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By L. Dr. Edeleanu

CRUDE petroleum is a mixture of various groups of hydrocarbons and some bodies containing oxygen or sulphur. These constituents possess properties differing considerably one from another and the proportion in which they are contained in the crude oils is also very different. Owing to this complicated composition the practical use of crude petroleum is much restricted. For example it is sometimes used as a liquid fuel. But its employment in this way is uneconomical because various valuable qualities of the individual constituents are not made use of. The rational utilization of petroleum can only be accomplished if the various groups of hydrocarbons are separated. The mixture of hydro-carbons present in the crude oil must be split up in such a way that the hydrocarbons are divided into various groups having certain predominant characteristics and uses. To accomplish such a separation is the aim of the technical refining of petroleum. ORDINARY REFINING BY DISTILLATION AND CHEMICAL TREATMENT Hitherto this has been accomplished by two processes, namely, fractional distillation and chemical treatment of the distillates obtained. Distillation Process The process of distillation consists in the separation of the constituents of petroleum into various fractions, the boiling points of which lie within certain defined limits. The fractions so separated possess certain special qualities in common, which enable them to be applied for specific purposes in practice. For example, we have the fractions known as benzene, illuminating oils, heavy oils, lubricating oils, etc.

Jan 9, 1914

By G. S. Scott, G. W. Jones, I. Spolan, R. E. Kennedy

In studies made by the United States Bureau of Mines to determine the causes of explosions in medium-pressure acetylene generators , it was shown that when these are operated at elevated temperatures the acetylene liberated in an acetylene generator carries enough water vapor to heat certain types of carbides to a high temperature , when the acetylene- water vapor mixtures are passed through the carbide . This report contains results of further work carried out to develop an apparatus to show the heating effects or reactivity of various types of carbides in contact with acetylene - water vapor mixtures .

Apr 1, 1947

By Rodney Hundermark, July Ndlovu, Lloyd Nelson, Phillimon Mukumbe, Paul van Manen, Whitey Seyanund, Bart Pieterse, Bertus de Villiers, Diale Mokwena

The 2003 redoubling in power to 68MW on the Polokwane Smelter furnace represented a significant intensification in platinum group metal (PGM) smelting. Combined with onerous ‘green’ PGM concentrate smelting requirements, this yielded conditions unusually corrosive to copper coolers and refractories. This presented unexpected operational and design challenges to reliable crucible operation and maintenance. Combined with specific operational control intervention, development of protective coatings has led to the life of water-cooled copper components improving from 9 to 40 months. The furnace matte endwall was extended in 2010 to address accelerated wear of refractories and the potential risk for contact of copper components by superheated matte. An 18 month planned endwall rebuild cycle has been demonstrated (versus catastrophic failure within 9 months). Finally, benefits including lower energy consumption, improved metal recoveries and higher productivity resulting from operational and in-house design developments will be described, that justify “Celebrating the Mega-scale” in PGM smelting.

Jan 1, 2014

By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By VIVEK KUMAR HIMANSHU, Murari Prasad Roy, Kaushik Dey, Rakesh Kumar Singh, Ashish Kumar Vishwakarma

Sublevel stoping is commonly adopted method in underground hard rock mining. Proper planning and its execution is the key requirement for stope extraction using this method. The stope extraction has been a challenging task since decades. The major reason being the unavailability of free faces as compared to open cast bench blasting. The geological and geotechnical parameters changes gradually even within the stope itself. So the blast design parameters should be planned according to the scenario of upcoming ring. Blast design parameters like burden, toe spacing, inclination of blast holes, diameter of blast holes, charge density of explosive etc plays an immense role in rock damage. For the proper breakage of rock, the movement of burden is prime objective. To study this, explicit dynamic based modeller of M/s Ansys was used. The burden values were varied from 20-65 times diameter to assess optimum burden value during the study. The models were simulated for the rock having 35 MPa uniaxial compressive strength and 102 mm blast hole diameter. Altogether three holes were blasted having hole depth 14-14.5m. The blast design parameters and respective blast induced ground vibration has been measured at the experimental site. Core sample of the rock of experimental site has been used for the evaluation of geotechnical parameters. These geotechnical parameters were inserted into the simulation model. The volume of rock excavated along free face has been calculated in each model. It has been found that the burden value can varies from 35-40 times blast hole diameter (3.6-4.1m) to achieve greater volume of rock along the free face for 102 mm blast hole diameter and rock of 35 MPa uniaxial compressive strength.

Feb 6, 2023

By Jerome P. Downey

In the thermal treatment of electric arc furnace (EAF) dusts, zinc is reduced, volatilized, and ultimately recovered either as liquid metal in a splash condenser or as solid zinc oxide in bag filters. During the process, the duet's chlorine and fluorine content also enters the gas phase and condenses as dross in the splash condenser or as salts which contaminate the zinc oxide product. Pretreatment of EAF dust by pyrohydrolysis appeared to offer a means of minimizing the duet's halogen content. The primary research objectives were to experimentally verify the technical viability of pyrohydrolysis and delineate the process parameters requisite for efficient halogen removal. To this end, representative EAF duet samples were secured and characterized by x-ray diffraction, scanning electron microscopy, and Mössbauer analyses. Specific- experimentation focused on the response of halogen extraction to variations in temperature, retention time, water vapor partial pressure, and various additives. The experimental results proved that 97 to 99 percent chlorine extraction and 80 to 85 percent fluorine extraction are consistently achieved when EAF dusts are blended with silica and roasted at temperatures of 850°C or greater in a furnace atmosphere of 75% steam (diluted by air). A statistical analysis further established that more than- a single optimal point exists, thus affording flexibility in parameter selection (e.g., by increasing temperature, the necessary retention time and additive concentrations are decreased). The findings substantiate the feasibility of pyrohydrolysis roasting in reducing the chlorine and fluorine in the EAF dust to a level that will obviate industrial concerns about halogen contamination. The end-product of the pyrohydrolysis procedure is a de-halogenated, self-fluxing calcine which can be directly charged to a plasma or flame reactor. The paper includes design parameters and flow diagrams illustrating the pyrohydrolysis process integrated with the plasma and flame reactor technologies.

Jan 1, 1992

By H. C. Young

This paper deals with roof bolting in Alabama coal mines and iron-ore mines from the time it was introduced in early May 1948 to May 1, 1953, a 5-year period. The Tennessee Coal & Iron Division of the United States Steel Corp. began systematic roof bolting in early May 1948 in a coal mine and in an iron-ore mine, which had some of the poorest roof conditions in the Alabama mines. After the efficiency of roof bolting had been proved by the Tennessee Co. it was gradually adopted by other companies throughout the State, until in May 1953 approximately 53 percent of Alabama's total coal production and 100 percent of Alabama's total iron-ore production, mined underground, was being produced from roof-bolted areas. Statistics in this report will show the advancement made in roof bolting in the 5 years and also the amount of roof bolting that was being done as of May 1, 1953. Significant progress has been made in the coal and iron-ore mines of Alabama in reducing the roof-fall fatality rates during the past several years by adopting systematic roof bolting. The groundwork was laid through successful experiments early in 1948 by the Tennessee Coal & Iron Division of the United States Steel Corp. in cooperation with the Federal Bureau of Mines. This experimental work was based upon the previous experience of the St. Joseph Lead Co.2/ in its Southeastern Missouri mines.

Jan 1, 1954

By D. Janney

Kennecott's Utah Smelter commenced operations in June 1995 utilizing Outokumpu Flash Smelting (FSF) and Kennecott-Outokumpu Flash Converting (FCF) technology. After some initial teething and equipment problems the smelter achieved its design capacity in mid-1997 and now processes over 1.0 million tonnes of copper concentrate per year with exceptional environmental performance. The smelting furnace has operated for 11 years and the converting furnace for 5 years without major shutdowns. The first major smelter shutdown commenced in September 2006 after extensive planning. The FSF was completely re-bricked and the latest above and below bath containment systems installed. The FCF was inspected and re-bricked with some improvements made to the above bath containment system. The FCF life is now anticipated to be the same as the FSF. Numerous improvements and modifications were made to the rest of smelter facility including extensive upgrades to the dry electrostatic precipitators. Production ramp-up was smooth with the smelter now frequently operating at acid plant capacity.

Jan 1, 2007

By Chris Ashton, Andreas Rädle, Taner Aydogmus

"The Contract C310 is part of the current biggest infrastructure project of Europe “Crossrail” which is a major new cross-London rail link project and comprises the construction of the North Woolwich Portal, Plumstead Portal and the twin tube Thames Tunnels with a length of approximately 2.6km. Two Mix-Shield TBMs (Diameter 7.12m) were driving through differing challenging ground conditions (Thanet Sand, Gravels, Flint and Chalk) below the ground water table. The two tunnels were underpassing several listed buildings, sensitive structures, operational railway tracks with low overburden and close to existing subway tunnels in an urban environment. Several additional measures as compensation grouting, micro piles and an intensive monitoring has been carried out to ensure a safe tunnelling process. PROJECT OVERVIEW CROSSRAIL Project Crossrail Crossrail is currently the biggest infrastructure project in Europe which has been developed to serve London and the southeast of England. The project includes the construction of twin-bore tunnels on a west-east alignment under central London and the upgrading of existing National Rail lines to the east and west of central London. The new rail track, as shown in Figure 1, starting in Shenfield/ Abbey Wood in the east of London and ending in Reading / Heathrow Airport in the west of London, includes the construction of nine central area stations, providing interchange with London Underground, National Rail and London Bus services, and the upgrading or renewal of existing stations outside central London.Altogether there will be 118km of new rail tracks, including 42km of tunnels and 40 train stations. After completion in 2018, Crossrail expects 200 million passengers per year (Tauriainen, Rädle, Ingram 2013)."

Jan 1, 2016

By Wayne Loel

THE application of aerial photographs to all phases of geologic mapping is set forth, indicating the advantages to be gained in different types of country and under varying climatic conditions, Methods of field and office procedure are given from a geological point of view, as well as suggestions regarding the best methods of aerial mapping for different uses and under varying field conditions, including the study of submarine geology. Aerial photographs with accompanying geologic maps are shown to illus-trate the appearance from the air of different geologic features under varying climatic and topographic conditions.

Jan 1, 1938

By John C. Machisak

THIS INFORMATION CIRCULAR covers the calendar year 1055 and contains statistical data on employment and injuries pertinent to metal and nonmetal mining and to their mills and processing plants that are voluntarily reported annually to the Federal Bureau of Mmes. This report, unlike previous publications, lists not only production and development workers but also office employees associated with mining and milling or processing. The last publication m the series, Information Circular 7798, Injury Experience in the Metal and Nonmetal Industries, 1954, also contains unpublished injury and employment statistics for 1943 through 1953. The Bureau is authorized to request data on injuries and employment from operators in the metal- and nonmetal-mining industries. The information voluntarily submitted by these operators contributes immeasurably to the promotion of safety in the mineral mining industries as it discloses the hazards to which metal and nonmetal workers are continually exposed during mineral extractive operations.

Jan 1, 1959

By Fernando Linares Quiroa

El diseño y operación de la mina es un proceso importante para la construcción de un modelo de cuerpo mineralizado. En este sentido, el presente texto describe la trascendencia del modelo geológico, construcción y uso de este para la extracción del mineral, donde este es una representación de la realidad que se genera a partir de la información predecible y proporciona a los geólogos e ingenieros de planeamiento los recursos más adecuados para una efectiva selección y extracción del mineral tanto física como económicamente. Asimismo estos bloques permiten la manipulación de la información contenida en estos a una escala local y describen contenido sobre las características tales como: leyes, dureza, peso específico, RQD, litología, mineralización, alteración, metalurgia, etc. Finalmente, los usos que se dan a los modelos de bloques se aplican al control del mineral, planeamiento a corto, mediano y largo plazo, el cáculo de los recursos geológicos y las reservas minerales, constituyéndose en la base para la optimización y del diseño del tajo.

Jul 31, 2003

By T. Yamazaki, T. Goto, R. Arai, N. Nakatani

The importance of cobalt-rich manganese crusts on the Pacific seamounts for possible future rare metal sources has been recognized these 30 years. The thin layer-type coverage and the micro-topographic undulation of basement affect not only the excavation efficiency but also the economy of mining venture. Because of these distribution characteristics, no economic feasibility has been recognized through the past economic analyses. On the basis of a recent geological study about seamount rocks, a possibility of by-product substrate recovery for phosphorous supply with cobalt-rich manganese crust mining has been highlighted. In the mining model, the substrate rocks are utilized as phosphates for agricultural and chemical usages. Under some preliminary technical and economic assumptions, the possibility of cobalt-rich manganese crust mining venture is examined. The results show a better economy of the venture including the substrate rock usage for phosphorous supply. Introduction Cobalt-rich Manganese Crusts and the Economic Feasibility Cobalt-rich manganese crusts on the Pacific seamounts received attention as potential sources for strategic metals such as Co, Ni, Cu, and Mn, due to their vast distribution and higher cobalt concentration than manganese nodules (Cronan, 1980; Halbach, 1982; Manheim, 1986). In the earlier stage, the geological distribution characteristics were reported (Cronan, 1984; Clark et al., 1984; Misawa et al., 1987; Pichocki and Hoffert, 1987) and a systematic feasibility of the mining was studied (Hawaii DPED, 1987).

Jan 1, 2018

By Subrata Dutta

Sindesar Khurd Mine is situated in Rajasthan, India, and operated by Hindustan Zinc Ltd, under Vedanta Group. The base metal mine is high in reserves of Lead, Zinc and silver and has been producing since 2007 with initial production of 0.3 mtpa. Recently the mine has gained prominence as a base metal underground mine in introduction of latest mining techniques and achieving high production at lowest costs. The promising Lead-Zinc reserves of Sindesar Khurd Mine (SKM) and high-tech exploration adopted by Hindustan Zinc Ltd (HZL), (Vedanta Group), raising the reserves and resources from a meager 9 Mt (1997) to 81 Mt (2012), has prompted HZL management to ramp up the mine production from 0.3 mtpa (2006-07) to 2 mtpa by 2013-14 with ambitious plans to reach 3.5mtpa subsequently (presently largest underground metal mine in India). The complete trackless system underground mine, recently equipped with latest leaky feeder communication system (unique in India), utilize modern drilling, mucking and hauling equipment aided with various utility/service vehicles. Excavation optimization and quality recovery maximization from the open and post filled stoping methods, continual expert analysis and feedback from International consultants like AMC (Australia) and SRK (UK), and involvement of renowned bodies in management excellence, have lead the mine towards highest productivity and lowest mine operating cost, earning the mine a prominent place in the global base metal industry. The paper deals with how the various challenges in mine planning and designing, mine development, operator skill, equipment introduction and maintenance, expertise availability, provide training and exposure to officials, prompt and effective communication/service, control of ground vibrations, maintain ventilation standards etc are faced in attaining high operational excellence and thus attain a record mine output/man shift (OMS) of 14 ton/man shift with targets to reach 20 ton/man /shift. Scientific designing using 2D/3D numerical mine-modeling techniques, faster stope sequencing with introduction of paste filling ( first time in India),latest leaky feeder communication system, control ground vibration to stringent standards using electronic delay system, faster raising techniques using raise borers to enhance development and ventilation, cavity scanners to monitor large stope voids, fast shaft sinking at 100 m/month(Chinese expertise) and maintaining adequate ventilation with close software monitoring are some of the highlights discussed in the paper towards achieving the targets.

Aug 1, 2013

By W. H. Jang

Although surface chemistry fundamentals of semi-soluble minerals have been studied by many researchers, detailed understanding of these systems is still incomplete. In-situ FT-IR/IRS techniques have recently been used to successfully describe the adsorption of carboxylates at semi-soluble mineral surfaces. However, the wetting characteristics of these adsorbed films require further consideration. In this regard, the hydrophobicity and stability of transferred Langmuir-Blodgett (LB) monolayers of fatty acids at fluorite and calcite surfaces has been studied by contact angle measurements with polar and apolar liquids. Generally, it was found that the transferred LB monolayers of fatty acids at a calcite surface are unstable whereas such monolayers transferred at a fluorite surface are stable, as revealed from advancing and receding contact angle measurements. These results are believed to be due to the incomplete reaction of fatty acid monolayer at the calcite surface. In addition it was found that a closely packed well-ordered stearate monolayer with good hydrophobicity, equivalent to that of a transferred LB monolayer, can be formed at fluorite surfaces by spontaneous adsorption and self-assembly from aqueous solutions.

Jan 1, 1995

By K Lee, L Mann, J Bygrave, G Sheldon

Ausmelt is supplying commercial quantities of an alkyl hydroxamate flotation collector AM28 for flotation of oxide and supergene base metal ores and tailings. AM28 is a non-hazardous product used as a ten per cent to 50 per cent solution in dilute potassium hydroxide. It is a selective flotation collector for oxide or oxidised base metal minerals and replaces conventional sulfidisation for oxide mineral flotation. At Radio Hill, the AM28 is used in conjunction with traditional sulfide collectors, which allows simultaneous flotation of oxide and sulfide copper minerals. The Fox Resources Radio Hill copper concentrator near Karratha, Western Australia, is currently configured to treat supergene copper ore sourced from the West Whundo open pit. This Archean VMS type copper deposit has been deformed and remobilised with uplift, erosion and weathering to form a significant supergene zone. The sulfide copper minerals present in the upper zone are digenite and chalcocite with lesser chalcopyrite and covellite. Oxide copper minerals present include cuprite, with lesser malachite and azurite. Gangue minerals include quartz, talc and chlorite. Plant trials at Radio Hill are reported for supergene West Whundo ore, where the AM28 was stage added into the circuit at nominally 80 g/t. Plant data over three months shows the copper recovery increased consistently from around 50 - 60 per cent to above 70 per cent when AM28 was added. This has been proven statistically. The grade of the concentrate was consistent with and without AM28, at nominally 22 - 24 per cent copper.

Jan 1, 2007

By Animesh Jha, Chris Dometakis

"Without the use of a flux, only a poor dispersion of ceramic phase can be achieved. A molten-flux-assisted ceramic phase dispersion technique for producing aluminium alloy metalmatrix composites has been developed. In this paper, we report the physical chemistry for the dispersion of TiB2 in molten aluminium. In particular, aspects of the interfacial energy and the thermodynamics of the dispersion reactions are briefly discussed for enhancing the volume of dispersion phase in the molten metal and for controlling their morphology. This investigation also addresses the role of molten flux in the fabrication of AI-alloy mmc using a casting technique. The morphological aspects of the dispersion are explained on the basis of the classical theory· of nucleation.IntroductionMetal matrix composites (MMCs), have long been recognised as an important class of material due to their greater wear resistance, specific stiffness and temperature capability when compared to conventional monolithic alloys. Particulate reinforced composites produced by melt casting techniques have been amongst the first MMCs to achieve commercial market viability. The advent of melt mixing techniques such as the Duralcan™ process have enabled low cost, easily fabricated composites based on the AI-SiC and AIAlz0 3 systems to be produced. In this process, uncoated ceramic particles with diameters 10ltm and larger, are incorporated into conventional monolithic alloys with reinforcement levels up to 25 volume percent. The AI-7Si-SiC metal-matrix composites have good wear resistance, high strength, low density and high thermal conductivity. The combination of these physical and mechanical properties has become a major attraction for the fabrication of light-alloy composite disc rotor brakes for the automotive sector2. However, in silicon-free alloys, SiC is thermodynamically unstable above the composite melting point and is extensively attacked by the melt to form aluminium carbide3 :"

Jan 1, 1996

By A. Perry Thompson

I. GENERAL DISTRIBUTIONS APPEARANCE, AND RELATIONS MINING in Butte has seldom encountered covellite in commercial quantities. The notable occurrences, extending vertically and laterally perhaps several hundred feet, presented scattered, bladed lenses of this mineral in a matrix of quartz, pyrite, enargite, bornite, and chalcocite. But under the microscope covellite is seen to be widespread in the Butte ores, though in such small quantity that megascopic examination will not discover it. In early mining operations covellite was found in the Gray Rock vein, a member of the Blue vein system. As described by Sales,1 it persisted as an occasional ore mineral, associated with quartz, pyrite, tetrahedrite, bornite, chalcocite, and minor amounts of sphalerite, from the 700-ft. to the 1,200-ft. level of the East Gray Rock and Diamond mines. Crushed quartz-monzonite and later quartz completed the vein filling between

Jan 4, 1915

By T. Neesse

In many cases, the use of hydrocyclone control is desirable for the stabilization of separation in the setting of changing feed conditions. Control concepts based on exact mathematical models are not satisfactory due to the complexity of the physical process. In this case, fuzzy control is a suitable solution. The data are primarily derived from an optical sensor that monitors the outside view of the free underflow stream. A throttling valve, serving as an actuator, is installed in the overflow pipe that regulates the volume split of the cyclone. Applications in closed circuit grinding and in separation plants for tunnel driving, fine sand dewatering, and classification of kaolin demonstrate the typical use of this development. Additionally, the technological characteristics of the cyclone may be improved by this control, which is mainly caused by the increased discharge capacity of the un-der flow nozzle. A further advantage is the option to operate at an optimal operation point. In many cases, this point is located at the transition spray/rope discharge. The improved operation characteristics present new options for extensive applications of fuzzy cyclone control.

Jan 1, 2014

By Jon Huff, Jeffrey Donville, Hannah Iezzoni, Dan Stevenson

Occasionally, in the design of deep foundations for a structure, a single deep foundation element may be used to support a building column. The most common type of element used in such cases is a drilled shaft (also referred to as a drilled pier, caisson, or bored pile). However, as installation capabilities have improved, large diameter augercast piles are increasingly more common. While drilled shafts and augercast piles differ significantly in construction methods, in the eyes of the International Building Code (IBC), both are treated as cast-in-place deep foundations and must comply with many of the same code provisions. Deep foundations are required to be braced such that lateral stability is provided in all directions, however isolated, cast-in-place elements that have a diameter (D) of at least 2-feet and a length (L) not more than 12 times the diameter can be an exception. In response to the concerns raised by some member professionals, the Deep Foundations Institute’s (DFI) Augered Cast-in-Place Pile and Drilled Displacement Pile Committee took a closer look at the code and its applications, the historical development of the code language through the years and performed analytical modeling to evaluate the impact of this ratio on a pile’s stability. The question is whether the limiting ratio included in the IBC 2018 code provisions is justified, or whether different criteria should be used to determine when isolated deep foundation members are allowed.

Sep 8, 2021