Search Documents

By James R. Boulton

Fire detection using Carbon Monoxide sensors is based on the assumption that a rise in the level of Carbon Monoxide in the atmosphere over a fixed, predetermined ambient level is indicative of a fire. The method is simple, reliable, and effective in those mines where the only source of CO is from undesired combustion. Ambience for this purpose is defined as that level of the gas that is present on a day to day basis whose source is not a fire. In a diesel powered mine the level of CO can and does vary so widely from hour to hour and minute to minute that the selection of a predetermined, fixed level represents a compromise between sensitivity and reliability. The compromise is a best of both and worst of both situations and the computer system often resembles the little boy who cried wolf instead of a state of the art early fire monitoring and detection system. Cyprus Coal personnel have developed method of determining the ambient level of CO in the atmosphere on a real time basis and using that dynamic ambient level to determine whether or not a fire exists in the mine. The method has been given the name of Wave Trend Crossing.

Jan 1, 1991

By Leszek W. Lunarzewski, Adam L. Lunarzewski, Raymond C. Pilcher

The Floorgas and Roofgas simulation programs are used to identify strata relaxation zones and their boundaries, to assess active gas sources from coal seams and gas¬bearing rocks and to determine relevant gassiness prediction coefficients for any local longwall. The paper shows that by use of the print-outs from the Floorgas and Roofgas programs the following benefits are achievable: • identification of the shear and gas discharge zone positions in the floor, strata relaxation angles and various gas discharge zone positions in the roof, which are both relevant to local geological and mining conditions • optimisation of cross-measure drainage hole length, location, number and angle of inclination calculation and definition of gas make prediction coefficients such as the release ratio from adjacent coal seams, specific gas emission during longwall extraction and the relationships between gas make, longwall width and coal production levels.

Jan 1, 1995

Simulation has established itself as an accepted tool for the design and optimization of complex minerals processing plants. This paper addresses the use of simulation as a tool for the design and optimization of carbon-in-pulp and carbon-in-leach (CIP/CIL) plants. The complex, interactive nature of CIP/CIL plants makes detailed experimentation an expensive and time consuming approach to CIP/CIL plant design and/or optimization. This paper discusses a simulation-based software tool that can make the process of CIP/CIL plant design and/or optimization much more cost effective. Many of the issues and problems pertaining to the use of simulation for CIP/CIL design and operation are generic. Thus, this paper also attempts to highlight generic issues that must be solved before simulation will become a more widely used design and optimization tool. Requirements for the application of simulation for CIP/CIL plant design and optimization are highlighted. Similar problems and issues can be identified for most mineral processing plants.

Jan 1, 1994

By S. L. Bessinger

The need for improved safety and productivity brought about the introduction of longwall mining to the Appalachian coal fields. These same forces continue to drive developments in modern longwall equipment and mining practices. Current initiatives to improve productivity and safety are focused on automation and the effects of scale in equipment design. Longwall roof-supports, shearers and face-conveyors have changed significantly. Panel layouts have evolved to include larger total tonnages and provide for more rapid development of gate-entries. These advancements have improved longwall productivity and new production records are continually being set. Roof supports Reliability is implicit in the quest for automation. It is impossible to automate equipment if it is not reliable. To a large degree, this has been the problem with longwall shield automation efforts. The "electronic control" of shields depends on the proper functioning of electronic equipment, electrohydraulic valves and full-flow service valves onboard every support.

Jan 1, 1995

By A. K. Haines, M. W. Godfrey, D. M. Miller, P. C. van Aswegen

The Bacterial Oxidation [(BIOX)] process for the pre-treatment of refractory ores for gold recovery developed by Genmin, the mining division of Gencor, has been operating successfully at the Fairvew Mine since October 1986. The continuous operation of a pilot plant at Genmin Process Research has resulted in further process developmenst to improve plant operating efficiencies. These new developments, which include a higher solids content of the pulp feed to [BIOX], lower retention times, higher operating temperatures, lower power utilizaton for oxygen dispersion and reduced nutrient addition, have all been successfully implemented on the Fairvew plant. It has furthermore been confirmed that the arsenic precipitate formed in the neutralization of effluent solutions complies to the United States of America EPA standards. Contineous cyanidation pilot plant work conducted on [BIOX] product has indicated that cyanide consumption can be drastically decreased if a continuons flowsheet is implemented in preference to a batch leaching system.

Jan 1, 1992

By S. Becker, M. Gruner

"Microstructure stabilized crushed rock salt is a newly developed backfill material for infrastructural openings in HAW repositories. The motivation for this research is based on the fact that the microstructure stabilized crushed rock salt is considered to be superior to the currently used crushed rock salt. The avoiding of settlements with a simultaneous 100% backfilling of openings, early stabilization of the geological barrier and low permeability (< 10-14 m²) are the main improvements. With the newly developed backfill material, the gap between the crushed rock salt and the saliniferous composite backfill materials is closed. Due to the minimized amount of a binding agent, the material will still be easy to handle like a bulk material, yet guarantees close to 100 % backfill success without any settlements. This is accomplished with a long-term stable re-mineralization that is formed by the components of the binding agent. INTRODUCTION The permanent storage of high active waste in underground geological formations (HAW-repository) is the labored method in Germany as well as internationally. Experiences have been made over the last decades, e.g. in the Waste Isolation Pilot Plant (USA) and the mines Morsleben and Asse (Germany). For this purpose salt formations are preferred as host rock due to the adequate heat conductivity, creep capability, and low permeability. In order to maintain the low permeability of the host rock and to avoid any contact of the stored waste with the biosphere, the formation of flow paths has to be prevented. The cavities which have been mined for the purpose of waste storage have to be backfilled with material that is alike to the host rock. Therefore crushed rock salt is considered as an appropriate backfill material. Crushed rock salt is a bulk material that is produced by mining saliniferous formations. This material is mainly used in underground repositories as a dry backfill that is brought into the cavities by the use of mechanical (loading machine, slinger machine or scraper) or pneumatic energy (pneumatic stowing). In Germany it is intended to use dry crushed rock salt with a maximal grain diameter < 64 mm for backfill in a future repository in saliniferous formations. With this method applied, the porosity of the backfill is up to 35 % [1]."

Jan 1, 2015

By D. R. Dixon

Since the critical role of oxygen in xanthate flotation of sulphides was established (1) subsequent studies have been concerned mainly with the galena-xanthate system. It is therefore surprising to find at the conclusion of a comprehensive review of the topic by Granville, Finkelstein and Allison (2) that it was not possible for them to draw unequivocable conclusions on the mechanism of xanthate adsorption. It was apparent that some new advances were likely if systems other than galena-xanthate (Pbs/x-) were examined. (2) Specifically a less reactive sulphide such as ZnS may interact with flotation reagents at a slower rate than PbS and more information per unit time gathered. Again ZnS is far less reactive electrochemically than PbS or stated equivalently, it is a poorer semiconductor than PbS. More importantly, the ability of ZnS to act as a semi-conductor can be controlled photochemically rather than by direct doping reactions for which it is difficult to assess the uniformity of doping. Thus the conductivity of ZnS can be made the same as that of PbS by irradiating the ZnS with ultraviolet light at circa 360 n.m. (3)

Jan 1, 1974

By Eleanor Kentish, Nathan Bond, Edward Batty, Simon Webber, Alan Skarda

"Crossrail is Europe’s largest construction project — a new 100km rail route running through central London. A joint venture of BAM, Ferrovial and Kier (BFK) has constructed the tunnels and escalator shafts at the new Bond Street and Farringdon Stations. The recent trend in the UK industry towards sprayed secondary linings is driven by the potential for significant savings in cost and time. BFK is unique within Crossrail by constructing both sprayed and cast secondary linings. This paper presents a direct comparison between sprayed and traditional cast in situ secondary linings at Bond Street and Farringdon Crossrail Stations. An objective comparison is drawn between procurement and mobilisation periods, production rates, flexibility, tolerances and logistics in the tunnels. The technical challenges surrounding cast and sprayed secondary linings are explored, and recommendations are made of how each method could be improved for future use. INTRODUCTION It is well established that sprayed concrete offers a fast and effective method to seal the face of an excavation. In a relatively short space of time, sprayed concrete can be applied to an open face to support the short term ground loading on the tunnels during construction. Advances in sprayed concrete lining (SCL) technology — such as the use of wet mix processes, improved accelerators, fiber reinforcement, remotely controlled spraying robots, innovative surveying equipment and nozzleman competency schemes — have greatly increased the speed and safety of tunnel excavations using this technique. As a result, design engineers have become increasingly confident to use SCL primary linings as part of the permanent structural lining (Su 2014). Historically, long term ground and water pressure loads have been considered to be carried by the main structural or secondary lining, constructed using cast in situ concrete (Pickett 2014). However, the advances described above have made sprayed secondary linings a viable option, which has already been proven on the A3 Hindhead Tunnel (Arnold 2012). Sprayed concrete secondary linings offer potentially significant savings in cost and time during the construction process. The contractor does not need to procure a bespoke formwork system for each different sized tunnel — the SCL plant required is already on site for the primary lining. Each bay is sprayed with accelerated concrete, becoming self-supporting almost immediately — compared to moving and resetting the shutter, pumping concrete and waiting for it to cure. With sprayed concrete, working sequences and cross sections can easily be changed."

Jan 1, 2016

By D. Akers, R. Dospoy

Introduction The geological processes that form coal can also concentrate trace elements in the coal. For example, the average concentration of arsenic in bituminous coal (20 ppm) is ten times the average concentration found in all the other rocks that make up the earth&apos;s crust (2 ppm). Similarly, other elements, such as antimony, cadmium, mercury and selenium, are more concentrated in coal than in the earth&apos;s crust. When coal is burned, trace elements can be further concentrated. Although no new constraints on trace clement emissions were placed on the power generation industry under the 1990 Clean Air Act Amendments, the act does mandate a three-year study of air toxics. Any new regulations aimed at electric utilities as a result of this Federally-mandated study will almost assuredly be very costly-an estimated $1 billion per year. Many trace elements in coal are associated with mineral matter. For example, arsenic is commonly associated with pyrite, cadmium with sphalerite, chromium with clay minerals, mercury with pyrite and cinnabar, nickel with millerite, pyrite and other sulfides, and selenium with lead selenide, pyrite and other sulfides (Finkelman, 1980). There are also cases in which some of these elements are organically bound. Just as both organic and pyritic sulfur can be found in the same coal, the same trace element may be both organically bound and present as part of a mineral in the sane coal. Physical coal cleaning techniques are effective in removing mineral matter from coal and can potentially remove at least some of the trace elements associated with specific minerals, thereby reducing the release of these elements into the atmosphere. Conventional coal cleaning to remove trace elements As part of a project funded by the Electric Power Research Institute, CQ Inc., a wholly-owned EPRI subsidiary located in western Pennsylvania, has demonstrated that large reductions in the concentration of many trace elements are possible if conventional coal cleaning techniques are properly applied. Four examples are given in Tables 1 to 4. In each example, the results shown were generated by cleaning the coal at CQ Inc.&apos;s commercial-scale cleaning test facility. Cleaning results for Upper Freeport Seam coal from Northern Appalachia are provided in Table 1. Data are presented in the table in two ways: as a weight-based concentration (parts per million) and as a concentration per heat unit (grams per billion Btu). Grams per billion Btu is analogous to pounds per million Btu, but avoids the use of numbers with many decimal places. The heat-based concentration provides a better measure of boiler impacts, because the increased heating value obtained through coal cleaning reduces the number of tons that must be burned to produce a given thermal output. Reducing the quantity of coal burned reduces the quantity of trace elements entering the boiler. This raw coal is relatively high in several trace elements of environmental concern, including arsenic, cadmium and chromium. Cleaning provided large reductions in the quantity of arsenic, barium, cadmium, chromium, fluorine, lead, mercury, nickel, silver and zinc. The results for tests with a Powder River Basin coal, Rosebud/McKay, are presented in Table 2. Large reductions in arsenic, barium, cadmium, fluorine, mercury, nickel, selenium and zinc were observed with cleaning. The concentration of chromium increased with cleaning, while lead concentration increased in one test and decreased in another. Table 3 presents test results for Croweburg Seam coal from Oklahoma. Large reductions in arsenic, barium, cadmium, chromium and zinc were obtained with cleaning. Smaller reductions were obtained with lead and nickel, while chromium, fluorine and mercury increased in at least one of the tests. Table 4 presents cleaning test data for Kentucky No.11 Seam coal. In this case, large reductions were obtained with all elements measured. In general, these data indicate that physical coal cleaning is effective in reducing the concentration of many trace elements, especially if they are present in the coal at relatively high concentrations. The degree of reduction achieved is coal-specific, relating in part to the degree of mineral association of the specific trace element and the degree of liberation of the trace element-bearing mineral. The extent of trace element removal also depends on the method of cleaning the coal. Figure 1 is a washability plot, by size fraction, of arsenic vs. ash content for Upper Freeport

Jan 1, 1994

By Carlos Viramontes Aldana

Mining in Mexico is one of its post traditional activities, whose influence in the development of important cities and communications has been decisive. Precious metals and, to some extent, copper and tin were known and used before the Colonial period, but from the sixteenth century to tie end of the nineteenth century, mining and metallurgical industries were concentrated in the precious metals, mainly silver. This silver was exported to Spain and other countries under the Spanish. Rule, Mexican peso was known world wide since the end of the sixteenth century and Mexico ranked as the first silver producer since the eighteenth century.

Jan 1, 1985

By M. Z. Dogan, M. S. Celik, G. Onal, O. Ozcan, I. Yildirim

A fluorite ore (51.85 % CaF2) containing high contents of calcite, quartz and iron oxides was upgraded by flotation using a new reagent, oleoyl sarcosine (OS). In addition, quebracho and sodium silicate were used as depressants for calcite and quartz, respectively. The effect of pH, collector and depressants concentrations on grade and recovery was determined with the aim of optimizing the flotation conditions. Application of the two-stage cleaning achieved a concentrate assaying 92.17 % CaF2 with 80.1 % recovery. The Si02 content (0.76 %) was below the required level of 1 % SiO2. The mechanism of interaction between OS and fluorite, as compared to oleic acid, is also elucidated based on the zeta potential measurements.

Jan 1, 1993

By B. D. Shah, H. S. Soto

Lack of selectivity in mixed mineral flocculation can be attributed to one or more of the following factors: dissolved ion interference, hetero- coagulation, mechanical entrapment in flocs, and entrainment of fines between flocs. In a study of the apatite-dolomite system, it was determined that dissolved ions do not have a significant effect on selectivity. Heterocoagulation was minimized by choosing proper process conditions and addition of a dispersant. Mechanical entrapment was proved to be insignificant and efforts were made to reduce entrainment by choosing an appropriate method of separation of flocs from fines. A new factor termed "polymer induced entrapment," which occurs due to limited affinity of the polymer to the mineral that is not flocculated, is postulated to be the cause for the loss of selectivity.

Jan 1, 1988

By R. Corriveaau

This paper is about a horizontally curved conveyor, which carries 6,050 stph of limestone over land from a new quarry to the owner&apos;s plant. The conveyor is 5,012 ft long with a horizontal curve radius of5,OOOft Site conditions made a curved conveyor design the most optimal and economic solution. Using our unique custom conveyor calculation program, TKRI was able to accurately model and design the conveyor to properly track the belt and prevent any spillage through the horizontal curve radius. A data monitoring system was installed that allows monitoring of the conveyor both locally and remotely. The remote monitoring allows TKRI to contact the owner for preventive maintenance. Preventive maintenance can reduce the conveyor downtime during normal operating hours.

Jan 1, 2004

By D. Kimball, P. Chambers

"BACKGROUND In the event of an explosion or fire in an underground mine, workers can be exposed to a deficiency of oxygen, an excess of carbon monoxide, or both. These threats can occur as separate conditions or simultaneously. A lack of oxygen in the breathing air can only be addressed via the use of a self-contained breathing apparatus (SCBA) acting as a source of oxygen. An excess of carbon monoxide can also be addressed via the use of an SCBA, but if the threat occurs in isolation (that is, the atmosphere still contains sufficient oxygen to support life) and the concentration of the threat gas is not extreme (< 2%) then the carbon monoxide threat can also be addressed by the use of a filter self-rescuer (FSR). Used together, the SCBA and FSR offer a far more efficient and universally capable life support system than when used in isolation. However, the SCBA does not take advantage of the fact that the surrounding atmosphere likely contains some level of useable oxygen; i.e., the SCBA always supplies the total required oxygen from its limited supply, resulting in a ceiling on its useful life regardless of the level of oxygen in the surrounding air. To address this technology gap, what is needed is a ""smart"" SCBA that provides filtration and catalytic protection against threat gasses and has an extended duration life-sustaining oxygen inhale stream independent of the threat content and oxygen deficiency of the surrounding atmosphere. DEVELOPMENT Developed under contract with NIOSH the Smart Escape SCBA is comprised of three major components including; 1) oxygen supply, 2) oxygen sensing & dosing electronics and, 3) a CO catalyst and carbon bed broad spectrum FSR. The SCBA is designed as a hybrid system that provides non-toxic breathing air by using an approved Chemical, Biological, Radiological and Nuclear filter self-rescuer and a catalyst to convert high levels of carbon monoxide to harmless carbon dioxide (CBRN FSR/CO). In addition, the Oxygen Sensing & Dosing Electronics (OSDE) package adds sufficient oxygen to make up for deficiencies detected in the ambient air (Figure 1). By making use of the ambient oxygen, less oxygen is required for a one-hour unit life. This means that the Smart Escape SCBA fits in a smaller and lighter package than a similar-duration conventional Self-Contained Self-Rescuers (SCSR). Alternatively, taking advantage of available ambient oxygen could offer a significant increase in working duration in a unit with the same size as current SCSRs. The research performed under this NIOSH contract involved numerous tasks including: (1) definition of performance and system requirements for the Smart Escape SCBA, including keeping environmental stressors within acceptable ranges, providing at least one hour of breathable oxygen supply, and using a mask or hood that allows high-quality voice communication; (2) designing, building, and evaluating prototype units to support extensive bench top testing at Avon Protection and third party labs to demonstrate the device’s capabilities; (3) building sufficient quantity of Smart Escape SCBAs designed to be intrinsically safe (per MSHA criteria); (4) testing and evaluation by the National Personal Protective Technology Laboratory (NPPTL)."

Jan 1, 2015

This paper presents the development of a knowledge based integrated decision support system (E.X.I.S) for the extractive industries to provide information concerning the environmental impact of extractive operations on land quality, surface and ground waters, and the best solutions for the rehabilitation/revegetation of the waste disposal areas to the relevant target groups (extractive industries, regional authorities, national authorities, research institutes, public). GIS was integrated with the decision-making models for the rehabilitation and revegetation of mine spoil. The system design involves several steps including site selection ? mine type identification ? waste identification ? selection of rehabilitation (revegetation or other methods). The knowledge based model consists of two integral parts: the model base, in which the input data are processed and classified using special fuzzy algorithms and criteria and the knowledge model, which hosts the various decision algorithms concerning evaluation of vegetation covers, selection of trees and plant species, selection of rehabilitation and revegetation schemes and also economic analysis for each option. The system input will include parameters on site characteristics (climate, topography, geology, hydrology etc), waste type and properties (physical-geotechnical and geochemical data) as well as environmental parameters of the existing waste disposal area. Based on the values of the above parameters and the characteristics of the rehabilitation technologies developed worldwide, the system, using IF-THEN rules will define a list of appropriate techniques for the rehabilitation of the examined waste. Then, the model will involve the application of multi-criteria analysis (MCA), i.e. a structured system for ranking alternatives and making selections and decisions. Each technique shall be judged based on its behavior into four fields, i.e. financial, social, technical and environmental criteria. In turn these fields will be analyzed into a lower level of evaluation criteria.

Jan 1, 2006

By D. E. Munson

To assure the safety of a radioactive-waste repository, the performance of the repository must be predicted far into the future. The Waste Isolation Pilot Plant (WIPP) Program is responsible for developing the technology for such performance predictions in bedded salt. An important technology-development activity concerns the, fielding of very large-scale in situ tests to determine the time-dependent deformation of underground openings in salt as a basis for validation of the predictive technology. This technology is necessary to predict repository seal performance and final closure times of rooms and may be of value to the salt and potash mining community, as well.

Jan 1, 1992

By Mark L. Blanford, Roger M. Zimmerman

INTRODUCTION Volcanic tuffs on and adjacent to the Nevada Test Site (NTS) are being considered by the Department of Energy (DOE) for the possible geo- logic disposal of high-level radioactive wastes. The Nevada Nuclear Waste Storage Investigations (NNWSI) project was established in 1977 to evaluate such disposal. Sandia National Laboratories (SNL), one of the participants in the NNWSI project, has as one of its responsibilities the development of a rock mechanics program for the Nevada site. SNL conducted three small-diameter heater experiments in welded and nonwelded tuffs in G-Tunnel on the NTS, to investigate the thermal (heat transfer) and hydrothermal (thermal- induced water migration) behavior as part of the rock mechanics program. These two aspects were investigated to increase knowledge about the behavior of tuff so that predictive capabilities are available for use by repository designers, waste-package designers, and performance analysts. Also, knowledge of the behavior of the tuff is invaluable for planning and designing future in situ experiments at Yucca Mountain, the candidate site for the repository. The evaluations of these three experiments is the subject of this paper. Designers, analysts, and experimenters are seeking a better understanding of the behavior of tuffs under the influence of thermal loads expected from radioactive-waste storage, because of two physical features peculiar to tuffs. First, tuffs are inherently porous because of the manner in which they are deposited (Smith, 1960). Tuffs utilized in G-Tunnel testing have porosities ranging from 15 to 46%, which cover the ranges of expected porosities in the target horizon at Yucca Mountain. It has been established that the G-Tunnel tuffs have similar bulk, thermal, and mechanical material properties to those at Yucca Mountain (Zimmerman et al., 1984), thus, G-Tunnel testing can be used to evaluate the effects of porosity on the thermal and mechanical behavior. The second feature is that tuffs above the water table contain pore water that influences the thermal properties of the rock; displacement of the water must be accounted for in repository designs and analyses. For example, G-Tunnel tuffs, located some 600 m above the static water level, have saturations in excess of 60%. Similar percentages are expected at the target horizon in Yucca Mountain (Zimmerman et al., 1984). The presence of and the removal of the pore water affects the thermal behavior of the tuffs, and these three experiments were designed first to determine the phenomenological behavior and then assess influences on predictive capabilities. The focus in this paper is to present the results and evaluations of the experiments as they apply to improving predictive capabilities. The thermal aspects are emphasized by comparing the measured temperatures (in and around heater emplacement holes) with calculations of predicted temperatures using numerical models, so that the effects of significant parameters can be evaluated and integrated into future predictive models. Observation of the hydrothermal aspects is needed to assess the effects of loss of pore water and subsequent migrations on the temperature fields during the heating, and also to define the expected environment in the vicinity of the outer metallic surface around the waste. The metallic boundary can be either the outer shell of the waste package system, which is the main engineered barrier for waste containment, or the borehole liner. A final decision has not been made as yet about the necessity for lining boreholes; thus, the emphasis is on predicting the characteristics of the environment around the outer metallic surface. Two aspects that limit the scope of this paper are (1) the experiments were performed at a smaller than canister scale for the purpose of

Jan 1, 1986

By R. J. Sweigard, G. T. Lineberry, B. K. Slone, F. A. James III, D. S. Maggard

The depth at which it becomes more economical to use slope access instead of box-cut access for nearsurface coal reserves is termed the "transition depth." The transition depth can be established for a given coal property by considering cost estimates for those parameters that determine respective access methods. Fourteen parameters that influence access cost were identified, and ranges for these parameters were determined. A transitiondepth formula was developed to permit the determination of which is the better method of accessing a reserve, given information such as high wall slope, road width, total bench width, pit dimensions, road grade, belt component costs, pumping costs and the cost of overburden removal and reclamation. In most cases in Appalachia, especially in eastern Kentucky, the observed transition depth ranges from 20 to 30 m (66 to l00 ft). This indicates that actual practice is consistent with the analytical approach used.

Jan 1, 2002

By J. Castaneda, J. Schmidt

"INTRODUCTION Chino is an open-pit copper mining complex faced with intricate material routing requirements. Historically, this was challenging at the mine, in part because the shovel dig plan, haul plan, and dump plan were prepared completely separately. The mine now uses an integrated workflow for faster evaluation of schedules, which facilitates preparing balanced cutoff grade-to-equipment requirements, supports better mineral production, and improves schedule viability, while considering operational implications. Located in the state of New Mexico, Chino is one of nine Freeport-McMoRan mining operations in North America. This presentation discusses the benefits of implementing an integrated approach to tactical mine planning, and shares practical examples that were learned as Chino implemented an integrated tactical planning method. This includes improvements in completion time for preparing a schedule, minimal risk from manipulating Excel macros, data integration required to make short-term planning decisions, and better understanding of the mine plan’s effect in relation to the business’s key performance indicators. Ultimately, the integrated approach to tactical mine planning at Chino has led to production forecasts which are more achievable and reduced planning and execution variance. PROJECT OVERVIEW Chino mine is a porphyry copper deposit wholly owned by Freeport-McMoRan, the largest publicly traded copper producer in the world. Chino mine is located in Grant County, New Mexico, a short distance east of Silver City. Ore material mined from the pit today includes oxides, primary sulfides, and secondary sulfides. The mineralized material is sent to a mill, with a rated throughput of 42,000 tons per day, or to ROM leach pads with variable dumping capacities. At Chino, the short-range objective is to maximize total copper pounds sent to the mill, but no fixed cutoff grade accomplishes this for all periods. Instead, 12 different material classifications, including four sulfide classes that can feed either the mill or other destinations, and 38 cutoff bins, are aligned with the needs from operations, leaching, and the concentrator to create a schedule. Cutoffs vary from one week to another to cope with a highly intermittent ore body."

Jan 1, 2018

By R. M. Bricka, T. J. Olin

Heavy metals contamination is an environmental problem at Army installations engaged in firearms training and munitions production. At these facilities, weathering and corrosion of expended munitions and leaching from wastewater lagoons, landfills and burn pits have resulted in heavy metals contamination of the soil. The principal metals encountered in firing-range soils are lead, copper and zinc. Cadmium and other metals, such as antimony, that are often incorporated in the munitions are sometimes seen in lesser concentrations. Mercury is associated with various propellants and, while present in much smaller concentrations, is of concern because of its acute toxicity. Chromium is primarily associated with plating operations. The transport of metals into groundwater has been confirmed at some locations, which has required treatment of the soil and groundwater at these sites. Certain treatment processes for contaminated soil produce metals-laden extracts, which also require treatment before reuse or disposal. Ion exchange is generally quite effective for removing metals from aqueous streams. However, resins are expensive and must be regenerated, and activated carbon is generally less effective for most metals and also requires regeneration. Therefore, alternative effective and economic sorbents are needed. Twelve sorbents were screened in initial batch testing. These included activated carbon, bark, chitosan, crown ether, corn cob, xanthate, clay (kaolinite and montmorillonite), peat moss, seaweed and reagent-grade zeolite (aluminosilicate, Sigma Product No. Z3125). Of these, zeolite demonstrated the highest capacity for Pb, Cr and Cd. For this reason, zeolite was selected for further testing in batch, kinetic and column studies. Materials and methods Zeolite. The zeolite used in the second-phase batch and column studies was obtained from a natural deposit of clinoptilolite-rich rock located in South Dakota (Rocky Ford SDH) (Desborough, 1996). Large blocks of the material were crushed and sieved into the following three particle size ranges: 0.5 to 1.0, 1.0 to 4.0 and 2.0 to 4.7 mm. This material demonstrates high structural stability in acidic solutions (pH 2.5) (Desborough 1996) and has a measured surface area of 30 m2/g. The measured total cation-exchange capacity (TCEC) was approximately 10 meq/100 g. This is well below what has been indicated for commercially available zeolite, which has been reported to be about 180 to 220 meq/ 100 g. The TCEC test was repeated (Method 9081, SW 846) using sodium acetate. The test resulted in a TCEC of 54.5 meq/100 g. The difference between values obtained for this material and published values for zeolites may be attributable to the greater heterogeneity in the material used in this study, compared to commercially available materials, or to the effect of the relatively large particle sizes utilized. Batch studies. Seven batch studies were conducted using synthetic metal solutions and soil extracts (Table 1). Extract composition: The P-extract was prepared by sequential surfactant extraction of organics from a burnpit soil followed by acid extraction of metals. The pH of this solution is approximately 1.1. A number of metals and organic compounds were present in the soil. Analysis of the extract was restricted to Pb, Zn and Cu concentrations for this study. The FBH extract was produced from a firing-range soil that was oxidized with a 0.01 M CaO solution and then extracted with 0.1 M acetic acid. This was filtered through 0.5-µm Whatman No. 5 filter paper and stored at room temperature. The pH of the FBH extract was approximately 4.5. pH Control: Calcium carbonate (CaCO3) may be present in the zeolite horizon or bed. Calcium ion (Ca") is released from the exchange sites when in contact with solutions containing ions for which it is more selective, such as lead. This results in a rise in solution pH over time. Acid washing removes most of the carbonates, eliminating the need for a buffer. Batch studies were conducted using both acid-washed zeolite (AW) and unwashed zeolite (UW) for performance comparison. The UW zeolite was rinsed with distilled deionized (DDI) water to remove fine soil particles. Both materials were dried at 105°C (220°F) overnight, so that the dry mass could be determined. Column studies. Ten column studies were conducted. Because it was expected to have the best hydraulic properties, the largest particle

Jan 1, 1999