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By Mark C. L. Patterson

Hydrothermal brines are extracted from significant depths below the surface of the earth and arrive at the surface at elevated pressure and temperature. The exact chemistry and conditions of these brines depends upon the rock formations through which the water travels, but many of the brines are rich in dissolved minerals especially silica which is often saturated in the brine. At pressure and temperature the minerals remain in solution but in order to extract heat from the brines, they need to be cooled and during which many of the minerals precipitate causing problems. Where precipitation is a problem in the downstream processing, the brines are maintained at a high enough temperature and pressure so as to avoid precipitation and injected back into the geothermal formation. This results in a significant loss in potential energy that could be recovered from the geothermal brines. If left to precipitate in an uncontrolled manner, many of the minerals will precipitate as gels, in a high surface area form which is difficult to extract from the liquor and which can causes problems. Precipitation in this manner often builds up on the inside of pipes, reducing the pipe cross-section available for fluid flow and reducing the overall efficiency of the plant. If the brines are seeded at the appropriate time or the precipitation conditions are changed, mineral particles can be grown and separated more easily from the brine. During this precipitation and growth phase the chemistry of the local environment can also be altered to grow more valuable particulates. Some of the specific chemistries will be discussed with reference to known geothermal brines and what needs to be done to precipitate value added products. A theoretical approach to the complete extraction of minerals from geothermal brines is also discussed with the goal of extracting more heat from the brine prior to reinjection into the well.

Jan 1, 2006

By D Craw, J Pope, B Peake

Southland contains over 70 per cent of New ZealandÆs recoverable coal resources, and an investigation into the potential effects of coal mining on SouthlandÆs water resources is therefore of interest. This paper investigates pit-lake water quality in relation to current mining activities within the sub-bituminous coal and lignite deposits of Southland.   Water quality data was collected from pit-lakes in sub-bituminous and lignite deposits from October 2005 to March 2006. After periods of settled weather, turbidity increased with depth at the sub-bituminous pit-lake (10 - 21 NTUs from 5 - 30 m). In the stratified sub-bituminous pit-lake in March 2006, heavy rainfall caused higher turbidity in the epilimnion than the top of the hypolimnion (20 NTU vs 13 NTU) reflecting surface water runoff (up to 1993 NTUs) and epilimnion mixing. In contrast, turbidity at the lignite sites was variable due to the shallowness of the lakes, but noticeable increases following disturbance and adverse weather were recorded. High turbidity at the sub-bituminous deposits was attributed to the presence of clay minerals such as kaolinite whereas turbidity at the lignite sites was more likely short term and a result of heavier minerals such as quartz.   Trace element concentrations at both sites were low when compared to mine waters in other coal areas in New Zealand and no samples exceeded ANZECC water quality trigger values for 80 per cent species protection. Pit-lake water pH levels were lower and more variable in the lignite deposit (4.18 - 7.30 vs 7.24 - 8.98 in the sub-bituminous deposits). In the lignite pit-lakes, higher concentrations of trace elements (eg Dissolved As - 0.034 ppm and Dissolved Mn - 1.09 ppm) and lower pH (ÿ4) were observed at the bottom of active pits compared to inactive pits. It is possible that quartz pebble conglomerates containing sulphide minerals within the lignite seams are responsible for this.   Further investigation into the mine waters, waste rock and lake sediments will help get a better understanding of the results observed and long term processes that occur.

Jan 1, 2006

By M. T. Davisson

Pile compression load capacity prediction methods are divided into four categories for purposes of discussing their reliability compared to static load test results. The categories considered are: 1) static analysis, 2) driving formulas, 3) wave equation analysis, and 4) dynamic measurement and analysis. It is concluded that any method of static analysis that works for the geological deposit in question may be satisfactory. However, any given method can be quite wrong when applied to other deposits of soil that are different in terms of their engineering and geological characteristics. Dynamic formulas are found to be theoretically unjustifiable. The ready availability of the wave equation analysis for microcomputers eliminates the need to utilize dynamic formulas. The wave equation analysis is found to be the best analytical method for making predictions both for design and for construction control. Dynamic methods of measurement and analysis are found useful, but have limitations that have caused troubles on many projects. Two case histories are presented that show the limitations of dynamic measurement and analysis, and of the wave equation analysis. Soil deposits exist that defeat both the wave equation and dynamic measurement techniques; static load tests are currently the only method of proving the load capacity of piles in such soils.

Jan 1, 1991

Errors in ore reserve estimation can occur during drilling and sampling, sample preparation and analysis, geological logging and modelling, database construction, statistical or geostatistical evaluation, selection of economic parameters, selection of ore reserve method and assessment of mining constraints. Core sample recovery can be a major source of error, and it is proposed that the modelling of grade, metal accumulation and thickness should be accompanied by the modelling of core recovery (or core loss) so that for each ore block a weighted block recovery factor is obtained. This gives a good indicator of the reliability of a reserve estimate. It is suggested that a resource reliability rating (RRR) system be established to quantify what is meant by geological assurance and to combine this with an estimate of the precision of estimation as gained by geostatistical analysis. Proven and probable minable reserves would be those with an RRR better than 50% and a precision of estimation better than 20%

Dec 1, 1996

By D. Boshoff

The ability of an explosive to break rock is influenced considerably by the extent of confinement in the blasthole. It is believed that confinement is improved by the use of adequate stemming. The aim of this paper is to present the results of the first and second stages of developing a stemming performance testing rig for small diameter boreholes. The rig was used to compare and contrast the performance of different designs of products. The results showed that different stemming products have differences in terms of their functionality, which can have a major impact on the efficiency of rock breaking. Two test procedures were used, one through the exclusive use of compressed air and the second using a purpose-built high pressure test rig with small quantities of explosives. Both tests were used to identify and evaluate the ability of various stemming products to resist the escape of explosive gas through the collar of a blasthole. An investigation was done to determine the types of stemming products most commonly used in South African underground hard rock mines, and these products were used during the tests. The first stage of tests using compressed air only did not prove adequate to predict with certainty the pressure behaviour in the borehole of a particular product under high pressure conditions. The purpose-built high pressure test rig also did not prove to be a very effective tool to test stemming products under high pressure conditions. The test rig incorporated only the effect of gas pressure on the stemming product, and excluded the effect of the shock wave. This study therefore proved that to take into account only the gas pressure generated in the blasthole is not sufficient to effectively test stemming product performance.

Jan 1, 2011

By E. Snyders

The upgrading process of an inferior grade of zircon to a superior opacifier for ceramic applications was investigated. A calcining process in the presence of mineralizers was used to produce the product in a conventional muffle furnace. A pre-milled inferior grade zircon concentrate, with a relatively high iron and alumina content generally not suitable for high quality ceramic applications, was used in this study. The influence of the upgrading process on the opacifying properties of the zircon material was compared to that of commercially available prime grade zircon opacifier products currently being produced in South Africa. The influence of a calcining step in the presence of mineralizers with regard to the milling characteristics of the treated zircon material was also evaluated in this study. The morphology of the treated and untreated zircon opacifier samples were investigated by SEM micrographs and the colours of zircon samples were characterized on the grounds of the Commission Internationale de l`Eclairage (CIE) standard procedure (CIE L* a* b* measurements) after application on a bisque ceramic tile. It was found that the treatment improved both the milling as well as the opacifying properties of the treated inferior grade zircon concentrate and renders it equivalent to or better than prime grade zircon opacacifiers currently produced. Keywords: ZrSiO4; opacifier; colour; milling; calcining.

Jan 1, 2005

By B. R. Reddy, Y. V. Swamy, B. V. R. Murthy, H. S. Ray

The Ni oxide was reduced with a CO-CO2-N2 gas mixture and the effects were observed of process variables such as roasting temperature, time and CO partial pressure. Extraction of over 90% of Ni was achieved by ammoniacal leaching of ore that had been reduced for 1 h at 760 degrees C under a gas mixture with a volumetric CO/(CO+CO2) ratio of 0.57. The kinetic data were found to conform to the Ginstling-Brounstein equation. The applicability of this model was confirmed by evaluating the apparent activation energy with the use of independently constructed differential and integral plots, which showed an excellent match

Dec 1, 1995

By E. Eccleston

The ConRoast process for the production of platinum group metals involves the use of a fluidized bed reactor for the removal of sulphur from ore concentrates by roasting prior to smelting in a DC-arc furnace. Test work was carried out in 2007 at Hazen Research in Golden, Colorado to provide the data necessary for a commercial roaster to be designed by Technip. This paper discusses the rationale behind the test work, the goals for calcine composition to be used as smelting furnace feed, the results of various roaster operating parameters in terms of calcine composition (particularly residual sulphur and the fate of trace elements), and the impact of the results in terms of a commercial roaster design.

Jan 1, 2009

By P. H. Morris

Nineteen field trials of the co-disposal of fine coal tailings and coarse coal wastes were conducted at the dual Goonyella-Riverside mine in Queensland and at the Hunter Valley No. 1 and Warkworth mines in New South Wales, Australia. The profiles of and the sorting that occurred on the co-disposal deltas are described and an existing theory of subaerial deposition, originally developed for mine tailings alone, is shown to apply to the co-disposed wastes. This enables the dimensionless profiles of large deltas, which may take years to deposit, to be predicted from data obtained from a small delta formed in a few days or even hours

Jun 19, 1905

Assessment of the Consistency Between Different Laboratory Froth Stability Measurements

Sep 13, 2010

The Khanong supergene-enriched copper resource, (~23 Mt at 3.0 per cent Cu), is one of several resources recently discovered in the intrusive-centred, sediment-hosted Au-Cu Sepon mineral field located in southern Lao PDR. The unusual style of hypogene mineralisation and unique set of conditions have resulted in the development and preservation of a supergene-enriched profile in this subtropical climate. Hypogene sulphide-rich mineralisation replaced calcareous cataclastite (fault rock) developed in the flat-lying, extensional, Khanong Fault. Spatially, the hypogene mineralisation was immediately out board of the skarn û hornfels Cu-Bi front and in board of sediment hosted Au-(As-Sb) mineralisation in a zoned intrusive-centred hydrothermal system. In situ supergene enrichment of the sulphide protore has resulted in a high-grade chalcocite-clay zone (~10.3 Mt at 4.6 per cent Cu) overlain by leached limonite-clay. A very high-grade in situ to exotic limonite-clay Cu-oxide-mineral zone is locally developed above impermeable dolomite at the base of chalcocite-clay zone. Exotic Cu-Mn-wad mineralisation developed for up to 1 km down the hydraulic gradient from the chalcocite-clay zone. Unique supergene enrichment conditions have resulted in the high-grade Khanong Cu resource in a subtropical weathering environment. The base of the currently active supergene profile coincides with the base of a flat-lying, pyrite-rich fault rock, dipping parallel to the hill slope, maximising Cu enrichment. Meteoric water has been channelled along subvertical faults and narrow horizontal subsurface zones. Low permeability of the fault host rock and footwall rocks has controlled the low volume and slow movement of groundwater required for supergene enrichment. Erosion has been slowed by the resistive ironstone and limonite-clay layer at surface, which assists in preserving the gentle slope over the chalcocite-clay zone.

Jan 1, 1999

By W. I. Nissen

This Bureau of Mines report presents the design for a commercial-sized flue gas desulfurization (FGD) demonstration plant that uses the citrate process. The goal of the Bureau's citrate process is to minimize the undesirable environmental impacts of industrial plants emitting SO2-bearing gas. The FGD plant is located at the George F. Weaton powerplant, Monaca, Pa. Construction was completed in April 1979 and will be followed by preliminary testing and a 1-year testing and evaluation program. Design capacity of the FGD plant is 156,000 scfm of 0.2-volume-percent-SO2 flue gas yielding about 16 tons of sulfur per day. The plant is intended to (1) clean fly ash, SO2, and Cl- from the gas while cooling the gas in a venturi scrubber, (2) absorb SO2 from the gas using 1,200 gpm of a countercurrent-flowing citric acid-sodium citrate-sodium thiosulfate solution, (3) react the absorbed SO2 in two 13,000-gal stirred closed vessels with added H2S, thus precipitating elemental sulfur and regenerating the citrate solution for recycle, and (4) recover the sulfur from the slurry by air flotation, followed by melting in a heat exchanger and separation from the occluded citrate solution in a sulfur decanter at 35 psi and 135° C.

Jan 1, 1979

The Greymouth Coal field is situated on the West Coast of New Zealand's South Island and has been mined for coal for more than 120 years. The area covered in this paper is within the Rapahoe Sector of this field and contains >200 million tonnes of low ash, low sulphur, bituminous rank coal. Paper No 6, presented to the 19th Annual Conference of the New Zealand Branch of The Australasian Institute of Mining and Metallurgy in Christchurch in August 1985 by R G Bowman, explained 'A Geologist's View' of the 'Economic Potential of the Greymouth Coalfield', and describes previous geological assessments of the Rapahoe Sector.

Jan 1, 1989

By Robert Bittner

The following is a report on the development of two unique and separate cofferdam systems used in the construction of the marine foundations for the I-205 Columbia River Bridge at Portland, Oregon for the Oregon Department of Transportation. The first of these two systems utilized interlocking H-pile 100 ft long to form a cofferdam 145 ft by 58 ft in plan and 100 ft deep. The second system consisted of two immense bell shaped steel forms. The larger of the two forms was 83 ft by 66 ft in plan, 62 ft high and weighed 450 tons. This form was externally stiffened for a designed hydrostatic head of 54 ft. Both forms were designed, except for the top 14 ft, to be set and stripped in one solidly welded unit. The supporting geological formation for the bridge foundations is the Troutdale, a cemented sand and gravel. This formation is at the ground surface on the Washington Shore and slopes downward to a depth of 115 ft below normal high water at about mid-channel. In this area the Troutdale formation is covered with a layer of fine to medium sand 90 to 100 ft thick. It was the variable depth of the Troutdale which determined the two types of foundations and the corresponding to the two cofferdam systems.

Jan 1, 2013

By R. Emmett Hughlett

The Bureau of Mines has developed a statistical approach to the laboratory evaluation of response bias and precision in gas detectors. The techniques described employ a computerized analysis and a new method of data presentation called composite graphing. The underlying theory, its practical application to the data, and the experimental equipment and procedure are described.

Jan 1, 1982

By Lon D. Santis

This paper summarizes explosives transportation incident and accident data collected by the U.S. Department of Transportation (DOT) from 1993 to 1998. The paper briefly describes the legislation and regulations that cover hazardous materials transportation. The multimodal incident data collected by the Research and Special Programs Administration (RSPA) contained 86 incidents involving Class 1 materials during transit. Thirty-two occurred on public highways. The Federal Highway Administration (FHWA) data showed there were 8 1 motor-vehicle accidents involving explosives. The FHWA Crash datafile extract contained 649 records categorized as involving Class 1 materials although closer analysis revealed that nearly 90% of these did not involve explosives. In both databases, there were no fatalities caused by the explosive materials although 7 fatalities were the result of injuries suffered during the motorvehicle accident. There were also no serious explosions during any of these incidents or accidents. The paper concludes with an analysis of the risk involved with transportation of commercial Class 1 materials on the highway.

Jan 1, 2000

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By Nobel Insurance Service

[Executive Director’s note: ISEE is committed to continuing its efforts to ensure that blasters be made aware of the issue of migration of carbon monoxide resulting from blasting operations. In the July/August 2001 issue of the J o u rnal we printed excerpts from “Carbon Monoxide - The Silent Hazard,” an article from the Safety Update, published by Nobel Insurance Services. We also re minded readers of the text from the 17th edition of the ISEE Blasters Handbook in its section on trench blasting as follows: “...consideration must be given to the proper venting of gases generated from the blasting. Should those gases spread laterally rather than vent directly to the surface, the gases may travel underg round and finally vent well outside of the planned area. Such events may be caused by the strata, soil conditions or root systems, or existing and/or abandoned utilities or other man-made structures. In the worst situation, gases resulting from the detonation such as CO2, CO, and/or N Ox may travel through the strata and find their way into basements of nearby homes or businesses.” While incidents are rare, a number of cases in re c e n t years have resulted from outdoor blasting operations p roducing carbon monoxide gas that has migrated t h rough the earth and accumulated in nearby enclosed spaces. T h e re are steps that a blaster can take to be proactive in preventing incidents. These steps and studies of the occurrence have been expertly presented in several papers presented at ISEE conferences and included in the ISEE Conference Proceedings, available th rough the Blasters Library. In addition, Material Safety Data Sheets provided with explosives used in surf a c e blasting should provide additional information on gases p roduced by detonation. Below, we have reprinted the IME white paper, entitled “Fumes from Blasting Operations.” The paper underscores the unique set of circumstances that combine to contribute to high concentrations of CO measurements in underground, enclosed spaces following the detonation of explosive materials and provides recommendations to blasters

Jan 1, 2004

By P. D. R. Maltby

"1. INTRODUCTIONMy talk today will discuss a new development in the thickening of slurries and clarification of waste water - the Enviro-Clear thickener. Several industrial installations of the thickener have been made in North America in the following applications:1.,water clarification in sugar beet processing plants.2.,separation of pregnant liquors from solid wastes following acid leaching in uranium mills3.,clarification of waste water from coal treatment plants as described in a paper in the June 1975 transactions of the SME entitled ""Application and Utilization of the Enviro Clear Thickener in a U.S. Steel Coal Preparation Plant"" by A.A. Terchnik, D.T. King and J.S. Anderson.2. HISTORYThe application of the Enviro-Clear thickener can be traced back to the filing of U.S. Patent 3523889 in 1970 by the inventor F. Eis. The claims of this patent are shown in Slide 1.The new concept was developed for sugar beet processing by the Spreckels Division of Amstar Corporation, and several such thickeners have subsequently been installed in various sugar beet plants. The Enviro-Clear Co. or New York took over the world-wide manufacturing and marketing of the thickener. Experience in the sugar beet industry indicated that the Enviro-Clear thickener volume requirements could be reduced to as low as one tenth that of a conventional type thickener. Various coal samples were supplied by U.S. Steel Research Laboratories for testing. The tests indicated that feed rate loadings of 3 gpm/ft.2 could be obtained by the Enviro-Clear thickener. Such results led to several industrial applications in the coal industry. Subsequently other branches of the mineral processing industry have come to learn of the possibilities of using this thickener. Slide 2 shows a list of commercial Enviro-Clear installations at the end of 1975."

Jan 1, 1976

By E. J. Babcock, W. W. Odell

The Bureau of Mines since its establishment has always taken an active interest in the utilization of lignite and in the development of the lignite dep'osits of the United States. Extensive lignite fields occur in the west central States, notably in North Dakota, Montana, Wyoming, Colorado, and Texas; there are smaller areas in several other States, some of which are widely separated. The total area of the deposits and the total amount of lignite in these several districts are so enormous that the economic value is seldom recognized. To the people of ·the west and west central regions, however, the larger utilization of lignite, in whatever form it may be, is of fundamental importance, and any new methods or uses that promise to open these great lignite fields for more general and more efficient use deserve careful study. Although these lignite deposits underlie areas of thousands of square miles, their development and general utilization has been rather slow. This is no doubt partly because many of the districts are not thickly settled or highly developed in manufacturing industries, but is largely because lignites, from their peculiar physical and chemical characteristics, are low-grade fuels. Most of the lignites in these areas are imperfectly developed coals; many have a more or less woody structure; some belong to the brown-coal type; and others are darker, denser, and more homogeneous, approaching subbituminous coal. The people living in the regions in which these vast deposits occur, especially in the west central part of the United States, are vitally interested in every effort toward bettering lignite as fuel and aiding its wider utilization.

Jan 1, 1923