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By A. Rousselet, H. Gilbert-Tremblay, A. Berton

"Robex Resources interrupted production at the Nampala Mine in September 2014 following throughput and gold recovery results which were below expectations during the first months of operation. After a thorough plant audit, an important brainstorming took place in order to identify an economical path to resume production. It was clearly identified that a significant investment was necessary at the concentrator prior to restarting the plant, namely the addition of a ball mill and a new elution system.The mineral processing simulation software USIM PAC was used in order to simulate the grinding circuit in design. The simulations’ outputs allowed the ball mill characteristics and the surrounding classification devices to be designed with more accuracy. Many ball mills available from second hand retailers were therefore studied in the simulated circuit. The chosen ball mill, which was in perfect condition, had the advantage of being available for rapid delivery on site.The paper first describes the ball mill sizing method in comparison with the conventional Allis Chalmers method. It then describes the phase 2 concentrator start-up (that took place in 2016) with the commissioning of the ball mill, the classification circuit, the gravity concentration, the four (4) new carbon-in-leach (CIL) tanks, and the Zadra elution system (The phase 1 start-up took place in 2014). It finally provides production data compared to expected simulation data, as commercial production was reached in January 2017.IntroductionDesigning a new concentrator or new equipment within an existing concentrator requires significant efforts to identify possible bottlenecks and their causes (i.e. limiting equipment or sectors) and accurate sizing of major equipment can have a tremendous impact on the economy of the whole project. In the presented case study, the ball mill was the critical equipment and oversizing it could have brought the Capex to a level where the project would not have gone through. Inversely, undersizing the mill could have resulted in lower production and therefore no economic viability for the project once it is in operation.During engineering studies, equipment sizing often relies on a static mass balance and one-by-one sizing of all pieces of equipment. The sizing is then left to the equipment manufacturer or in the case of mills, evaluated with empirical models mostly relying on the Bond equations (Allis Chalmers method) [Rowland and Kjos, 1978]. This methodology shows the disadvantage of not considering interaction between equipment in a mineral processing circuit, especially when recirculation occurs. Also, it has the disadvantage of not using the more advanced grinding models that include the use of the whole particle size distribution as well as phenomenological components by only using limited parameters in the ore particle size distribution (i.e. the P80). This can be explained by the lack of data that sometimes needs to be gathered in order to tune the more advanced models but also by the conservative mindset in mineral concentration engineering which does not always favor the use of process simulation. In many aspects of process engineering, Soutex has demonstrated its affinity to using simulation in order to size equipment with more accuracy, consider process variability, simulate complex systems, and study supply chain management (Berton et al., 2015)."

Jan 1, 2018

By D. W. Bridges, S. R. Borrowman

Thorium and yttrium oxides were recovered from siliceous ores of the Powderhorn , Colo . , area . Processing comprised ( 1 ) acid curing and subsequent ( 2 ) acid baking , ( 3 ) leaching , and ( 4) solvent extraction of thorium , using a primary alkylamine , and yttrium , using di - 2 - ethylhexyl phosphoric acid . About 95 pct of the contained thorium and yttrium was recovered from ore containing 1.2 pct Th02 and 0.5 pct Y₂ 03. The thoria product was 99 pct Tho ; the yttria product was 77 pct Y₂ 03. A 150 - to - 1 concentration ratio was effected on the latter , but some contaminating lanthanon - group oxides remained .

Jan 1, 1964

By M Berner, N A. Sifferlinger, E Fimbinger

Today, the advance rate of underground roadway development by drill and blast operation is limited by the need to ventilate the toxic blast fumes after each cycle. In deep mines this usually is only possible during shift changes when the related mine sections are free of persons. This results in roadway development advance rates of 4 m per shift, or 12 m per day. For long roadways this is a limiting factor in mining development in deep mines. Companies like EPIROC, KOMATSU, ROBBINS and SANDVIK are making serious R&D efforts to disc-cutting mobile miners to overcome this bottleneck. However, today, the achieved advance rates are less than 12 m per day in hard rock. If we achieve full robotisation and/or teleoperation from a safe place for drill and blast operation of an underground roadway development section, we could eliminate this bottleneck. Poisonous blasting fumes do not affect robots and machines as long as these fumes do not create aggressive acids. If we can keep the blast fumes isolated in the roadway development section for the shift until the next ventilation opportunity (eg shift change or designated ventilation times), we can do the drill and blast cycle more often in a shift, which will significantly speed up the advance rate. This requires robotisation of all work steps in the section: surveying, drilling, charging of explosives, blasting, loading and transporting material, roof support, installation of infrastructure etc. Also, cache storage for the material is needed. Special care for the ventilation system to keep the blasting fumes under control in the section is necessary. The paper discusses the aspects needed to achieve this robotisation and the related technical and operational tasks.

Sep 1, 2024

By J. Chupak, D. J. Salley, G. L. Simard

Radiotracers were demonstrated to be of considerable value in a study of the interaction of dithiophosphate with galena. The interaction had characteristics of both chemisorption and chemical reaction, being complex because of the nature of the galena surface. Sorption was rapid and markedly reversible, and flotation occurred at relatively small amounts of dithiophosphate sorbed.

Jan 1, 1950

By X. Chen, F. An, H. Chen, Z. Wang

The bottom drainage roadway plays a crucial role in preventing coal and gas outbursts by using underground gas drainage methods. Therefore, it is essential to select the ideal position of the bottom drainage roadway. In this paper use a combination of geological data and numerical simulation to study the ideal position of the bottom drainage roadway, we taking the gas drainage of the first workface of No. 3 coal seam in the Yuxi coal mine in China as an example. The geological study showed a limestone marker layer at an average vertical distance of 14 m from the first mining face. Using this marker layer, the bottom drainage roadway could be excavated without the risk of accidentally exposing the coal seam, and less crosscutting borehole drilling from the bottom drainage roadway would be required. Based on the needs of gas control, the layout of the bottom drainage roadway was selected as an external stagger type. Combined with the numerical simulation results, when located 20 m outside of the mining workface ‘footprint’ on the horizontal projection, the bottom drainage roadway was a sufficient distance from the stress concentration area during mining of workface 1301, which facilitated roadway maintenance. Furthermore, the length of the crosscutting boreholes is also relatively short, which reduces the amount and cost of drilling. The results of this study are expected to provide a reference for the selection of an ideal position of the bottom drainage roadway in field engineering.

May 2, 2022

By N. E. Hanna

To be approved for use in underground coal mines in the United States, explosives and blasting devices must pass certain safety tests prescribed by the Federal Bureau of Mines. These tests are described in Schedule 1-G4/ (explosives) and Schedule 26A5/ (blasting devices). An explosive or blasting device that passes the appropriate tests is placed on the active permissible list. As this list is subject to continuous revision, it has been the practice of the Bureau of Mines to publish periodically the names of explosives and blasting devices that have been added to the active list, as well as those that have been transferred to the inactive list; changes in brand names also are reported. The present circular gives all explosives and blasting devices on the active permissible list as of December 31, 1957, and shows all changes, additions, and transfers in that list between December 31, 1951,6/ and December 31, 1957.

Jan 1, 1958

By AIME AIME

APROXIMATELY one third of the world's iron ore is mined in the United States; and about 80 per cent of this third is mined in the Lake Superior ore region, and about 60 per cent in Minnesota. The Lake Superior iron ore region covers a vast area in the vicinity of Lake Superior that contained in early geological times large areas of iron-bearing sediments, which today form metamorphosed iron-bearing rocks, such as jasper, chert, taconite, and slates. Concentration of the iron content chiefly through solution and resultant removal of silica produced the ore bodies we find today in rock folds as on the Menominee range, at dike or impervious wall intersections such as on the Gogebic range, and blanket-type enriched ore bodies ly¬ing on or within the ore formation, such as occur on the Mesabi and in steeply pitching ore lenses elsewhere. In many places, folding and subsequent erosion of the tops of the folded areas has resulted in steep dips in the ore formation and contained ore bodies. The upper eroded edges are mostly buried under glacial over-burden. The slightly dipping Mesabi formation is the principal exception as to steeply dipping ore bodies.

Jan 1, 1941

By R. A. L. Black, J. E. Jennings

The problems of slope stability in open cast mines are examined. A criterion, the instantaneous stripping ratio, is suggested for use in the design of pit slopes and as an index of control at all stages of the exploitation of the orebody. This criterion may also be related to safety and to the maximizing of profits. Two approaches to safe design of slopes, one from the point of view of soil mechanics and the other from the point of view of rock mechanics, are described and critically compared. The effect on slope stability of the regional tectonic stress field is discussed. Explanation is given of the application of the Terzaghi effective stress concept to problems in both soil and rock environments, including possible effects when borehole deformation techniques are used to measure stresses in rock in situ. A company embarking on open cast mining is faced with two basic questions: 1) will the venture be profitable and 2) can it be carried out with safety? The two questions are obviously interrelated because both depend upon the slope angles adopted for the pit. The cost of open cast mining depends largely upon the stripping ratio, defined as the volume of overburden that must be removed to the volume of ore recovered. The steeper the slope angles, the more favorable the stripping ratio, but the stability of the slopes, and therefore the safety of men and materials in the pit, require that the angles be made relatively flat. Consequently, the design depends upon a compromise: the slopes must be steep enough to result in economical mining and flat enough to ensure safety. Today there is a world trend towards deeper mining by open cast methods. This is mainly due to the higher cost of underground mining and the lower cost of open excavation resulting from the introduction of large modern earth and rock-moving machinery. Deeper open cast mining has led to a very great increase in the volumes of wasted overburden, and much thought is being given to the considerable economic benefits which would result if pit slopes could be made steeper by even one or two degrees. The result has been an increasing interest in research into slope stability problems in the expectation that the application of scientific principles will provide solutions leading both to economies and to more predictable operation of the mines. In at least four places, the U.S., Australia, Western Germany and Southern Africa, comprehensive investigations are at present in progress, and it is the object of this paper to review some of the more important aspects of these programs. RELATION BETWEEN ECONOMY OF OPERATION AND SLOPE ANGLES The main object of any industrial enterprise in a free economy is to make a profit. In mining, where profits must be made from a wasting capital asset, a further definition of the profit motive is imposed, namely that the economic aim should be to maximize the total possible profit. But since profits deferred for a number of years are not as valuable as profits that are immediately available, it is usual to discount deferred profits at some rate of interest which reflects their current or present value in the hands of the investor. Thus, in mining the logical aim can be defined more closely still: to maximize the present value of the total future profits. In commercial terms the present value represents the market value of the operation as a going concern. Many factors enter into the forecast of current and future profits. They include the volume of production, the price of the salable product and the cost of production. Current profits can be estimated with reasonable accuracy by the operating engineers; but it is the task of economists and management to assess future trends in the mineral markets and in the economy as a whole, and together with the engineers, they can then estimate the future cost and profitability of the mining operations. In open cast mining, the rate of ore production once decided on remains a virtually constant factor unless a major change in the capital structure of the mine is made. But one factor over which the operator has a considerable measure of control is the ratio of the volume of ore mined to the volume of waste over-

Jan 1, 1963

By J. Forster, C. A. Pickles, Mackowiak. K.

The future development of nickel laterite deposits is crucial with regards to satisfying impending nickel demands. The commercial implementation of new hydro/pyrometallurgical processes in recent years has led to significant improvements in the extraction of nickel from the laterite ores. One potential alternative pyrometallurgical processing route would be to selectively reduce the nickel and produce a concentrate with nickel contents similar to those attainable in the conventional flotation of sulphide ores. However, even bench scale studies have not yet been able to produce a high grade (>15% nickel) concentrate from a low grade laterite ore. The present research involved the microwave vacuum reduction roasting of a nickel laterite ore to yield a high grade concentrate, rich in nickel. Firstly, the effects of temperature and pressure on the nickel grade and recovery were investigated using a thermodynamic model. Secondly, briquettes containing a mixture of charcoal and a low grade silicate nickel laterite ore were reacted in a microwave vacuum system. The experimental variables studied were the input microwave energy, pressure and absorbed microwave power. Thirdly, the ferronickel in the reacted briquette was concentrated by magnetic separation and nickel grades of up to 21% could be achieved.

Jan 1, 2015

By M. Holmes, R. Molnar, E. Norton, K. Baxter, J. Riordan

The Boleo Copper-Cobalt-Zinc-Manganese Project of Baja Mining Corp. is situated adjacent to Santa Rosalia on the Baja Peninsula of Mexico. The El Boleo ore is a mixed oxide-sulfide deposit with major values in copper, cobalt, zinc and manganese. The metallurgical process designed to treat the El Boleo orebody involves a sulfuric acid leach in seawater using oxidative and then reductive leaching to maximize metal extraction. The leach solution is separated from the barren solids via counter current washing through a series of high rate thickeners. Copper is recovered using conventional SX-EW processing as cathode. Zinc and cobalt are extracted from the copper SX raffinate after iron and aluminum precipitation. The CSIRO DSX solvent system (Versatic® 10 and LIX® 63 mixture) are used in this extraction. Manganese remains in the DSX raffinate and is recovered by soda ash addition as a high quality manganese carbonate precipitate. Zinc and cobalt are acid stripped from the loaded DSX solvent. Zinc is then re-extracted away from cobalt using Cyanex® 272 extractant and stripped into a highly concentrated strip liquor (+100 g/L Zn) and directed to either a spray dryer or a granulator for production of zinc sulfate monohydrate. The zinc solvent extraction raffinate, containing cobalt, advances to another SX circuit using Cyanex® 272, for the recovery of cobalt as cobalt cathode. In this paper, the detailed results from bench and integrated pilot plant testing for zinc recovery from the El Boleo ore will be described. The results of this testing are currently being used to engineer the commercial plant at El Boleo.

Jan 1, 2008

By James F. O'Neill

Brown iron ore deposits in Quitman County , Ga . , were investigated by the Federal Bureau of Mines in cooperation with the State of Georgia , Department of Commerce , and the University of Alabama . Ninety- one holes were drilled , having an aggregate footage of 2,188 feet ; seventy- one holes penetrated 248 feet of iron mineralization . Average thickness of the ore zone was 3.5 feet under an average thickness of 14.7 feet of overburden . The drilling developed inferred reserves containing nearly 30 million long tons of crude ore with an average analysis of 28 percent iron plus minor quantities of manganese . Test work done by the Bureau on the crude ore samples indicated that they would upgrade by current log washer practice , with the use of a 1 /8 - inch screen , and yield 4.4 million dry long tons of concentrate with an average analysis of 52.1 percent iron plus manganese . The weight recovery obtained was 14.7 percent . Research studies made by the Bureau showed that the weight recovery would be increased by changing the screen size without any appreciable sacrifice of grade . The average weight recovery was increased to 18 percent with a 10 - mesh screen and 22.8 percent with a 20 - mesh screen . Screen tests studies indicated that there was no appreciable interlocking of the iron and manganese minerals and the clay and silica waste particles of the materials retained on a 200- mesh screen . Clay was prominent in micron - size slimes . Silica was deleterious in the minus 20 - mesh size .

Jan 1, 1965

By John W. Sweeney

Shales and clays from Illinois were sampled, tested, and evaluated to determine feasibility of producing lightweight aggregate by rotary-kiln methods. Sampling procedures and the 1 ,,,y of the Pennsylvanian shale units are discussed. Chemical, X-ray spectrographic and X-ray petrographic analyses were run on the samples to determine if a correlation existed between chemical mineralogic composition and expansion. Preliminary expansion testing was conducted in a muffle furnace. Rotary-kiln tests were conducted in a 16- inch by 14-foot rotary kiln. The weight of the aggregate ranged from 27 to 59 pounds per cubic foot. Concrete cubes employing the aggregate were tested to determine the qualities of the concrete. Compressive strength of the concrete using the 7-bag of cement cement per cubic yard mix, after autoclave curing for 6 hours, ranged from 2,950 to 6,750 psi. No correlation was found between the chemical, X-ray spectrographic, and X-ray and petrographic analyses and expansion, Sixteen samples made suitable lightweight aggregates in the laboratory rotary kiln. The expansion temperature range of eight of the samples was extremely narrow, and difficulties would probably be encountered in processing these materials commercially.

Jan 1, 1965

By J. A. M. Cano

Since the beginning of operations at the pellet plant at Ponta Ubu ES, Samarco Mineração SA has produced pellets for direct reduction and blast furnace processes. Of the total amount of pellets produced from 1977 through 1993, 55% are used in the blast furnace, about 45 Mt (49.6 million st). The principal components of pellet gangue are calcium oxide, magnesium oxide, silica and alumina. They should be added in adequate quantities to guarantee the mechanical resistance of the fired pellets under blast furnace conditions. Over the years, the pellets produced by Samarco had a silica content between 2.5% and 2.8% and varying binary basicity preferably between 0.8 and 0.85. On the other hand, the increasing amount of industrial waste in siderurgical plants caused by the increase of steel production has caused some countries to put into practice methods to reduce the volume of slag produced in the blast furnace. This paper’s goal is to find an alternative for decreasing the amount of slag produced in the blast furnace. It is possible to decrease pellet gangue by decreasing the silica content to about 2%, leaving the metallurgical properties and quality of pellets unaltered. For this work, Samarco pellets were used with SiO2between 2.5% and 2.8%, pellets with high silica and pellets with SiO2 between 2.0% and 2.3% low silica. Both were partially fluxed by the range of varying basicity CaO/SiO2from 0.8 to 0.95 during production.

Jan 1, 1995

By Edward Jacobsen, Patrick J. Lydon

"The ongoing expansion of the Oak Creek Power Plant in Oak Creek, Wisc., includes a tunnel bored in rock that connects to four vertical intake shafts approximately 1.5 miles (2.4 km) offshore in Lake Michigan. In 2004, Case Foundation Company was awarded a lump sum contract to install these intake shafts. In spite of delays that shortened the May to September construction season by up to 50%, four shafts and liner assemblies were drilled in 2005 and 2006. The shafts were connected to the tunnel in 2007 by mining upward to reach the lower portion of each liner and then removing its internal bulkheads so that lake water fl owed into the tunnel. The project is one of the largest private construction projects ever undertaken in Wisconsin. The expansion adds 1,230 megawatts of generation. In addition to the tunnel and offshore work, there will be 16 miles (26 km) of railroad track and 6 million cubic yards (4,600,000 m3) of earth work. The 27 ft (8.2 m) diameter tunnel, drilled some 150 ft (46 m) below the surface of Lake Michigan, originates onshore at a pump house. A structural slurry wall was constructed as the foundation for the pump house. The tunnel passes to the south near the current water intake before bearing east toward the new offshore intake shafts, which are 12 ft (3.6 m) diameter by 108 ft (33 m) long steel liner assemblies. These were grouted in place from approximately 3 ft (1 m) above the crown of the intake tunnel and then to 20 ft (6 m) below the lake bottom.Site GeologyOffshore. The plant site is north of the Racine-Milwaukee county line in an area affected by glacial activity. The soil conditions encountered at each shaft location were consistent, with noticeable variations occurring in the top of rock elevations that sloped downward from the innermost to the outermost shaft."

Jan 1, 2008

By Ruilin Yang

Explosive blasting is a widely used method for rock breaking, recognized for its energy efficiency and cost-effectiveness. Despite its advantages, the efficiency of blast energy can vary significantly between different blasts. This paper introduces a new blast efficiency index to assess the energy efficiency of rock blasting, incorporating factors such as explosive consumption, the energy required for fragment surface generation (based on fragment size distribution), and the strength reduction of rock fragments due to blasting. Several examples presented in this paper demonstrate the calculation of the blast efficiency index using data from the literature. The findings indicate that blasting may be the most efficient method for rock breaking compared with direct mechanical techniques of rock breaking used for excavation. On the other hand, blasting is much less efficient compared with the controlled fracturing, such as the cleavage and fracture toughness testing, which highlights the significant potential to further enhance the efficiency of explosive energy usage for rock fragmentation during blasting. The proposed blast efficiency index can be integrated with advanced blast modeling techniques to optimize blast designs, thereby increasing the effective utilization of explosive energy for rock fragmentation and fragment strength reduction.

Jan 26, 2026

By Thomas M. Barczak

A survey of the longwall industry was conducted to examine the performance of modern shield technology. The results of this survey indicate that state-of-the-art shields perform better and last longer than ever before, but premature failures do still occur. In addition, longwalI operators are now using shields longer than ever before and a greater number of fatigue related failures on aging shields are now occurring. A generic assessment of these shield failures is provided, describing the nature of the failures and how widespread they are throughout the industry. An engineering assessment of shield design and factors that cause shield failures is made using both strength of materials and fracture mechanics principles. From this analysis, design practices to improve structural margins of safety and extend the life of the shield are proposed. The existence of unexpected shield failures indicate that current shield performance testing is at times inadequate. Recommendations are made relative to improved shield performance testing protocols including the benefits of testing in an active load frame such as the National Institute for Occupational Safety and Health's (NIOSH) Mine Roof Simulator. Even the most rigorous shield testing procedures, which strive to simulate in-service loading conditions, fail to consider key environmental issues, such as corrosion which is often the cause of structural fatigue failures in modern shields. The survey also indicated that hydraulic failures occur much sooner in the life cycle of a shield than structural failures, and although they can significantly degrade support capability, often go undetected for long periods of time. Methods to detect the hydraulic failures are also provided. The paper concludes with key points to maximizing shield design and life expectancy and ideas for future generation shield designs.

Jan 1, 1999

By Willy Ank de Morais

Pontos estratégicos de solos foram analisados com o objetivo de estudar a possível contaminação de água pluvial, por difusividade, mantidas em reservatórios existentes na Ilha dos Arvoredos, localizada no Guarujá, litoral de São Paulo, Brasil. Iniciou-se o procedimento com a preparação das amostras (homogeneização e quarteamento), seguida das análises físicas (granulometria e umidade). A caracterização foi realizada por espectrometria de fluorescência de Raio-X e por espectrometria de absorção atômica. As concentrações de enxofre foram quantificadas por forno de combustão e as cinzas e matéria volátil por TGA (Analisador Termogravimétrico). As análises realizadas em Raio –X mostraram composição química de solo argiloso com altas concentrações de SiO2 e Al2O3 e as realizadas no equipamento de combustão mostraram concentrações de enxofre menores que 0,03%. Os resultados se apresentaram negativos para metais pesados ou outro tipo de elemento que poderia comprometer a potabilidade das águas contidas nos reservatórios.

Oct 30, 2017

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By V. Aghazadeh, E. Bidari, M. Aazami

In this study, mineralogical and microanalysis characterization, as well as diagnostic leaching and cyanidation tests, were performed to gain a better understanding of the refractory nature of the arsenical zone of a Carlin-type gold deposit and also to evaluate possible treatment routes to maximize gold recovery. The results obtained showed that only 56% of the ore’s gold content is amenable to direct cyanidation. The majority of the remaining gold was found as submicroscopic gold and in association with sulfide minerals, such as orpiment, pyrite, and sphalerite. It was also found that despite the abundance of silicate and carbonate minerals in the arsenical zone, they do not play a key role in the refractory nature of the ore, and gold can be liberated from such minerals by appropriate grinding. The analyses further revealed that orpiment dissolves readily during cyanidation, and this dissolution retards the kinetics of gold extraction. Pyrite and sphalerite were generally found to occur in fine network texture and in association with quartz. Flotation of such auriferous sulfides may be difficult due to their oxidized surface. Fine grinding (−20 μm) was found to be partially effective in improving gold extraction.

May 28, 2020

By Djona M. Gaballah I.

Selective chlorination of unroasted and roasted spent hydrorefming catalysts was studied between 300 and 600°C using the following gas mixtures : C12+CO, C12+N2 and CI2+air. Such materials contain Co, Ni and Mo compounds supported by alumina and/ or silica. They also contain variable amounts of V compounds, C, S, etc., accumulated during the life time of the catalyst. Direct oxychlorination of the C+S rich sample allows higher extraction rates than those obtained by the carbochlorination of the same roasted one. It seems that the roasting step doesn't favor the economic metals' recovery. Results of the chlorination of C+S poor spent catalysts, in the presence of CO, in the chlorinating gas mixture, or of carbon added to the sample, were comparable. Cobalt and nickel chlorides were .extracted from the chlorination residues by their dissolution with acidified water, whereas molybdenum and vanadium chlorinated compounds were recovered by selective condensation from the vapor phase. The recovery rates of valuable metals as well as the selectivity were higher for the chlorination of spent catalysts than results obtained by the hydrometallurgical processing of the same sample. Results of the scale-up of the oxychlorination of the unroasted sample confirmed those of the laboratory scale. The global recovery rates were about 88 pct of cobalt, 93 pct of molybdenum and 76 pct of vanadium. The carbochlorination was applied to the recovery of W and Ti from Denox catalyst that is a carbon and sulfur free one. Recovery rates higher than 99 pct at temperatures lower than 500 °C could be obtained. This may indicate that the chlorination process can be applied to the treatment of various industrial wastes or by-product containing transition and/or refractory metal compounds A flow - sheet for the pretreatment of these materials is proposed.

Jan 1, 1995