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By You-Hai Wen, Yinkai Lei, Tian-Le Cheng

A phase field model is developed to simulate the performance of SOFC electrodes. By solving the conduction equations on both the electrolyte and electrode phases, and incorporating the three-dimensional microstructure and reaction front at triple phase boundaries, the current-voltage relation of an electrode is directly simulated. By further coupling it to our recently developed coarsening model, we are able to investigate the effect of initial microstructure on the performance degradation in SOFC electrode. This model is applied to LSM-YSZ cathodes with different LSM volume fraction. The volume fraction effect on the electrode performance and its degradation rate has been analyzed and discussed.

Mar 1, 2018

By Jones KW, McClelland RA, Denholm WT, Taylor RN, OÆShea J

Associated Tin Smelters, Sydney, are developing tin smelting operations in a prototype commercial SIROSMELT plant comprising two furnaces of 5 to 8 tonnes capacity. Features of the plant and its operation are discussed and results of its application to tin slag reduction and high-grade tin concentrate smelting are presented. Development work is still in progress but experience indicates that the technology has potential for lowering the costs of tin smelting and relieving constraints on grade and iron content of concentrate imposed by conventional technology.

Jan 1, 1984

By Aleksandar D. Bugarski

Three types of uncatalyzed diesel particulate filter (DPF) systems, three types of high-temperature disposable filter elements (DFEs), and one diesel oxidation catalytic converter (DOC) were evaluated in underground mine conditions for their effects on the concentrations and size distributions of diesel aerosols. Those effects were compared with the effects of a standard muffler. The experimental work was conducted directly in an underground environment using a unique diesel laboratory developed in an underground experimental mine. The DPF systems reduced total mass of aerosols in the mine air approximately 10-fold for light-load and 20-fold or more for high-load test conditions. The DFEs offered similar reductions in aerosol mass concentrations. The efficiency of the new DFEs significantly increased with accumulation of operating time and buildup of diesel particulate matter in the porous structure of the filter elements. A single laundering process did not exhibit substantial effects on performance of the filter element. The effectiveness of DPFs and DFEs in removing aerosols by number was strongly influenced by engine operating mode. The concentrations of nucleation mode aerosols in the mine air were found to be substantially higher for both DPFs and DFEs when the engine was operated at high-load modes than at low-load modes. The effects of the DOC on mass and number concentrations of aerosols in mine air were relatively minor when compared to those of the DPF and DFE systems.

Jan 1, 2009

By J. E. Jennings

The problems of slope stability in open-cast mines are examined. A criterion, the instantaneous stripping ratio, is suggested for use in the design of pit slopes and as an index of control at all stages of the exploitation of the ore body, This criterion may also be related to safety and to the maximizing of profits. Two approaches to safe design of slopes, one from the point of view of soil mechanics and the other from the point of view of rock mechanics, are described and critically compared. The effect on slope stability of the regional tectonic stress field is discussed. Explanation is given of the application of the Terzaghi effective stress concept to problems in both soil and rock environments, including possible effects when borehole deformation techniques are used to measure stresses in rock in situ.

Jan 1, 1963

By A. C. Fieldner

"Purpose and Nature of Tests:The rapidly increasing use of motor vehicles and trucks in the United States is creating an entirely new problem in the proper ventilation of tunnels, subways and other confined spaces through which such machines must pass. This problem has become of immediate importance because a tunnel 3,000 ft. long is being designed to pass under the Hudson River between New York City and New Jersey. Another tunnel at Pittsburgh 5,700 ft. long through the South Hills, is already under construction, and a third tunnel, 6,000 ft. between Boston and Past Boston is proposed. It is probably that other tunnels will be started in various parts of the United States in the near future.The ventilation of such tunnels is a serious matter, on account of the poisonous nature of automobile exhaust gases. It not uncommon to read about finding a man dead in his garage. Generally this happens on a cold, winter morning, after he has been running the engine with the doors and windows closed."

Mar 1, 1920

By Rospigliosi RT, Krouse HR

The San Vicente stratabound zinc-lead rhythmite deposit, Peru, is hosted in carbonates of the Late Triassic - Early Jurassic Pucara Group. These strata were deposited in a large, shallow water, carbonate platform which extended nearly continuously for 150 kilometers (north-south) in the eastern part of the Pucara basin.The distinctive sulfide-bearing rhythmites occur in three dolomite units which, from bottom to top, include the San Judas horizon with one sulfide-bearing manto; the San Vicente horizon with seven sulfide-bearing mantos including the main ore horizon; and the Alfonso horizon with three sulfide-bearing mantos. The dark gray sulfide-bearing dolostone layers range in thickness from a few millimeters to a few centimeters and contain variable amounts of carbonaceous material, pyrite, quartz, fine-grained sphalerite and galena. They are bordered on each side by selvages of yellow to red-brown coarse-grained sphalerite containing minor amounts of galena. Coarsely crystalline white or gray sparry dolomite is found between the coarse-grained sphalerite layers. Although commonly stratiform and uniform in thickness, the dark layers curve, "pinch out," coalesce, and form "islands" and "peninsulas."Mineral replacement textures, the paragenetic sequence, and presence of sparry dolomite, bitumen, intraformational breccias and isotope data support a hydrothermal replacement origin by metal-bearing solutions that deposited the ore and related minerals in space previously occupied by dolomite and evaporite minerals. The alignment of the Zn -Pb deposits, and at San Vicente the orientation of the mantos, the spatially and temporally associated igneous sills and the tourmaline-bearing sandstone support hydrothermal mineralization driven by a magmatic heat source in a tensional regime.

Jan 1, 1990

By W. A. Doble

Opinions differ as to whether the water-wheel almost universally known as the Pelton type belongs to the impulse, the tangential, the reactive, the jet or the percussion class, or to a cross between two or more of these classes. The fact is, that for an almost infinitesimal part of a second the axis of the jet of water strikes the bucket of this wheel at a true tangent to its base-line. The percussion of the water, striking the bucket, imparts an impulse to the wheel, causing rotation; and generally the bucket is so shaped that the direction of the jet is

Jan 1, 1900

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0.5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that quenched slags can be treated at slightly lower cost than slow-cooled slags. However, the cost advantage of processing quenched slags is more than offset by the higher copper recoveries obtained from slow-cooled slags.

Jan 1, 1971

By W. L. Dare

This paper is one of a series being prepared by the Bureau of Mines on the methods and costs of mining uranium on the Colorado Plateau. The Continental No. l mine is at the south end of the Big Indian mining district, San Juan County, Utah. The mine is on a school section owned by the State of Utah and leased by Continental Uranium, Inc. A 70,000-ton uranium-vanadium ore deposit was discovered as a result of an exploratory drilling program completed in 1954.

Jan 1, 1957

By Thomas D. Boyce

Minewater from many western U.S. uranium mines often contains radioisotopes in concentrations higher than permissible for discharge to unrestricted areas. .Radium 226 has the lowest permissible concentrations of all radioisotopes and usually greatly exceeds this limit in untreated effluents. This radionuclide is derived from the natural radioactive decay of uranium: [ ] The treating of minewater effluents has been studied previously (1) and the classical removal method for radium has been adsorption on barytes or freshly precipitated barium sulfate. This paper describes the removal of radium from minewater by utilizing a selective complexer based on a crosslinked organic polymer matrix.

Jan 1, 1982

By Danfeng Xu

The majority of the world?s nickel (Ni) resources occur as laterite ores, which are exceptionally complex, lower grade (<1.5% Ni) and expensive to treat using conventional smelting and high temperature/pressure autoclave methods. Heap leaching is a promising, less costly, alternative technology for processing low grade nickel laterite ores. However, significant technical challenges remain with Nickel laterite heap leaching, preventing its general adoption. This paper presents some highlights of laboratory column leaching studies undertaken to characterise, evaluate and optimise sulphuric acid leaching behaviour of Nickel laterite agglomerates. They provide basic but valuable information regarding Nickel laterite agglomerate structure stability and leaching performance under industrially-relevant, continuous acid irrigation conditions. In particular, Nickel and other key metals? (e.g. Co, Fe, Al and Mn) extraction rates, free acid concentration, bed slump and structural changes were determined at a given acid percolation rate as a function of time. Potential implications of the findings, for devising strategies for improved Nickel laterite plant heap leach operations are discussed. Keywords: nickel laterite, column leaching, agglomerates, leaching kinetics, acid consumption

Sep 1, 2012

By Wood P. D, Pettifer G. R

In the upper coal surface in the Latrobe Valley, craters known locally as fireholes have developed due to prehistoric coal fires. They can be several hundred metres across and up to fifty metres deep, and are now filled with overburden materials varying from hard baked clays to very soft lacustrine clays. In addition to reducing coal reserves, continuous mining operations are seriously affected by fireholes. Large undulations in the upper coal surface result in a mixture of coal and overburden on the upper mining levels. The very soft lacustrine clays are unstable in the mine batters and the overburden dump, are difficult to handle on the bucket wheel excavator/conveyer system, and have insufficient bearing capacity for the large bucket wheel excavators. Early identification is essen- tial and both drilling and dynamic core penetrometer have been exten- sively used. However, this has not proved adequate in locating and defining the extent of all fireholes, due largely to their irregular shape. To overcome this a range of geophysical techniques has been trialled with very promising results. A trial area has been covered on a twenty metre grid using gravity and Geonics EM34 conductivity measurements and the same area has been covered at a closer spacing with high resolution magnetics. Image processing of contoured magnetic, EM34 conductivity and residual gravity data has resulted in very good correlation with drilling data.

Jan 1, 1989

By G. Granata

In this work, we studied the recovery of copper from AMD by cementation with iron powder. To control the size of copper particles within the nanoscale range, we tested the use of the anionic surfactant sodium dodecyl sulfate (SDS). We tested three concentration levels (0.2, 0.4 and 0.6 M) and temperatures (25, 50 and 75 °C). The activation energy of cementation was also assessed by fitting the experimental data with the Arrhenius equation. Under all investigated conditions, the cementation reaction was found to be a diffusion-controlled process. Without surfactant, the activation energy was 19.9 kJ/mol. In the presence of SDS the activation energy increased up to about 35 kJ/mol. With or without SDS, the particle size of the copper product was strongly affected by the cementation temperature. Without SDS, the cemented product aggregated into micro-sized clusters of about 15 μm at 25 °C, 2–3 μm at 50 °C and 1 μm at 75 °C. The addition of SDS resulted in a dramatic decrease of copper particle size up down to the nanoscale range. Under the best operating conditions, the particle size of copper was <100 nm.

By Warren L. J

The recovery of phosphate minerals from the Mt Weld deposit by froth flotation has been studied by many researchers. Most of the flotation experiments were carried out with a tall oil fatty acid as collector and sodium silicate as dispersant and gangue depressant at pH about 10. Several rougher stages and cleaner stages and, sometimes, a desliming stage were included. The major difficulty was to reduce the Fe2O3 impurities in the concentrate to the required level. We used QEM*SEM (Quantitative Evaluation of Materials by Scanning Electron Microscopy) to provide a comprehensive and accurate mineralogical analysis of the flotation products. The analysis indicated that the Fe2O3 impurities were mainly recovered in the second concentrate, owing partly to the incomplete depression of the liberated iron oxides by the sodium silicate and partly to composite particles containing iron oxides. The selective depressing action of sodium silicate was improved by adjusting the variables such as the modulus (SiO2/Na2O), pH and time of standing of the stock sodium silicate solutions or by adding some polyvalent metal salts into sodium silicate solution. The flotation process was optimised to produce a phosphate concentrate with the required grade and recovery (38.6 per cent P2O5, 2.67 per cent Fe2O3, 13.7 for P2O5/(Fe2O3 + A1203), at P2O5 recovery of 81.5 per cent). The possibility of recovering the rare-earth phosphate, monazite, from the Mt Weld deposit by flotation was also studied.

Jan 1, 1991

By T. M. Garland

This report presents a Bureau of Mines assessment of crude oil and associated gas production and reserves that would result from different drilling efforts in the lower or contiguous 48 States during the 1972-85 period. The drilling effort was based upon five growth rate assumptions from the 1971 level. Additions to crude oil reserves were computed for nine cases resulting from the use of three equations for findings per foot drilled and three constant revision factors. The results indicate that the United States will not become self-sufficient in crude oil production by 1985 and also illustrate the lead time required to reverse the decline in oil production. Discussion is limited to three of the nine cases to provide high, intermediate, and low results. More emphasis is on the intermediate case because it is indicative of the most probable trends. The methodology and statistical data are included in the appendices.

Jan 1, 1974

By R. T. Jones

"Technical publications in the field of mining and metallurgy have existed for a long time. Recent developments in electronic publishing on websites make it possible to disseminate information more widely and cost effectively than before. Professional societies have an opportunity to serve their members and their industry by publishing high-quality peer-reviewed papers on their websites as well as in printed form. Older publications can be scanned, and optical character recognition can be used to provide searchable text. Various business models exist around this process. This paper outlines the approach used by the Southern African Institute of Mining and Metallurgy (SAIMM) to provide free open access to their journal papers and conference proceedings, as well as the work being done by OneMine.org to collect technical papers from a number of international societies and make them available to subscribers via a large database. An approach is outlined that should be of benefit to authors, readers, and society at large.INTRODUCTIONGeorgius Agricola (1494-1555) was not the first writer on the subjects of mining and metallurgy, but is well known as the author of De Re Metallica (‘of things metallic’ or ‘on the nature of metals’), a book that documents and illustrates the observations he made in the course of his extensive travels in the 1500s. Agricola wrote extensively about mining methods and metallurgical processes that were in place in the Middle Ages. The original Latin version of De Re Metallica was published in 1556, the year after Agricola died. It was translated into English by Herbert Hoover, a mining engineer and later President of the United States, and his wife Lou Henry Hoover, a geologist and classicist. The English version of De Re Metallica was published in 1912."

Jan 1, 2012

By Kan Song, Lin Liu, Hengzhi Fu, Jun Zhang, Haijun Su, Xiaojiao Jia

"Al2O3/YAG/ZrO2 eutectic in situ composite has been regarded as new generation of high temperature structural material due to its excellent performance even close to its melting point. The directionally solidified Al2O3/YAG/ZrO2 eutectic ceramics are prepared by recently developed Laser Floating Zone Melting (LFZM) apparatus in which a splitter mirror is used to obtain two beams with the same quality from one CO2 laser. With the two laser beams irradiate the sample from opposite directions, the sample is zone melted. The apparatus configuration and the solidification processing are described in detail. The solid/liquid interface morphology is studied and the mechanism of microstructure formation especially the characteristic of eutectic cellular is discussed. It is shown that YAG and ZrO2 phases play a leading role during the ternary eutectic growth. Meanwhile, the relationship between the solidification microstructure and the processing parameters are investigated.IntroductionAl2O3/YAG/ZrO2 ternary eutectic in situ composite, due to its excellent high temperature mechanical properties, is now considered to be a promising candidate material as a replacement of nickel based super alloy for new generation aero space engine turbine blade [1]. They exhibit flexural strength of 360-500 MPa from room temperature to 2073K in air atmosphere [2]. The compression creep strength at 1873K is 433MPa with the strain rate of 104/s [3]. However, because of the high melting point and complex physical properties, there remain still many difficulties for its application. One of the bottlenecks is the poor understanding of the relationship between microstructure and solidification conditions."

Jan 1, 2012

By P. C. Parsons, G. C. Milligan

"IN FIELD WORK in the Cape Breton Highlands, which are heavily covered with vegetation, it is necessary to run traverses along the valleys of small brooks. We encountered difficulty in closing such traverses, and the following technique was developed to solve this problem. It has been tested in the field for four seasons by several people, and found to be simple, efficient and more accurate than any other compass-and-pace system of which we are aware. So far as we can find, the technique has not been described previously. It may be of use to others.The Cape Breton Highlands of Nova Scotia consist of hills of old intrusive and metamorphosed sedimentary rocks protruding up to 1,000 feet above the general level of the younger sediments which underlie the valleys. The flat hill-tops are the remnants of a plateau; drainage off the edge of this plateau has produced many small steep brooks. They occupy valleys which are up to 800 feet deep, and V-shaped in cross section, with steep sides covered by mixed conifers and hardwoods. The stream at the bottom is rarely more than a few feet wide, with a negligible meander belt, but with many bends, rapids and falls. Visibility along the stream, in consequence, is rarely more than a few hundred feet, and in many places much less.It was found impractical to map the streams by the method of meander lines, as described in many standard surveying texts and hand-books. The limited visibility, and the numerous bends of the brooks, necessitated many corners. Every corner introduces errors. To 'close' a survey with 40 or 50 such corners proved either very time-consuming or impossible. In most cases, however, the general direction of a valley may be obtained from an aerial photograph, or by direct observation, and this became the basis of the method adopted."

Jan 1, 1971

By A. S. Michaels, R. S. Timmins

A study of the effect upon oil recovery from an un-consolidated porous medium of chromatographic transport of selected reverse-wetting additives during water displacement is described. Flow tests were performed on hydrocarbon oil-saturated sand columns (containing connate water) into which small volumes of short-chain aliphatic amine solutions were introduced during water flooding. Concurrently, meusurements of oil-silica contact angles, oil-water interfacial tensions and oil-water distribution coefficients were measured us a function of additive concentration. Certain treatments were found to cause a slight reduction in oil recovery, while others produced a significant increase (up to 50 per cent of the normtzl irreducible rninimum oil saturation). Recovery eficiency was correlated most satisfactorily with the maximum degree of reverse wetting produced during additive transport; conditions which resulted in only mild oil wettability of the sand reduced recovery, while those favoring strong oil wetting increased recovery. A mechanism of reverse-wetting additive action during chromatographic transport is developed which ascribes the results to transient changes in oil-solid contact angle during flow, with consequent release of oil trapped by capillary forces. Implications of these observations with regard to improved waterflood efficiencies are discussed. INTRODUCTION The need for finding improved methods of oil production is amply illustrated by the large volume of oil considered economically unrecoverable by existing production practice. Water flooding has long been an excellent method of secondary recovery. However, even in those areas of a formation which are well swept by a water flood, 20 per cent or more of the oil remains trapped within the formation and is not recovered. This trapping of oil within the pores of the rock structure results primarily from interfacial forces. If these interfacial forces were altered, it is possible that the trapped oil could be released and recovered. The addition of surface-active agents to a water flood to alter the interfacial properties of the oil-water-solid system has received considerable attention as a method of increasing oil recovery. Studies of surfactant treatment have yielded varied and, in some cases, apparently conflicting results. Increased oil recovery using surface-active agents has been reported by a number of investigators. Others have found that use of surfactants in a water flood either has no effect upon oil recovery or decreases it. Since surface-active agents tend to alter the formation wettability and oil-water interfacial tension simultaneously, several investigators have tried to determine the role these two factors play in oil recovery. Data have been presented which indicate that the most desirable condition for the solid surface is strongly water-wet. Other results indicate that, although breakthrough recovery may be less, the greatest ultimate recovery is obtained when neutral wettability prevails.", " The desirability of low interfacial tension seems to depend upon the wettability of the formation. Reports of higher recoveries, when the interfacial tension is high in a water-wet system and low in an oil-wet system, are at odds with reports of increased recovery in water-wet systems when surfactants which decrease the interfacial tension are added to the water flood. A review of previous work studying the effects of using surface-active agents in a water flood shows that these agents produce widely different effects and that opinions as to the role of the various interfacial properties are diverse. The consensus, however, is that the interfacial properties are quite important in the displacement of oil from a porous medium by water. Even in those investigations where appreciable increases in oil recovery resulted from treatment with a surface-active agent, economic considerations generally made practical application of the treatment unattractive because surfactants tend to be adsorbed within the formation. This adsorption would necessitate using large quantities of surfactant if all of the flood water were treated to contain a given surfactant concentration, even if this concentration were quite low. Preston and Calhoun suggested that the principles of chromatography could be applied to the use of surface-active agents as a means of increasing oil recovery. A small volume of surface-active material is injec-

By Albert Sauveur

IT WAS in June, 1889, that I was first admitted to the society of educated men. The admission ticket had been signed, on the recommendation of my old and beloved teacher, Bobby Richards, by General Francis A. Walker at the time President of the Massachusetts Institute of Technology, an institution familiarly known as M. I. T. I immediately proceeded to take advantage of that privilege by departing for Steelton, Pennsylvania, where I understood I was eagerly awaited by the educated officials of the Pennsylvania Steel Company. I was some. what disappointed at the casualness of my reception and at being tucked away in that preserve closet of steel works known as the chemical laboratory. At Steelton I met Major Bent who was president of the company. When I say "met," that is a figure of speech as my acquaintance with him was confined to my being shown

Jan 1, 1937