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By N. Edmonson

Frasch sulfur production/pricing decisions are based on market demand, less nondiscretionary sulfur supply. Price covers the cost of Frasch production and byproduct sellers accept the Frasch price structure. Large stocks have led Canadian byproduct producers to price aggressively at times, but their near-term drawdown suggests more passive price policies in the 1990s. Expanding continental nondiscretionary supply is combining with sizable Frasch supply increments to weaken prices. Simulations using a market model embodying these structural characteristics indicate that expanding demand may not result in substantial recovery from 1992 price lows before 1996.

Jan 1, 1995

By D. G. Fredlund, J. A. Wilson

Conventional disposal of waste rock results in the construction of benches with fine and coarse layers dipping at the angle of repose. This interbedded structure influences flow pathways within the waste rock. A numerical modeling program was conducted to study a four-layer system consisting of alternating fine and coarse waste rock. The system was inclined from the vertical to forty-five degrees with heights varying from one to twenty meters. The results show the effects of gravity as preferential flow developed under unsaturated flow conditions.

Jan 1, 2000

By R. L. Pozzo, A. S. Malicsi, I. Iwasaki

The electrochemical nature of mineral-grinding media interaction in the wet grinding of one and two sulfide mineral ores was investigated with regard to the flotation behaviors of the minerals. Two iron sulfides (pyrite and pyrrhorite) and mild steel were used to represent the sulfide minerals and the grinding media, respectively. Galvanic currents in two- and three-electrode combinations under abrasive and non abrasive conditions were correlated with the floatabilities of these minerals under corresponding conditions.

Jan 1, 1991

By Hassan El-Shall, Abbas A. Zaman, Brij M. Moudgil

The addition of organic and inorganic dispersants to aqueous suspensions of heterogeneous particles (kaolin) was found to significantly affect the solubility of metal ions from kaolin particles and stability of the dispersion. In most of the industrial applications of kaolin, highly concentrated slurries of controlled stability and fluidity are required. The solubility of kaolin particles in terms of aluminum and silicon ions and its effect on the stability of the slurry was investigated. The main objectives of this study were (1) to study the effect of the extracted metals on the properties and performance of the slurry, (2) to understand the reaction mechanism of dissolution of metals from kaolin, and (3) to understand the interaction mechanism of dispersants with kaolin particles. The controlling variables were dispersant dosage, slurry pH, solids loading, and aging.

Jan 1, 2003

By F. M. Doyle

Metal removal kinetics and metal ion selectivity in ion flotation were studied from a thermodynamic perspective. Surface tension data could be used with the Gibbs adsorption equation to quantitatively predict the metal-ion removal kinetics in alkylsulfate-Cu systems. However, surface tensions predicted cation selectivity coefficients in the sodium dodecylsulfate (SDS)-Cu-Ca and SDS-Cu-Pb systems rather poorly, although the predicted order of the selectivity (Cu2+ < Ca2+ < Pb2+) was correct. Another thermodynamic selectivity model, which used the Grahame adsorption equation and a geometrical analysis, predicted cation selectivity coefficients that agreed very well with experimentally measured values.

Jan 1, 2002

By L. S. Leal Filho, L. A. F. Barros, S. M. Assis

Zeta potential determinations and microflotation tests (with starch, sodium oleate and flotigan EDA-B) versus pH, pCa and pMg were performed with apatite and typical silicate minerals that occur in Brazilian phosphate ores: schorlomite, diopside, quartz and micas. Unlike quartz and micas, schorlomite and diopside were depressed by cornstarch during anionic flotation with sodium oleate (pH 1 9). The selectivity of the separation apatite/quartz and apatite/micas by flotation with sodium oleate was adversely affected by the presence of calcium (pCa) and magnesium (pMg) in flotation pulp. Solubility/cation exchange capacity of micas is an important source of dissolved calcium and magnesium in the system.

Jan 1, 2002

By Kathleen S. Smith, Katherine Walton-Day, James F. Ranville

Four different scales of observation were used to evaluate the potential effects of a fluvial tailings deposit on water quality along the flood plain of the upper Arkansas River south of Leadville, Colorado. First, we collected surficial material and subjected it to batch water-leaching test. Second, we excavated and leached an intact eight-inch diameter core. Third, we examined the water quality of the shallow ground water beneath the fluvial tailings deposit, and fourth, we monitored water quality along a 5-km reach of the adjacent Arkansas River. Leaching of surficial samples indicates that there is a reservoir of readily water-soluble material yielding elevated metal concentrations and high acidity. However, there are minimal measurable water quality effects of the fluvial tailings deposit on the adjacent reach of the Arkansas River.

Jan 1, 2000

By J. J. Carlson

Studies were carried out to determine whether filtration rate changes observed in an iron ore concentrator were due to variations in particle shape. It was confirmed that ores mined from different locations differed in filtration rates by as much as 60%. However, when image analysis was used to quantify the shapes of the individual particles in the filtration feed, it was found that the particle shapes showed almost no variation, and the shapes did not correlate with the filtration rate. It was also determined that the filtration rate variations were not caused by changes in particle size distribution. These results suggest that the differences in filtration rate are due to factors other than size and shape, such as surface chemistry.

Jan 1, 2008

By Cynthia S. A. Wallace, Joseph E. Crawford

The Culberson ore body is a bioepigenetic sulfur deposit located in the Delaware basin. Sulfur occurs in the Upper Permian Castile, Salado and Rustler Formations. Most of the ore body forms a subhorizontal layer within the Salado Formation. Abundant cave fill deposits of Rustler and younger lithologies occur within the Salado Formation and predate mineralization. The cave fill deposits provided porosity zones within the otherwise impermeable sulfate host rock and controlled sites of mineralization. A northeast trending fracture zone near the west edge of the ore body localized some deep mineralization and may have allowed migration of hydrocarbons from depth.

Jan 1, 1992

By D. W. Fuerstenau, J. Vazquez-Favela

This paper shows how the efficiencies of size-reduction processes depend on the mode of particle constraint and energy transfer within the comminution device: namely, whether the process consists of single-particle loading, confined-particle-bed comminution or loose- (unconstrained-) particle grinding. The relative efficiency of single-particle comminution, ball-mill grinding and particle-bed comminution in the recently invented high-pressure roll mill is evaluated by making use of the self-preserving nature of the size distributions of comminuted products. The highest energy efficiency can be achieved by utilizing a hybrid two-stage system in which the material is first ground in the high-pressure roll mill and then the ball mill.

Jan 1, 1998

By Sukumar Bandopadhyay

In recent years planning of surface mines in general and reclamation and post-mining land uses in particular have become very complex. Due to the lack of suitable techniques, land use plans are rarely based upon structured decisions. Data collection may be conducted in a rigorous manner and certain analyses may be performed on the data; the decision to put the land to a specific use, however, is finally based upon the intuitive judgment of one or several individuals. This paper demonstrates how techniques from fuzzy set theory can be used in order to select an optimum post-mining land use plan. The various land use planning alternatives have been characterized according to both qualitative information and quantitative factors and the "fuzzy" aspects of the collected information are incorporated into the analyses. In a practical application, the methodology is used to obtain the most reasonable solution to a post-mining land use planning problem in Interior Alaska.

Jan 1, 1986

By C. P. Lazzara, F. J. Perzak, C. C. Hwang, C. D. Litton

Fire development and spread along conveyor belts in ventilated ducts were investigated experimentally and theoretically. Various types of conveyor belts used in mining applications were ignited and burned in a full-scale gallery under various flow conditions. The flame spread rates depended strongly on the ventilation air speed. The time-temperature traces of gas and belt obtained at 12 feet from the entrance show that a rapid belt surface temperature change takes place prior to a change in the gas temperature, indicating that radiative heat transfer from the flame to the belt surface plays an important role. Further, anomalies in the flame spread rate in the vicinity of 1.5 m/s air speed (i.e., much greater rate than that observed at either higher or lower speeds) can be explained through the mechanism of flame tilt and the resultant view factor between the flame surface and the belt surface. In order to correlate the fire spread with material properties of the conveyor belts (such as the specific heat, the thermal conductivity, and the pyrolysis temperature) and the fire environment (such as the gas temperature and the ventilation air speed), a theoretical model has been developed. This model is based on the experimental observation that the radiative heat transfer is the dominant mode of energy transfer ahead of the flame front. Agreement between the theory and the experimental results is good.

Jan 1, 1991

By Gregory A. Hope, Kym Watling, Matthew I. Jeffrey, Ronald Woods

Surface enhanced Raman Spectroscopy carried out in real time has been applied to identify surface species formed during gold leaching in chloride and thiosulfate media. Chloride ion is adsorbed prior to the gold dissolution potential, but its coverage is significantly diminished at the beginning of leaching. A gold chloride band is again observed when dissolution is rapid, together with bands characteristic of AuC14- ions in solution. With thiosulfate, a thin gold sulfide layer is formed slowly in the potential region where leaching occurs. At higher potentials, thiosulfate is oxidized to sulfur and sulfate, both products being identified by Raman spectroscopy.

Jan 1, 2005

By D. R. Lowe

Silicic volcanic ash and its alteration product, bentonite (montmorillonite and cristobalite), occur widely within sedimentary phosphate deposits. The genetic link, if any, between volcanism and phosphate deposition has yet to be satisfactorily established The phosphatic member of the Santa Margarita Formation (upper Miocene) in northwestern Ventura County, California, consists of approximately 15 per cent volcanic ash and bentonite. Ash and bentonite units greater than one foot thick can be subdivided into a lower zone of airfall origin and an upper zone of mixed ash and terrigenous detritus washed in from surrounding land areas. This upper zone also contains up to 20 percent phosphate pellets. These thick volcaniclastic units are typically overlain sharply by thin beds (less than 6 inches thick) of relatively pure, silica-cemented pelletal phosphorite. The shelf basin in which the phosphatic sediments accumulated was characterized by quiet, reducing but not euxenic bottom waters; Abundant decaying organic debris, mainly diatoms, served as a reservoir of readily available phosphate. The sudden influx of a large volume of silicic volcanic ash into this basin and its subsequent alteration to montmorillonite had two profound effects on thechemistry of the interstitial and bottom waters: (1) during alteration magnesium was removed from these waters and incorporated into the montmorillonite lattice, and (2) the pH of these waters increased as alteration progressed Both of these effects led to the crystallization in the bottom waters of carbonate fluorapatite. This accumulated as thin phosphorite beds immediately above the volcaniclastic units.

Jan 1, 1972

By John L. Stauffer, Allan Lipton, Kim Leitzel, Lesley Gaydos, Laurence M. Demers, Douglas C. Kuhn

Eicosanoids and cytokines produced by the alveolar macrophage (AM) are key mediators of pulmonary inflammation and fibrosis resulting from occupational exposure to mineral dust. In order to determine if eicosanoid and cytokine production are altered by chronic inhalation of coal dust, we compared the production of prostaglandin E2 (PGE2), thromboxane A2 (TxA2), leukotriene B4 (LTB4), interleukin 1 (IL-1), tumor necrosis factor (TNF) and platelet-derived growth factor (PDGF) by cultured AM from non-smoking normal human volunteers and coal miners. Inhibitors of eicosanoid biosynthesis were administered to AM from coal miners in order to determine if a link between eicosanoid and cytokine production exists in these cells. Basal PGE2, TxA2, TNF and IL-1 production by AM from active miners was increased compared to AM from normal volunteers. However, the production of these eicosanoids and cytokines by AM from former coal miners was reduced compared to control AM. Administration of the cyclooxygenase inhibitor, suprofen, and the lipoxygenase inhibitor, nordihydroguaiaretic acid, reduced PGE2 and TxA2 production in miners&apos; AM but had no effect on LTB4, IL-1 or PDGF production. Specific inhibition of thromboxane synthase by UK38,485 was associated with a significant reduction in TNF production in active miners&apos; AM but had no effect on PGE2, LTB4 or IL-1 production. The prostacyclin analogue ZK96,480 also specifically inhibited TxA2 production in active miners&apos; AM. The results of these studies suggest that coal dust exposure is associated with alterations in AM eicosanoid and cytokine production which may be relevant to the development of pulmonary inflammation and fibrosis. In addition, the lack of effect of inhibitors of PGE2 biosynthesis on IL1 production in miners&apos; AM suggests the production of these intercellular messengers may not be linked in AM chronically exposed to coal dust.

Jan 1, 1991

By A. W. Khair, S. S. Peng

Background The mine is located in Ebensburg, Cambria County, PA. Cambria County is located within the Allegheny Mountain section of the Appalachian Plateau Province. The geologic structures in the mine area included folds, faults, joints and cleats in the coal. These geologic structures seem to have genetic relationships with the Allegheny Front (lannacchione and Puglio, 1979). The mine&apos;s geologic structures have been influenced mainly by Ebensburg Anticline and Wilmore Syncline (Watson, 1979). Current longwall panels lay along the western limb of the Wilmore Syncline oriented south 30° west. Surface topographic relief in the area is less than 152 m (500 ft) and overburden thickness varies from 183 to 244 m (600 ft to 800 ft). The coal seam in the mine is part of the Lower Kittanning Formation. The thickness of the B-seam is the subject of discussion. It varies from 1.2 to 1.5 m (48 to 60 in.) and consists of two parts. The lower part is 1.1 to 1.2 m (44 to 48 in.) of soft coal and the remainder is bony coal. The coal seam dips slightly from 0° to 6° to the east-south direction. Panel entries are driven 61 m (200 ft) wide, consisting of three 5.5 m (18 ft) wide entries and two pillars 24.4 x 30.5 m (80 x 100 ft) centers. The mine has a history of cutter roof problems in the entries (Fig. 1) that has delayed the advance rate of entry development considerably and the cost of maintaining those entries is very high due to the requirement of very heavy artificial supports (Fig. 2). Due to excessive convergence in the headgate, installation of additional support and often resetting of steel beam, to provide enough clearance, in these entries imposed additional delay during the retreat of the longwall face, as the shearer cuts coal adjacent to the headgate and shield support at the headgate needs to advance under the steel beams (Fig. 3). Methodology Extensive underground observation indicated that roof cutter [ ]

Jan 1, 1992

By Ron Jackson

The report gives a general method for the geological evaluation of a gold deposit. Recognizable parameters associated with gold mineralization are used to develop a model of an orebody. The California Mother Lode is used as an example.

Jan 1, 1987

By Nina I. Fedunec, Olga E. Fomicheva

Results of researches on creation of the intelligent adviser system for mining dispatcher are represented. A method of the analysis of subject domain is considered and results as the generalized expert questionnaire and diagrams are represented. The system-adviser REALTREE, functioning in real time, is represented, results of an estimation of a system effectiveness during decision making by the dispatcher are submitted.

Jan 1, 1996

By Robert Martinez

A proven high grade reserve of gold mineralization located in Mexico is evaluated to determine which gold recovery process is best suited for this deposit. The processes evaluated are; Heap leaching, Vat leaching and a CIP circuit. All qualify as viable options, however each one presents a different economic picture which is impacted substantially by the financial constraints of the project. Taking this into consideration the most economic process was selected.

Jan 1, 1987

By William F. Riggs

The characteristics of frothers can often be determined by the proper selection of various chemical groups. There are three basic groups utilized in the application of frothers. These are alcohols, polyglycol ethers, and polyglycols. Some of the chemical groups are separated in subgroups. Each chemical group provides particular characteristics which affect load support, bubble diameter, water retention, air dispersion, and kinetics of froth formation. These chemical groups may be preblended in various percentages to optimize frother characteristics for a particular ore deposit.

Jan 1, 1986