Search Documents

By T. R. Carter, A. C. Colvine

"Rocks of the Grenville Province in southeastern Ontario are currently largely dismissed by many geologists as having little or no potential for discovery of significant deposits of metallic minerals. The present study demonstrates that the area contains numerous deposit types which elsewhere are major metal producers. Therefore, there is significant unrealized potential, especially for gold, zinc, uranium, and possibly copper.The variety of deposits of metallic mineralization include stratiform zinc in marbles; stratabound base metal sulphides in volcanic and sedimentary hosts; gold-quartz veins; quartzmagnetite iron formation; copper-nickel and iron-titanium in intrusive rocks; magnetite skarns; molybdenum in skarns and pegmatites; uranium and thorium in pegmatites, veins, and calc-silicate gneisses; hematite veins; dolomite marbles (magnesium); and barite-jluorite-celestite-galena-calcite veins. There has been significant production of iron, lead, zinc, magnesium, gold, silver, and uranium.The vast majority of the metallic mineral deposits are confined to late Precambrian supracrustal and related intrusive rocks of the Grenville Supergroup. Many of the deposits are stratiform and/or stratabound and occur within units toward the top of major volcanic successions and in the lower portions of younger carbonate-clastic sedimentary successions.Processes responsible for mineral concentration in the area include: (I) syngenetic hydrothermal activity related to both volcanism and sedimentation; (2) epigenetic processes related to diagenesis, regional metamorphism, and igneous intrusive activity; (3) magmatic processes related to igneous intrusions; and (4) supergene concentration and enrichment. The genetic classification of the mineral deposits presented is based on observed geological relationships and these interpreted geneses. The deposit types have counterparts in volcanogenic and sedimentary exhalative, Mississippi Valley type, magmatic, contact metasomatic, and lode gold deposits. Many of the exploration criteria for deposits of these types may be applicable in the Grenville Province, despite the generally high metamorphic grades and complex deformation."

Jan 1, 1985

By S. Averill, B. Schreiner, V. Sopuck

The La Ronge. Kisseynew, Glennie Lake and Flin Flon domains. the main focu for gold exploration in the southeast part of the Saskatchewan Shield, were subject to continental glacial ice advances from the northeast during the Quaternary. Based on forty-four auger hole along with surficial mapping, the general Quaternary stratigraphy in this area is observed to be composed of a lower till unit , an overlying stratified unit of glaciofluvial sand and gravel and/or a glaciolacustrine silt-clay unit. an upper till. and an upper tratified unit. The lower till is commonly found throughout the geological domains except where it has been eroded in glaciofluvial or fluvial channels. Glacial Lake Agassiz fo rmerly covered most of these prospective domains. The lacustrine deposits associated with the lake impede surficial geochemical surveys including soil. lake sediment. and biogeochemical surveys. The approximate extent of clay cover can be predicted from beach elevations. For instance. in the Waddy Lake area. clay i not known to occur above about 1,400 feet (425 m) elevation. Exploration techniques are hampered by clay in at least one third of the volcanic belt. Thi s influence is indicated by the fact that nearly all gold prospect found to date are located above 1,400 feet (425 m) while the area of clay cover is vi rtually unexplored. The upper till i related to a minor ice readvance. This till is the medium often sampled during soil surveys in the area . lts value as a geochemical ampling medium is dependent on the extent of erosional contact with bedrock highs on the lower till. Those areas which are relatively free of lacustrine and fluvial deposits are those where surface geochemical methods work best. In the Waddy Lake volcanic belt approximately 25-50% of the area may be suitable for surficial surveys. The area of the Star Lake prospect occurs above the 1,500 foot (460 m) elevation and was not covered by Lake Agas iz. The effectivene of till sampling as a surface sampling medium was tested in those areas above the clay level. Till orientat ion surveys were carried out at the Star Lake property and the Tower Lake prospect (Waddy Lake area) within the La Ronge Domain . Gold grain counts and analy es of heavy mineral concent rate from 7 kg surface ti ll samples were used to delineate dispersion trains down-ice from mineralization. In addition, the clay fraction and a 30 g (-80 mesh) subsample from the same till sample, were analyzed for gold . In the Star Lake area, ice direction is subparallel to the strike of several narrow northeast trending auriferous structures. arrow dispersion trains down-ice from known

Jan 1, 1986

By S. Aram

Concrete reinforcing requires coordination among many roles: structural engineer, estimator, detailer, fabricator, installer and others. The methods used to define and represent concrete reinforcement elements and assemblies in building information models is crucial in determining the efficiency of sharing data among BIM platforms and the effectiveness of using the carried data in production planning, fabrication and site work activities. Starting from the information items that are required to be provided by BIM platforms, as defined in earlier work, we have developed the Industry Foundation Classes (IFC) bound Concepts and Model View Definitions (MVDs) for concrete reinforcement. Furthermore, in coordination with software developers, we propose guidelines for best practices for concrete reinforcement modeling. Implementing these guidelines by software providers will improve reinforcement modeling with regard to various aspects of reinforcement products like geometric representation, placement, and property specifications. The proposed approach is selected as a way to improve functionality of the shared data for production planning, fabrication, project management, and site activities. Guidelines for assigning information to rebar type and instance definitions as well as to rebar elements and assemblies are provided. An efficient method of sharing geometry and property sets among rebar instances of a rebar array is also defined.

Aug 1, 2013

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By W. E. Segsworth

Introduction By far the largest part of the money raised for mining is raised by honest and legitimate means; but a not inconsiderable amount is raised by fraudulent sales methods. It will be conceded without argument that the greatest menace to the mining business is the fraudulent promoter. The sale of worthless mining stocks to the public by high-pressure. salesmen, house to house canvassers, telephone campaigns, fraudulent use of the mails, fraudulent statements, and reloading, has seriously prejudiced the public against even legitimate mining. A very small percentage of the funds raised by such fraudulent means is ever spent on the property, but instead is absorbed by the promoter in illegitimate&apos; profits, enormous commissions, high office rents, and other expenditures, and is just so much subtracted from the fund which the legitimate developer needs to bring new mines to the point of production. The mining fraternity has been at fault in that, while they recognized this situation, they made no adequate attempt to rectify it. They knew that these fraudulent practises were conducted by parasites who attached themselves to the mining business in boom times and claimed to be part and parcel of it, but who were merely professional salesmen and promoters who, when there was not a mining boom, were selling sky-line real-estate, worthless oil stocks, or fraudulent securities which happened to be popular with the public. While mining people had this distinction well in mind, the public did not differentiate between the crooked promoter temporarily selling fraudulent mining stock and the honest promoter who made mining finance his life work; and we did little to make this distinction clear to the public or to sweep these money grabbers out of our house. The historic boom of 1927-8 and &apos;29 brought with it the usual crop of crooked mining promoters, and the scandals resulting from their operations forced the Governments into the enactment of laws to attempt to protect the gullible public against the operations of these meanest of thieves and to appease public clamour.

Jan 1, 1934

By M. Yao, D. Thibodeau

"Selective mining, such as post pillar cut and fill, is used in large, flat, irregularly shaped ore bodies where ground stability is to be maintained. This selective mining is used to open the stope to the full lateral extent of the ore body in order to minimize the dilution and maximise the recovery. For increased mining depth, design of the post pillar becomes more challenging since those pillars will eventually fail as mining progresses upwards. The post pillar should be designed such that failure does not occur at the early mining stage, such as at the first cut. After mining progresses upwards, the post pillars are expected to fail but be confined by backfill. In order to maximise ore recovery, both drift width and post pillar size must be designed adequately with a consideration of all geomechanic parameters. This paper will describe the process used to design post-pillar cut and fill for one of the ore bodies in Vale’s Copper Cliff Mine using a combination of both empirical deterministic and numerical modelling techniques. By utilizing both empirical deterministic and numerical modelling techniques drift width and post pillar size can be effectively designed. Current post pillar cut and fill design in the existing Vale operations are used to validate the design for Copper Cliff Mine. INTRODUCTIONCopper Cliff Mine is located within the Copper Cliff Offset in the limits of City of Greater Sudbury, Ontario, Canada, as shown in Figure 1. The Copper Cliff Offset extends about eight kilometres south from the Sudbury Igneous Complex into the footwall rocks. Until 2008, the current Copper Cliff Mine was operated as two separate mines i.e. North Mine and South Mine. However, as part of restructuring of Vale Ontario Operations, the North and South Mines were merged in 2009 to form the “Copper Cliff Mine”."

Jan 1, 2015

By S. Kariyawasam, R. McNealy

Pipelines are subject to multiple threats often requiring quantification of pipeline risk and engineering evaluation of in-line inspection and other data to effect discovery of conditions defined by the regulation. Public concern and pressure from regulatory bodies are accelerating the need for pipeline operators to formalize and intensify their approach to integrity management. Most operators need a phased approach to progressively adopt the most relevant and needed assessments. The organized and relevant assessment steps need to be introduced according to data available and maturity of the integrity management program. Each refinement to the quantification offers distinct advantages to the user. In this paper, the progressive integrity assessment solutions using quantitative methods are presented. Methodologies for engineering evaluation of integrity in-line inspection data for immediate and future integrity are summarized. Corrosion is used as an example, but the approach is applicable to any time-dependent defect based hazard. Strategies for pipeline integrity management are discussed.

Jan 1, 2005

By B. Konda, R. Lauer, D. Camilucci, D. Gladwin

"Income based taxes are significant cost elements to be considered in evaluating investment in new mine development. This paper presents the results of comparative analysis of effective income-based tax rates for mining in the Northwest Territories (NWT), selected Canadian provinces and international jurisdictions. The study was done as background to a review of royalty regulations for the NWT. ObjectiveThis paper presents results of comparative analysis of effective mining royalty1 rates, and combined effective mining royalty and income tax rates on selected mine models for the Northwest Territories (NWT), with those for several other jurisdictions in Canada and abroad which compete with the NWT for mining investment.BackgroundThe February 27, 1995 federal budget directed the Department of Indian Affairs and Northern Development (DIAND) to proceed with a comprehensive review and amendments to northern natural resource management legislation in order “to increase revenues and ensure a fair return to the Crown.” DIAND is responsible for the administration of the Territorial Lands Act, and its regulations.The Territorial Lands Act gives the Governor-in-Council the authority to “… make regulations for the leasing of mining rights in, under or on territorial lands and the payment of royalties therefor,…”. In the NWT, the Canada Mining Regulations (CMR) provide for the disposition of mineral rights for most minerals, other than coal, petroleum and related hydrocarbons, in return for the payment of a royalty to the Crown.As part of this review of the NWT mining royalty regime, several computer mine models were developed and tax regimes in a number of jurisdictions were analyzed. Effective mining royalty rates, and the combined effective mining royalty and income tax rates were compared across the jurisdictions. The results presented in this paper are a part of the background work done in preparing a discussion paper on proposed changes to the NWT mining royalty that is expected to be released for public consultation in the very near future."

Jan 1, 1997

By Thomas. L. O.

Apart from a few sketches and incomplete maps, mainly topographical, and one or two detailed maps of placer-creeks, there is little information on the topography and geology of most of the country adjacent to the sections of the Alaska Highway in the Liard River area, particularly that part east of Kechika river. In 1943, the Geological Survey of Canada made a recon-naissance from Fort Nelson clown the river of that name to the Liard, thence up the latter to Hell Gate, and also up Beaver river for a distance of fifty miles. The whole of the area covered was found to be underlain by sedimentary rocks, not a single igneous dyke being seen. The British Columbia Department of Mines began reconnaissances near the highway both in and north of the drainage basin of Prophet and Muskwa rivers with a view to finding structures favourable for the accumulation of oil. In Liard River valley near the mouth of Smith river and at intervals from there clown to Devil&apos; s Portage occur warm springs whose character and origin are not definitely&apos; known, since they have not been investigated (21, p. 38A). Similar springs are said to occur at several localities over a broad belt extending from Muskwa river across the Liard to the Nahanni River country (26, p. 11). On Liard river below the mouth of Dease river, stratified sands, gravels, and clays of Pleistocene (?) age are constantly met with and in one or two places are underlain by sandy clays. The distribution of the latter, however, is very limited in the section cut by the river west of the Rocky mountains. The only range of these mountains that reaches the Liard is the high limestone ridge which approaches the mouth of Vents river from the southeast and then almost vanishes a few miles to the northwest of it (27, pp. 43-45). In general, the ranges of the Rockies in the area under consideration have been but little explored, but they are undoubtedly very largely sedimentary and, with the exception of some volcanics and intrusives on their western flanks, are probably almost entirely so. Unlike the high, deeply incised ranges in southern British Columbia, they dwindle in elevation north of Terminus mountain to low-wooded ridges separated by wide swampy valleys, and practically lose their identity between it and the Liard. The foothills, which, along the Liard, have a width of 38 miles (from near the mouth of Trout river to Hell Gate) are composed of a great series of alternating shales and sandstones, with some limestones, all folded closely together, which resemble those found in the foothills farther south (27, pp. 50, 19-20).

Jan 1, 1944

By B. Yu, S. Kelebek, C. Gibson, M. Aghamirian

There are a number of high grade niobium deposits worldwide which have been deemed untreatable by flotation due to the very fine grained nature of the in situ pyrochlore, the primary niobium bearing mineral. A known method of recovering extremely fine particles is through the use of chelating reagents such as hydroxamic acids which have a strong affinity for transition metals. However, one of the major issues in the flotation of niobium bearing minerals using hydroxamic acids is the corresponding recovery of other transition metal gangue minerals including magnetite, hematite, and pyrite. In order to better understand the differences in behavior of niobium and iron bearing minerals in flotation with benzohydroxamic acid (BHA) and sodium hexametaphosphate (SHMP) at a range of pulp temperatures, a Box-Behnken experimental design was employed. Regression models for the global recovery of iron indicated that iron mineral recovery was significantly influenced by both BHA and SHMP dosage. Upon examinination of flotation products by semi-quantitative XRD, it was observed that recovery of iron oxide and sulphide minerals (hematite, magnetite, goethite, and pyrite) was problematic at high benzohydroxamic acid dosage, while sodium hexametaphosphate was mainly helpful for carbonate mineral depression. Iron rich carbonates (likely an iron rich dolomite) largely reported to the tails with increased SHMP dosage.

Jan 1, 2015

By C. O. Swanson

"OUR INTEREST in estimates of world reserves of lead and zinc is focussed mainly on the information they give about the sufficiency of metal supplies for the future. However, we soon realize that the estimates can be interpreted in several different ways. Accordingly, it is necessary to have some under-standing of the elements represented by a compilation of world re-serves, and we will start by examining the accuracy of the estimates and what they attempt to measure.Variations in Estimates of the ReservesIf we study the estimates of world reserves that have been published in recent years, we note immenediately that they vary over a considerable range. For example, an article by Shea in 1947 gave world reserves as about 36 million tons of lead and 60 million tons of zinc. Shea did not in elude the United States but I have added to his totals the estimates made by the Bureau of Mines for that country in arriving at the foregoing figures. For approximately the same date, the American Zinc Institute and the Lead Industries Association reported world reserves as about 50 million tons of lead and 77 million tons of zinc. A comparison of the two sets of figures shows a mean variation of 30 per cent. For individual countries the difference between estimates can be even larger. A few years ago the estimate of Canada's reserves made by the United States Bureau of Mines was 7.4 million tons of lead and 14.0 million tons of zinc, while the Gordon Commission reported 1 O. 7 million tons of lead and 26.0 mil-lion tons of zinc. In this case the mean variation was 55 per cent."

Jan 1, 1960

By K. Thuro, L. Wilfing, H. Kasling

"In mechanized tunneling, performance prediction is a crucial issue for estimating excavation costs and construction time of a tunnel project. The aim of this work is to compare the calculated parameters by penetration prediction models with the results of penetration tests during excavation by a Tunnel Boring Machine (TBM) at actual tunnel projects. This comparison helps to improve the existing prediction models (Gehring, 1995 and Rostami (Colorado School of Mines), 1997.) and to develop a new, so-called “Alpine Model” (research group ABROCK; Schneider et al., 2012).On-site penetration tests are a common tool to determine performance of a TBM in certain geological environments. During a test, the TBM is operated under defined conditions that allow comparing the results of different projects and machine types. There are two different types of penetration tests in use. The more common type, described by Bruland (1998a), is based on test drives at different thrust levels. The tests in this study are performed as start-stop-tests, meaning that the TBM starts from zero to the maximum possible thrust and reverse with slowly increasing respectively decreasing steps (Frenzel et al., 2012). To gain information about the interaction between TBM and rock mass, a detailed geological documentation including an analysis of the discontinuity pattern and laboratory testing for rock strength characterization are mandatory.Within the last year 16 penetration tests have been performed. The results are thrust- penetration curves (Figure 2) showing that up to a certain penetration rate only crushing occurs (subcritical penetration). From there the desired rock fragmentation process called chipping takes place (Frenzel et al., 2012). These two different fragmentation processes can be described best by a bilinear function as seen in Figure 3. Both, CSM- and Gehring-model, do not fit to the trend of the penetration rates determined during the excavation process as they are using potential or simple linear functions.Another parameter that has to be implemented into the new prediction model is the influence of discontinuities. In case of favorable orientation and spacing, discontinuities reduce the required thrust at same penetration rates. In contrast, unfavorable discontinuity systems can cause blocky faces and hence worse performance than predicted. Besides discontinuities, the toughness of rocks has to be taken into account when predicting the penetration as tough rocks need more energy to obtain complete failure than brittle rocks.Key advantage of these tests in comparison to existing are more data points in less time. By improving respectively extending the existing penetration prediction models with the stated parameters, the penetration prediction for TBMs can be more accurate and also wear calculation can benefit from this approach."

Jan 1, 2015

By A. E. Boone

"The paper presents critical areas in which improved coordination of effort by industry, government and sup-pliers will be essential to continue the growth record of the Canadian mining industry into the 'seventies'. The analysis includes: exploration, production, mining methods, research and development, markets, management and industrial relations. Performance objectives are suggested where tangible results can be measured. The author suggests the methods by which the 'seventies' can be the greatest decade in the history of Canadian mining. It is indicated that a national mineral policy is essential to the Canadian mineral industry."

Jan 1, 1970

By D. Larouche, M. Mardan

Hot tearing is a complex defect in aluminium castings which is produced during solidification when a certain amount of liquid phase remains and weakens tensile resistance of the alloy. In direct chill casting of aluminium alloys, hot tears initiate at the surface of sheet ingots just after the primary cooling zone, where the microstructure is particularly vulnerable. In order to study the hot tearing susceptibility of these alloys, and the effect of grain refiners on their thermo-mechanical behavior , tensile tests were carried out in the semi-solid state ( ~95% solid) and at low strain rates using an apparatus called DCSS, for Direct Chill Surface Simulator. This apparatus, originally developed at Alcan Arvida R&D Centre (ARDC), is an instrumented rig test reproducing the conditions prevailing during the primary cooling stage of the DC casting process. The mechanical behavior of solidifying shells and the hot tear formation under applied tensile loads were measured and the occurrence of hot tearing was observed. Temperature in different locations of the casting, applied load and surface strain were monitored during the tensile tests conducted on aluminum alloys AA5182, AA6111 and AA3104. The microstructure of the tested samples was examined using the optical microscope to evaluate their columnar or equiaxed aspect and their effect on the mechanical response of the alloy. A special emphasis has been given to the evaluation of fractions solid existing in the castings at the start of the tensile tests, taking into account the local temperature, thermal gradient and cooling rates experienced. It was found that excessive grain refiner additions decreased the strength of solidifying shells because of the increased level of porosity induced by easier nucleation of new phases (gas included). It was also observed that cooling rates increased with the level of grain refiner, a phenomenon that was associated to the higher number of contact points obtained with small equiaxed grains. Finally, the concept of a stress based criterion for hot tearing was reinforced by the strengths obtained on not grain refined AA5182 and AA6111 showing similar fraction solid near the surface, but significantly different grain sizes.

Jan 1, 2006

By A. Elsayed

Lightweight metals such as magnesium show potential in replacing aluminum alloy castings for engine cradles, cylinder heads and transmission cases. Unfortunately, magnesium alloys are susceptible to entrapping oxides and other impurities during casting that hinder strength and ductility. The current study examined various filter sizes and configurations with the aim of improving the mechanical properties of permanent mould cast AZ91E. The unfiltered casting had a yield strength, tensile strength and ductility of 93.3 MPa, 153.3 MPa and 2.2 % respectively and increased to 96.5 MPa, 167.0 MPa and 3.1 % with the use of a fine mesh filter within the well of the mould. The increased strength and ductility was likely due to the filtered castings containing fewer inclusions on their fracture surfaces as compared to the unfiltered castings.

Jan 1, 2011

By M. O. Pekguleryuz, D. S. Aydin

The high temperature oxidation and ignition resistance of Mg-(0-6) wt% Nd alloys have been investigated via isothermal and continuous heating experiments conducted in air atmosphere. Alloy composition is observed to be effective in low levels (~ 0.5 %) in the ignition temperature (Ti) of the alloys; the Ti of pure Mg increased from 630 °C to 770 °C with 0.5 wt% Nd addition. However, no noteworthy improvement was achieved with further additions up to 6 wt% Nd. The initial microstructure was observed to determine the oxide structure on the surface due to the differing oxidation behavior of the phases (a-Mg + Mg12Nd intermetallics). It has been found that the formation of a Nd-depleted region at the subsurface due to extensive Nd oxidation at the oxide/intermetallic interface lowers the protective ability of the oxide scale.

Jan 1, 2015

By Andrew Gillam

Outline of Presentation ? AMEC overview ? Benchmarked companies ? GRI 3.1 Guidelines ? Best practice examples ? Report content and boundary ? Strategy and profile ? Environmental ? Social GRI G3.1 ? Gold Standard for Reporting ? GRI ? Global Reporting Initiative ? 1997 outgrowth of Coalition for Environmentally Responsible Economies (CERES) and UN Development Program (UNDP) ? Official collaborating centre of UNDP and works in collaboration with UN Global Compact ? Coalition of companies, business organizations, accounting firms, CSR consulting firms and nogovernmental organizations (NGOs) ? Mission: develop and disseminate globally applicable Sustainability Reporting Guidelines ? Now de facto CSR reporting standard; appeal lies, in part, with supported flexibility in reporting approach and scope ? Latest generation G3.1 (March 2011); includes expanded guidance for reporting on human rights, local community impacts and gender

Aug 1, 2013

By S. Gößling-Reisemann

Most copper ores contain valuable co-products such as molybdenum, gold, silver, nickel, etc. Sulphuric acid and steam are valuable by-products, which are generated dur¬ing copper production. The environmental impacts from mining and refining therefore need to be shared between these by-products and co-products, an issue in Life Cycle As¬sessment (LCA) referred to as allocation. There are different, recognised methodologies for doing so: burdens can be allocated based on the market values of these commodities, they can be allocated by mass, volume, molar amount, functionality, or other physical, technical or economic factors. All of these methodologies have their respective merits and restrictions, and the choice is usually case specific. Nevertheless, the choice between alternative methodologies can have dramatic effects on the LCA results. Recycling in LCA has to be handled in a similar way, as it essentially constitutes a special case of co¬production. The existing standards (ISO 14040 ff.) allow different methods for imple¬menting recycling and allocation into metal LCAs (open loop, closed loop, value cor-rected substitution, etc.), which are still a subject of discussion in the scientific community. However, the methodology used can significantly influence the ecological profile of copper and copper products. We will present an overview of the different methodologies available for including recycling and allocation and give an analysis of how the meth¬odological choice affects the final LCA results. This work will be followed up by quantitative case studies.

Jan 1, 2007

By J. C. Gathje

Newmont acquired the Phoenix Project through the acquisition of Battle Mountain Gold in 2000. Shortly after the acquisition, Newmont Metallurgical Services (NMS) and Nevada Operations began development work on a process to Pressure Oxidize (PDX) precious metal rich copper concentrates from Phoenix using the Lone Tree PDX facilities at Valmy, Nevada. The high precious metals content of the Phoenix concentrate - Au up to -300 g/t and especially Ag, up to -1700 g/t - led Newmont to the development of a High Temperature PDX process that achieves high cyanide leach recovery of Au and Ag, from the PDX solids, without the requirement for a messy and expensive "lime boil" or sulphate destruction process. Base metals content in Phoenix concentrates range from: 15-25 % for Cu, 1-10 % for Zn and 0-2 % for Pb. Excellent solution extraction of Cu and Zn is achieved while Pb is precipitated in the PDX residue. In addition to achieving high Au and Ag recovery this process produces very clean PDX discharge liquors that require minimum effort to remove contaminant metals and PDX solids that have superior settling and filtration characteristics. All of these factors contribute to lower capital and operating costs for the overall process. This paper describes the laboratory and PDX pilot plant developments for this process.

Jan 1, 2004

By W. R. Tyson

IT HAS BEEN KNOWN for many years that alloy steels can become brittle when tempered in the range of 350-600°C, or cooled slowly after heating to higher temperatures. The metallurgical literature reveals that blacksmiths were aware as early as 1883 that water quenching was necessary after heat treatment above 600°C to avoid brittleness. It has also been known for years that the problem is associated with trace impurities; a paper in the Journal of the Iron and Steel Institute of 1894 refers to the brittle, faceted fractures that occur in steels containing arsenic, phosphorus or sulphur. However, definitive investigation of the mechanism of embrittlement has been possible only within the last decade with the introduction of new experimental techniques to investigate surfaces, especially Auger electron spectroscopy. It is now possible to study in detail the chemistry of surfaces with a resolution of an atomic layer or two, and enormous progress has been made recently in studying the segregation of impurities to grain boundaries by exposing the boundaries by fracture inside the microscope. A clear picture of the processes occurring and their interpretation is now emerging, as was particularly clear at the recent 1977 ASM Materials Science Seminar on Interfacial Segregation held in Chicago in October. Recent research in this area has pointed the way for commercial exploitation of this new knowledge and experimental technology. It is the purpose of this article to trace progress in understanding temper embrittlement and to indicate other areas where control of interfacial segregation and its effects can be important in metallurgical applications.

Jan 1, 1978