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The present study investigates the nature of gold mineralogical distribution and association in a Cu-Au flotation circuit (1.6 g/t Au, feed head grade). The approach used in this study involves a combination of bulk gold assay and quantitative X-ray diffraction (QXRD), on a size-by-size basis, followed by QEMSCAN analysis on the -75+53 µm, -53+38 µm and -38+20 µm size fractions. The QXRD and QEMSCAN analysis showed that gold mineralogy is complex and fine-grained in the flotation feed, particularly in the -38+20 µm size fraction. Gold and pyrite concentration follow each other closely, suggesting gold-pyrite association. Quartz as the major gangue mineral shows a bi-modal distribution with respect to particle size. The identified gold particles were completely locked (~94 %) in pyrite as fine inclusions and 6 % locked as complex aggregates (-75+53 µm size fraction) whereas in the -38+20 µm size fraction, the identified gold grains occur as fine inclusions (~1-3 µm) within pyrite and silicates. However, in the intermediate size fraction (-53+38 µm), 75 % of the identified gold grains (10-22 µm) were over 90 % liberated and 25 % associated and locked in pyrite and complex aggregates (~2-4 µm). The identified gold grains in the -53+38 µm size fraction occurred as native and electrum with varying silver concentration between 8 and 20 % by weight. In the -38+20 µm size fraction, a gold telluride was also identified. Based on the mineralogical analysis of the feed, possible flotation strategies are discussed. Optimizing the flotation of pyrite is suggested as the primary Au recovery strategy. Keywords: flotation, pyrite, gold, liberation, QXRD, QEMSCAN

Sep 1, 2012

The Indian steel industry is growing at a rapid pace and expected to be the 2nd largest steel producer in the world after China. To cope up with this growth and to sustain it, the industry needs to focus on effective utilization of domestic metallurgical coals. While the importance of indigenous coal has increased, its supply from the domestic sources is declining. This is primarily due to high ash content in Indian coals leading to its difficulty in washing to a low level competitive to imported coals. Non-availability of a suitable beneficiation technology to bring down the ash to such a low level is the other reason. Effective utilization of current technologies has enabled Tata Steel to bring down the ash to 13-16% from its captive collieries. However, further lowering the ash using the conventional beneficiation technologies is difficult and unsustainable. New technologies should be developed for bringing down the ash further. A thrust area research program has been undertaken at Tata Steel for producing clean coal with 8% ash maintaining the yield currently achieved in its washeries. The technologies attempted are based on chemical beneficiation of coal. In leaching process, suitable chemicals are used for extracting ash minerals from the coal. As an alternative process, the combustible part of the coal is being extracted using a suitable organic solvent through an organo-refining process. Both the processes have been successfully developed in the laboratory and are being demonstrated in pilot scales. Various beneficiation processes practiced at Tata Steel including the efforts made for developing new processes for achieving clean coal with 8% ash have been discussed in this paper. Keywords: metallurgical coals, washing, beneficiation technologies, chemical beneficiation, leaching, solvent, and organo-refining process

Sep 1, 2012

By Hemant Nerurkar

The destination of human development journey is envisioned as human well being. Human well-being is the extent to which individual share the ability and the opportunity to live the kinds of lives they value it includes environmental security, good health and living conditions, all of which are closely related to each other. The breakthroughs, which transformed the human race, have close interdependency with the environment. With the increase in world population, the requirement of natural resources is increasing every day. The nature is still stronger than man is but we must use natural resources more responsibly. The key to our well being is sustainable development Development effort for human well being may have adverse impact on the environment also. To keep the net impact positive is critical for sustainable development. For mineral processing industry, the value of a mineral is in the actual value as perceived by the end user. The process designs, investments in technology development all have direct relationship with the value of use and making a net positive impact on our ecosystem The value proposition has shifted towards raw materials and is a big differentiator. The availability of good quality raw material is difficult or is available at a premium. The challenge today is to develop green technologies that make effective and efficient usage of low grade raw materials The low grade raw materials as available pose a significant opportunity for human race for delivering value. They offer an easier reach to a value as perceived in end use but the journey is full of challenges. The first challenge is development of technology for maximizing grade recovery as required by the downstream process. The second challenge is to make the technology viable so that it contributes value to end use and the third challenge is to keep the net impact of the process positive The mining and mineral processing fraternity, being at the beginning of this value chain is set to take the first step in this journey for a tryst with ultimate human well being. Keywords: sustainable development, challenges in mineral processing

Sep 1, 2012

By M. V. S. Cavalcante

The quality of iron ore pellets, represented in terms of parameters such as cold compressive strength (CCS) and Tumble Index (TI), has a strongly influence on the productivity and energy of reduction furnaces like the blast furnace and on the quality of hot metal or liquid iron. The main objective of pelletization operations is to produce iron ore pellets of desirable specifications and ensure high levels of plant productivity and energy efficiency. Advanced process control of an industrial iron ore pellet induration process using a soft sensor for pellet quality and fuzzy-logic based control algorithm is described in this paper. The pellet quality soft sensor consists of a rigorous mathematical model of the induration process and a statistical model for the pellet quality parameters. The mathematical model is based on the fundamental principles of heat and mass transfer between gases and pellets, kinetics of drying and condensation of moisture, combustion of coke, calcination of limestone, and melting and solidification of pellets. The predictions of wind-box temperature profiles are in close agreement with the measured profiles. The time-temperature profiles of the pellets during induration, along with raw material characteristics and induration process operating conditions, are used as inputs to the quality model to predict cold compressive strength and the Tumble Index. The predictions of the quality soft sensor along with the rules based on fuzzy-logic derived from simulation results and operator experience are then utilized to control the induration process to achieve precise control of the quality parameters and to optimize the induration process in terms of fuel efficiency and productivity. The mathematical model is also utilized as a soft sensor for temperature, moisture and composition profiles of pellets and gases. Results of implementation of this model-based control strategy on an industrial scale induration process will be presented. Keywords: iron ore, pelletization, simulation, process control, optimisation

Sep 1, 2012

By T. C. Rao

This presentation identifies how mineral (coal included) processing profession should look at the challenges (threats) being faced by mineral industry. Presently, the focus is more on supply and demand on minerals. In addition, the R&D activities in the chain of mine-to-metal are paying more attention (if not only on) the processes being adopted, development of new equipments and modeling and simulation. But the profession is grossly ignoring aspects such as impact of the processes on other resources, of the ways we extract, use and dispose them socio-economically and efficiently. A business model which may encompass all these dimensions are essential for the sustainable development of mineral industry and a possible approach in this direction is presented. To start with, for the sustainable growth and existence, the profession must be aware of the prospective impacts of their activities on critical factors such as ? political (changing government policies), geographical (environment, land, water and habitat), which have major bearing on the survival and growth of the industry. Mineral Processing professionals have to join hands with mining engineers to answer some relevant questions related to the impact of mineral industry on society. Mining can become economically viable only if mineral processing engineers come out with innovative solutions to reduce capital and operating costs. The solutions have to be adoptable and practically feasible so that industry looks at us for directions. In fact, we have to move towards beneficiation of nano particles striving towards zero waste. Some of the gaps in the knowledge of procedures being followed in the design and operation of processing plants are highlighted. Enhancing the knowledge base for solving unexplored possibilities, solutions to evolve sustainable development measures which demands innovation both at academic and practicing levels is the need of the future. Well-structured academic programmes are to be formulated so that the graduates of these programmes can make an effort to look at processes/concepts with a new insight and approach; the profession should excite the young brains with challenges. R&D funding agencies have to have a long-term perspective on mineral processing so that closer interactions between academic institutes, industry and R&D organizations are sustainable and that innovations are at least a few years ahead of needs of future challenges. Keywords: sustainable growth

Sep 1, 2012

By S. Kelebek, A. Khan, J. Caceres, Beckett. D.

"Pyrrhotite in nickel-copper sulphide ores is nickeliferrous and intimately associated with pentlandite. Due to its low nickel content, pyrrhotite rejection is an important step in processing of these ores. In our laboratory, various reagents were investigated for their effect on pyrrhotite depression. Among these, a combined use of triethylenetetramine and sodium metabisulphite was found highly promising.The work described in this paper has two parts. The firs part is a summary of results obtained on process samples from the pyrrhotite rejection circuit at Falconbridge’s Strathcona Mill. The second part involves simulation of the circuit performance based on the reagent conditions used in the experimental work and the concept of split factors.Two sets of reagent conditions were evaluated. The first one involved baseline conditions, simulating the current reagent performance. The second one simulated the impact these new reagents can have on the circuit performance.The simulation results obtained under baseline conditions indicated a good agreement with the current circuit performance. The simulation results suggest that at practically the same pentlandite recovery and tailing grades, the circuit concentrate nickel grade can be doubled through effective pyrrhotite rejection by these new reagents."

Jan 1, 2003

By Ivan Bonchev, Elisaveta Djurova, Evgeni Visariev, Viktor Stoilov

"Two types of slag cooling is used world wide - cooling in ladles and cooling in pits. The flotation comparison of the type cooling regimes was done at Aurubis Bulgaria. In Copper smelter Aurubis Bulgaria (Pirdop), the residual copper in the slags from Flash furnace and Converters is recovered by flotation. The slag flotation plant processes blend of three parts FSF and one part converter slag. The slag processing comprises: pit cooling, crushing, two stages grinding (autogenous and ball) and flotation. The copper content in flotation concentrate is over 20 % and in flotation tail is under 0.5 %. In order to improve the copper recovery, different cooling rate of the liquid slags should be achieved. Three cooling experiments with flash smelting furnace (FSF) slag have been done: two of them in pits with different volume and one cooling experiment in metallic ladle. The ambient air temperature during the cooling tests was from -4 to +4 OC. Laboratory flotation tests in open cycle were done with an aim to compare the slags behaviors cooled at different conditions. In this paper the effect of different cooling on the flotation process will be presented. The copper recovery and distribution by sizes in the tails, copper content in the rougher concentrate, and the concentrate yield are discussed."

Jan 1, 2014

By Z. B. Pan

The innovative point of this new technology can be described that under normal pressure and 70°C, using a new combined activating and oxidizing agent, the minerals bearing arsenic and organic carbon are oxidized effectively. This technology can be applied in commercial scale. The high carbon and arsenic bearing gold ore is taken from Gansu, where hundreds of tons gold deposit. The ore has 0.51% of arsenic and 1.75% of carbon (1.07% of organic carbon). The gold occurs mainly in native with particle size 0.02~0.6 mm and a few are enwrapped by pyrite and arsenopyrite. The traditional cyanide leaching process gains a very low gold leaching rate with only 5%. Through systemic experimental study, the technological flowsheet of flotation process for concentrating gold, then pre-treating the gold concentrate followed by cyanide leaching the gold concentrate are used. With 4.92 g/t gold of head sample, the gold concentrate with 46.52g/t gold grade and 96.53% gold recovery is gained by flotation process. Followed by pre-treatment for 6 hours, the gold concentrate is leached with cyanide after filtration and washing. The total gold leaching rate is up to 95.44%.

Jan 1, 2014

By P. Oliveira, A. Peres, A. Silva

"The decrease in iron content and increase in contaminants grade, associated with greater participation of compact and semi-compact materials, has impacted the recovery of a mechanical cells flotation circuit in the Iron Quadrangle, Brazil. The recovery decrease in the flotation stage motivated the current conventional flotation circuit reevaluation seeking alternatives to restore the recovery, without affecting the final concentrate quality parameters, with low investment. Sampling, chemical characterization of samples, bench scale flotation experiments, and mass balances were conducted. Analysis of the results showed opportunities to improve the circuit performance. The stages prior to the flotation circuit changes were: rougher, cleaner, recleaner and scavenger. In the previous configuration, recleaner was operated as cleaner scavenger and the iron grade in the scavenger concentrate was 23%, representing 38% of the new feed. After the circuit change, the circulating load was reduced from 38% to 15% and the iron content was upgraded to 42%, resulting in increased residence time. The iron content in the global tailings of the concentrator was decreased from 10.9% (year of 2013 average) to 10.2%, representing gains in both mass and metallurgical recoveries.INTRODUCTIONRegarding plant practice, the year 1972 represents a landmark for the concentration of iron ores in Brazil. VALE started up 28 units of WHIMS (wet high intensity magnetic separators) at the Cauê plant in Itabira, each one producing 1x106 t/year of concentrate. Later 17 WHIMS machines were commissioned at Conceição. During the 80’s decade of last century, changes in the ROM required the addition of a cleaner flotation stage to decrease the silica content in the pellet feed.The first company to use reverse cationic flotation as the only concentration operation of iron ore was SAMARCO (start up in 1977). Since 2015 flotation has been utilized at VALE in Itabira as major concentration process, magnetic separation acting as scavenger stage.The Jones matrix type WHIMS were manufactured for decades under patent by KHD Humboldt Wedag. After the expiration of the Jones patent, Eriez Magnetics took the world leadership regarding WHIMS manufacturing. The Brazilian branch of Eriez is Inbras. Based on plant practice experience at the Fabrica concentrator, the Brazilian company Gaustec was established (RIBEIRO and RIBEIRO, 2010) and is now present in different countries. The mega sized WHIMS GHX-1400 (18.000 Gauss, gaps smaller than 1.5 mm) were developed to face the challenge of huge throughput required by iron ore processing (Ribeiro et al, 2017)."

Jan 1, 2018

By Fedotov. K. V., A. Y. Senchenko, V. A. Chanturiya

"The paper describes an efficient process to treat the ore from the largest in Russia copper deposit – Udokan. The recommended process is universally applicable to Udokan ores different in composition and allows reaching high copper recoveries during production of high-grade cathode copper and sulphide concentrate with 45% copper content. There are several promising trends for the process optimization and in the case they are implemented, economics of the whole project could improve significantly. One of the most important optimization options implies reduction of specific energy consumption in the course of comminution operations. Another possible option to optimize the already selected process flowsheet is production of cathode copper from sulphide concentrate directly at a mining and metallurgical plant without sending the latter to other metallurgical works.INTRODUCTIONUdokan copper deposit with resources of more than 20 million tons of copper is the largest in Russia and one of the largest copper deposits in the world. The deposit is located in Kalar District of the Trans-Baikal Territory, 30 km away from Novaya Chara railway station of the Baikal-Amur Mainline.Scientists and engineers from various research institutions have studied Udokan copper ores for years. Along the way, some conceptual process flowsheets have been proposed and each of them has its own pros and cons. The key requirement to the processes being developed was their universal application for processing of all the ore types using a single flowsheet. Due to the hard mining and geological conditions and because of complex material composition of Udokan ores it is of great difficulty to design a process which would provide for maximum economic benefits. That is why the process optimization has been ongoing until now.According to the Russian standards, the main input document for design of a metallurgical plant is referred to as a Process Design Report that covers the following key data sections: analysis of metallurgical testing results, validation of the process, design criteria, process flow diagrams, the mass and metallurgical balances, process description, equipment list and other information necessary for the subsequent design."

Jan 1, 2018

By T. Fujita

The incinerated bottom ash includes titanium oxides and a small amount of chromium oxides. Initially, 89 % of chromium was removed from ash at magnetic flux density at several stages of wet magnetic separation from 0.05 T to 6 T. The bottom ash from an industrial waste incineration process includes about 10 % of TiO2. The minerals that contain titanium are rutile and perovskite. These minerals are paramagnetic and show low magnetic susceptibility, therefore, the high magnetic field strength, created by a superconducting magnet, is necessary to capture these minerals. At the first stage of separation, a magnetic field strength of 6T was applied in order to attract the particles that contain iron oxides to the higher magnetic field region. At the second stage of separation, the magnetic capture rate of weekly magnetic particles decreased with increasing the magnetic susceptibility of the aqueous solution (i.e. the medium for dispersing the particles) in order to separate the highly magnetic materials. The para-magnetic salt such as ferric chloride was dissolved in the water to increase the magnetic susceptibility of the medium. After a two-step wet HGMS with superconducting magnet, the grade of TiO2was increased from 10 % to 28 % with a recovery of 64 %.

Jan 1, 2014

By S. M. Narbekova, L. V. Semushkina, Zh. A. Aldybayeva, A. A. Mukhanova, D. K. Turysbekov, N. K. Tussupbayev

More complex and heavy-concentrating oxidized and mixed sulphidic oxidized ores are involved in production because of increasing needs for non-ferrous metals. Extraction of the oxidized minerals of non-ferrous metals general in current technologies. The problem is solved to oxidized polymetallic ores the preliminary selective sulphidization is the oxidized surface of the components by means of hydrogen sulphide, sulphide and calcium polysulphide, and also element sulphur, etc. The task was to study details of flotation of the oxidized lead-bearing ore of the Zarechnoe deposit (Kazakhstan) with calcium polysulphide as sulphidation. According to chemical analysis initial samples of the ore contain, %: lead – 4.8; zinc – 0.1; general iron – 0.81. Phase structure lead is characterized by the oxidized form of 57.76-64.5 %; by sulphidic status of 25.5-32.64 %, and by plyumboyarosite of 19.0-23.02 %. Researches on flotation beneficiation of oxidized lead-bearing ore are conducted. Sulfidizator gave to grinding, on flotations there were used the collector (butyl xanthogenate of sodium) and frother (T-80). Experiments were conducted with a new sulphidizator – calcium polysulphide. The latter is obtained by interaction of CaO calcium oxide with sulfur and water at high temperature with component mass the following ratio S:CaO:H2O =10:5:85. Extent of mill initial ore was optimised (88.42 % of - 0.071 mm grade). For the optimum mill mode the studies on matching of an optimized consumption of sulphidizators are performed. On basic technology with application of sulphide of sodium as a sulphidizator at optimum mill, the lead concentrate with the content of lead 64.4 % at extraction of 86.6 % was received. The content of cerussite in a concentrate was about 14.9 % at extraction of 82.1 %. With application of calcium polysulphide as a sulphidizator the lead concentrate with the content of lead 68.0 % at extraction of 88.0 % was received. The content of cerussite has made 16.0 % at extraction of 85.0 %. Application of a new sulphidizator allows to increase extraction of lead in a concentrate from 64.4% to 68% and cerussite extraction – from 82.1 % to 85.0 %. The possibility of application of calcium polysulphide as a sulphidizator instead of conventional sulphurous sodium was established.

Jan 1, 2018

By A. Luszczkiewicz

An innovative hybrid technology for beneficiation of difficult-to-process sedimentary copper ores comprising acidic leaching stage of the feed combined with subsequent flotation has been presented. Acidic leaching, preceding the flotation process, plays a beneficial role of efficient chemical grinding for liberation of copper sulphide minerals finely disseminated in the copper-bearing carbonate-shale rocks. The process was applied on a fully industrial scale. Flotation results were analysed for both chemically modified and unmodified flotation feeds. After several months of industrial scale operation, it was found that both metals recovery and concentrate grade remarkably increased as a result of application of chemical modification of the flotation feed. Beneficial effects of chemical pre-treatment of flotation middlings on selectivity at a comparable concentrate yield in industrial flotation scale, revealed a considerable increase of the total copper recovery by 3.5percent. Based on the industrial and laboratory investigations we consider a further development of the process and introduction of hydrometallurgy for better recovering of metals from low-grade copper concentrates

Sep 1, 2012

By N. A. Dementyeva

To improve gold recovery from preg-robbing carbonaceous ores a technology including gravity, flotation, recleaning of the flotation concentrate, intensive cyanidation of the gravity concentrate and carbon-in-leach (CIL) process for intensive cyanidation tailings and the recleaned concentrate was developed. The final flotation tailings are shipped to tailings disposal. Total gold recovery by the proposed technology from the ore with the head grade of 0.8 g/t was 83.9%. The gold loading onto the activated carbon from CIL process was 6.5 g/kg.

Jan 1, 2014

By D. Chakraborty, Neeraj Kumar

"The study provides the comparative analysis of the performance of water only cyclones and hydrocyclone for iron ore fines processing at Joda Iron ore processing plant, Tata Steel. Joda iron ore deposits have higher proportion of kaolinite in the finer fractions and are meant to be separated with cyclones. The iron processing flowsheet of Joda comprises of water only cyclone for beneficiation of iron ore fines. Water only cyclones are used for the beneficiation of fines in the iron ore processing industry and have a larger cone angle compared to that of conventional hydrocyclones to enhance the density effect in the separation. They are aimed to achieve better product quality of underflow however; the desired result could not be achieved at the Joda processing plant. The water only cyclones were operating at the corrected cut-size of about 60 micron with an imperfection of 0.40 and water split to underflow was approximately 10%. The overall Fe recovery from the water only cyclones were 60%. Since the quality of fines produced from the water only cyclone couldn’t be improved, an attempt was made to process the fraction in the conventional hydrocyclone to achieve the desired product quality. The trial results indicated better product quality with the Fe recovery of 72% at corrected cut-size of 70 microns and imperfection of around 0.29. In view of above results it was recommended to replace the water only cyclones with hydrocyclones to achieve higher product quality of about 60% Fe content.INTRODUCTION Water only cyclones were installed at wet plant, Joda to process the classifier fines where the cyclone underflow is considered as concentrate and overflow is discarded as slime. Because of the lower capacity of the cyclones 30% of the classifier overflow was bypassed directly to thickener. Apart from this the quality of fines produced from the water only cyclone couldn’t be improved further hence an attempt was made to process the fraction in the conventional hydrocyclone to achieve the desired product quality and quantity. Hydrocyclone was installed at Joda after replacing stub-cyclone and came into operation on 23rd Aug’ 2017.The process variables of water only cyclones and hydrocyclones are tabulated below:"

Jan 1, 2018

By J. Yianatos

The regrinding stage is necessary to achieve the particle size (liberation) for the final upgrade in the cleaning flotation process. At present, vertical mills (Vertimill) are employed at industrial scale, using small steel balls as grinding media. The regrinding process characterization requires mixing regime knowledge along with the mean residence time of the liquid and solid phases. The residence time distribution (RTD) and the actual mean residence time estimations from theoretical relationships are complex due to the presence of three components (solid mineral, balls and water), mass transport characteristics and segregation affecting solid holdup. Therefore, the experimental RTD determination is suitable for industrial mills. In this work, RTD measurements were performed in two different industrial flotation plants. Both plants operate with Vertimills of 1000-1500 HP in the regrinding process with different circuit arrangements according to the plant treatment capacity. The RTD was measured using the radioactive tracer technique. This technique allows for non-invasive tracer detection where the procedure consists of selecting a liquid (Br82 in aqueous solution) or solid (irradiated solid) tracer for RTD data acquisition in real time. The RTD was modelled by the Large and Small Tanks in Series (LSTS) model, which allowed the characterization of the different mixing regimes for both liquid and solids in the regrinding mills. Effective mean residence times in the range 2-11 min were obtained with RTD shapes similar to those obtained in tumbling ball mills. It was found that residence times of liquid and fine particles were similar, which is consistent with results observed in other mixing systems, e.g. mechanical flotation cells. Also, the mean residence times estimated from the RTD allowed the mass balance adjustment to be validated from metallurgical sampling data. RTD estimations are useful for better understanding the Vertimill behaviour and to identify the actual breakage rates. Keywords: vertical mill, residence time distribution, particle size, modeling

Sep 1, 2012

By S. J. Neethling

"This paper examines the impact of several key variables on the performance of flotation cells. The study makes use of a simulator for the froth phase of the flotation vessel, as the main purpose of this study is to separate the impact of different variables from one another. In experiments it is very difficult to separate the effect of variables from one another as a change in a singe input parameter, such as air rate, invariably also affects many of the other key variables, such as bubble size and bubble bursting rates.In order to achieve this a base case simulation that is typical of many of the rougher cells found in sulphide flotation circuits was carried out. Four key variables, air rate, incoming bubble size, surface bubble size and the fraction of the bubbles flowing out of the cell unburst, were varied in order to obtain the system.s response.The most significant results were obtained when the bubble size was varied. An increase in the incoming bubble size has the effect of reducing the pulp zone recovery, but increases the froth zone recovery. If it were possible to vary the incoming bubble size without influencing the overflowing bubble size, the impact of the change would be unclear because of these two competing effects. The effect of a change in the overflowing bubble size has an opposite effect on the froth recovery, with larger bubbles resulting in lower froth recoveries.A final interesting result is that all the effects examined affect the process to a similar degree, which implies that none of these variables can be disregarded, either in industry or in further research."

Jan 1, 2003

By A. Vidyadhar

Printed circuit boards (PCBs) constitute a majorpart of electrical and electronic equipment containing valuable metals such as Cu, Ni, Au, Ag, Pd, Fe, Sn, Pb, etc. The concentration of base and precious metals in PCBs is observed to be several times more than those in their respective ores. Therefore, the recycling of PCBs is necessary to recover the valuable materials. However, the ultrafine particles pose a big challenge. Removal of them is suggested prior to processing by flotation. Froth flotation is observed to be a promising technique for rejecting the plastics from the comminution product. In the present work, enrichment of ground 1.0 mm PCB powder was investigated through flotation route by varying the operating variables such as frother dosage, pulp density, air flow rate and rotational speed of the impeller. The liberation studies indicate that excellent liberation of metal values is achieved from the non-metallic constituents at -1.0 mm size and below. The particulate system is quite rich in metal value with about 23% total metal content. The non-metallic constituents such as plastics are observed to possess strong hydrophobicity while the metal particles in the pulverized mass are hydrophilic in nature. Froth flotation kinetics is studied in depth with a view to facilitate high rejection of plastics and identify optimum operating conditions for the same. A number of experiments are performed to establish the influence of the operating variables on flotation performance. The conditions for achieving higher yield of the metal-rich fraction with respect to a specified grade are discussed in the light of the experimental results. It is found that the requirement of reagents is negligible which could be a very important factor from the commercial stand point. Single-stage flotation increases the metal content from 23% to over 32% with a mass yield of around 75% and over 90% recovery of metal values. 32% of the materials in the feed could be effectively rejected in the float fraction losing less than 4% metal values. The dependence of kinetics on the process variables is also discussed. It was concluded that a high rotor speed helps in efficiently rejecting the plastics. Frother should be added to help stabilize the froth and enhance the kinetics. A moderate air flow is required while pulp density must be kept low for efficient pre-concentration. It is established that the entire -1.0 mm comminution product could be treated by flotation for generating a pre-concentrate. Keywords: printed circuit boards, recycling, froth flotation, kinetics, recovery

Sep 1, 2012

By O. L. Kachor, A. V. Bogdanov

"In 2015 in the frames of federal special-purpose program «National system of chemical and biosafety of Russian Federation (2009-2014)» Federal State Budget Educational Institution of Higher Education ""Irkutsk National Research Technical University” (further–INRTU) performed works aimed at disposal of accumulated arsenical residues at industrial site of the former Angarsk arsenical plant (AAP) processing arsenious ores from Svirsk town in Irkutsk region. The plant in 1934-1949 produced arsenic trioxide for the defence industry. Prior to starting the works on disposal of industrial pollution focus the total amount of cinders stored on 13 ha of industrial site of AAP was 156 900 tons with 1% average arsenic content. Close to the cinders there were also remains of industrial buildings and process equipment in the amount of 6 600 m3 that contained 150 tons of arsenic. Additional source of pollution at the industrial site of AAP is contaminated soil amounted to 48 000 tons. Proven reserves of gold and silver in the cinders were 6.1 and 47 g/t respectively. In 2015 the source of arsenious pollution was detoxificated according to mineral matrix technology and stored in a special landfill with separate stocking of gold-containing cinder and other arsenious residues. This technology of waste disposal specifies extraction of valuable metals from cinder in future. The similar case is with Vershino-Darasunsky settlement in Trans-Baikal Territory where the abandoned industrial site of the former arsenic plant is located in the central part of the settlement. The concentration of arsenic and valuable components can be compared to the concentration at AAP. Since 2016 the demand for removal of such industrial pollution sources is legislated due to amendments in Federal Law No. 7-FZ on environmental protection. It results in a real possibility to remove such dangerous industrial residues deposits as the one located in Vershino-Darasunsky settlement. INTRODUCTION In the frames of federal special-purpose program «National system of chemical and biosafety of Russian Federation (2009-2014)» as well as the Irkutsk region program “Environment protection in Irkutsk region"" for 2006-2015, INRTU performed the works aiming at disposal of accumulated environmental deprivation–arsenical residues from the former Angarsk arsenic plant (further - AAP) (Figure 1) on processing of arsenopyrite ores of Svirsk town in Irkutsk regionThe plant produced arsenic trioxidein 1934-1949."

Jan 1, 2018

By Alexander V. Epiforov, Stanislav V. Balikov

This paper describes of processing tests of 8 flotation concentrates containing precious and base metals by pressure oxidation (POX) method. Concentrates 1 and 2 were gold-copper concentrates. Zinc and silver were by-products in these concentrates. These concentrates were processed by POX with following cyanidation of POX solid residues, copper solvent extraction and zinc carbonate precipitation. The recoveries of gold, copper, silver and zinc from these concentrate were 98, 99, 30 and 99%, respectively. Concentrates 3 and 4 were lead-zinc concentrates. Silver was by-product in concentrate 3. Gold, silver and copper were by-products in concentrate 4. Concentrate 3 was processed by POX with following reduction smelting of POX cakes for primary lead recovery and zinc carbonate precipitation from POX solution. The recoveries of lead and silver into ingot were 96 and 98%, respectively. The recovery of zinc was 99%. Concentrate 4 was processed by POX with following zinc carbonate precipitation and reduction smelting of POX cakes. Copper was precipitated from the POX solution using sodium sulphide prior zinc precipitation. The recovery of zinc into carbonate concentrate was 99%. The recoveries of lead, gold and silver into lead bullion were 95, 99 and 98% respectively. The recovery of copper into sulphide concentrate was 99%. Concentrate 5 was gold-pyrite concentrate, and concentrates 6-8 were double refractory gold-arsenopyrite concentrates. Silver was by-product in these concentrates. These concentrates processed by POX and CIL. The recovery of gold from concentrate 5 was 98%, and from concentrates 6-8 was 85-90. Low gold recovery from concentrates 6-8 was associated with preg-robbing factor. The recovery of silver from gold-sulphide concentrates did not exceed 10-20%. The low silver recovery was associated with argentojarosite formation that is resistant to cyanidation. The flowsheets for complex processing of precious and base metals sulphide flotation concentrates based on this test work results were proposed.

Jan 1, 2018