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By R. S. Conti, L. L. Chasko

To deal with an unexpected event such as fire, prevention and preparedness are important elements in an underground mine's strategic plan. The purpose is to prevent afire before it initiates and to be prepared to deal with it when it does occur. This paper highlights a technology that may be used by the mining workforce to minimize such occurrences. It discusses thermal imaging cameras and their many applications to detect equipment failures or hot spots before they develop into afire. It also evaluates the feasibility of using thermal imaging cameras for emergency responders to assist them during exploration, rescue and fire fighting efforts. These thermal imaging systems allow rescue personnel to see in darkness and through dense smoke, thus making it easier to locate heated areas and missing or trapped personnel.

Jan 1, 2003

By Alden B. Carpenter

The Dead Sea is the only relatively large body of surface water having bromide concentrations comparable to those in the brines of the Smackover Formation in Arkansas. The Dead Sea, like the Smackover brines, contains a great deal of calcium and is very low in sulfate and iodide. The relationships between potassium, divalent cations, and chloride indicate that over 20 percent of the bromide in the Dead Sea is derived from some source other than by the evaporation of sea water. A similar type of study of the Smackover brines in Arkansas indicates that approximately 60 percent of the bromide has been derived from some source other than sea water. Both the Dead Sea and Smackover brines are very low in iodide suggesting that the excess bromide has not been derived from organic matter. The origin of the excess bromide is probably the same for both of these brines, but the source of this bromide remains unknown.

Jan 1, 1978

By Zhuang Jianming, Liu Qinxia, Yuan Mingliang, Mei Xiangong, Chen Jin

Up to now, the leaching of manganese carbonate ore is usually performed at high temperature of 363K and the leaching rate is lower than 90%. Although in laboratory test, the leaching rate is only 90%. This paper introduced an improved method for leaching of manganese carbonate ore. Certain ammonium salt was added to the pulp to raise the solubility of Mn2+ and reduce the adsorption quantity of Mn2+ on the ore surface. Experimental results show that a leaching rate over 95% can be obtained at the temperature >273K. The activation energy is calculated to be 7.15 KJ/mol and is lower than that of normal leaching technique. The effects of the parameters, such as particle size, pulp density and initial acid concentration on the process results are investigated. A leaching rate higher than 95% can be obtained under the following conditions: particle size below 0.25mm, leaching time 60 min, stirring speed higher than 960 r.pm. H2SO4:MnCO3>1 .2, pulp density 105-205 g.L-l. A kinetic model was deduced, verifying with actual experiments. It showed that the model can describe the leaching process successfully.

Jan 1, 1995

By R. J. Pugh

The surface chemical sites on several fillers (quartz, feldspar, calcite and granite) were studied by the adsorption of well defined acid and basic probe molecules (benzoic acid, benzyl alcohol, ethyl benzoate, pyridine and benzyl amine) from cyclohexane. The results provided a wide variation of adsorption data, emphasizing the extensive range of site heterogeneity on the filler surfaces. In addition, it was shown that the acidic probes were strongly adsorbed on all of the minerals, thus indicating that the basic surface sites dominate the acidic ones. Also, through FTIR studies with vapor-phase probes adsorbed on orthoclase, it was possible to identify the nature of specific sites and the type of bonding occurring between the filler surface and the probe molecule. These types of surface analytical techniques could give useful information for predicting the adsorption functional groups on dispersants, dyes, thickeners, etc. and could lead to enhanced interfacial bonding between the filler and the matrix.

Jan 1, 1993

By S. D. Morrison, J. L. Watson

It is well known that the density and viscosity of a mill pulp have optimum levels for grinding efficiency, and sophisticated control loops are employed to control pulp density in industry. However, these control loops rely on a number of plant measurements, and often the input data will not permit effective determination and control of the mill pulp density. The use of a single remote pulp density measurement has obvious advantages, and it is suggested and demonstrated for laboratory batch grinding that mill noise measurements can indicate the effective density of the mill pulp. In addition, the mill noise is shown to indicate the actual effective pulp viscosity in the mill and hence permit the identification of the dynamic rheological regime existing in the mill. It is demonstrated that mill noise increases with grind time and, at any given grind time, with increasing pulp density in the pseudoplastic range. This increase in mill noise level with pulp density is interpreted as indicating a decreasing pulp viscosity. The results show that the transition from dilatant to pseudoplastic conditions within the mill, with increasing pulp density, can be identified by this increase in mill noise. When the pseudoplastic pulp started to exhibit yield characteris- tics, the mill noise fell dramatically. The technique of mill noise analysis is then used to investigate the effect of a grinding additive on the batch grinding of two ores. With a magnetite ore, the additive was shown to increase the mill noise, and hence decrease the pulp viscosity, in the pseudoplastic region and to increase the effective grinding. The molybdenite ore, however, did not show significant noise level changes and did not show improved grinding efficiency.

Jan 1, 1987

By E. Topuz, M. J. McPherson, I. M. Konduri

The research is carried out to investigate the flow mechanics and effectiveness of face ventilation using induction fans, as an effort to provide a more efficient alternative to conventional auxiliary duct or brattice ventilation systems. The induction effects and plume longevity of fluid jets are being studied with the help of a plexi-glass model, using water as the fluid medium and creating a system that is dynamically similar to the flow in mine headings. This scaled model represents a typical 1.5m x 6m x 25m heading connecting to a crosscut. Reynolds Number criteria are used to obtain dynamic similarity of the flow in the designed model to simulate real mining conditions. The role of various parameters such as nozzle position in three dimensions, airway roughness, nozzle geometry, and flow rate in the jet are studied. During the laboratory tests, flow visualization techniques, coupled with still and video photography, were employed to identify the flow patterns. The results indicate that in typical coal mine headings, jet fans can produce effective face ventilation for distance up to 30 meters.

Jan 1, 1995

By M. G. Gorman

The effects of particle size, particle shape and degree of aggregation on n-dodecylamine flotation of -20 µ m quartz and glass beads were studied. A microflotation cell suitable for use with very fine particles was used in the flotation experimentation. Degree of agglomeration of particles was estimated by comparing size distributions of the quartz and beads in a dispersed system to size distributions in systems in which the collector was present. Results obtained show that in such flotation systems the fine particles are not generally present as individual particles during flotation but rather as aggregations. However, the quartz floats more readily than the beads indicating that there are some shape effects in the systems, considering the large specific surface areas of the materials it also appears that substantial amine consumption in the systems may limit flotation or lead to a requirement of greater reagent dosage for equivalent flotation to that tor larger particles.

Jan 1, 1990

By Malcolm Reeves

The heavy oil reservoirs of Alberta and Saskatchewan include sequences of unconeolidated silts and fine sands which respond in an unusual manner when subjected to the high temperature and pore-fluid-pressure associated with steam injection and other thermal enhanced recovery techniques. Apparent transient connections are suddenly established between producers and injectore and there is an associated enhancement in oil (and sand) production. These phenomena have been attributed to local fluidization and piping processes which are known to occur in situations where high pore-fluid-pressures prevent the mobilization of intergranular friction. These breakdown processes may be associated with the penetration of tongues of the heated reservoir fluids with suspended sand into the creep sensitive intact reservoir since the viscosity ratios are sufficiently high for viscous fingering instability of the fluid-fluid interface. A program of laboratory tests has been carried out to measure the strength characteristic of saturated oil sands at a variety of temperatures and fluid pressures. These tests suggest, that in common with the coarser Athabasca sands, the Waseca sands have very little cohesive strength and show the characteristic dilational failure response of dense sands. Some special tests, devised to determine the relative ease with which samples can be fluidized, confirm the expected susceptibility of the fine- sand silts. Both piping and fluidization can be readily induced at in-situ reservoir temperatures and pressures. Analysis of stresses around wellbores suggests that fluid-pressure gradients may be sufficient to initiate piping and that backward erosion along streamlines may link producers and injectors. Such pipes may act as well “adits” gathering oil from the heated reservoir and contributing to enhanced production rates. Mechanical breakdown of the reservoir by drilling, injection and production processes provides a consistent possible explanation for the sand-cut response of production wells.

Jan 1, 1986

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

By Terry P. McNulty

During the last 30 years, at least ten authors have dealt with startup ("ramp-up') times for minerals beneficiation, hydrometallurgical, and/or pyrometallurgical plants. Most have attempted to identity the reasons for delays and some have suggested attributes common to successful startups, as well as those shared by unsuccessful ones. The most recent has advanced a project characterization matrix as a predictive tool for qualified users. This paper will summarize past work, will review cause and effect, will outline an approach for refining our ability to avoid costly delays, and will seek guidance from professionals most likely to use such a tool. INTRODUCTION During the last few decades, many billions of dollars have been lost by investors in mineral industry projects that did not perform as well as their developers had hoped. The most common form of failure has been the inability to generate a profit quickly, and delayed achievement of planned production rate has been the chief cause. Minerals processing projects are by no means the only kind of plant to suffer from startup delays, as some authors cited in this paper considered inorganic chemical plants and other types of facilities. Furthermore, mines are not without fault and there have been many that were closed after years of disappointing performance. However, our interests as a group are most sharply focused on mineral processing and our database for such projects is relatively extensive. It is sufficient to say that the conclusions made or repeated in the following text can be readily extended to most types of projects.

Jan 1, 2004

By T. Negeri, Y. Breau, M. Plante, A. Orumwense

As part of a joint project on fine particle processing, sponsored by the Consortium de Recherche Minérale (COREM), Natural Resources Canada (NRCan) and Hydro-Quebec, two flotation plant circuits were sampled to identify and quantify the causes of mineral losses within several particle size ranges. Size distributions, size-by-size assays and global chemical assays (Cu, Zn, Fe, S) were determined for the major streams. Size distributions were measured in 13 classes by sieving, cyclo sizing (-45 µm), and laser beam diffraction analysis. BILMAT, a material balance computation software package, was used to optimise the sampling, to estimate the unmeasured variables, and to assess and improve the quality of the information generated. The methodology has been extended to correct cyclo sizer data and reduce discontinuities of up to 20% at the transition from sieves to cyclo sizer. The paper describes the methodology and the main conclusions emerging from material inventory of the flow sheets.

Jan 1, 2003

By Daniel Hodouin, Claude Bazin, Sami Makni

Computer systems, installed in mineral processing, are designed to accumulate massive amounts of real-time data. Frequently these data are only partially processed because of the lack of adequate methods and the limited accuracy of mineral processing sensors. Methods are proposed to estimate missing data and reconciliate sensor data on a real-time basis. They are based on dynamic extension of steady-state techniques such as the node imbalance minimization or the least-squares mass balance adjustment techniques. The methods are illustrated for simulated and actual flotation data. Their data upgrading ability could be used to improve process monitoring, control and optimization.

Jan 1, 1993

By K. Y. Haramy, B. T. Brady

A scale-invariant theory of the strength and deformability, of rock masses in static equilibrium and at incipient failure is proposed The theory provides a rationale, for designing structures in rock. This paper presents results of experiments conducted by the US Bureau of Mines and presents theoretical methods to determine and interpret the in situ strength of rock masses using the borehole shear tester.

Jan 1, 1996

By André Vervoort

The roof behaviour in room and pillar panels during the development of roadways and the subsequent pillar extraction was monitored underground and numerical simulations were conducted. For several underground sites, a satisfactory, correlation was found between underground measurements and three-dimensional numerical simulations using a boundary element code in the linear elastic domain. However, to simulate bed separation, and roof block collapses more complex models were required, of which examples are presented.

Jan 1, 1992

By Steve Van Kouteren

Filters and absorbents purify, clarify, and clean many types of liquids by removing solid particles. In addition, absorbents provide a convenient way to handle liquids and to clean up liquid wastes or spills. Filtration or absorptive processes are accomplished either in a mechanical way, as in absorption and filtration, or in a chemical way, as in adsorption. In filtration, minerals and rocks used as filter mediums are extensively utilized in applications requiring the filtration of high volumes of liquids. End use applications include liquid food products, waste waters, petroleum and chemicals, and drugs and pharmaceuticals. Upon closer examination of all of the materials used as filters and absorbents, industrial minerals and rocks represent only a small proportion of the total amount, as shown in [Fig. 1] (Rees, 1991). Given all the industries that use these minerals, most of the volume is concentrated in a few major end-use markets. Within these major end-use markets, a handful of minerals account for most of the total volume and value. The focus for this chapter will be to discuss the industrial minerals and rocks used as filters and absorbents in the most important markets. The selection of the minerals and markets to review is solely based on the total volume of material used and in special cases, those where the value of the market and material is high. The major materials include diatomite, perlite, sand, gravel, and such specialty clays as montmorillonite and attapulgite. These materials are mainly used for the filtration of food, chemical, and petroleum products. In addition, they are used as absorbents for pet litter and oil and grease spills, and as carriers for pesticides and fertilizers.

Jan 1, 1994

By Richard R. Klimpel

This paper will summarize the trends resulting from the data generated in a large number of laboratory and industrial studies con- ducted by this author where various slurry rheology factors have been carefully changed and controlled. Factors such as percent sol- ids, addition and/or removal of fines, slurry mill filling level, specific material oriented breakage properties, chemical additions, etc. are discussed with a number of illustrating examples. This paper is specifically aimed at developing rheologically related operating guide- lines for plant engineers so that improved operating conditions can be selected.

Jan 1, 1997

By R. C. Shodde, R. D. La Nauze

Major societal and industry changes over the last four decades have influenced the management of technology in the minerals industry. From the authors' experiences in both private and public sector R&D, the paper analyzes the range of strategic and structural changes and provides examples of some key technology delivery responses. For those charged with managing technology, the two key challenges facing them over the next decade are (I) moving technology development from a cost focus to a value focus (that is, from "how much long-term research can we afford?" to "identifying and capturing the value created from R&D”) and (2) the recruitment and retention of key talent. THE NEED TO ADAPT "Change is slow and gradual. It requires hard work, a bit of luck, a fair amount of self- sacrifice, and a lot of patience (Greene 1998)." Since the 1960s the world has changed and the minerals industry has had to adapt to the changing circumstances. In the '60s, minerals were there to be discovered and fortunes to be made; in Australia, the World War I1 embargo on exporting iron ore was lifted and the Western Australian iron-ore boom commenced, to be followed by the exploitation of the Darling Range bauxites; copper, lead, zinc and nickel were discovered and mines developed. The Australian dollar was worth US$1.11 whereas today it is around US$0.65. The oil crisis of 1976 sharpened focus on the sensitivity of the minerals industry on energy costs. By the late 1970s The Club of Rome was predicting the imminent demise of certain key metals-a prediction that has not been fulfilled-though the signs of the shift

Jan 1, 2004

By R. E. Johnson, M. Schipper-Zablotskaja, B. R. Palmer, van Sandwijk A.

A procedure has been developed for the removal of zinc from acid solutions containing aluminum, silicon, calcium, magnesium, sodium, potassium and manganese ions and high concentrations of chloride ions. The first step of the procedure involves the precipitation of aluminum and silicon at pH 4.2. The second step, the removal of the zinc as zinc oxide, was studied in detail to get in- sight into the formation of oxychlorides. A diagram was developed giving the conditions at 75O C under which the formation of oxychlorides is avoided. Under optimal conditions a zinc oxide with less than 0.5 weight percent of chloride can be produced from 11 - 16 g/l chloride solutions.

Jan 1, 1993

By R. Debkowski

Mining methods used to protect the workings in underground salt mines against the destructive activity of natural factors are presented in this paper. Major hazards and methods of elimination of their impact on the stability of workings, were determined. Old and modern technical means and technologies used for protection and preservation of the selected most interesting sites were characterized. The results of surveys and studies allowed proposing the change of mine structure i.e. dividing it into monumental and not-monumental part, which should improve execution of necessary protective works.

Jan 1, 2006

By J. Iannicelli

High intensity, high gradient magnetic separation can economically remove weakly paramagnetic contaminants down to 0 1 micron from industrial minerals This process is employed by all waterwashed kaolin producers in Georgia where seventeen huge magnetic separators are used to upgrade this product As a result, reserves of kaolin in Georgia have been doubled Design improvements have steadily increased the efficiency of separators and reduced power consumption below 300 KW for a nominal 65 TPH unit Beneficiation of ultrafine minerals is discussed based on pilot plant results on bauxite, ball clay, calcium carbonate, glass sand, talc, and numerous other minerals Operating parameters of the process are reviewed and some alternative equipment configurations discussed

Jan 1, 1983