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By M. S. Seehra, V. S. Babu

"INTRODUCTION The accurate determination of the free silica index in coal mine dusts is an important requirement because severe health hazards are believed to be associated with the inhalation of respirable-sized silica particles.1-6 Free silica refers to the three polymorphs of silica (Si02)viz., quartz, cristobalite, and tridymite-although quartz is usually the dominant form in most mine dusts.6 The free silica index is the concentration in micrograms of free silica in air per m3 of air sampled corrected to standard conditions of 25°C and 760 mm/Hg, the present MSHA (Mine Safety and Health Administration) limit on time-averaged basis being 100 µ.g/m 3 for coal mines. A recent review7 has concluded that quartz, cristobalite, and tridymite particles impart nearly equal long-term hemolytic damage when compared on a per unit surface area basis.At present, two experimental methods-viz., transmission infrared spectroscopy (TIRS) and x-ray diffraction (XRD)-are commonly used for the determination of silica concentrations in mine dusts. In TIRS, which has been adopted by MSHA and is commonly called the P7 method, the silica absorption band near 800 cm - 1 is used for quantification. However the mineral kaolinite, which is commonly present in mine dusts, also has absorption band, albeit weaker, at 800 cm- 1• To correct for this interference, one uses the stronger 915-cm -1 band of kaolinite to determine the concentration of kaolinite, and the kaolinite contribution to the absorbance at 800 cm-1 is then determined from a calibration curve, leading to the determination of silica by subtraction. In the XRD technique, usually an internal standard such as CaF 2 is used to determine the concentration of silica from line intensity measurements. XRD has the added advantage that concentrations of quartz, cristobalite, and tridymite can be determined.8•9 In an exhaustive study on the precision of the techniques ofTIRS and XRD for monitoring worker exposure,9 the conclusion has been reached that both methods measure silica within 253 of the ""true"" value 953 of the time in a single laboratory."

Nov 1, 1995

By T. R. Kostecki

"Instrumented rock bolts are effective tools for assessing the reinforcement and condition of immediate roofs; however, instrumentation can have relatively high costs, which can be justified by high reliability and repeatable and representative data measurements. The instrument’s durability and operational life are of great importance, along with accuracy, applicability, and usefulness. This paper develops reliability models for three instrumentation technologies used in slotted rebar, drawing data from studies at five underground coal mines. Three case studies demonstrate instrument applicability and usefulness. Finally, two types of instrumented rock bolts are used to determine the direction of bend and maximum bending strain. RÉSUMÉ Les boulons d’ancrage instrumentés sont des outils performants qui permettent d’évaluer la consolidation et la condition des toits immédiats. L’instrumentation peut cependant se révéler très onéreuse, des coûts qui se justifient par sa fiabilité élevée ainsi que par des mesures de données reproductibles et représentatives. La durabilité de l’instrument et sa durée de vie opérationnelle sont très importantes, de même que son exactitude, son applicabilité et son utilité. En s’appuyant sur des données issues d’études menées dans cinq mines de charbon souterraines, cet article développe des modèles de fiabilité pour trois technologies d’instrumentation utilisées pour des barres d’armature nervurées. Trois études de cas démontrent l’applicabilité de l’instrument et son utilité. Enfin, deux types de boulons d’ancrage instrumentés sont utilisés pour déterminer la direction de la flexion et la contrainte de flexion maximale.INTRODUCTION Using instrumented rock bolts to monitor strain changes in a rock bolt array allows engineers to understand the per-formance and effectiveness of the rock reinforcement system and the response of the rock mass to such support; however, instrumentation remains a niche solution for solving complex ground-control problems—particularly for underground coal mines, which is where they are needed most. From 2000 to 2016, fall-of-ground fatalities still accounted for an average of approximately 30% of the total annual underground coal mine fatalities in the United States alone (United States Department of Labor, 2018). These tools would also be useful for deep hard-rock mining conditions. The main reasons for the lack of widespread use are not only cost but also accuracy, applicability, implementation procedures, intrinsic permissibility, and reliability (Peng, 2015). As a result, measurements of coal mine roof behaviour using instrumented rock bolts are quite scarce, not widely published, or inadequately presented to provide a seamless understanding of a roof’s response to support."

Jan 1, 2018

By S. Ajima

The Naoshima Smelter and Refinery is the most important copper operation of Mitsubishi Materials Corporation. There are a Mitsubishi Continuous smelter and a conventional type of copper tankhouse. The continuous smelter with 240,000 mtpy of anode production was commissioned in May 19914 replacing two existing smelters, i.e an original Mitsubishi Process line and a conventional reverberatory furnace line. In July 1992, the copper tankhouae was expanded for the purpose to close the gap of production capacity between the smelter and the tankhouse. The cathode production capacity was increased from 13,800 to 15,800 mtpm. By these plant modifications, the distribution of minor elements was significantly changed and the impurities load is getting on increase reflecting recent shortage of clean copper concentrates supply. The paper discusses the distribution of minor elements and the impurity control strategy at the smelter end the refinery.

Jan 1, 1995

By Larry Meinert

Most large skarn deposits are zoned in both space and time relative to associated intrusions, and this zonation can be used to guide exploration. Zonation occurs on scales from km to, and reflects infiltrative fluid flow, wallrock reaction, temperature variations, and fluid mixing. In most skarn systems, there is a general zonation pattern of proximal garnet, distal pyroxene, and vesuvianite (or a pyroxenoid such as wollastonite, bustamite, or rhodonite) at the marble front. In addition, individual skarn minerals may display systematic color or compositional variations within the larger zonation pattern. Such patterns are reviewed for several well-studied examples of Cu, W, Au, and Zn-Pb-Ag skarns. In addition, many deposits have endoskarn or other alteration of the associated intrusion and recrystallization or other subtle changes in the surrounding wallrocks.

Apr 24, 2001

By William Y. Mo

This Information Circular provides a detailed background documentation of how the Bureau of Mines projects U.S. mineral demand to the year 2000. These statistical projections serve as a quantitative basis for contingency forecasting of the low, high, and probable U.S. demand for nonfuel minerals by end-use categories and are published in the Bureau of Mines Mineral Commodity Profiles and Mineral Farts and Problems series. Aluminum is used as an example in this study.

Jan 1, 1980

By D. Harrington

"In at least three out of every four working faces in metal mines there is no attempt made to cause air circulation other than by use of compressed air, and in at least nine cases out of ten the compressed air is released merely by opening, or partly opening, the valve and allowing the compressed air to escape through open air hose used to convey the compressed air to the drilling machines. Usually no blowers are in use during periods of drilling, as the exhaust from the drill provides cool, comparatively fresh air for the driller; however, in some instances, the compressed-air line is provided with a tea connection, which permits taking air for the drill from one side of the tee, and air for ventilation through a separate hose used as a blower, simultaneously with drilling.Table 1 contains temperature and humidity data as to compressed-air blowers from open end of air hose at 36 working places in eleven metal mines of four States, embracing the mining of gold, silver, copper, lead and zinc ores, and at horizons ranging from 500 feet below the surface to as low as 4900 feet.It is noticed that the ordinary air surrounding the worker at the face gives an average wet bulb temperature of 81.7° F. for the 36 working faces, with 84.7° F. dry bulb and 87.2 per cent relative humidity. The average wet bulb tem¬perature of 36 readings at these working faces of compressed air at the end of the,hose as the air issues from the hose was 67.4° F., or 14.3 degrees lower than the average wet bulb readings of the air of the working places; however, the average dry bulb temperature of the 36 readings of compressed air as it issued from the end of the hose was 79.7° F., or only 5 degrees less than that of the general air (84.7°); the relative humidity was 51.1 per cent as against 87.2 per cent for the surrounding air. Readings were taken in five raises, seven crosscuts, ten drifts and 14 stopes.It will be noted that the velocity or movement of the general atmosphere at each of the entire 36 working faces, was found to be practically imperceptible; this might readily be inferred since compressed air is rarely used on blowers if there is adequate circulation of the general air of the place. Where rook temperatures could be obtained readily, they are shown; it is noticeable that the dry bulb temperature of the air of the working place varies little from the rock temperature, and that the dry bulb temperature of the compressed air as it issues from end of air hose varies only a few degrees from the temperature of the surrounding rock; in some instances the dry bulb temperature of the compressed air as it issued from the end of the air hose was higher than the rock temperature or the dry bulb temperature of the surrounding air."

May 1, 1921

By L. F. Heising

The Bureau of Mines evaluated 42 composite samples from selected Michigan-Wisconsin iron formations by reductive roasting-magnetic separation and flotation at minus 325 mesh. Samples having poor to marginal response on initial examination by conventional methods were reevaluated by finer grinding, by reagent suite modifications, and by selective flocculation-desliming techniques. Results ranged from excellent on Menominee Range samples to relatively on Gogebic Range ores. Marquette Range samples ranged from responsive to nonresponsive, depending upon grain size and mineral association.

Jan 1, 1967

By J. W. Lyman

Nickel-metal hydride (Ni-MH) battery electrodes have been developed as a substitute for cadmium-containing negative electrodes. Use of Ni-MH electrodes offers enhanced electrochemical properties in many instances as well as reduced environmental toxicity. Rechargeable batteries using Ni-MH electrodes are also strong candidates for electric vehicles. During the production and secondary reclamation of these battery types, recycling procedures will be needed to prevent environmental impact caused by these wastes as well as to recover the value inherent in the scrap. The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical technology that separates and recovers purified metallic components from Ni-MH battery scrap of two types, AB, and AB,. An investigation of acid dissolution and metal recovery techniques has determined several processing alternatives that may be used to promote the successful recycling of much of the battery fabrication scrap and eventual secondary scrap. Although recovery techniques have been identified in principal, their applicability to mixed battery waste stream and economic attractiveness remain to be demonstrated.

Jan 1, 1995

By Pinakin C. Chaubal

Today?s steel industry is in a vibrant and resurgent mode. This transformation has been in the making for some time now. Over the last few decades, the industry was steadily transforming itself into becoming a high tech industry. New technology was adopted, efficiencies were enhanced, lean manufacturing concepts were brought in and a strong customer focus was developed. Today?s mills employ sophisticated instrumentation, computerized monitoring, on-line smart systems etc. driving processes that are producing at rates of many tons/minute. All this is not possible without judiciously using the latest available technologies in various fields and developing a more sophisticated work force. Prof. Sohn has been a pioneer in driving the concept of process engineering in process metallurgy. In this paper the focus is on some aspects of process engineering ? primarily process modeling - as applied to iron and steelmaking processes. Examples are shown to demonstrate how problems have been addressed. Some thoughts on future directions are presented.

Jan 1, 2006

By Frank E. Scott

During the past year interest in the use of hydrazine and hydrazine hydrate as a fuel has increased in the United States; For this reason it was felt to be desirable to obtain information on the explosives properties (if these materials in order that hazards inherent in their manufacture, storage, transportation, and use might be evaluated.

Jan 1, 1949

By Robert M. Becker

Part 5, the last of this series, deals with the theoretical confirmation and application of results developed in parts 1 and 2. The bulk-sampling variances of Hassialis and Kassel and Guy are compared with those in part 2, both as to formulation and as applied to ores and coal. The results provide confirmation for much of the development in part 2. Examples are presented for determining the reliability of bulk samples with respect to various measurable characteristics. These characteristics include, for example, assays for elements or compounds and particle surface area. The bulk samples considered consist either of a given weight, a given volume, or a given number of particles. In addition to problems of sample reliability, some of these examples may also be applicable to quality control. Several possible applications of results developed in parts 1 and 2 are outlined. These include tests for random data, degree-of-mixing indices, and particle-fineness indices.

Jan 1, 1966

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By B. Vasanthakumar, H. Ravishankar, S. Subramanian, J. Braun

The flotation of sphalerite and galena in the presence of intra- and extra-cellular components isolated from Bacillus circulans before and after adaptation to the chosen minerals has been studied. Based on various biochemical treatments, the key biomolecule primarily responsible for the flotation of sphalerite has been identified as DNA, which functions as a bio-collector. A noteworthy finding is the considerably higher flotation recovery of sphalerite obtained in the presence of single stranded DNA (79.8%) vis-à-vis double stranded DNA (50.2%). Selective flotation tests using the soluble fraction obtained after thermolysis treatment highlight that sphalerite-adapted cells yield a higher selectivity index (S. I.) of 31.2 compared to galena-adapted (S.I. 4.3) or unadapted (S.I. 12.2) cells. During bacterial adaptation to the above chosen minerals, the quantitative and qualitative changes in the surface potential, surface morphology and cell wall components have been monitored. The prior adaptation of the bacteria to sphalerite results in the secretion of a higher amount of proteins, eDNA and phosphate, whereas adaptation to galena leads to a higher amount of polysaccharide, uronic acid and acetylated sugar, vis-à-vis the unadapted bacteria. A significant observation is that the bacteria undergo a change in morphology from rod to sphere as a strategy to resist metal toxicity during adaptation to galena. Interestingly, this phenomenon is not observed during bacterial adaptation to sphalerite. This morphological transition has been shown to involve changes in crucial cell wall components as well as changes in the levels of expression of bacterial cytoskeleton element mreB gene involved in the maintenance of the rod shape. The sequence of B.circulans mreB gene has been identified using Polymerase Chain Reaction (PCR) followed by DNA sequencing.

Jan 1, 2014

By Uwe Wyink, Guenther Thiele, Isabel Gollnick, Klaus Thyrock

"The application of a thin spray on liner was implemented in longwall T-junction sections in 2009 for the first time. The development of the material and the application is based on a technical cooperation between RAG Deutsche Steinkohle AG and BASF Corporation. The report gives an overview of the first trials. The underground test occurred in a seam with a height of 1.5 m (5 ft) in a depth of 1,100 m (3,609 ft). The roadway is dual-use entry and the roof strata is composed of shale and sandy clay. In some sections geological faults impact the surrounding strata. The poor conditions induce separating and loosening of roof rock. Several remedial actions have to be implemented for decreasing deformations at the face entrance.The application of thin spray on liner (TSL) provides simplification and cost reduction of supporting work at longwall T-junction. The installation of TSL to avoid roof and coal fall operations for lagging are omitted.INTRODUCTIONFor safe operation of face retreat in dual-use roadways, the processes of securing and stabilizing the face end area are very important in order to minimize deformation and stress. Avoiding roof and coal fall are the main concerns for safe operation. For that reason different methods of reinforcement are tested in underground operation. In this paper the application of TSL is presented.The specifications of TSL are described, followed by the case study results. The underground study is located in one mine of RAG Deutsche Steinkohle. The extraction of the hard coal in this mine is characterized by great depth and high stress. There are poor geological and geotechnical conditions. The roadway used for the underground application was headed with the support system combination type A, which will be described later in the paper. After the first face retreat, deformation of steel arch support and bagging destroyed the roadway, so for the second face retreat remedial actions had to be undertaken. For this a new system of reinforcement, simplifying the supporting work at the longwall T-junction was tested. The reinforcement consisted of different parts that are described in the following report. Furthermore two different versions were applied. One method is the operation with TSL and the other one is the use of concrete for sealing. Both methods are compared in the text."

Jan 1, 2010

By P. James

Blue Planet Strategies (BPS) focuses on improved resource utilization and targets converting wastes into resources. New BPS capability (DEMET) wrings extra value from mining and processing wastes by enabling new production from waste and residual sources. This powerful platform technology provides considerable processing flexibility and enables various new economical treatment options to extract key metals from low level and process byproduct stream sources normally left as waste by traditional processing methods.[1]

Feb 23, 2014

By J. D. Scott

The counter-current jarosite acid wash circuit presently in operation in the zinc plant produces a combined jarosite plus Pb/Ag residue which is discarded. Extensive pilot-scale testwork, and some past in-plant operational experience, has shown that the zinc plant can be easily reconfigured to produce two residues during periods of high silver feeds and/or prices. Plant.optimized circuit configurations are available for silver recovery to a Pb/Ag residue and are in use for the prevention of Pb/Ag-jarosite formation in both the neutral and high-acid leaching circuits. Silver in the zinc plant undergoes several changes in state as it proceeds through these circuits. The roaster calcine is ~3:1 silver sulfate: silver metal, with metallic silver mainly as micro-Inclusions In an aluminosilicate phase. In neutral leach residue, the majority is as silver sulfide or Pb/Ag/Zn-sulfide coatings on unroasted sphalerite grains, with minor Pb/Ag-jarosite and some residual metallic silver in unreacted alumina-silicate grains. In high-acid leach residue, silver occurs as Se-rich silver sulfide particles in sulfur/jarosite ball aggregates, as silver sulfate impregnations in silica-gel masses and in solid solution in Pb/K/Zn~jarosite. Silver concentrations in solution range from 20 to 60 ppb.

Jan 1, 1990

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By Douglas R. Shaw

Normal dodecyl mercaptan was evaluated as a collector for flotation of sulfide minerals and precious metals. The reagent is from the class of normal mercaptoalkanes (n-alkyl thiols), and is commercially available in the form of a mixture of n-dodecyl mercaptan and a dispersant, under the trade name Pennfloat(TM)3. Reported are results of bench-scale flotation experiments on many commercially treated base metal and precious metal sulfide ores. Dosages, points of addition, and flotation pH were among the uariables studied. Most notable results were increased copper, molybdenum, and precious metals recoveries. Dosages of dodecyl mercaptan on some ores were considerably lower than required for conventional collectors.

Jan 1, 1979

By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By H S. Mitri, A Sainoki

Destress blasting techniques have been widely employed in underground mines for the purpose of preconditioning highly stressed rock mass. Appropriate applications of the technique successfully contribute to increasing mine safety (eg mitigating the risks for rock bursts). This paper presents a simulation technique to estimate the extent of damage zones induced by destress blasting. A 3D numerical model with a single blasthole is constructed with FLAC3D code, whereby static analysis is carried out in which horizontal and vertical stresses are applied to the model in order to simulate stress conditions in a deep underground mine. Afterwards, dynamic analysis is performed whilst applying time-varying blast pressure along the blasthole. The blast pressure profile takes into consideration an instantaneous increase and gradual decrease in blast pressure as well as the propagation of detonation along the blasthole. In this paper, constitutive models allowing for shear and tensile strengths of rock mass that are dependent upon strain rate are newly implemented into FLAC3D code with C++ programming language, whereby blast-induced damage is assessed by the extent of tensile and shear failure zones. The results obtained from the dynamic analysis show significant decrease in the extent of yielding zones induced by destress blasting with increasing the magnitude of in situ stress. They indicate that considering in situ stress state is indispensable in order to propose proper blast design for each level in underground mines. Based on these results, the relationship between the extent of the damage zone and depth at which destress blasting is performed is established. Furthermore, stress dissipation induced by destress blasting is examined with static analyses, in which the modulus of elasticity is decreased according to a rock fragmentation factor, a, only for the area where tensile and shear failures takes place during the dynamic analyses. A model parametrical study with respect to a is undertaken. The relationship between the rock fragmentation factor and the stress dissipation in the yielding zones is developed from the parametrical study. The developed relationship can be useful when destress blasting is designed for massive rock masses.CITATION:Sainoki, A and Mitri, H S, 2015. Simulation of damage zones induced by destress blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 245–256 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015