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By E. -U. Reuther

To improve the climatic environment underground the German coal mining industry has installed refrigerators with a capacity of 300 MW cooling power. One third of this total is accounted for by central refrigeration plants with more than 5 MW capacity. The central refrigeration comprises three stages: mechanical cooling, transport and distribution of chilled water via pipelines and exchange of heat in the air coolers. Of these three stages only the mechanical generation of chilled water has been resolved satisfactorily. Transport (including distribution) and exchange require further technical research. The Mining Institute of the Aachen University of Technology has done extensive studies on this subject, concentrating on controlling the flow of chilled water according to demand in the mine. Additionally, the favourable exchange in the air coolers is taken into account. The studies are based on a model mine which simulates the conditions in deep coal mines in Germany. The simulation program represents firstly the condition of the mine air at the location of the air being cooled, then the heat exchange in the air cooler itself, and finally the transport of the chilled water from the central refrigerator to the consumer. The program also reproduces the seasonal and operational changes in conditions of mine air as well as different air cooler designs. A regulated distribution of chilled water is also suggested. Finally, estimations of costs can be made as an aid for further planning.

Jan 1, 1987

By I. Beukes, H. Kotze, B. Krause, R. P. Hattingh

Hillendale Mine is operated by Exxaro KZN Sands, and is situated on the north coast of KwaZulu-Natal in South Africa near the towns of Empangeni and Richards Bay, some 200 km north of Durban. During the mining operation the heavy minerals rutile, ilmenite, zircon and leucoxene are extracted for further beneficiation at a processing complex near the town of Empangeni. The deposit contains approximately 25% slimes (defined as the sub-45 micron fraction), and is mined using hydraulic monitoring. Run of mine is gravity fed down launders to pump stations, which deliver the material to a primary wet plant. Slimes is separated from the run of mine prior to the heavy minerals being separated from the sand. Sand tails containing approximately 2-5% slimes is pumped to the mining void. The slimes is thickened to a density of approximately 1.2, and most of the resultant material is pumped to a sub-aerial deposition site (residue dam). The area is characterized by an annual rainfall of approximately 1300 mm, which is relatively high by South African standards. From an agricultural perspective the soils are deep and well weathered. Dryland agriculture has been practised on an extensive scale in the area for the past 70 years. Sugar cane in particular is cultivated on and around the mine area. In terms of environmental approvals, the post-mining land use and objectives are defined as economically viable and sustainable sugar cane cultivation in the mined areas. During mining the soil profile is destroyed. In this paper the establishment of a reconstituted soil profile is discussed, with specific reference to the methodology that is being followed to achieve the homogeneous blending of sand and slimes. Defining the rehabilitation strategy and soil specification Strategically Exxaro KZN Sands divided rehabilitation into four aspects, comprising physical rehabilitation (restoration of soil structure), vegetative rehabilitation (restoration of vegetative cover), ecological rehabilitation (restoration of sustainable ecological communities), and sustainability (sustainable man/environment interface) (Hattingh and Viljoen, 2006). It is believed that the key to successful rehabilitation lies in achieving a substrate (soil) suitable for the establishment of the target vegetation. During the development of the rehabilitation strategy the key factor in the establishment of a suitable soil profile was shown to be the soil water retention of this material. Since dryland agriculture is practised, this aspect becomes critically important in ensuring that the post-mining land use is sustainable (Hattingh et al., in prep.). From a financial perspective, a closure certificate being issued implies that the state takes over financial liability for the rehabilitated land. This has significant implications for the state-the default position will be that all possible latent and residual impacts must be identified and known prior to a closure certificate being issued. From the mine's perspective this precautionary approach by the state implies that post-operational costs cannot be quantified exactly, and our approach is therefore to mitigate the risk of a long post-closure care and maintenance phase by means of addressing all potential latent defects during the operational rehabilitation phase. The financial viability of the soil reconstitution process itself is therefore not measured against other rehabilitation methods, but against the risk of not achieving closure. During a series of technical workshops comprising experts in the various disciplines in the rehabilitation of the soil profile were identified. These aspects include the re-establishment of a functional soil profile, soil physical characteristics, soil chemistry, soil biota, salinization potential, erodibility and soil weathering. The natural soils in the Hillendale area have been classified in terms of the South African soil classification system (MacVicar and co-workers, 1991) and consist of Hutton (orthic topsoils on red apedal subsoils) and Clovelly (orthic top soils on yellow apedal subsoils) soil forms. The topsoils consistently comprise medium to fine grained sand overlying heavier textured sandy clay loam to clayey subsoils. The topsoil structure consists of a single grain structure, whereas subsoils are apedal. These soils are typically deeply weathered and do not show secondary structures. During the mining process a layer of topsoil (300 mm) is stripped off, and the balance of the material down to the footwall is processed. Sand with 2-5% slimes (defined as the sub-45 micron fraction) is returned as backfill in order to re-establish the dune to approximate the previous landform. From an agricultural perspective this material is not suitable for the dryland cultivation of sugar cane. A capping of more suitable material therefore has to be provided. The most significant difference between the premining soil form and the backfill material is the percentage slimes, consequently a mixture of the sand and slimes is required as a capping over the backfilled sand. The required thickness of the cap is a function of specifically plant growth requirements, erodibility, weathering and runoff (Hattingh, et al.; in prep.). The percentage slimes required in the cap is a function of mainly soil water requirements (Hattingh and Viljoen, 2006). The conservative indications to date show that the reconstituted soil profile should consist of a homogeneously blended mixture of 70%-80% sand and 30%-20% slimes up to a maximum of 2 metres thick. This will be sufficient to ensure growth during dry periods.

Jan 1, 2007

By C. Musingwini, T. C. Sebutsoe

"The primary objective of any mining business unit is to make profit by extracting, processing, and selling minerals from a particular mineral deposit. It is important to optimize extraction of the mineral resource given time, capital, and space constraints. Mineral extraction is often associated with uncertainty due to variable technical and human factors. Technical factors such as grade distribution, ground conditions, and equipment reliability influence the performance of a mining production system (MPS). The performance of the MPS is also impacted by human factors such as employee skills, health, and attendance. Uncertainty associated with technical and human factors often leads to actual output differing from what was planned. Therefore an in-depth analysis of the significant causes of deviations from the planned outcomes is relevant.In this paper we investigate the empirical relationships between inputs and outputs in a MPS in order to assist management in directing efforts at key production drivers. Once a MPS has been empirically characterized, more effort and resources can be focused on the key decision-making variables (DMVs) in order to meet the planned outcomes.For a typical underground, tabular, narrow-reef conventional drill-andblast platinum mine the face advance, face length mined, number of teams, team efficiencies, and team size have a statistically significant relationship with the centares (m²) produced, which is a key performance indicator (KPI). The production function derived in this study can be used to align the physical, technical, and human factors together to predict the optimal output level. The most significant production lever of the MPS is the face advance. IntroductionA mining production system (MPS) is a result of an iterative process of design, planning, and optimization of mining input variables and decision-making variables (DMVs). The MPS exists within the mineral extraction link of the complete mining value chain. It represents the stage where mining companies have the opportunity, through production, to start generating returns on the investments undertaken. Returns on shareholders’ investments can be realized at this stage."

Jan 1, 2017

By B. Nemutudi, X. Zhang, B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, S. Pikinini

The comparison study on adsorption of potassium normal butyl xanthate (PNBX) and sodium (nbutyl) dithiocarbamate (SNBDTC) on sperrylite mineral forms a basis in understanding the floatability improvement and paves a way for the design of collectors that may impact on a wide range of arsenide minerals. This study used a computational density functional theory (DFT) and experimental microcalorimetry approach to determine the adsorption energies of PNBX and SNBDTC collectors onto a sperrylite mineral surface. From a computational aspect, we considered the most stable surface plane of (100) surface, which had been found to give the lowest surface energy, compared to the other surface planes. It was observed that the PNBX and SNBDTC preferred to bridge on the As and Pt atoms through the S atoms. These findings showed that the collector adsorbed on the surface through both Pt and As atoms and indicated that the As atoms were significantly active in the adsorptions. We found that the adsorption energies were in the order: SNBDTC (–278.38 kJ/mol) > PNBX (–270.92 kJ/mol), indicating that the dithiocarbamate had stronger exothermic adsorption than the xanthate. From the microcalorimetry test it was also found that the SNBDTC was more exothermic than the PNBX and the adsorption energies were: SNBDTC (–473.50 kJ/mol) > PNBX (–331.13 kJ/mol). These results showed that the nitrogen atom in the SNBDTC collector had a great influence on the adsorption strength of the collector on the mineral surface. This is due to the electron deposition behaviour of nitrogen atoms compared to the electron withdrawing character of oxygen and as such the SNBDTC showed better collecting ability than the PNBX. These results paved the way for the design of collectors for sperrylite and other arsenide minerals and suggested that nitrogen in a collector may significantly improve the ability of the collector for improved recovery. Keywords: Computational modelling, microcalorimetry, SNBDTC and PNBX collectors, adsorption energies

Jan 1, 2020

By Z-P. Song, Z-B. Jiang, A-N. Jiang

"In deep excavations under conditions of high ground stress, even hard rock undergoes creep and other time-dependent effects that may result in instability. This study involves an analysis of the typical damage to the surrounding rock in the deep tunnels of the Jinchuan nickel mine in China. In order to understand the creep mechanism, triaxial creep laboratory tests were conducted under high stress. The creep characteristic curves and the Nishihara model parameters of typical rock were obtained from these tests. The numerical simulations, with which the creep model is developed, were performed using Flac3D. The creep model parameters were back-analysed on the basis of field monitoring data. Finally, appropriate support schemes for deep tunnels are suggested. The creep deformation of rock increases with time and axial load. At the same load level, the creep deformation of unloading is greater than that of loading. The simulated deformations of the surrounding rock are coincident with those from in situ monitoring, indicating the applicability of the presented rock creep model in situations of high ground stress. The results constitute a reference for support design in deep mining tunnels.IntroductionThe excavation of underground caverns can alter the natural stress field of the surrounding rock. In deep engineering projects under conditions of high ground stress, even hard rock shows obvious creep properties and time effects (Yao, 2005; Liu, 1994). The time effect of excavation not only causes decompression of the floor and increases sidewall stress, but also leads to stress concentration at the corners of the excavation, which influences the stability of the surrounding rock in a very complex manner.Many researchers have studied the creep properties of rock. ‘Griggs (1939) showed that creep occurs in sandstone, shale, and silty sandstone rock under the load of 12.5%–80% of the failure load.’ Subsequently, much research has been published on rock creep tests, including the uniaxial compressive creep test, the triaxial compressive creep test, the discontinuity rock shearing test, and field tests (Wawersik, 1974; Amadei et al., 1980; Okubo et al., 1991; Jin et al.,1995). A rheological model is used to describe the complex rheological deformation of material. This model is based on various fundamental parameters including rock elasticity, plasticity, and viscous properties, which can be combined into a constitutive model to reflect the rheological properties of various types of rocks. Wang et al. (2014) studied the creep– damage–rupture characteristics of rock salt by applying a creep-damage model. Munson (1997) developed a multi-mechanism constitutive model of creep of polycrystalline rock salt based on steady-state creep and modified it to incorporate transient creep through work hardening and recovery. An elasto-viscoplastic approach was developed to simulate the timedependent nature of the fracture zone (Malan, 1999). Rheological models were proposed to understand the collapse of iron ore mines in Lorraine by Dragan et al. (2003)."

Jan 1, 2016

By T. C. Marshall

A comparison between hydraulic and pneumatic rockdrills by T. C. Marshall, Pr.Eng. (Member) The greatly increased output of rockdrills has placed new demands on booms, carriers, and drill steels and bits. Limited scope for further improvement in pneumatic rockdrills has led to the development of hydraulic rockdrills, which compare favourably with their pneumatic counterparts: they are more efficient, more flexible in coping with variations in the working conditions, more economical in the consumption of drill steel, and less productive of noise and mist. Their disadvantages include a greater need for a reliable power supply, a greater vulnerability to dirt, greater complexity (requiring more skilful maintenance), and the liberation of heat into the working environment. They should be regarded as a complement to, and not as a substitute for, pneumatic rockdrills.

Jan 2, 1974

By B. Mienie, J. F. Morrison, C. H. Wyndham, M. J. Martinson, N. B. Strydom

Contribution to discussion M. J. Martinson (Associate Member)*: Application of the simple selection test mentioned in the penultimate paragraph of the paper (reference to a more detailed description of the test would not have been inappropriate) should assist South African mining engineers to make more efficient and possibly more humane use of available labour. The authors mention that the test 'is in use in the gold mining industry', and it would be interesting to know the extent of this usage in terms either of number of mines or as a percentage of the total number of labourers employed on 'heavy' tasks. The paper would have been of greater interest had the authors attempted to relate their findings to the statistics of labour usage in gold mines, members of the Chamber, and to the 'heavy' tasks in particular. On this the authors confine themselves in their Introduction to the somewhat ambiguous statement that 'A relatively high proportion of the 360,000 Bantu mine labourers are employed underground on manual tasks'. To appreciate the practical significance of the authors' work one needs a detailed breakdown of the underground labour force by occupations, together with estimates of quantities such as: (a) total stope and development tonnages moved manually per shift: by shovelling by shovel/tram by tramming together with distances and any other relevant data; (b) theoretical energy expenditures required to accomplish (a); (c) actual energy expenditures required to a accomplish (a); (d) energy theoretically available to accomplish (a) based on 50 per cent of the total maximum oxygen intakes of the labour force allocated to these tasks. Analyses of this sort on an industry basis might demarcate the more promising areas for detailed investigation. Stress is often laid on the need for increased mechanisation to increase stope productivity, but it may be questioned if enough is known about the characteristics, performance and potential of our underground labour force to warrant blind acceptance of stope mechanization as the industry's panacea. Provided that health and safety are not compromised, the ultimate yardstick for assessing any form of stoping is profitability; obviously the industry must investigate very thoroughly any form of mechanization which might reasonably be expected to increase profitability, but it should also be remembered that a radical overhaul of existing systems-which have after all evolved by trial and error over the past 75

Jan 11, 1968

By B. Strohmeier

The role of large, ultra-high-powered arc furnaces in a fully integrated steelworks for the production of flat products is outlined, and an account is given of the technological improvements that have been implemented over the past few years to enable the arc furnace to remain competitive against the conventional route using blast furnaces and top-blown-oxygen steelmaking (LD). Modern secondary refining facilities have been installed, enabling the arc furnace to operate at high production rates in the manufacture of high-quality flat products.

Jan 1, 1985

By S. T. L. Harrison, J. R. Amaral Filho, M. Smart, J. Broadhurst, J. Weiler

Technosol production from mine waste, following amendment with additional organic residues, to provide healthy and functional topsoil is an advantageous alternative to the long-term dump disposal of mine waste. Minimising the legacy of mine waste and supplying soil for mine site rehabilitation contributes towards more sustainable mining practices. Following the creation of the physicochemical structure of the soil from appropriate mixtures of coal waste with low sulfur content, physical ameliorants and nutrient sources, the inoculation of Technosols with active microbial suspensions may accelerate the decomposition of organic matter present and ensure nutrient availability for plant growth through active nutrient cycling, particularly of nitrogen, sulfur and phosphorous. In this paper, South African ultrafine coal waste was used as the main mineral matrix, and malt residue was used as source of organic matter and nutrients. In order to evaluate the effects of Technosol inoculation, five microbial treatments were used, including the addition of: commercial grade efficient microorganisms (EM Prosoil), anaerobic digested sludge supernatant from treating brewery waste, and ‘tea’ extracts prepared from compost, vermicompost and soil native to the mining area. Growth experiments were carried out using Eragrostis teff, commonly known as teff, a grass typically used for the rehabilitation of mined areas in South Africa. Preliminary results showed that Technosols inoculated with microorganisms performed better in terms of nutrient availability and plant growth. Varied performance was observed as a function of the microbial inoculation applied. This suggests that the inoculation of Technosols with appropriate microorganisms may be recommended to accelerate nutrient availability assisting plant growth during the initial establishing of the Technosols. Technosols continue to show promise as an alternative to both mine waste disposal and the burrowing of topsoils for mine rehabilitation. Keywords: Fabricated soil, mine waste, coal discards, malt residue, nutrient availability, soil microbiology, plant growth

Jan 1, 2020

By R. D. Lama

This paper presents the results of a study of the mechanics of methane gas flow in coal. Desorption tests carried out on cylindrical coal specimens showed that an analytical formulation can be made to model the process of gas flow in coal based on an integration of Darcy's law, Fick's law and Langmuir's relation. The diffusivity term in the flow equation varies directly with local gas content. Permeability tests carried out on the same coal result in permeability constants with values higher than equivalent permeabilities obtained from desorption tests by many orders of magnitude. The study also revealed that permeability is highly dependent on the applied gas pressure and the rock stress.

Jan 1, 1987

By T.R. Stacey

Physical testing of rock support for rockbursting conditions has been carried out for over 40 years. A review of this testing shows that it has been mostly component based, rather than actually testing support systems. Further, it is concluded that none of the testing is truly representative of rockburst loading in a similitude sense. Similitude conditions are not achievable, mainly because the real conditions in a rockburst event, such as seismic source location and magnitude, wave frequencies, amplitudes, and interactions, are not all known. Because such information is not available, and because the results of all testing carried out to date have not been able to define, for support design purposes, the capacity of support systems, ongoing physical testing of rockburst support systems is essential. It is essential that the test should simulate, or actually take place in, a supported rock excavation. A rock support system is a combination of individual support components that work together to retain and contain the rock. In doing this, the components are subjected to loading by the rock and to interactive loading between one component and another. It is necessary to prove the capacity of such rockburst support systems by subjecting them to severe loading, as in direct blasting. The direct blasting approach, pioneered more than 40 years ago, probably still provides the greatest validity as a significant test of rockburst support capabilities, even though it does not simulate a rockburst. Direct blast testing of rockburst support systems in a surface environment, such as in a quarry or on exposed rock cutting surfaces, could represent a practical development of the approach, facilitating the execution and monitoring of tests.

Jan 1, 2012

The mining rock-mass rating (MAMA) classification system was introduced in 1974 as a development of the CSIA geomechanics classification system to cater for diverse mining situations. The fundamental difference was the recognition that in situ rock-mass ratings (AMA) had to be adjusted according to the mining environment so that the final ratings (MAMA) could be used for mine design. The adjustment parameters are weathering, mining-induced stresses, joint orientation, and blasting effects. It is also possible to use the ratings (AMA) in the determination of empirical rock-mass strength (AMS) and then in the application of the adjustments to arrive at a design rock-mass strength (DAMS). This classification system is versatile, and the rock-mass rating (AMA), the mining rock-mass rating (MAMA), and the design rock-mass strength (DAMS) provide good guidelines for the purposes of mine design. However, in some cases a more detailed investigation may be required, in which case greater attention is paid to specific parameters of the system. Narrow and weak geological features that are continuous within and beyond the stope or pillar must be identified and rated separately. The paper describes the procedure required to arrive at the ratings, and presents practical examples of the application of the system to mine design.

Jan 1, 1990

By P. W. Ocerbeek

The occurrence, properties, and uses of andalusite, and its advantages over other refractory minerals and materials, are discussed. Ore reserves are given for the five producing areas, and statistics on production, export sales, and prices are included to illustrate the growth of the industry since the early 1960s. The mining and beneficiation procedures are described, with special reference to new techniques in concentration and magnetic separation. As fines dumps represent a considerable source of andalusite, possible methods of recovery are discussed. . The outlook for the future appears favourable, and possible competition from other sources and substitute refractory minerals are mentioned. It is concluded that the industry is in a sound position to maintain South Africa's status as the world's foremost producer and supplier of andalusite.

Jan 1, 1989

By C. Kirmanli

The purpose of this paper is to develop an expert system for hydraulic excavator and truck selection in surface mining. Hydraulic excavators and trucks are finding increasing applications in mining operations. Hydraulic excavators are extensively used especially when bringing electricity to rural areas is difficult and for small-scale mining. This paper describes an expert system, which selects the optimum hydraulic excavator truck configuration such that unit production cost is minimized and technical constraints such as geological, geotechnical and mining constraints are satisfied. The system has four modules: user interface, rules and an methods, databases and output module. The expert system in this study is developed within KappaPC shell. It supports object-orientated technology for the MS Windows environment. The software provides a very useful tool to practitioners, saving time and cost. Equipment selection is a recurring and expensive problem of mine planning and often involves interdisciplinary experts from different fields. It is very difficult and expensive to bring together all these experts. The capabilities of the expert system developed are illustrated in the paper. The software overcomes the difficulties of selecting the proper equipment for surface mining operations, which is very important, and results in substantial savings. Equipment databases for hydraulic excavators with 15-59 yd3 capacities and trucks with 35-360 tons are constructed and these databases are used to select the proper configuration. A case study is carried out for Soma Surface Coal mines in Turkey. Keywords: surface mining, expert systems, equipment selection, hydraulic excavators, diggability

Jan 1, 2009

By R. S. Sarracino, M. J. Louw, S. M. Vather

Two detonation models, IDeX for ideal VOD and CPeX for non-ideal VOD, were used to predict the velocities of detonation (VOD) of five explosives: ANFO, a bulk emulsion, and three repumpable emulsions (R100 Gold, R100 Diamond, and R105). The theoretical VODs were compared with the in-hole VODs of the explosives, and the predicted and actual values were found to be within experimental error for ANFO and the bulk emulsion. The results were not consistent for the repumpable emulsions. The discrepancies can be explained as being due to variations in mining and loading practices. The results show that the detonation models can be effective tools in predicting the behaviour of explosives in different diameters and rock confinements, provided that the user is aware of the factors that can affect the optimal usage of explosives and equipment.

Jan 1, 1993

By S. J. Bluhm

Recommendations are given for the design of multi-stage spray chambers in which air flows horizontally through water sprays. A detailed description is given of one such spray chamber at Hartebeestfontein gold mine that is used for bulk cooling of the incoming ventilation air, and that has been constructed according to these recommendations. A method for predicting the performance parameters of horizontal multi-stage spray chambers is given, and the method is illustrated with some examples. The method is equally applicable to spray chambers in which the water, rather than the air, is cooled.

Jan 1, 1979

By C. L. de Jongh

The number and scale of backfilling operations in the South African gold mining industry have grown rapidly in recent years. The application of backfilling as a means of stope support in a wide range of geological conditions and mining systems has resulted in the development of a variety of alternative fill systems. Experience gained in the evaluation of operating fill systems has contributed to a knowledge of the essential concepts to be considered in their design. This knowledge can also influence management's perception of what is expected of a backfilling system. The factors to be assessed in stating and satisfying these objectives are examined. The areas of investigation cover the selection of a suitable material, its preparation, distribution and placement, and the engineering logistics involved in the management of such a system. Finally, the integration of a filling system with an existing mining operation is examined.

Jan 1, 1988

The kinetics of adsorption of gold di-cyanide onto activated carbon has been investigated extensively over the past two decades. These studies have demonstrated that both film and intra-particle mass transfer affect the kinetics. The dominant mechanism of intra-particle mass transfer has not yet been identified. In the work described, surface diffusion and pore diffusion are considered as possible rate-determining mechanisms of intra-particle mass transfer. Mathematical models are described that incorporate film mass transfer and the respective intra-particle mass transfer mechanism with equilibrium described by a Freundlich isotherm. Rate constants of film mass transfer and pore or surface diffusivities were estimated by the fitting of the respective models to experimental carbon adsorption data. The estimated pore diffusivities, after they had been corrected for the porosity and tortuosity of the carbon, were found in most instances to be higher than the molecular diffusivity of dilute gold di-cyanide in aqueous solution. This situation is not physically viable. The surface diffusion mechanism acting in parallel with the pore-diffusion mechanism is thus responsible for the intra-particle transportation of most of the gold.

Jan 1, 1996

By R. G. B. Pickering, H. H. Haase

Few innovations in the South African gold mining industry could have a more significant impact on improving profitability than non-explosive methods of mining. The far-reaching benefits of this approach are explained and the progress made through development work funded by the industry is described. Three methods are considered: impact ripping, sloting with abrasive waterjets and diamond saws, and breaking from drilled holes with waterguns and electric pulses. Of these methods, impact ripping is the most advanced and requires only minor refinements before production applications can be initiated. Although this method, based on current performance, is expected to yield considerably increased profits, it is predicted that it could perform several times better than at present with further development. The other methods of rockbreaking also show potential. Waterguns and electric rockbreaking would be attractive in unfractured rock for difficult geological conditions, and for confined areas such as gullies and development ends. Methods based on sloting could be combined with any of the other methods to enhance their effectiveness and thus yield further improvements in profitability; also, they could be used to advantage in specific applications. Al the discussed methods, therefore, deserve to be developed further.

Jan 1, 1991

By L. A. Cornish, I. A. Mwamba, R. A. Couperthwaite

"In previous work by the authors, it was established that additions of 0.2 at.% Ru to an Fe-40 at.% Al alloy improved the corrosion and oxidation resistance of the alloy. The alloy was produced by mechanical alloying and spark plasma sintering and the work showed that nonequilibrium processing was able to significantly refine the grain size of the material. The sintered material had a higher hardness than the as-cast material and the change in grain size did not significantly affect the oxidation and corrosion. In the present research, the mechanically alloyed powder was coated onto a mild steel substrate using cold-spray coating at a gas pressure of 10 bar and a temperature of 500°C. The coatings were found to be 5–10 um thick, although thicknesses of up to 30 um were observed. The coated materials were subjected to oxidation and corrosion tests to determine the effectiveness of the coating in increasing the oxidation and corrosion resistance of mild steel. This was done to determine the effectiveness of cold-spray coating as a technique to coat these mechanically alloyed powders. IntroductionPrevious work conducted by Mintek (Couperthwaite et al., 2013, 2015) investigated the effect of precious metal additions on the structure, oxidation and corrosion properties of an Fe-40 at.% Al (Fe- Al) alloy. Initial work determined that additions of more than 0.5 at.% precious metal did not improve the oxidation and corrosion properties of the materials and in some cases even decreased the resistance to corrosion. Further work identified Pt and Ru as beneficial additions to the FeAl alloy. Four alloys were then produced by mechanical alloying and sintering (FeAl–0.2 at.% Pd, FeAl–0.2 at.% Ru, FeAl–0.5 at.% Ag, FeAl–0.5 at.% Pt). These alloys were all successfully produced by melting and casting and mechanical alloying sintering and it was found that the nonequilibrium processing greatly decreased the grain size of the materials compared to the ascast materials. It was found that the additions of Ru and Pt were still the most beneficial to the oxidation and corrosion properties, with Ru being considered the most beneficial."

Jan 1, 2016