Search Documents

By H. Braun, T. Kind, K. Gloe, D. B. Dreisinger, H. Stephan, O. Heitzsch, G. A. Kordosky

Municipal garbage incineration processes with coupled wet flue gas cleaning systems generate effluents containing toxic heavy metals such as mercury, zinc, cadmium and copper. The separation of these metal ions from the obtained scrubbing solutions is possible using liquid-liquid extraction. Extraction studies has been performed both with commercial extractants Aliquat 336, di(2-ethylhexyl) phosphoric acid and novel chelating agents as acyl thiourea and lipophilic oxathiaaza alkanes. Advantages and disadvantages of the investigated extraction systems are discussed. The paper reports on the basic research as well as on the testing in a laboratory scale.

Jan 1, 1993

By A. G. Journel

The indicator random function formalism allows a common coding of hard numerical data, constraint intervals, and soft qualitative information as prior probability distributions. The soft kriging algorithm allows interpolating these priors into posterior probability distributions of the unknown. The curse of ?negative kriged grades? is solved. The consideration of additional soft information, whenever deemed necessary, becomes possible within the framework of well-proven kriging techniques.

Jan 1, 1986

By Ricardo Gomez, C. T. Ogryzlo, A. A. Dor

This paper reviews the historical background leading to the development of the project. It gives a description of the exploration program and resulting geological and ore reserve information together with plans for mining. A discussion is included of the three processes investigated for the project: 1. Rotary Hearth and Magnetic Concentration 2. Shaft Furnace and Electric Furnace 3. Rotary Kiln and Electric Furnace Results of pilot plant campaigns conducted at Fiskaa, Norway, and Riddle, Oregon, on the process chosen for the production of ferronickel are presented. The paper continues with a review of the considerations involved in selection of commercial plant equipment and concludes with comments on the current status of the project.

Jan 1, 1979

By Paul C. Lingo

Two recent antitrust cases, coming from widely separated areas, different industries and involving wholly different facts were decided by the Supreme Court on June 7, 1965. The decisions in these two cases may well prove to be the most important and far-reaching decisions in the field of labor law that have been handed down in the last 24 years. These cases, although quite dissimilar factually, had one common element. In both, the gravamen of the antitrust violation was bottomed on the terms of labor agreements negotiated by a multiemployer group. These cases are usually referred to as Pennington1 and Jewel Teat. Since a number.-of references will be made to the antitrust laws, it may be well to state briefly the applicable portions. Section I of the Sherman Antitrust Act makes "every contract, combination in the form of trust or otherwise, or conspiracy, in restraint of trade or commerce among the several states, or with foreign nations, is declared to be illegal...". Section 2 imposes criminal sanctions against "Every person who shall monopolize, or attempt to monopolize, or combine or conspire with any other person or persons, to monopolize any part of the trade or commerce among the several states...". Under Section 4 of the Clayton Act a person who sustains damages as a result of a violation of the antitrust laws is entitled to recover treble damages plus costs.

Jan 1, 1965

By J. F. Stenebråten, W. P. Johnson

Carbonaceous material (CM) from the Barrick Goldstrike Mines, NV, was characterized with respect to its gold sorption (preg-robbing) and gold recovery behavior. The breadth of graphite peaks measured by X-ray diffraction were used to calculate crystallite dimensions (002) of the CM. The (002) dimension was found to vary inversely with preg-robbing activity and directly with gold-recovery behavior, indicating that the degree of graphitization (maturation) experienced by the carbonaceous material is correlated with gold-loss during ore processing. The inverse correlation of preg-robbing activity was improved when percent preg-robbing was regressed against (002) crystallite size and carbon content. The (101) crystallite dimensions of all samples were calculated from laser Raman analysis, and were not found to correlate with preg-robbing behavior of the CM. BET surface area and micropore size distribution results were affected by grinding history, negating comparison of these characteristics between samples.

Jan 1, 2000

By Huijun Shao, Qiang Liu, Zhengming Yi

The increase of the proportion of high Al2O3 content iron ore fine in iron and steel enterprises has brought about a series of problems such as the increase of the viscosity of blast furnace slag and the difficulty of the separation of slag and iron. In order to solve this problem, the effect of increasing MgO content on the technical and economic index, the cold strength, and metallurgical properties of high basicity and high-alumina sinter was studied through sinter pot test. Nova400NanoSEM field emission scanning electron microscope was used to analyze sinter microstructure. The experimental results show that when the MgO content fraction in the sinter with high basicity and high aluminum increases from 1.72 to 2.49%, the vertical sintering speed decreases by 4.38mm/min, the utilization coefficient decreases by 0.51t/(m2 h), and the low-temperature reduction degradation index increases by 6.7%. When MgO content in sinter is 2.11%, drum index and reducibility index are the highest, reaching 61.93% and 86.39% respectively. Mg2+ is mainly solid dissolved in the magnetite lattice and replaces Fe2+, up to 3.64%. The generated magnesie-containing magnetite inhibits the phase transition from Fe3O4 to Fe2O3 oxidation process in the sinter cooling process, which reduces the generation of secondary hematite and is conducive to improving the low-temperature reduction degradation performance of sinter.

Jul 4, 2021

By S. J. Lefond

Most people, when Borates are mentioned, mentally visualize the famous twenty mule team (really eighteen mules and two horses), trudging across the Mojave Desert or "she burns green Rosie, we are rich." Actually, however, the first use of borax was prior to Babylonian times. Their emissaries had orders to bring borax Iron the Gobi desert for use as a flux by the Babylonian goldsmiths. The borate mineral imported for this is not known but probably was borax. The ancient Persians and Arabians knew about borax and the Arabic word "Baurach" appears in a two thousand year old manuscript. The Sanscrit word for borax was tincana which has been corrupted to tincal. The Chinese were using borax as a glaze in three-hundred B.C. Marco Polo brought the first borax, along with gunpowder and spaghetti, from Mongolia to Europe in the late 1300's. Borax from Tibet was imported to Europe for nearly 500 years. In 1772 boric acid (sassolite) was discovered around Tuscany, Italy as a precipitant from volcanic steam vents. Production of boric acid started there about 1815 and provided the sole competition to the borax from Tibet. Borate deposits in Turkey have been known and exploited on a small scale since the 13th century. It is only recently that the operations are being modernized and production increased. About 1836, borax minerals were found in Chile and Argentina with borax production starting in 1852 in Chile and in Argentina in 1886. During the latter half of the 19th Century, Chile was the principle world producer of borax.

Jan 1, 1980

By Nicola Della Valle

The Singapore Land Transport Authority (LTA) is currently expanding capacity by extending their Metro system from South of the city to the North East end of the island. The scope of Contract 704 involved excavating a long reach of tunnel which had a complex rock/soil interface comprised of fresh granite overlaid by clayey sand. Two 6.5 m diameter Earth Pressure Balance (EPB) TBM’s were used to bore the tunnels. These machines were designed so that both hard and soft rock could be excavated. The cutter head was equipped with a combination of both rippers and disk cutters. Soil conditioning was achieved by delivering foam through a multiple port injection system. This very irregular profile of the interfaces posed many challenges to the equipment and the people.

Jan 1, 2001

By R. Canello, J. Jenkins

El Abra has the world's largest leach, solvent extraction and electrowinning facility, The crushing plant capacity is 120,000 metric tonnes per day and the cathode production capacity is 225,000 metric tonnes per year. The El Abra mine and plant are located in the Province of El Loa, in Region I1 of Chile, 55 km. north of the city of Calama. The ore deposit outcrops on the southern slope of Cerro Pajonal at an altitude of 3,900 to 4,100 meters above sea level. The processing plant and camp facilities are located at a lower 3,300 meter elevation on an alluvial slope, 15 km southeast of the deposit. The operating company, Sociedad Contractual Minera El Abra, is 51% owned by Cyprus Arnax Minerals Company through the Cyprus Climax Metals Company subsidiary and 49% owned by Corporaci6n Nacional del Cobre de Chile (Codelco). The present paper describes the ore reserves, mine operations, crushing, leaching, solvent extraction, electrowinning and infrastructure facilities.

Jan 1, 1998

By P. F. Ziemkiewicz, A. S. Knox

Large-scale use of CCBs in mine environments involves filling surface and underground coal mines with ash to address hydraulic problems, AMD, backfilling and subsidence. The environmental risk of land filling CCBs is generally evaluated by the Toxic Characteristics Leaching Procedure (TCLP) or the Synthetic Precipitation Leaching Procedure (SPLP). However, there is doubt regarding the applicability of these tests to long-term CCBs leaching behavior in groundwater associated with coal mines. The Mine Water Leaching Procedure (MWLP) was developed to provide a site specific risk assessment tool. The MWL Pprocedure is presented in this paper and compared with TCLP as a study.

Jan 1, 2003

By H. -S. Yoon, C. -J. Kim, K. W. Chung

"With the final goal of ultrasonic application to ion exchange in a resin-in-pulp (RIP) system, the feasibility of an indirect ultrasonic application with a submersed ultrasonic probe was investigated first for the enhancement of ion exchange in the following resin-in-solution (RIS) system: Lewatit MonoPlus MP 600XL in an artificial solution with 106 ppm uranium. Ultrasonic radiation enhanced the ion exchange efficiency without mechanical degradation of resin. For 3.6 g/L of resin, the enhancement was 79 percent after 10 min of ion exchange and it gradually decreased to 11 percent at 60 min. In addition, a preliminary test of the mechanical stability of the resin in the RIP system showed little mechanical fracture of the resin due to ultrasound, which indicates that indirect ultrasonic application by a submersed ultrasonic probe is applicable for RIP systems. IntroductionIn uranium ore processing, the ion exchange process has been used on a commercial scale for preconcentration and purification (Gonzalez-Luque and Streat, 1984). The ion exchange process is divided into two processes: (1) a resin-in-column process with the uranium-bearing solutions passed through columns containing resins and (2) a resin-in-pulp (RIP) process with the leached ore pulp exposed to resins. The latter does not require the separation process of leach liquor and ore solids, which reduces process costs. This process, which has been developed commercially since 1955, has a certain drawback. The adsorption rate and efficiency in the RIP process are relatively low, so numerous contacts between resins and leached ore pulp are needed, which adds to the cost (Merritt, 1971). It is necessary to study methods to reduce process costs.Ultrasound can intensify mass transfer, increase the rate of chemical reactions, and change reaction pathways (Thompson and Doraiswamy, 1999; Luque de Castro and Priego-Capotem, 2007; Adewuyi, 2001; Luque-Garcia and Luque de Castro, 2003). It has great potential in chemistry and is especially considered to be a promising method for enhancing mass-transfer-limited processes, such as ion exchange. Enterzari and Tahmasbi (2009) reported the effect of ultrasound on water softening by ion exchange. Band et al. (1997) proposed a modulated ultrasound application to water desalination with ion-exchange hollow fibers. These reports revealed that ion exchange kinetics could be enhanced by the application of ultrasound. As for hydrometallurgy, Feng and Aldrich (2000) reported that the elution of an ion exchange resin was enhanced by the use of ultrasonication."

Jan 1, 2015

By S. N. McIntosh

Column bioleaching was evaluated by the U.S. Bureau of Mines as a means of recovering manganese from a low-grade ore from the Three Kids deposit in Southern Nevada. Manganese was solubilized from the ore using indigenous heterotrophic microorganisms. Diluted molasses medium was provided as nutrient for the microorganisms. The medium was recirculated through the ore bed until the sugars were spent. Two methods were evaluated to recover manganese from the sugar depleted bioleaching solution: (1) adsorption with a weak cation exchange resin followed by stripping and precipitation techniques, and (2) direct precipitation of the manganese using ammonium carbonate. Both methods removed up to 95 pct of the solubilized manganese from the medium as a carbonate salt. After manganese removal, the medium was replenished with fresh molasses and recycled back through the column. More manganese was effectively leached. This process of manganese solubilization and recovery followed by replenishment and recycling of the medium was repeated until 98 pct manganese was extracted from the ore.

Jan 1, 1993

Application of flotation for the removal of hydrophobic compounds from soils was studied. Bench scale flotation tests were conducted on artificially contaminated soil, using both conventional mechanically agitated machine and flotation column. Flotation parameters tested include surfactant collector type, conditioning time, flotation time, surfactant dosage, pulp pH, solid/liquid ratio in conditioning and pulp temperature. It is found that with conventional flotation 74% removal of the contaminant was achieved from soil particles in the range of 75-830 µm; with column flotation up to 80% of oil could be removed from the 250-830 µm soil fraction, and 65% from the 75-830 µm fraction. Flotation was found to have considerable potential for cleaning up contaminated soils.

Jan 1, 1998

By James J. Brady, Kenneth L. Faught, Chadi El Mohtar, Chaoshi Hu

"During construction of a 9.5-ft. diameter sanitary sewer tunnel, the City of Edmonton encountered a large pocket of flowing sand that flooded their TBM and caused significant surface subsidence, stopping further tunneling by the TBM through this zone. A unique collaborative effort ensued between the authors representing the city, consulting engineers and academic researchers to develop the optimal strategy for grouting the problematic soils. The site has a layer of very find sand between 20 and 30 ft. in depth with fines contents ranging from 5% to more than 40%. The collaboration extended from requesting additional site investigation efforts to shipping samples to the UT-Austin laboratories for grout testing plus ground and grouting characterization tests resulting in field recommendations for a full scale ground improvement program. New research information on the grouting of fine sands along with a collaborative framework for the design of in-situ grouting projects are the key topics presented. INTRODUCTION Encountering a large unexpected pocket of flowing sand with an open-faced TBM while excavating a tunnel below the groundwater table is never a good thing. This was certainly true for the City of Edmonton when one of their Lovat TBM’s became inundated by flowing sand while excavating the 9.5-ft. diameter Millwoods Double Barrel Replacement Tunnel in September 2013. However, since the City of Edmonton self-performed this work, a rare situation existed where the site could be investigated objectively, without the prejudice of contending parties selectively influencing how information was gathered and presented, to accurately examine site conditions with a goal of identifying the best remediation measures."

Jan 1, 2016

By Paul F. Richardson

Liquids containing suspended solids are encountered in most mineral processing applications. Solids levels cover a very wide range, from ppm levels in cooling water systems to slurries containing greater than 70% solids. When the aqueous phase is recycled or further processed, a solid/liquid separation process is used. Chemical additives used to carry out this process are called coagulants and flocculants. In other cases, one seeks to control or modify the properties of the suspension. Dispersants are chemicals used to aid in suspending solids in a liquid as well as to control the properties of the resulting suspension. Dispersants find a range of uses in mining and mineral processing such as scale control, filter aids, flotation aids, and slurry viscosity modification. Materials used as dispersants include inorganic salts, alkalies, organic surfactants, and polyelectrolytes. This paper discusses the use of dispersants in mineral processing, with an emphasis on control of slurry viscosity. The mechanism of dispersion and factors that affect the choice of dispersant will be discussed.

Jan 1, 1986

By Sandip K. Mukherjee

In underground mining operations, ventilation and water sprays are the common methods of controlling dust. In recent years there has been a proliferation of technical literature dealing with water sprays for dust control. However, guidelines for the design of an effective water spray system have not been presented to the mining industry. This paper reviews developments in water spray dust control technology and recommends guidelines for water spray systems to control dust in under- ground coal and non-coal mining operations. These guidelines suggest type, number, location and orientation of nozzles, desirable operating water pressure, and associated filtration system.

Jan 1, 1983

By Baojie Zhang

The main goal of this study was not only to investigate the effectiveness of the FGX Dry Separator for removing pure rock from run-of-mine coal producing a better feed stock for conventional coal preparation plants but also to optimize the FGX Dry Separator performance for producing a salable clean coal product without using the conventional wet coal preparation processes. A Model FGX-1 Dry Separator with feed throughput capacity of 10 tph was extensively tested at the Illinois Coal Development Park using two coal samples having distinctly different cleaning characteristics. Statistically designed experimental programs were conducted to indentify critical process variables and optimize FGX Dry Separator performance by systematic adjustments of critical process variable parameters. The coal cleaning performance of the FGX Dry Separator was evaluated for the particle size range of 63.5 x 4.76 mm in most cases, although FGX Dry Separator feed consisted of nominal -63.5 mm run-of-mine coals. The best cleaning performance obtained from the FGX Dry Separator is described by specific gravity of separation (SG50) and probable error (Ep) values of 1.98 and 0.17, respectively. The SG50 and Ep values for individual size fractions were as follow: 1.90 and 0.12 for the +50.8 mm size fraction, 1.95 and 0.18 for the 50.8 x 25.4 mm size fraction, 2.01 and 0.19 for the 25.4 x 12.7 mm size fraction, and 2.03 and 0.23 for the 12.7 x 4.76 mm size fraction. These process efficiency measures produced a clean coal with ash content of 13.38% from a feed coal with ash content of 34.45%. Ash content of tailings and middlings streams were 85.09% and 39.57%, respectively. Total sulfur contents of corresponding streams were 3.87%, 4.68%, 6.87%, and 4.62%. For a relatively easy to clean Illinois No 6 seam coal (Cleaning Index: 0.72), only about 0.42% of the clean coal (i.e., 1.6 float fraction) present in the feed was lost to the tailings stream. For a relatively difficult to clean coal (Cleaning Index: 0.53), about 0.98% of the clean coal present in the feed was lost to the tailings stream.

Jan 1, 2012

By David A. Summers

In May 1975 the U. S. Bureau of Mines contracted with the University of Missouri-Rolla, Rock Mechanics and Explosives Research Center to develop a Hydrominer modification to a long-wall shearer unit, wherein the rotating pick-laced drums and connecting gear drives are replaced by a water jet cutting head.1 The concept of the water jet cutting head is based on using the high localized energy of the water jets to isolate a slice of coal by cutting a slot under, at the back of, and at the top of the web. The plow blade of the head then advances into the cut and wedges the pillar over onto the conveyor (Figure 1). There were several potential advantages foreseen for the system of which perhaps the most significant were the elimination of coal dust from the working area2 and the ability, with a variation in nozzle geometry, to cut webs of greater depth with a small increase in equipment horsepower. The University initially designed the head, based on experiments carried out in the laboratory, under an earlier Bureau of mines contract. The experiments showed that it was more advantageous to work at a pressure of 10,000 psi with an estimated flow rate of 50 gpm than go to the higher pressures and lower flow rates which have been advocated elsewhere.

Jan 1, 1977

By Charles H. Jacoby

The economic importance of salt domes has been recognized throughout the world primarily because of oil and gas accumulations on their flanks and, to a lesser degree, for the value of their salt and potash. Recently they have become of value as hosts for cavities used to store hydrocarbons. In the near future we believe that their main value will be as a source of geothermal energy. Although tremendous effort has been expended on the understanding of the geology and physical characteristics of the strata intruded by salt domes, relatively little energy has been exerted in the comprehension of the salt dome itself. Salt domes have long been recognized as a geological heat anomaly. With respect to other sedimentary rocks, salt is a good conductor of heat. Expressing values in 10-3 cgs units, sedimentary rocks vary from 1.0 to 8.0; metamorphic rocks from 5.2 to 8.4 and igneous rocks from 3.1 to 9.8. Rock salt in its pure form has a thermal conductivity of 17. (Gussow, 1970). Thus a salt dome (Fig. Ml) can be expected to act as a conduit bringing heat vertically from deep within the Earth's crust. This was, in part, substantiated when in 1958 a horizontal core hole was drilled from within the Avery Island Mine at the 500 foot level. The horizontal hole was started where the ambient temperature of the salt was 74° F. and drilled toward the center of the dome. At the end of this 2,000 foot hole the temperature was 90° F. thus depicting a horizontal temperature gradient of 7° F./1,000 feet. Because this core hole penetrated a shear zone connate water that appeared as a "cold spot" on the temperature gradient, the foregoing data can only be regarded as indicative.

Jan 1, 1974

By J. S. Roti

Calcium-based scale precipitation is a common problem in mill reclaim waters. An accumulation of these adherent deposits can result in a rapid reduction in water flow, loss of pump efficiency and eventual interruption in ore production. Heap leach applications can also experience the added problems of plugged sprinkler heads, blinded leach pads and fouled carbon columns when scale control is not maintained. The primary cause of scaling in precious metal recovery is the relative insolubility of calcium carbonate. The presence of the calcium ion and bicarbonate alkalinity is common in almost every water source. If the temperature or pH of the water is allowed to increase, the bicarbonate breaks down to carbonate and combines with calcium by the following reaction: Ca +2 +2HCO3 ? CaCO3 + H2 + CO2

Jan 1, 1986