRODUCTION AND RESUMEThe Reward zinc property was one of the first selected for exploration by the Bureau of Mines at time when zinc supplies for war production were very short. Preliminary examination indicated that an appreciable tonnage of zinc that could be developed for early production might be found by diamond drilling. The geology was mapped by the Federal Geological Survey, and 14 holes were diamond drilled by the Bureau of Mines. This work was started in September 1942 and completed in September 1943.The Reward is an old property in southwestern Pinal County, 26 miles from Casa Grande on the Southern Pacific Railroad. Mining was begun in the early 1880's and was continued intermittently by several operators to about 1917. About 400,0oo pounds of copper was produced from the north¬eastern part of the property, mainly from a 600-foot incline in oxidized copper ore that replaced a bed of limestone. This ore was mined out. A 400-foot vertical shaft in the copper area was inaccessible. A 325-foot vertical shaft had been sunk near the southwest end of the zinc-bearing area, and a 600-foot crosscut tunnel had been driven near the northeast end of the zinc area, but little zinc ore was produced. There were several shallow inclines and numerous surface pits between the main workings.The ores were deposited in Paleozaic limestones that strike northeast and dip about 40 degrees northwest. These are capped by Cretaceous clastic and volcanic rocks in the zinc area. The outcrops show mineralization in a segment of the limestone 4,500 feet long, which is limited by large cross faults at each end. Another large fault, which strikes north, separates the northeast third of the mineralized belt from the remainder. Copper predominates northeast of this fault and zinc southwest of it. The ore beds are cut by numerous small cross faults. Ore was deposited for short distances along some of these, but more of it made out from the fissures along certain replaceable limestone beds."

Nov 1, 1946

By Kenneth M. Maas

The Bureau of Mines inventoried the land availability for mineral exploration and development in northern Alaska and compared this land with known mineral terranes and mineral deposits, to quantify the potential for favorable location of mining claims for metalliferous mineral deposits. This report includes thirty-three 1:500,000-scale maps that depict land availability, and the accompanying text and tables relate availability acreage to areas of favorable mineral terranes. Three categories of land availability and ownership are identified, along with 12 subcategories of land status. Available land comprises approximately 14.5 million acres or 16% of the 90.3-million-acre study area; land available with restrictions accounts for 7.5 million acres or 8%; and unavailable land encompasses 68.3 million acres or 76%. Mineral terranes underlie 37.8 million acres or 42% of the study area; 5.3 million acres or 14% are available for mineral location, 2.8 million acres or 7% are available with restrictions, and 29.7 million acres or 79% are unavailable. There are 500 known mineral deposits or occurrences within the study area. This includes 271 lode deposits, of which 171 lie within a recognized mineral terrane and 55 are on available land. The remaining 229 are placer deposits.

Jan 1, 1987

By C. L. Karr

Researchers at the U.S. Bureau of Mines (USBM) have developed adaptive process control systems in which genetic algorithms (GA's) are used to augment fuzzy logic controllers (FLC's). GA's are search algorithms that rapidly locate near-optimum solutions to a wide spectrum of problems by loosely modeling the search procedures of natural genetics. FLC's are rule-based systems that efficiently manipulate a problem environment by modeling the "rule-of-thumb" strategy used in human decision-making. Together, GA's and FLC's include all of the capabilities necessary to produce powerful, efficient, and robust adaptive control systems. To perform efficiently, such control systems require a control element to manipulate the problem environment, an analysis element to recognize changes in the problem environment, and an adaptive element to adjust to the changes in the problem environment. The control system also employs a computer simulation of the problem environment. Details of an overall adaptive control system are discussed. A specific laboratory acid-base pH system is used to demonstrate the ideas presented; all results are from the physical laboratory system and not from a computer simulation.

Jan 1, 2010

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963

By A. G. Starliper, H. Kenworthy

A procedure was developed for the separation of lead and sulfur in industrial concentrates of galena by a combination of chlorination and fused - salt electrolysis . Galena could not be satisfactorily electrolyzed in the various media tried ; however , when it was treated with chlorine the resulting lead chloride could be effectively separated electrically into lead and chlorine . An apparatus was designed and constructed to chlorinate galena and to volatilize simultaneously most of the chloridized impurities . By electrolyzing the chlorinated concentrate , a high percentage of lead was recovered . Anodic chlorine was drawn from the cell and was used to chlorinate new feed . In many runs , the recovered metal analyzed from 99.8 to 99.9 percent lead . Lead was also distributed as a chloride in the bath , and a small portion was in the volatile fraction produced during the chlorination step . During a tinuous operation , only 0.1 percent of the total lead was discarded ; 99.9 percent was accounted for in the metal , electrolytic bath , and washed or leached chlorination condensate which was essentially lead chloride . About 95 percent of the sulfur from the galena was recovered as a byproduct of over 90 - percent grade .

Jan 1, 1964

By F. D. Everett

This report, based on information made available by four uranium-producing companies, describes the geology, exploration, open-pit development and mining, and shaft sinking in the Gas Hills uranium district of Wyoming. Open-pit stripping features motor-scrapers push-loaded by crawler or rubber-tired tractors. The ground generally can be ripped, and little blasting is necessary. Detailed data are given on grouting for ground stabilization in sinking a small-diameter shaft in the relatively unconsolidated sandstone and siltstone, Cost and performance data are presented as made available by the companies.

Jan 1, 1963

By F. D. Everett

This report, based on information made available by four uranium-producing companies, describes the geology, exploration, open-pit development and mining, and shaft sinking in the Gas Hills uranium district of Wyoming. Open-pit stripping features motor-scrapers push-loaded by crawler or rubber-tired tractors. The ground generally can be ripped, and little blasting is necessary. Detailed data are given on grouting for ground stabilization in sinking a small-diameter shaft in the relatively unconsolidated sandstone and siltstone, Cost and performance data are presented as made available by the companies.

Jan 1, 1963

By Walter I. Enderlin

To economically extract ore from great depths in the earth while sustaining an acceptable working environment will require the development of new technology and equipment, involving large capital expenditures. Moreover, careful analysis and advance planning will be required. But, the literature is lacking in data pertaining; to the thermal properties of various host rocks and to quantities of heat generated by various underground heat sources. This types, of data is required to forecast nine heat loads during advanced planning and design. This thesis sets forth a practical method for evaluating underground sources of heat in deep mines and provides an improved information base. Moreover, seven topics for further research are recommended. The heat sources considered are: wall-rock, ground water, adiabatic compression, equipment, service lines, blasting, metabolism, curing of cement, and oxidation of sulfides and timber. Seven deep metal mines with high production rates and high heat loads were visited to obtain data necessary to assess their thermal environments. Mine records were examined, wall-roc:, temperatures were measured and a survey of the mine ventilating air and mine drainage was performed. Also, the thermal conductivity of wet and dry specimens of the host rock were measured in the laboratory. Data analysis disclosed that rock heat and adiabatic compression account for stout 60 per cent of the mine heat load at depth. Equipment currently contributes approximately 20 per cent; however, to offset increasing costs with depth, increased mechanization is anticipated. The treat from ground water averages 19 per cent and the contribution from blasting, metabolism and cement is negligible. Also, approximately [0] per cent of the increase in the enthalpy of the ventilation air is in the form of latent heat. Moisture, however, did not significantly affect the thermal conductivity of the rock specimens measured in the laboratory. Also, from the data, it is evident that a negative correlation exists between the thermal conductivity of the host rocks and the per cent of the heat load derived from the wail-rock. Furthemore, steady state heat flow renditions may be assumed in airways where there has been no major changes in the ventilation system for a period of two years or more. Under these conditions, the author found it more convenient and reliable to compute heat influx using the steady state equation for heat flow into a cylinder, rather than Carrier's method for transient heat flow, which is so often used.

Jan 1, 1973

By David W. Tongue

This report describes the engineering work leading to the design of an underground coal mine piping system to transport approximately 2,000,000 cubic feet per day of methane gas to the surface from degasification holes drilled horizontally into the coalbed in existing coal mines. Safety instrumentation for detection of gas leaks and provisions for automatic emergency shutdown are included in the design. It also includes specifications for a safe system of handling gas, water, and drill cuttings during drilling of the horizontal holes and recommendations for compressor and metering facilities at the surface. The main pipeline is recommended to be constructed of polyethylene plastic pipe joined by a butt fusion method while lateral lines and separator and meter piping at the horizontal holes are recommended to be screwed steel piping. The materials used are to be resistant to the forces of impact exerted by falling rock. The pipelines are to be suspended from the ceiling with pipe hangers. All steel components are protected from chemical corrosion by applying protective coatings and the vertical casing to the surface is protected from electrolytic corrosion by a rectifier station. Methane gas detectors monitor the mine atmosphere to detect the presence of gas leaks and a pneumatic plastic tubing line provides for control of the safety shutdown system. Both the recommended design and the required construction procedures are in compliance with the applicable Federal codes for coal mine safety.

Jan 1, 2012

By W. W. Adams

"The fifth annual National Safety Competition conducted by the United States Bureau of Mines to determine the best safety records at mines and quarries during the calendar year 1929 has been concluded, and the general results of the contest are presented herewith. To the winner in each of the five groups into which the contestants were divided there has been awarded the bronze trophy 'Sentinels of. Safety,' donated by the Explosives Engineer magazine. The trophy for bituminous coal mines was won by a mine in Alabama; that for metal mines by an iron-ore mine in Michigan; that for nonmetallic mineral mines by a salt mine in New York; that for quarries and open-cut mines went to a limestone quarry in Michigan;. the trophy provided for anthracite mines was, of course, won by a mine in Pennsylvania, as all of the anthracite mines participating in the contest are situated in that State.Winners of the trophies were selected by a committee of sward in accordance with rules governing the contest and on the basis of accident records furnished by the various companies to the Bureau of Mines. These records were summarized by the bureau and the results submitted to the committee. Members of the committee are W. H. Cameron, managing director of the National Safety Council. William Green, president of the American Federation of Labor; James F. Callbreath, secretary of the American Mining Congress; T. T. Read, Vinton professor of mining of Columbia University and editor of 'Mining and Metallurgy'; C. B. Huntress, executive secretary of the National Coal Association; A. J., Curtis, assistant to the general manager of the Portland Cement Association; A. T. Goldbeck, director of the engineering bureau of the National Crushed Stone Association.Thirty-four States were represented in the l29 contest. Among the plants which participated were 68 bituminous coal mines, 29 anthracite mines, 54 metal mines, 19 nonmetallic mineral mines, all of the foregoing being underground mines, and 141 quarries or open-cut mines. A total of 106,533,006 man-hours of work was reported by all of the companies. Accidents during the year numbered 7,008 and represented a period of disability equal to 986,306 man-days. Hence the accident-severity rate for all plants combined represented 9.3 man-days of disability for each thousand man-hours of exposure to hazard. Similarly, the combined accident-frequency rate for all plants showed that 66.3 accidents occurred for every million man-hours of exposure to hazard. Both of these rates indicated an improvement over the combined rates for all plants in the previous year's contest. The reduction in the accident-severity rate centered chiefly in the metal mine group, though all except the quarry and open-cut mine group shared in the reduction; the improvement in the accident-frequency rate was in all croups except anthracite and metal, the rate for the former having increased while that of the latter remained unchanged."

May 1, 1930