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By Benedetto Corain

The production and dispersion of metal nanoclusters onto inorganic supports and amorphous carbon rest on well consolidated technologies belonging to the realm of industrial catalysis and of basic catalysis research (1). In spite of the existence of a variety of specific synthetic strategies, their very rationale relies on three main approaches i. e.: A: precursors of both the metal nanoparticles and of the relevant supports (or the support itself) are intimately mixed (even let to react) at ambient conditions and then thermo-reduced according to very controlled protocols (2); B: precursors of metal nanoclusters are let to be adsorbed onto suitable supports from the gas or liquid phase and subsequently thermally decomposed (3); C: metastable size-controlled metal nanoclusters are previously generated in a liquid medium and subsequently transferred onto pre-formed support particles (4). The production and dispersion of metal nanoclusters onto organic soluble supports is also a rather well documented academic praxis (5, 6, 7, 8) able to provide e.g. size-controlled Au0 nanoclusters of 4.4±1.7 nm (5). Our group started in 1997 developing (9) an innovative approach to the synthesis of metal nanoclusters dispersed inside insoluble, albeit accessible (see below) mechanically robust gel-type resins (10), which procedure was tested so far on palladium metal. Metal ions are previously dispersed upon ion-exchange inside of the polymer framework, followed by chemical reduction and by the aggregation of born metal atoms into nanoclusters, the size of which is templated (11, 12) by the three-dimensional intercommunicating meshes that build up the overall polymer framework (Figure 1).

Oct 1, 2003

By W. J. Kingwell

My comments and questions are addressed to Mr. Troughton. It seems to me that the tests were very well tailored to determine long term effects on performance of bearing piles as groundwater pressures rise in the London Basin. This rise is being simulated by means of a groundwater recharge system but it would be informative to have further details of the controls of conditions simulated. Ideally the porewater pressure in Standpipes 1, 2 and 3 should be the same throughout the test. Under test conditions are there not practical dif­ficulties? Recharge Well C2 is a lesser dis­tance from the pile than the other wells. Was the rate of recharge to C2 regulated to a lesser rate than the other three? In my experience the rate of acceptance usually varies from well to well. Under a common feed pressure were mea­sures taken to compensate for this? Since the problem does not only affect London, but also Liverpool, Nottingham, Birmingham and to a lesser extent, Manchester, I question whether an ideal procedure is being used. It is well known that rates of acceptance decrease with time and often recharge wells need to be flushed out at regular intervals. Other pro­cedures may need to be adopted to accurately simulate the effect of groundwater rise, if tests of longer duration are to be considered.

Jan 1, 1991

The Round Hill gold-scheelite deposit is located three kilometres from Macraes Flat and approximately 60 kilometres due north of Dunedin, New Zealand. A mining feasibility study is currently being undertaken on the deposit by BHP Minerals (New Zealand) Limited, who are the managers and operators of a Joint Venture with Home Reef Mining Limited. BHP has a 70 per cent equity in the project area.

Jan 1, 1987

By E. Özberk

Uranium minerals are often associated with iron minerals, and during the hydrometallurgical processing of the uranium ores, iron plays several significant roles. The presence of Fe(III) in solution promotes the oxidative acid leaching for the recovery of uranium. The control of the distribution of impurities in milling and refining is also affected by dissolved iron. When rejected from the process streams, iron usually collects other impurities and contributes to the stabilization of the wastes for final disposal. These roles of iron, as they relate to current uranium processing operations, are discussed in detail, and some broad and historical perspectives are also presented.

Jan 1, 2006

By K. P. Wright

"Twenty-five years ago, there were about thirty-two gold mines operating in Canada; nine of these have been in continuous operation since then and are still operating. Three of these are part of the Dome Group. Operations of these three and of the newer mines in the Group are referred to in discussing process development over the last twenty-five years.Of the Dome Mines Group, Dome Mines Limited, Sigma Mines (Quebec) Limited, Campbell Red Lake Mines Limited, Detour Lake Mine and Kiena Gold Mines Limited, three have been in continuous operation for the last twenty-five years. Dome has operated for seventy-seven years; Sigma about to complete fifty years, and Campbell approaching forty. Overall, milling processes are virtually the same as they were twenty-five years ago. Tota1 go1d production from the three mines has hardly changed; 1960 production, 416,700 ozs. versus 411,300 in 1985. Milling costs have risen by a factor of six or seven and gold price from $35/oz. in 1960 to $322 in 1985.Basic flowsheets are relatively unchanged. Sigma is an all cyanidation mill grinding in cyanide solution; Dome operates gravity concentration and cyanidation; Campbell gravity concentration, flotation, roasting and cyanidation. All three use Merrill-Crowe zinc precipitation.Detour and Kiena are two examples of the major change in gold processing in the last twenty-five years - carbon-in-pulp. This process has brought along with it other changes, such as, carbon stripping and reactivation, electrowinning, and induction furnace melting. Modern mill design with its use of outside thickeners and agitators, bulk handling of reagents, instrumentation, etc., has made a radical change in operating conditions and appearance of the new plants."

Jan 1, 1987

By Víctor Siña

El presente trabajo describe una alternativa de sistematización de las observaciones preventivas generadas en las áreas operativas de la minera Antamina a través del programa de Prevención de Riesgos para así reentrenar, reforzar y evitar perdidas por accidentes en cualquier tipo de industria. En ese sentido, cada miembro ya sea propio o socio estratégico de Antamina, es conciente de la prevención mediante la observación. Dicho enfoque evidencia no solo lo malo, sino también todas las consecuencias que esto conlleva. Por ello, la base de dicho programa es la detección anticipada de los actos y condiciones que nos puedan generar pérdidas.

Sep 9, 2007

By J. M. Davidson, F. Fraas, J. E. Conley

"A number of Reports of Investigations pertaining to the extraction of potash from cal¬cined polyhalite have been made by various members of the Nonmetallic Minerals Experiment Station of the United States Bureau of Mines. These reports describe results obtained in the study of samples of polyhalite (2CaS04.K2S04.MgS04.2H20) from deposits of possible com¬mercial importance in Texas and New Mexico.3Storch and Clarke6 in their initial paper presenting data on the properties of Texas polyhalite demonstrated the desirability of calcination and subsequent hot extraction with water as a satisfactory pronedure for treatment of this potash-bearing salt. Their preliminary data have been supplemented by an additional report7 dealing more particularly with the leaching of raw and calcined polyhalite with water and with saturated sodium chloride solu¬tions. Further data8 have been reported as a result of experiments made in a small labora¬tory rotary-tube furnace under various calcination and extraction conditions. Hot water was used as the leaching solution in all of these tests.In addition to the data on calcination and extraction, two processes as proposed by Storch and Clarke have been published by Wroth,9 and more recently a number of very promising processes have been proposed by Storoh and Fragen.10"

Apr 1, 1932

By F. Grajales Muñoz

The Ciénega project, now under construction by Peñoles group, is located in the mountains of northwest Durango, Mexico. The gold and silver deposits are found in a 4-km (2.5mile) long system of veins. An underground operation will be built. The planned 1 kt/ d (1100 stpd) process plant will contain a countercurrent cyanide circuit for oxide ore and a flotation circuit for sulfide ore. Considerable resources have been devoted to the development of infrastructure in the isolated location, as well as for the mitigation of environmental impacts. Startup is scheduled for the third quarter of 1994. Ciénega’s ore bodies consist of quartz veins containing gold, silver, lead and zinc values. The vein thicknesses vary from 2 to 10 m (6.5 to 33 ft) with a northwest trend and nearby vertical dip. Veins are hosted in Tertiary volcanic rocks. The district has intermittently been explored since 1971 by Penoles. After the third series of diamond drilling and direct development work on vein, Peñoles decided to begin project construction.

Jan 1, 1994

By Joseph H. Bilbrey

COBALT is a silvery gray metal which closely resembles nickel in appearance and properties although it is somewhat harder and more brittle. It is rather widely disseminated and is estimated to make up about 0.001 percent of the earth's crust as compared to 0.020 percent for nickel. Cobalt, one of the four ferromagnetic elements, is used for many magnetic applications. It is oxidation resistant, a property which when coupled with its moderately high melting point of 1,495° C., makes it useful in high-temperature applications. Although cobalt had been used by man as a coloring agent for glass and other ceramic products for 4,000 years, it was not isolated as a metal until 1742 and not established as an element until some 40 years later. Early in the 20th century, cobalt began to be used in alloys, and soon these applications displaced ceramics as the major consumer of cobalt. The use of cobalt in alloys gave considerable stimulus to production, and the world output of cobalt increased rapidly, rising from 400 tons in 1920 to 1,400 tons in 1930 and 5,500 tons in 1940. With the advent of the jet plane in the mid 1940's and the consequent increased need for cobalt-bearing high-temperature alloys, cobalt production again increased, reaching 7,900 tons in 1950. The increased demand for cobalt during the Korean war coupled with a large demand for stockpiling caused world production to more than double within the next 10 years, reaching a peak of 17,300 tons in 1959.

Jan 1, 1962

Heap leaching of copper sulphide and oxide ores' has been conducted at Rum Jungle since the end of 1965.A review of operations was made and this led to an examination of some theoretical aspects of copper sulphide heap leaching. Ox,ygen diffusion was indicated to be the factor controlling copper leaching rate at Rum Jungle and in other similar operations. Suggestions are made for measuring the heap leaching rate. Prediction of full scale operational results from pilot scale testwork are discussed.

Jan 1, 1969

By C. Feng, C. Elbaum

Knoop hardness measurements were carried out on large grains of iodide titanium containing different amounts of oxygen. For each oxygen content the hardness is recorded ainingas a function of the crystal orientation and of the angle 4 between the indenter diagonal and the projection of the C (hexad) axis in the surface. The results can be expressed by the following relation; hardness = n-k cos 2ø, where n and k are constants for a given oxygen content and crystal surface orientation. A NISOTROPY of hardness is a well-known phe-nomenon and has been reported for many metals.1-3 At the present time, however, such information is not available in the literature for titanium. Consequently, a systematic study of the simultaneous effects of oxygen content and crystallographic orientation on the hardness of titanium was undertaken in this laboratory. Evaluations of oxygen content in titanium are frequently carried out through hardness tests. Although such procedures may be justified in small grain specimens, the results of the present investigation indicate that the anisotropy of hardness should be taken into account in the case of coarsegrained specimens as well as in the case of pronounced preferred orientation. Materials and Experimental Procedures Iodide titanium, 99.99 pet pure and containing of the order of 0.002 wt pet O, was used throughout this investigation. The metal was arc melted in an argon atmosphere and cold rolled into strips 1/16 in. thick. These strips were subsequently recrystal-lized and strain annealed in vacuum (10" mm Hg or better) at 850°C in order to produce crystals varying in diameter from 10 to 25 mm. Oxygen was introduced into selected large crystals by heating at 700°C in an atmosphere of pure oxygen under an observed pressure of approximately 50 mm Hg. Each sample was subsequently annealed in vacuum at 850°C for 100 hr, in order to homogenize the oxygen content throughout the specimen. It was found that longer annealing was not necessary, for no change of surface hardness in a given direction was detected after prolonged annealing. The oxygen content was determined by the difference in weight of the specimens before and after the oxidation-annealing cycle. The accuracy of oxygen determination is within ±0.1 mg in samples weighing 0.5 to 1 g. A vacuum fusion analysis of oxygen was performed on several samples and gave results in good agreement with the ones obtained by the weight change. It should be emphasized that expected weight losses through evaporation of the metal in vacuum at 850°C' are many orders of magnitude lower than the precision of these measurements. Following the annealing treatment, both oxidized and unoxidized crystals were carefully polished. All detectable traces of surface cold working were removed by repeated polishing and etching. Laue back reflection X-ray patterns were taken for each crystal for the purpose of determining the orientation and ascertaining the absence of substructures detectable by this method. Hardness measurements, using a 1 kg load, were subsequently carried out on a Tukon hardness tester equipped with a Knoop indenter. The Knoop indenter was used throughout this work because indentations obtained by means of a Vickers indenter are considerably distorted due to the anisotropy of the elastic constants in titanium. Such distortions are much less pronounced in the case of Knoop indentations, although for some orientations a cer-

Jan 1, 1959

In formulating its strategic plan in 1998 the New Zealand Minerals Industry identified two related critical issues facing it. These are, broadly speaking, the issues of access to minerals; and the perception the public has towards the industry and its behaviour towards the environment. This presentation will report on the Industry's response to the public perception issue. The Industry has, through the NZMIA Council, and its Communication and Website Committees, developed and implemented strategies covering: communication through the print media, and through its website www.minerals.co.nz, a long-term educational outreach programme with schools, focussing on the significance of minerals, their contribution to community wellbeing and the negligible long-term environmental effects of the Industry's activities.

Jan 1, 2000

With the change in legislation under the Resource Management Act 1991 (RMA), the responsibility for administering the effects of blasting on the environment, has transferred from an essentially central government system to local bodies. This naturally will allow for a variety of compliance levels and control procedures which will depend on the particular local body and rather ad hoc arrangements. It is anticipated that the existing NZ Standard on blast vibration levels will soon be replaced by the Australian Standard. These changes raise the question as to what should be used as suitable compliance levels to prevent damage to structures. The paper will address the measurement, control levels and the appropriateness of current standards in relation to the overall legal framework of the RMA.

Jan 1, 1996

By Harald Ludwig

In 2002, excavation support work commenced on the Capitol Visitor Center project located adjacent to the nation?s Capitol building in Washington, D.C. The outlying work (Slurry Wall Work at Main Site is not discussed) consisted of providing excavation support for a new truck tunnel approximately 1900 feet long up to 50 feet deep as well as support for the new underground auditorium and Library of Congress tunnel. The excavation support consisted of a combination of conventional drilled in soldier beams, lagging, tiebacks and braces; intricate underpinning inside the existing Capitol building; support of an existing Russell Tunnel; soil nailing and tiebacks underneath the existing Russell Tunnel; two temporary bridges; and a deep soil mixed wall with lateral support provided by braces. As part of an on-going research program, some of these braces were instrumented with strain gauges. The deep soil mixed wall was approximately 300 feet long and 65 feet deep on either side of the truck tunnel. Approximately 34,000 sf of deep soil mixed wall, 90,000 sf of conventional excavation support, 200 braces, and 320 tiebacks were installed. This paper describes the large scope and breadth of the project that required a variety of excavation support techniques. A few of the challenges in designing and installing the support of excavation are discussed. This paper also presents the results of the instrumentation program conducted on the deep soil mixed wall, which stood open for more than a year.

Jan 1, 2006

Our modern cities are almost incapable of sustaining themselves without subsurface infrastructure, which is not identifiable at first glance. This very soon becomes evident when the chaotic conditions prevailing in some cases in the multi-million cities on the African, Asian and South American continents are taken into consideration. This does not simply apply to the hopelessly congested streets in the downtown areas. If anything, it is shown here too that a subsurface infrastructure represents an important prerequisite for public health right up to banishing the danger of disease. Even during the 1990s, this has been clearly underlined through examples of cholera and plague epidemics in parts of Central and South America as well as on the Indian subcontinent. The overriding significance of an inner urban subsurface infrastructure in order to create decent conditions in the major built-up areas was once again emphasised not all that long ago at the United Nations HABITAT-II Conference in Istanbul, Turkey, in June 1996. More than 15 000 delegates from all over the world mulled over and discussed the prerequisites for humane living conditions in human settlements taking the varying climatic, topographical and cultural marginal conditions in different regions of the globe into account. Apart from the built-up areas themselves, the utilisation of underground space is experiencing high and ever increasing significance in less densely populated regions. Attractive and fast transport links between industrial centres call for high- performance transport arteries for the economic, speedy and unhampered carriage of people and goods. Important impulses for the economic power of a region or nation are provided by transport development and links. As a consequence, tunnels for roads and railways are being built or planned to a great degree for crossing mountain ranges, rivers and straits.

Jan 1, 1999

By C Johnstone

Project management is not a task to be undertaken lightly. Mining projects generally present even more challenges due to ChinaÆs remoteness and complexity. Having experiences in project management in the West is certainly an asset, but China can present the uninitiated with any number of headaches. To undertake a project there can have many problems that are unique to China. For the last 15 years, China has seen an increasing number of foreign capital investment projects in the mining industry. Practices involved in mining project development have experienced/are experiencing an evolution. Since 1996, Sino Gold Mining Ltd has delivered three mines in China, ie Jianchaling Gold Mine, Jinfeng Gold Mine and White Mountain Gold Mine. Through the work, Sino Gold has established a solid knowledge base and a capable and skilful workforce in effectively undertaking mining projects in China. This paper is concerned with the experiences accumulated so far by Sino Gold in project management in China. An overall review is conducted regarding the reform of the mining project development in China. Opportunities and challenges are highlighted within the political, economic and culture context. Brief summaries of the development of the three gold mines are presented.

Jan 1, 2009

By J. W. Davis

In the last few years major industrial companies have begun to realize the importance of Reliability as an enterprise strategy that, properly implemented, will improve financial performance. Typical results of an effective Enterprise Reliability Strategy include a 20% -50% reduction in maintenance cost accompanied by a 5% - 10%increase in real production capacity, with no capital investment in production equipment. One factor fueling the race to acquire and implement enterprise reliability is the pressure for companies to be increasingly cost-effective and competitive in global markets. In a recent study, Asset Productivity: The Next Wave, the Boston Consulting Group (BCG)stated that, “In order to compete for funds, companies must offer investor returns that are competitive with other opportunities. Alternative investments such as dot-com and others with non-traditional business models have raised the bar.” (APDF version of the study can be downloaded at www.bcg.com). BCG views asset productivity as the most powerful mechanism for increasing shareholder return. The author believes that the most effective way to increase Fixed Asset Productivity is to maximize asset utilization by increasing the Reliability of the Assets and the associated processes. Developing and implementing an ERS requires significant effort and knowledge. Most companies have difficulty finding a sufficient supply of these valuable commodities to implement an ERS Program internally. Many companies also struggle with figuring out how to get started and what direction to proceed.

Jan 1, 2003

By D. A. Cormode

"INTRODUCTIONPine Point Mines, operated by Cominco Ltd., is located approximately 55 miles east of Hay River, N.W.T. by the southern shore of Great Slave Lake.The milling operation commenced in the fall of 1965 at a design capacity of 5,000 tpd. An addition which came on stream late in 1968 raised the nominal capacity to 8,000 tpd. Currently the milling rate is 11,000 tpd.The lead and zinc sulphides occur in dolomite host rock. Typical feed grades at present are 2% lead, 5.5% zinc and 5 % iron. When dolomite is present even in relatively minor amounts in the zinc concentrate, it presents serious treatment problems and causes inefficient operation of electrolytic zinc refineries.By 1972, it had become apparent that magnesium rejection in the form of dolomite was deteriorating because of increased plant throughput of less amenable ore. This paper will briefly outline the Pine Point zinc flotation circuit and will discuss the two phase program for reducing the magnesium level in the zinc concentrate. The program included changes and alterations to the flotation circuit and the construction of an acid leaching plant."

Jan 1, 1977

Ecuador a gross domestic product (GDP) grew 8% despite a slowdown in production and sales of petroleum, the dominant economic sector. Crude petroleum exports, which amounted to about 35% of total exports in 1977, were valued et $484 million,2 a decrease of 14% from 1976 values. Petroleum export sales were depressed because foreign buyers were somewhat uncertain that State-owned Corporación Estatal Petrólera Ecuatoriana (CEPE) held legal title to the oil until final settlement with Ecuadorian Gulf Oil Corp. In addition to the legal complication, Ecuador maintained a relatively high export price for oil until late in the year. There was also a shrinkage of traditional U.S, markets owing to the Alaskan pipeline becoming operational and an increased availability of Mexican supplies. The export market was also affected by increased domestic production in Peru and Chile, which lessened their import needs, and the pressure of greater competition from the Middle East in supplying crude oil to Caribbean refineries. About 20.4 million barrels or 40% of Ecuador's total crude exports went to the United States. Only 27 wells were drilled in Ecuador during L977; of these, 16 produced oil, 3 were dry holes, and 8 were suspended. About 31 wells were planned for 1978. Three new oilfields were discovered during 1977; two by CEPE in northeastern Ecuador and one by the Argentine State oil company Yacimientos Petraliferos Fiscales (YPF), operating in Ecuador under a service contract. CEPE's two discoveries tested at 5,000 and 1.450 barrels per day, respectively. The YPF discovery tested at about 1,000 barrels per day. Ecuador altered its position regarding

Jan 1, 1981

By Y. X. Tong

The simplicity off Ø=0 analysis has been taken advantage of to evaluate the geotech­nical problems of open caissons, slurry trench walls and piles in Shanghai. Undrained shear strengths obtained by various testing methods are correlated with case record and experimental data. Some problems posed by the construction of tall buildings are briefly discussed. Comments on applications are made to help engineers deal with practical problems.

Jan 1, 2010