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By Jerry Danni

In order to remain viable today, corporations must view the environment as a strategic issue, and integrate environmental management throughout the organization. Corporate programs that used to be based primarily on regulatory compliance now must emphasize strategic environmental management systems, and must integrate these environmental systems with basic business functions. The mining industry today is global, and must have an organizational structure that can embrace different cultures, physical settings, and regulatory regimes. Sound environmental management practices are not different from good management principles. An effective environmental management system should be a complementary system to an organization?s overall management framework, integrated and aligned with the existing management structure. Integrating environmental management into core business functions is just good business. An effective environmental management system is a critical component of a company?s commitment to environmental, social and economic accountability. This paper presents the elements of the Kinross Gold Corporation strategic environmental management system and discusses the integration of the environmental management system into the core business functions throughout the Company

May 1, 2003

By Marcel Vallée

"This text consists of two parts, comments on "Classification and Reporting of Mineral Resources for High-Nugget Effect Gold Vein Deposits," by S.C. Dominy, P.R. Stephenson and A.E. Annels, Volume 10, No. 3, pp. 215-233, and related comments on some features of the JORC Code.This paper is, in many respects, a very elaborate and valuable account of the problems encountered in the estimation and classification of high-nugget gold deposits. However, in some key areas, it appears to fall short of its objective to help "resolve satisfactorily most issues" and "contribute to improved estimation and classification" (abstract). One must realize that high-nugget effect gold deposits constitute a very narrow field, despite the occasional bonanzas. This is a field of mostly smaller sized deposits, where limited success and a significantly higher rate of failure occur relative to larger deposits of mostly lower grade. This is shown by the six deposits described in the paper. Thanks for contributing to greater understanding of these complex and nevertheless challenging deposits."

Jan 1, 2002

By V. Ramachandran

The successful advent of solvent extraction (SX) reagents for copper recovery and improvements in electrowinning of copper to produce LME grade A copper cathode have paved the way for the hydrometallurgical treatment of copper oxide and low grade sulfide ores. This has resulted in about 25-30% of the world's copper being produced today by the Leach-SX-EW process. The obvious next step was to develop processes for the hydrometallurgical treatment of copper sulfide concentrates, as an alternative to a typical smelter-refinery complex. The current paper updates the processes that have been developed to date with emphasis on processes that are being commercialized or that are seriously under consideration for commercialization. Most of the discussions relate to the hydrometallurgy of chalcopyrite concentrates, which account for about 70% of the world's known copper reserves. In summary, in the last thirty years, the hydrometallurgical treatment of copper sulfide concentrates has attained full maturity and will be a serious option to contend with while evaluating any future new copper plant.

Jan 1, 2007

By Mary Jean Buchanan

The last twenty years have seen the advent of environmental concerns and sustainable development, and the industry has witnessed the rise of Environmental Management Systems and their registration through several international standardization systems such as EMAS and ISO 14001. Beyond EMS and ISO 14001, which new goal the mining industry should aim at. Life-cycle assessment (LCA), another tool from the Environmental Management System series, is also on the rise and currently the object of an international standard (ISO 14040:1997). Through LCA, it is possible to assess the environmental aspects and potential impacts associated with products and services, taking into account all the activities required for its fabrication, its use, its transportation and its disposal. How could LCA be applied to the mining industry ? Is the international market pressurizing on mining companies to supply an ?environmental ore?? What about the automobile industry and its use of LCA ? Will it influence the ferrous and non-ferrous metal industry, suppliers of raw materials ? This paper presents a review of possible applications of LCA for the mining industry as well as world trends.

May 1, 2001

By A. J. Harrison

"The introduction of an amendment to the Mines Regulation Act in the Province of British Columbia, passed in July 1974, and similar amendments since enacted by other provinces introduced the Canadian underground mining industry to the use of fire-resistant hydraulic fluids.Few, if any, of the hydraulic circuits in use in underground mining at that time were specifically designed for use with fire-resistant fluids, compared with the increasing number of such circuits conceived and in production today. The technology required in designing equipment for use with fire-resistant fluids may be likened to that associated with conventional mineral oils, but, in many respects, a variety of additional and / or alternative considerations must be taken into account. The fast-increasing use and development of fire-resistant fluids throughout all facets of industry, world wide, during the past 20 years has led to a whole new technology in system construction and component design, whereby acceptable performance can be achieved . However , the transition from conventional mineral hydraulic oils has not been without its problems, particularly when retro-fit of existing units was involved."

Jan 1, 1981

By R. C. Bryce

"Accident prevention has been an on-going priorty for five years. In 1987, adherence to the ILCI five-star rating loss control program was started, and a first star was awarded. Extensive training programs have been undertaken to establish standard procedures and upgrade employee skills. Due to its location, Selbaie owns and rents housing in the town of Joutel and contracts a busing service to and from the mine. Employees from other areas are lodged in dormitories and fed in the site dining room. Accounting and warehousing services are carried out in efficient fashion. Employee relations are structured to provide prompt resolution of complaints and differences. No lost time due to industrial relations differences has been encountered during the history of the mine.Safety and Loss ControlAll mines are concerned and occupied with a wide range of activities to ensure the safety of its employees. Selbaie is no exception. Programs to achieve success in safety and loss control have been implanted since the start of construction and development at Selbaie and have followed three interesting stages of evolution."

Jan 1, 1990

By Z. F. Lodhi, J. H. W. De Wit, H. A. Terry

Zinc and its alloys have been extensively used as replacements for Cadmium coatings in aeronautical and automobile industries. Zn alloys with low Co or Fe have been highly investigated but coatings with higher amount of Co are very difficult to achieve due to anomalism associated with these coatings. Anomalous Zn-Co-Fe alloy is a relatively recent addition to the family of Zn alloys. It is found that the addition of Fe in the electrolyte assist in overcoming the anomalism. In this research Zn-Co-Fe alloys especially with higher amount of Co (>15%) and Fe (~1%) are investigated, after overcoming the anomalism associated with its deposition, and the corrosion resistance is compared with pure Zn and Cd. It is found that an increase in Co to higher than 25 % accounts for a shift in the OCP to a level near Cd yet keeps it electronegative to steel. The coating shows superior corrosion resistance, in terms of its sacrificial and barrier properties in 3.5% NaC1 as compared to Zn and Cd.

Jan 1, 2006

By R. Wirth, B. Orberger, C. Wagner, A. Tudryn, B. Baptiste, S. Miska, Université Paris-Sud

Banded iron formations (BIFs) comprise complex textures and mineralogy, which result from fluid-rock interactions related to high and low temperature alteration. The initial iron oxy hydroxide mineralogy and associated phases such as carbonates, quartz, apatite and phyllosilicates were transformed leading to an upgrading of these BIFs into the world’s largest source of iron ore. In low-grade BIFs, a large part of the iron is related to micro- and nano- metric iron-bearing inclusions within micrometric quartz and/or carbonates (mainly dolomite). We studied laminated jaspilitic BIF samples from a drill core containing 26.71 wt.% total iron, 0.2 wt.% SiO2, 0.32 wt.% MnO, 15.46 wt.% MgO, 22.32 wt.% CaO, 0.09 wt.% P2O5, < 0.05 wt.% Al2O3, 0.15 wt.% H2O and 34.08 wt.% CO2 (Aguas Claras Mine, Quadrilatero Ferrifero, Brazil). Bright rose coloured dolomite and quartz bands alternate with massive specular hematite bands. Raman spectroscopy, X-ray diffraction and FIB-TEM analyses reveal that the micro- and nanometric inclusions in dolomite are mainly hematite and minor goethite, partly occurring as clusters in voids. Curie Balance analyses were carried out at different heating steps and temperatures on whole rock samples and a synthetic mix of decarbonated sample and pure dolomite. X-ray diffraction on the products of the heating experiments shows that that hematite is stable and new phases: magnesioferrite (MgFe2O4), lime (CaO), periclase (MgO), portlandite (Ca(OH)2) and srebrodoskite (Ca2Fe2O5) were formed between 680°C and 920°C. These finding gives hints to optimizing the beneficiation process, as the presence of hydroxyl ions bearing goethite micro- and nanoinclusions lowers the sintering temperature. Prior separation of coarse hematite and barren dolomite and quartz, followed by lower temperature sintering of the inclusionbearing dolomite/quartz leads to transformations into phases with higher magnetic susceptibilities (such as hematite and magnesioferrite). The entire Fe and Fe/Mg oxide feed (the priorly separated fraction added to the sintered fraction) can then pass through wet-high intensity magnetic separation after crushing.

Jan 1, 2016

By S. Shimaya, T. Maejima, M. Shimo

"The authors conducted the in-situ gas-tightness tests in a fractured rock at the Namikata underground LPG storage site in Ehime prefecture, Japan. The test consisted of two independent setups, a gas-tightness test that used boreholes, and a chamber-scale test that used a horizontal drift sealed with a concrete plug. In each test, the gas pressure was increased up to the onset of the measurable gas flow to obtain the maximum containment pressure. This paper discusses the hydraulic conditions for gas leakage initiation and the importance of the pore pressure measurement for monitoring the gas-tightness of the LPG storage cavern based on the test results.INTRODUCTIONJapanese first underground LPG storage plant was constructed by JOGMEC, the Japan Oil, Gas and Metals National Corporation, at Namikata in Ehime prefecture in granitic rocks (Kato et al., 2007). The “hydraulic sealing principle” (Åberg, 1977) that utilizes groundwater flow into an unlined cavern to prevent the leakage of gas through fractures in the surrounding rock mass was employed for storage of LPG. This paper describes the results of the in-situ tests performed at the Namikata Site to obtain information on fundamental gas-tightness characteristics of fractured rock. Two types of in-situ tests, a borehole gas-tightness test and a chamber gas-tightness test, were carried out near the storage caverns. Figure 1 shows the cavern layout of the Namikata underground storage plant and the test locations. The storage facilities consist of three caverns (W26m×H30m×L485m). The cavern crown lies at a depth of 150m below the sea level in Cretaceous granitic rock (Figure 1). Water curtain boreholes excavated from the water gallery tunnel at EL-125m level are located above and side of the caverns to prevent water drainage from fractures during the construction stage as well as during operation. The borehole tests were performed from a drilling adit excavated from the eastern end water gallery tunnel, while the chamber test was conducted at the southern edge of an exploratory drift extending from the central water gallery tunnel."

Jan 1, 2015

By Robert Maquil, Gilles Didier, Walter Steiner

"The 1580 m long dual-tube motorway tunnel Markusberg near Schengen, Luxembourg experiences strong swelling phenomena in each tube related to a 35 m wide diagonally crossing rock layer, some150 to 200m from the east portals. Overburden over the roadway is 26 to 30 meters. Tunnel construction started in 1998 and the tunnel was opened in 2003. The tunnel was driven downgrade from the West, the heave phenomenon started to occur as the tunnel approached completion. No indications of the presence of anhydrite and dissolved sulphates were known prior to tunnelling. Water samples had been taken from the beginning of construction and the concentration of anions and cat ions determined. Sulfate content was substantial, in one well it reached 22 mg/l, this high concentration requires the presence of other ions, in particular sodium and chlorine. Based on the knowledge at the time of construction heaving ground was removed from the tunnel invert and a free space was left below the roadway that is covered by a transversely spanned slab. In addition a series of posttensioned tiebacks were installed below the sidewalls. The void left in 2003 was 1.7m high and closed to less than 0.5 meters in 2007 then it became necessary to widen the free space. A central trench was dug with a height of about 2.5 meters and the benches were lowered.Level surveying had been carried out since 2002. In 2006 two extensometers were installed, one in the zone of strongest heave, the second at the edge of the swelling zone. The extensometer in the center of the swelling zone indicated heave with an essential constant rate with seasonal variations, the heave is concentrated in layer from 2 to 5 meters that heaved by nearly 300 millimeters within 5 years or 60 mm/year, which equals to approx. 1% extension per year. At the abutments heave rates of 20 mm/year where the support resistance is higher were observed. With data from other case histories a relation of heave rate with support resistance was established. Based on the numerous field observations hypotheses for the complex in-situ swelling processes, involving rock mechanics, mineralogical, soil mechanics and hydrogeological aspects were developed"

Jan 1, 2015

By V. S. Melamud, A. G. Bulaev

"Sulfide ore processing is characterized by significant losses of metals, for example, with flotation tailings. Therefore, flotation tailings can present an important source of metals. The treatment of flotation tailings is a technological issue due to low content of valuable metals (e.g. copper and zinc) and high iron content. The goal of the present work was to investigate extraction of base metals and gold from old flotation tailings containing 17% iron, 0.26% copper, 0.22% zinc, and 0.7 g/t gold. Chemical leaching in columns with 0.5 to 10% sulfuric acid solutions and bioleaching in air-lift percolators were used for the extraction of base metals. 1% H2SO4 provided high extraction of base metals and best selectivity. Recovery of copper and zinc reached 35% and 40%. Increasing H2SO4 concentration did not lead to significant increase in base metals extraction, but led to increased iron concentration in the pregnant solutions. The 1% H2SO4 leaching solid residues were used for further experiments. Acid leaching and bioleaching did not result in significant increase in base metals recovery. Leaching of the residue with 10% H2SO4 provided extraction of 4% copper and 20% zinc, and bioleaching for 100 days provided extraction of 16% copper and 12% zinc. The recovery of gold by cyanidation from the flotation tailings, the 1% H2SO4 leaching solid residue and residue of two-step acid leaching were 50, 49, and 65%, respectively. The results suggest that acid leaching can be effective approach for treatment of old flotation tailings.INTRODUCTIONAbout 80% of base metals (copper, nickel, zinc) are produced through pyrometallurgical treatment of sulfide ores. Mining and metallurgical treatments of sulfide ores are presently characterized by significant losses of non-ferrous and precious metals into the various wastes. For example, flotation of sulfidic ores yields formation sulfide flotation tailings. These wastes pose a problem not just because of their sheer volume, but some of them may affect local ecosystems. Nowadays, mining and metallurgical wastes can be considered as technogenical source of base metals."

Jan 1, 2016

By Heather Budney

Objectives 1. Evaluate the effectiveness of ON?s EA processes using criteria from the EA and policy sciences literature. 2. Recommend improvements to the EA processes and draw lessons from the ON case for the consideration of other jurisdictions. Evaluation Process 1. Chose criteria ? 14 primary criteria (Wood 2003) ? Subcriteria from Wood (2003) and Lasswell (1971) 2. Gathered information ? 6 key informant interviews ? Published literature, policies, legislation 3. Assessed criteria and formed Recommendations

May 1, 2008

By Denni Nikols, Farrukh Z. Khan

"Highvale Mine, located at Wabamun, Alberta, produces thermal coal for TransAIta&apos;s Keephills and Sundance generating plants. Overburden stripping in the mine is conducted by draglines which normally operate on top of the overburden bench. In certain areas oj the mine, however, these overburden benches are susceptible to slope failure. In these areas, due to safety considerations, the draglines are utilized in the less productive chop-cutting mode, supplemented by mobile equipment where the bench height exceeds the dragline chop-cutting limit. This paper proposes maintaining the draglines in their normal digging mode through areas of unstable or jailed overburden, by utilizing a dragline carried toe buttress 10 ensure adequate bench stability. The data requirements and methods of slope analysis to design a toe buttress across an unstable highwall area are examined in rigorous detail. INTRODUCTIONLocationHighvale Mine is owned by TransAlta Utilities Corporation and operated under contract. It is Canada&apos;s largest coal mine with an annual coal production in excess of II million tonnes. The mine is located approximately 80 km west of Edmonton on the south shore of Wabamum Lake (Fig. I) and production is currently provided by three pits 02. 03 and 04 (Fig. 2). The entire coal production is consumed at the nearby Sundance and Keephills power generating plants.ScopeThe mining operation at Highvale Mine has had occasional slope stability failures of its high wall overburden bench. This paper examines one such failure which occurred in the summer of 1983 at Pit 03. In addition to an investigation of the failure, Terracon was asked to recommend mine operation procedures which would minimize the impact of these slide zones on dragline productivity. A method of removing the failed material by utilizing the dragline in its normal digging mode is designed. The method&apos;s advantages and disadvantages as well as the required support procedures are reviewed."

Jan 1, 1989

By René G. del Villar, Jules Thibault, René del Villar

"Some key control variables of industrial processes, associated with product quality, often cannot be measured directly or frequently enough to establish adequate control. In such cases, it is possible to use available measurements to provide a prediction for these process variables and use them in a control strategy, thereby giving rise to what is now commonly called a softsensor.In some industrial grinding circuits, the on-line particle size analyzer is shared between various sampling points. Therefore, for a given location, the actual measurement is only available every 10 to 20 minutes, a delay which is unacceptable for automatic control purposes. To alleviate this problem, a softsensor based on an artificial neural network has been investigated. First, the structure of the neural network and different schemes for the training process are analyzed. Then, the performance of the neural network softsensor is compared with other inferential methods such as ARMA models and Kalman filters.IntroductionGRAHM, French acronym of the Research Group on Computer Applications in the Mineral Industry at Laval University, began in 1990 a research project on Knowledge Based Automatic Control (KBAC). This project, sponsored by a consortium of eight mining companies and the federal and provincial governments, seeked to screen advanced (knowledge-based) methods for data processing (filtering, mass balancing, etc) and automatic control (model-based) for their use in the mineral processing operations and the transfer of the project results to the sponsor companies.In parallel to more academic research work, a number of case-studies have been undertaken with the cooperation of partner companies. Among such works, a very successful one has been the design and installation of a new control strategy for one of the Kidd Creek (Falconbridge Ltd.) grinding circuits. This project was related to the evaluation of a number of control strategies and the implementation of one of them, as selected by the plant management, in the concentrator.A total of sixteen control schemes were evaluated on one of the dynamic phenomenological simulators developed at GRAHM, a trademark of this research group [ l]. The calibration of the simulator models was done based on industrial data gathered by GRAHM and Kidd Creek personnel. Then, the simulator was used to test the performance of various PID-based control schemes, designed to achieve the control objectives set by the Kidd Creek personnel. The best scheme proposed called for controlling the cyclone overflow particle size by manipulating the water addition rate to the cyclone feed box and the circulating load by manipulating the circuit ore feed. The particle size analyzer (PSI-200) available for monitoring the product size, was unfortunately shared (multiplexed) among various streams of the plant, which meant a 14 min delay between two consecutive readings for any particular stream. This induced the plant personnel to choose an alternative control strategy, one which controlled the cyclone feed density instead of the cyclone overflow particle size."

Jan 1, 1996

By Francis Dakubo, Courtney Young, Avimanyu Das

"Hydrometallurgy of copper ores typically involve acid leaching followed by solvent extraction and electrowinning (SX/EW). EW is the final purification stage in which a voltage is applied across two electrodes causing the copper ions to reduce and deposit on the cathode. Applied voltages are near 2 volts with current densities around 300 amps/m2. In this study, research was undertaken to decrease the energy consumed in the EW process. To do this, various cell designs were constructed and tested in which a membrane was used to separate the cathode and anode compartments with concentrated solution from SX serving as catholyte and raffinate from SX serving as anolyte. Therefore, copper in the concentrated solution would be deposited on the cathode while ferrous in the raffinate would be oxidized to ferric at the anode. Because it is assumed that ferric acid leaching is used, resulting ferric would be recycled to the leaching process. A positive side effect of the envisioned process would be the elimination of oxygen evolution at the anode and thus the prevention of acid-misting. After a cell design was selected, it was used to test a number of variables: flowrate, concentration, temperature, ion-exchange membrane, and applied voltage. Following experiments in which variable ranges were determined, statistical modeling was conducted using STATEASE software. Optimal results indicate the voltage can be decreased to 1.5-1.7 volts with current densities of 300-400 amps/m2. Significant reduction in the energy consumption was accomplished by reducing the applied voltage. Furthermore, current efficiencies and copper production rates was increased by application of the membrane.INTRODUCTIONLeaching of copper ores is achieved using mostly sulfuric acid. The copper pregnant solution is contacted with an organic solvent or resin adsorbent which picks up copper ions as in Equation 1:"

Jan 1, 2016

By R. Pakalnis, H. Miller, Madill. T.

"This paper describes a methodical approach to the estimation of the orientation and the magnitude of in-situ stresses. The study was performed at the Ruttan Mine, Sherritt Gordon Mines Ltd. , a 6,000 T.P.D. underground operation, located in northern Manitoba, Canada. It involves an initial estimate to be made based upon: structural interpretation • virgin stress measurements conducted in other areas (world wide, regional)The verification of the prevailing stress regime was made by conducting CSIRO hollow inclusion(1) overcoring measurements. The current cost for a virgin stress determination is about $7000 per measurement(2) and the difficulty encountered in attaining a good reading is high. This paper will describe the analytical procedures employed at Ruttan in evaluating the in-situ stress magnitude and orientation based on three overcore tests. It is proposed to perform an additional six measurements in order to verify the following results:Vertical stress = av (MPa) = 0.027 by depth (m)Major principal stress = o! """" 2.5 xav (340°/-20°)*Intermediate principal stress = a2 - 1.2xav (070°/0°)Minor principal stress = a3 """" o.8xov (160°/-70°)IntroductionThe Ruttan Mine of Sherritt Gordon Mines Ltd., a 6,000 T.P.D. underground operation, is located in northern Manitoba, Canada (Fig. I). The Ruttan copper-zinc orebody is a multi-lensed, steeply dipping (70 degrees) en-echelon deposit. Individual lenses have a maximum strike length of 350 m with widths varying from 7 m to 61 m. The mining method is o pen stoping with delayed backfilling and extends from surface to 860 m below surface."

Jan 1, 1985

By Leibniz University, D. Zapf

"The demand for gas storage operations with high withdrawal rates and operation modes different to a seasonal storage regime requires a more detailed rock mechanical consideration of thermal induced stresses in the vicinity of the caverns. This means that the change of gas temperatures during operation and the consequences of these temperature changes on the stressing of the salt rock mass must be taken into account in the rock mechanical dimensioning. Within the rock mechanical calculations a loading history, i.e. a pressure versus time dependency, has to be defined. As rock salt has a time dependent material behavior stress redistributions in the rock salt mass take place even under constant internal pressure conditions. Therefore not only withdrawal and filling periods but also the duration of phases with nearly constant internal pressure is significant for the resulting state variables. Within the paper the differences and consequences for the rock mechanical recommendations are discussed. As a result it can be concluded that recommendations with respect to minimum operation pressure as well as for maximum withdrawal rates can be answered only in connection with the respective time intervals."

Jan 1, 2015

By D. Hamilton

The electrode of a PEM fuel cell consists of two distinct sections - the catalyst layer and the porous transport layer (PTL). There are several kinds of PTL material, although all use carbon fibres as the solid fraction. The fibres can be matted to form a paper, woven into a cloth, or chopped to form a felt. Despite the different morphologies of the media, they are all anisotropic in structure, that is the majority of continuous fibres lie perpendicular to the direction of bulk transport. Currently, no models account for anisotropy and all transport coefficients are calculated as volume weighted averages or from empirical correlations (not developed for fibrous porous media). The present work presents a new methodology for determining anisotropic transport coefficients in fibrous porous media. A numerical experimentation process is employed wherein random samples of the PTL are generated and used to solve a diffusion transport equation. Effective transport coefficients are determined by integration of flux across the domain boundaries once a steady state solution has been reached. Multiple random samples at each porosity are generated in order to predict statistical variance. The results are correlated for ease of implementation in full PEM models.

Jan 1, 2005

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005