Search Documents

By A. G. Belova

With the federal climate change legislation in progress, there is a need for demonstration-stage technologies aimed at providing clean energy from coal. Our research aims to experimentally illustrate the feasibility of capturing CO2 on a novel sorbent system from a gaseous stream. The gas is then released resulting in a regenerated sorbent and a pressurized stream of pure CO2 to be used for storage. The proposed sorbent is a ceramic honey-comb structured monolith coated with CaO supported on a high-surface area alumina. CaO is a natural acceptor of CO2 and our design ensures the physical stability and chemical reactivity of CaO over a large number of CO2 capture/release cycles. Furthermore, the use of the monolith ensures a uniform flow through the reactor, minimizes pressure drop across the reactor, and maximizes the surface reactive area. In this paper, we will present the results from a flow-through laboratory-scale reactor that establishes the efficiency of the proposed system to capture CO2. Future applications of the reactor include integration within the new-generation coal gasification power plants, such as IGGC, as means of providing decarbonized electricity.

Jan 1, 2010

By J Seppelt

The Kanmantoo Copper Project is owned and operated by Hillgrove Resources Limited and is situated in the Adelaide Hills region in South Australia. Mining in the area has taken place off and on over the last 140 years to recover metal from both copper and lead-zinc ores. This paper focuses on the commissioning, ramp up and future outlook for the copper concentrator at the Kanmantoo Copper Project with major focus on issues encountered and operating performance achieved to date.CITATION:Seppelt, J, 2012. Commissioning of the Kanmantoo Copper Concentrator, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 127-136 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By J. Y. Foley

Platinum-group elements (PGE) are preferentially associated with chromian spinels, including high-iron chromite, magnesian-chromian hercynite, and chromian magnetite in clinopyroxene-rich upper stratigraphic portions of the Tonsina ultramafic complex in southern Alaska. Ratios of Pt:Pt+Pd are proportional to chromium content in the associated chromian spinels. The maximum PGE content of geochemical rock samples from Dust Mountain is greater than 20.000 ppb (>0.6 oz/ton) with minor gold values. The maximum PGE content of tabled chromite concentrates is 3.430 ppb (0.1 oz/ton) at Dust Mountain. 1.029 ppb (0.03 oz/ton) at Sheep Hill, and 1,749 ppb (0.051 oz/ton) at Bernard Mountain. High-iron chromite at Dust Mountain yields tabled chromite concentrates with Cr:Fe ratios between 0.5 and 1.2. Lower PGE contents are found in more chromium-rich chromitites from Sheep Hill and Bernard Mountain that yield concentrates with Cr:Fe ratios between 1.0 and 2.8. Platinum-group minerals include amalgams. arsenides. PGE alloys, and sulfides. These minerals are between 3 and 40 microns in size and are concentrated along grain boundaries and fractures of metasomatically and hydrothermally altered chromian spinel grains.

Jan 1, 1987

By G. L. Gates

The Bureau of Mines studied the scales formed in producing wells in the Wilmington field, California. The scales were primarily barium sulfate and resulted from the mixing of injected sea water and formation waters; there was excess sulfate in the injection water and the formation waters contained appreciable barium. After breakthrough, the produced brines were supersaturated with barium sulfate. Laboratory tests indicated that barium sulfate precipitated quickly When the supersaturated brines were agitated with crystals of barium sulfate and fairly rapidly when more sulfate solution was added. Precipitation occurred slowly on standing or under nonturbulent conditions. Both the apparent and equilibrium solubilities of barium sulfate in these brines were determined and compared with equilibrium solubilities in distilled water and sodium chloride solutions.

Jan 1, 1965

By Zabetakis M. G.

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1973

By R Mann, R Prasad, S Vink, V Nanjappa

The level of salinity that various aquatic organisms can tolerate without incurring any adverse effects is dependent on several environmental and evolutionary factors. These factors include the relative concentrations of different types of dissolved salts in the water that makes up their habitat, the regimes to which organisms are exposed to waters of differing salinity levels (including naturally derived variations), the degree to which an organismÆs life history stages have adapted to salinity, an organismÆs ability or behaviour to avoid adverse levels of salinity and an organismÆs capacity for osmoregulation.Release of saline water into rivers of the Fitzroy catchment has created concern about the impact on aquatic organisms. Not only is salinity itself a stressor on organisms but different ionic compositions will moderate the effects. Ecotoxicology experiments were conducted using artificial saline water based on mine water chemistry using sensitive macroinvertebrates collected from the catchment, as well as a range of laboratory organisms in accordance with the ANZECC and ARMCANZ (2000) guidelines. The 95 per cent ecosystem protection value calculated from species sensitivity distribution derived from the commercial tests was estimated to be ~2.0 mS/cm. For the protection of 99 per cent of the species the salinity has to be reduced by more than 50 per cent to 0.91 mS/cm. The electrical conductivity (EC) values, derived by commercial testing and species sensitivity distribution in this study suggests that salinity contaminant trigger values previously developed using a referential approach for protection of aquatic ecosystems from saline mine water releases in the Fitzroy may be conservative.CITATION:Vink, S, Mann, R, Nanjappa, V and Prasad, R, 2013. Determining the impacts of salinity on freshwater organisms, in Proceedings Water in Mining 2013 , pp 149-154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) am-mines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Jan 1, 2011

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) ammines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Nov 1, 2011

By E. L. Singleton

The electrochemical reduction of aluminum chloride to aluminum was investigated in a closed, two-compartment cell utilizing a molten chloride electrolyte. The externally heated cell was divided into a reduction compartment and a combination AICl3 feed and metal removal compartment. Aluminum was deposited at 700° C on a molten aluminum catbode from a KCI-NaCI-AICI3 electrolyte. The AICl3 content of the electrolyte was replenished by either vapor or solid additions. The chlorine evolved was collected and measured to give a quantitative evaluation of AICl3 reduction. The effects of anode and cathode current densities and AIC13 concentration on anode current efficiencies were studiedo A range of 64 to 84 percent anode current efficiency was obtained with the 25-pound electrolyte capacity cell and related auxiliary equipment.

Jan 1, 1968

By Qingxia Liu, Mingbo Zhang, Hongbo Zeng

The shortage of freshwater has been a major challenge for mineral flotation in arid areas. When using high salinity water, certain electrolytes are detrimental to flotation while others can improve the flotability of minerals. In this paper, the flotation behaviors and contact angles of pyrite in both Milli-Q water and high salinity water were investigated using different collectors at various pH levels. Results show that the thionocarbamate has a less affinity to pyrite in different solutions under mildly alkaline conditions as compared with potassium amyl xanthate (PAX) and N-isopropoxypropyl-N’-ethoxycarbonyl thiourea (iPOPECTU). At high pH levels, the slime coating on pyrite surfaces, which is caused by colloidal precipitates of magnesium and calcium ions in seawater, was confirmed by SEM, EDX and in-situ zeta potential measurement. The slime coating of colloidal precipitates on mineral surfaces led to low recovery of pyrite at high pH levels. The study of flotation behavior of pyrite in high salinity water improves our fundamental understanding of mineral flotation in seawater.

Jan 1, 2015

By V. V. Ivanov, A. I. Khanchuk, E. V. Mikhailik, M. G. Blokhin, P. E. Mikhailik

At present, marine ferromanganese crusts of seamounts are of great interest as a source of high-tech metals. The metals most enriched in these deposits are essential for a wide variety of green-tech, emerging-tech, and energy applications (Hein et al., 2013). There is a grate number data on the content of major and minor metals (thousands analyses). However, information on the content of such elements as platinum, gold and silver in the world literature is limited. The concentrations (N – number of analyses) of platinum, gold and silver in the Pacific are 418 ppb (N = 105), 35 ppb (N = 72), 1.02 ppm (N = 26), respectively, and in the North Pacific Prime Zone - 477 ppb (N = 66), 55 ppb (N = 13), 0.1 ppm (N = 4); in the Atlantic Ocean is 567 ppb (N = 2), 6 ppb (N = 2), 0.20 ppm (N = 18), in the Indian Ocean, 211 ppb (N = 6), 21 ppb (N = 2), 0.37 ppm (N = 9) respectively; (Hein et al., 2013). The northern part of the Pacific is poorly studied in this question. The samples of ferromanganese deposits (FMD) was recovered from the Govorov Guyot (Magellan seamounts), MZh-33 Guyot (Marshall Islands), as well as the Detroit Guyot (Imperor Ridge) and Yomei Guyot (Fe-Mn placer Holes 431 and 431A DSDP, Imperor Ridge).

Jan 1, 2018

By V. Yahorava

Efficient recovery of precious metals from process solutions is essential for improving process economics. Traditionally, precious metals are relatively effectively recovered from waste streams via precipitation or cementation. However, these approaches have a number of drawbacks, including poor water balance, creation of environmentally unfriendly waste streams, and losses of precious metals. Ion exchange technology is an alternative for the recovery of precious metals from waste or low-grade streams. This technology allows the recovery of the precious metals to extremely low levels (micrograms per litre) with relatively high upgrade ratios from the solution onto the resin without major water balance concerns, while the impact on the environment could be minimized or avoided. Research was conducted on the recovery of platinum group metals and gold from different low-grade and waste streams from one of the precious metals refineries in South Africa by means of ion exchange. Various functionalities and matrices (granular and fibrous) of ion exchange materials were evaluated. The results from these studies indicated that in some cases ion exchange could be very effective for the recovery of precious metals, and that the PGM concentration could be reduced to < 1 mg/L. The upgrading ratios of the various PGMs onto the specific fibres were relatively high for the specific streams evaluated, which might in some cases justify incineration of the loaded material instead of stripping and recycling the adsorbent. The cost of direct incineration for one of the waste streams tested would be less than 1% of the value of the PGMs recovered. However, the adsorbent has to be carefully selected and the process design optimized for each specific stream.

Jan 1, 2014

By D. L. Moellenberg

Under various state laws enacted mostly within the last 20 years, reclamation requirements and standards for hard-rock mining operations have been established virtually everywhere in the western United States. Unlike the uniform and detailed coal mine reclamation requirements under the federal Surface Mining Control and Reclamation Act ( "SMCRA" ) and state programs mode led after SMCRA, the various state law hard-rock mine reclamation requirements are based upon a variety of objectives, and therefore are subject to varying standards from state to state. While the diversity of reclamation requirements complicates the determination of what reclamation measures will be required at any particular mine, there are valid reasons for this diversity. There are dozens of different commodities mined in the United States, and mining methods are different for each commodity. Local natural conditions such as climate, precipitation, geology, hydrology, and biology vary widely across the county. Site-specific conditions also affect mining and reclamation methods. Also, factors such as economics, land use, and environmental protection issues receive different priorities in different states and communities within those states. State reclamation requirements in general provide the flexibility to consider site-specific circumstances, allowing operators to design and engineer the best reclamation measures for each mining site. To the mine developer or manager, reclamation requirements must be translated into design, operational, and closure measures for mine planning. Each of these measures must then be assigned additional costs to be factored into the economic decisions for a particular mining operation. On a broader level, reclamation costs must be factored into decisions such as where to invest in exploration and mine development. The purpose of this paper is to provide a summary of the state non-coal mine reclamation requirements in twelve western states. This summary comparison may be useful as a starting point in considering how local reclamation requirements will impact potential mining costs.

Jan 1, 1994

By M. Z. Emad, Y. Majeed, G. Rehman

Massive deposits of rock salt are mined in the Salt Range area of Pakistan. The main export products of rock salt include salt lamps, blocks, and tiles, while local consumption includes the chemical industry and domestic use. The profitable production of salt for value addition depends on the quality, size, and shape of the block. Salt processing for value addition is easier when very few cracks are present in the blocks. The current salt mining practice involves drilling and blasting, which introduces undesired fractures in the material. This paper focuses on the extraction of rock salt blocks by applying conventional cuboidshaped block mining methods used in quarries. The techniques include wedges and feathers, expansion chemicals, and blasting with low-yield explosives. Experimental work involved both laboratory-scale and in-situ field testing. Laboratory experiments assisted with the determination of splitting force, loaddeformation curves, and other rock mechanics parameters. Regression analysis proposes a relationship for the estimation of radial strain from the load in the case of the wedges and feathers method. The splitting force obtained from the laboratory tests was used to confirm the accuracy of the already published empirical relationship. The results of the laboratory as well as in-situ tests showed that the wedges and feathers technique is the most suitable method for mining rock salt blocks of the desired size, shape, while minimizing cracking.

Mar 2, 2022

By J. D. Clucas, N. Verbaan, T. Grammatikopoulos, D. B. Dreisinger, C. Forstner, M. Aghamirian

"Search Minerals is currently exploring the Port Hope Simpson (PHS) Rare Earth Element District in southeastern Labrador, Canada. The Foxtrot Rare Earth Element (REE) Project in the PHS District has a 43-101 resource estimate consisting of 3,410,000 tonnes of Indicated Mineral Resources and 5,850,000 tonnes of Inferred Mineral Resources. The indicated and inferred resources contain 1.07% and 0.98% total rare earth element oxide (including yttrium), respectively. The dysprosium and neodymium grades are particularly attractive at 218 ppm Dy2O3 and 1687 ppm Nd2O3 for the indicated resources and 208 ppm Dy2O3 and 1494 ppm Nd2O3 for the inferred resources. The mineralization remains open along strike and at depth and is only one of a number of attractive exploration targets in the Port Hope Simpson area. The REE minerals fergusonite and allanite are present. The ore can be beneficiated by gravity, magnetic separation and flotation to a recovery of +80% for the individual REE. Acid bake and water leaching may be used to extract REE into solution for subsequent purification and recovery. The extraction range for single stage leach tests were 91-96% for Nd, 84-87% for Tm and 92-94 % for Dy with modest acid consumptions. INTRODUCTIONSearch Minerals Inc. (Search) is exploring the 100% owned Port Hope - Simpson District in Labrador, Canada for rare earth elements (REE). This District is approximately 135 km by 12 km in size, and is highly prospective for heavy and light rare earth elements. A total of 11 REE prospects have been discovered in the District to date, including the Foxtrot. In addition, Search is exploring in the 100% owned Henley Harbour region and has joint ventures with Quest Rare Minerals in the Strange Lake region, and with Great Western Minerals Group in the Red Wine complex, all in Labrador. These exploration locations are illustrated in the Figure 1. The focus of this paper is the investigation of the mineralogy and processing of Foxtrot REE materials. The Foxtrot resource falls within the claims held by Search in the Port Hope Simpson REE District. The infrastructure available at Foxtrot is excellent with a deep water port, air strip and road and power infrastructure at Port Hope Simpson. Over $7 Million has been spent to date on exploration and development of the District. The Foxtrot has been explored using prospecting geochemical methods, geophysics (airborne and ground), channel sampling of surface outcrops, mapping and three phases of drilling (18,934 m total)."

Jan 1, 2012

By İbrahim Alp, Emine Yoğurtcuoğlu

This article includes the application of roasting pretreatment by assisting the cyanidation process in the recovery of Au–Ag from Bolkardağ Gossan refractory ore and the characterization studies of the ore, roasting sample, and postcyanidation waste sample. While ore contained many metals along with gold and silver, the environment in which these metals were found was carbonate, sulfated, silicated, and iron oxide-containing deposits that have undergone oxidation. In mineralogical studies, there were Fe oxy/oxyhydroxides, Pb/Zn carbonates, and jarosite-bearing structures such as beudantite, calcite, dolomite, clay, and quartz in the ore. The sample used in the experiments was d80 = 29.6 μm, and the test parameters were determined by examining the TG analysis made to the ore. Preroasting experiments were carried out at a roasting temperature range of 200–800 °C, during a roasting period of 10.0 min. Three different samples were characterized by TG for temperature changes, FT-IR for bond structures and permeability, SEM/EDX for visual inspection of structural changes, and XRD Rietveld’s analysis for mineral % content differences. As a result of the cyanidation experiments carried out after the pretreatment, gold was recovered with 80–90% yields and silver with 40–48% yields, respectively.

Aug 21, 2023

By Yongsik Jeong, Kwangmin Kim

Most tailings storage facility (TSF) failures occur in active, upstream-type TSFs, often due to extreme and unexpected weather conditions—specifically, heavy rainfall and strong winds. This case study of a TSF in southern Arizona examines the use of the optimum safe beach distance (Doptimal, the optimum distance between the crest and decant pond) as a tool for monitoring geotechnical stability and reducing catastrophic failures. A digital model of the TSF was used to determine the critical beach distance (Dcritical) under normal weather conditions, and Doptimal was then determined by adding incremental distances to account for the effects of heavy rainfall (Drainfall) and strong winds (Dwind). To overcome accessibility issues, a drone was used to map the TSF geometry and create a digital model. This model served as the basis for conducting a coupled stress-seepage, finite-element (FEM) analysis with a safety factor of 2.0 to assess geotechnical stability (Dcritical). The safe beach distance increments were determined using the PMP (probable maximum precipitation) and possible maximum wind speed. Based on this analysis, the optimal safe beach distance at the study site was identified as 202.2 m. Since the current beach distance (371 m) exceeds this value, the TSF was considered to be stable and satisfied the design safety factor of 2.0. However, this distance should be reassessed periodically to account for changes in the TSF geometry and other conditions. Furthermore, it applies only TSFs that are well-managed and feature a smooth, non-undulating beach surface with a consistent slope.

By B. Abedian, L. M. Racz, S. R. Berry, R. W. Hyers

"The presented work represents an effort to improve understanding and prediction of turbulent flow inside electromagnetically-levitated droplets. We show that the flow field in a test case, a nickel droplet levitated under microgravity conditions, is a low Reynolds number turbulent flow, i.e. in the transitional regime between laminar and turbulent. Past research efforts have used laminar, enhanced viscosity, and k - E turbulence models to describe these flows. In our study, we compare the RNG algorithm to laminar and k - E turbulence model results. We show that accurate description of the turbulent eddy viscosity µr is critical in order to obtain realistic velocity fields, and that µr cannot be uniform in levitated droplets. In the RNG method there are no characteristic length or time scales associated with the flow, thus allowing such anisotropic features to be captured. We perform calculations and analyses for two cases (1) a small, non-deforming, spherical nickel droplet and (2) a deforming, oscillating droplet. In addition to flow field calculations, we compare numerically-obtained surface tension and viscosity values to those obtained experimentally by the oscillating drop technique.IntroductionElectromagnetic levitation (EML) is a containerless processing technique for conductive materials. Its advantages are the avoidance of contamination or chemical reaction at container walls and the ability to perform long-term experiments in a metastable state. Because of its current limitation to small sample sizes, its primary use is in the laboratory. One application of interest is the measurement of thermophysical properties of undercooled liquid metals [1, 2, 3, 4]. In EML, a sample weighing approximately 1 gram is positioned inside an electromagnetic field generated by alternating currents flowing through an axisymmetric water-cooled copper coil. The coil must be designed appropriately so that thesample levitates in a stable manner.Traditionally, mathematical modeling has been performed in tandem with both earth-and spacebound electromagnetic levitation experiments, in order to determine the effect of the magnetic field on material and flow characteristics [5, 6, 7, 8]. These calculations are important because they allow design, planning, and correct interpretation of experiments. In addition, the calculations are of fundamental scientific interest, as they can be applied to other electromagnetic materials processing applications [9]."

Jan 1, 1999

By David B. McWhorter

Conventional analyses of seepage through saturated media do not apply when tailings impoundments are located above a partially saturated zone. Three stages of seepage are identified and methods for estimating the seepage rates and duration of each stage, based upon flow in partially saturated and saturated porous media, are demonstrated. The effectiveness of earthen liners is discussed and procedures for estimating the required properties of the porous media are provided.

Jan 1, 1978

By Ihsan Berk Tulu, Michael Sloan, Ted Klemetti, Michael M. Murphy, Gabriel S. Esterhuizen, Jame Sumner

"In this paper, the advantage of using numerical models with the strength reduction method (SRM) to evaluate entry stability in complex multiple-seam conditions is demonstrated. A coal mine under variable topography from the central Appalachian region is used as a case study. At this mine, unexpected roof conditions were encountered during development below previously mined panels. Stress mapping and observation of ground conditions were used to quantify the success of entry support systems in three room-andpillar panels. Numerical model analyses were initially conducted to estimate the stresses induced by the multiple-seam mining at the locations of the affected entries. The SRM was used to quantify the stability factor of the supported roof of the entries at selected locations. The SRM-calculated stability factors were compared with observations made during the site visits, and the results demonstrate that the SRM adequately identifies the unexpected roof conditions in this complex case. It is concluded that the SRM can be used to effectively evaluate the likely success of roof supports and the stability condition of entries in coal mines.INTRODUCTIONSince the introduction of roof bolts in the coal mines during the late 1940s and 1950s, roof bolts promised to dramatically reduce roof fall accidents (Mark, 2002). However, ground falls still remain a significant factor in underground coal mine injuries and fatalities. In 2013, ground falls accounted for 4 of the 14 fatalities and 166 of the 1577 reported lost-time injuries in underground coal mines (MSHA, 2015).The design of appropriate support systems requires the understanding of: 1) the variable nature of the rock mass, 2) the performance and characteristics of the roof support, 3) the interaction between the rock mass and the installed support system, and 4) the in-situ and mine-induced stress distribution around the excavation. Over the past 25 years, multiple design approaches have been used in coal mine ground control. The approaches include empirical mechanistic methods, empirical statistical analysis, rules of thumb, and numerical methods (Hebblewhite 2006). In the U.S., Analysis of Roof Bolt Systems (ARBS) can be given as an example of an empirical method. ARBS uses relatively simple equations to calculate the intensity of support provided by a roof bolt system and compares it with a suggested ARBS value (Mark et al., 2001). The suggested ARBS design equation is derived from an analysis of 100 case histories. The ARBS design equation is dependent on two parameters: depth of cover and Coal Mine Roof Rating (CMRR). More recently, a probabilistic design approach was developed by Canbulat and van der Merwe (2009) in South Africa. In this method, the variability of the rock mass, the mining geometry, and support characteristics are included in the analytical models. The major advantages of these two methods are: 1) they can be applied rapidly and easily, 2) complex rock mass/ roof support interaction mechanisms are represented with simple equations, and 3) they are supported by large databases. However, both methods generally ignore mining-induced stress distribution, details of the roof support system, details of the geological setting, and the interaction between the support system and the rock mass."

Jan 1, 2015