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By R. T. Tshikhudo

Nanotechnology can provide solutions to many of the world?s socio-economic challenges. The application of nanomaterials for water treatment and analysis, point-of-care diagnostics and targeted drug delivery systems or devices could improve the quality of life for people in developing countries. Gold colloids have a long history (dating back to the 4th century AD) and are particularly well known for their aesthetic appeal and their therapeutic properties. Since Faraday published a report on the synthesis and properties of colloidal gold in 1857, a reasonable insight into the nature of gold sols (nucleation, growth and kinetics of coagulation) has been developed. Considerable attention has been drawn during the past few decades to the development and optimization of methods for the preparation of gold nanoparticles. In nanoscience and nanotechnology today, gold nanomaterials appear to be the most widely used material by both academics and industrialists. This is due to the extraordinary properties of gold nanoparticles (e.g. optical, catalytic, and magnetic?they are also known to act as strong Raman enhancers and may also amplify fluorescence under certain circumstances). Mintek, through Project AuTEK and the DST/Mintek Nanotechnology Innovation Centre (NIC), has been at the forefront of the development of new industrial uses for gold. Mintek?s gold nanotechnology programme focuses on the development of gold-based nanostructured materials and their applications in health, water and other related areas. While few projects use gold nanoparticles for water treatment and analysis, Mintek?s gold nanoparticles are widely used in the health sector. For example, gold nanoparticles are engineered and produced in large quantities as systems for targeted drug delivery. They are also used as tools for advanced rapid diagnostic tests. Both optical and electrochemical rapid diagnostic methods are developed for the human and animal health sectors for point-of-care testing. This paper gives a brief introduction and overview of gold nanotechnology, and desrcibes the development of some of Mintek?s gold nanoparticle targeted drug delivery systems and lateral flow point of care prototype devices.

Jan 1, 2009

By J. Saunders, N. Pretorius, G. Krafft, T. P. Katakwa

Imagine being able to see all the future planned mining activities in real time. This is exactly what SIMS (Short Interval Management System) will enable you to do. SIMS is a real time short interval control system that continuously measures and sets optimised plans for mining production processes. The system utilises algorithm-based software that takes resources (people, equipment, tasks, and workplaces) and gives you the best achievable plan. The algorithm was developed using methods found in the field of metaheuristics. A metaheuristic is a strategy to designed to efficiently search for optimal or near optimal solutions to problems that are very complex computationally. (Glover, 1986) There are several algorithms that have been developed to solve optimisation problems which are difficult to solve using traditional techniques. This has given rise to a field called evolutionary computing. (Simon, 2013) Examples of these techniques are genetic algorithms, particle swarm optimisation, and ant colony optimisation. These methods are used to solve problems in a variety of fields. As an example, Kok and Lane (2012) used particle swarm optimisation for equipment allocation in a mechanised underground mining environment. The first SIMS deployment took place in a platinum underground tabular mechanised mine near Burgersfort (province?) from 2017-2019. This included the development from a paper-based system to a fully operational online system. SIMS then moved to a second site and is currently being tested in a second platinum underground tabular mechanised mine in South Africa. Full deployment of the system is currently being phased in. SIMS was built in response to issues that have been plaguing the mining industry for years. These issues are all aligned into one major problem statement: how can we optimise mining production processes without compromising safety? This product was developed by combining years of mining experience with software development. SIMS is based on a four-pillar concept. Safety, productivity, accountability, and business improvement. SIMS uses a set of pre-configured mining and production rules, and with the resources that are available, to determine valid short term production plans. A background algorithm then determines the optimum plan to be executed. The system continuously produces a set of job cards that are pushed to respective operators on their allocated tablets. The management portal component allows you to view and manage all current and planned work on any connected device available. This allows real time visibility of completed, current, and planned work to operators, service departments and management, i.e., seeing into the future.

Sep 1, 2021

THE BRITISH COUNCIL AWARDS 1971-1972 The British Council invites applications from permanent residents of the Republic of South Africa and South West Africa, for the following awards: SCHOLARSHIPS Scholarships are available to such permanent residents who hold university degrees or comparable professional qualifications. The scholarships are tenable for postgraduate study at universities and other educational establishments in Britain for the academic year of approximately ten months beginning 1st October, 1971. BURSARIES Bursaries are available to such permanent residents who hold university degrees or who, being already established in their professions or trades, hold other qualifications. The bursaries are tenable at British educational institutions or other suitable establishments in Britain for a course of training, study or research lasting not less than two months or more than six. The British Council may, at its discretion, bear the cost of single or return fares to Britain. The closing date for applications is 31st July, 1970. TRAVEL GRANTS Travel grants each of £300 are available in respect of journeys to Britain undertaken between 1st April, 1971 and 31st March, 1972 and are provided to facilitate visits to British universities by persons holding staff appointments or graduate research posts at South African universities. Visits must normally be of at least six months duration. The closing date for applications is 31st October, 1970. For further particulars and the relevant application forms please write stating the type of award for which you wish to apply to: The Cultural Attache, British Embassy, Pretoria. THE SECOND INTERNATIONAL CONFERENCE ON THE PROPERTIES OF LIQUID METALS Tokyo, September 1972 The Second International Conference on the Properties of Liquid Metals will be held under the auspices of The Japan Institute of Metals and The Physical Society of Japan from 3rd to 8th September, 1972 in Tokyo. The purpose of this conference is to continue and extend the efforts towards the objective of the First International Conference on the Properties of Liquid Metals at Brookhaven, 1966. The tentative Conference subjects presently planned are: Structure of Liquid Metals and Alloys; Atomic Transport Properties (Diffusion, Viscosity, etc.); Electronic States and Transport Properties; Thermodynamical Properties; Melting and Phase Transitions. Correspondence regarding the Conference and the request for the First Notice should be addressed to: Professor S. Takeuchi, Chairman of the Organizing Committee, The Research Institute for Iron, Steel and Other Metals, Tohoku University, Sendai, 980, Japan. PROCEEDINGS OF THE NINTH COMMONWEALTH MINING AND METALLURGICAL CONGRESS 1969 Volume 4 of the Proceedings of the Ninth Commonwealth Mining and Metallurgical Congress 1969- Physical and fabrication metallurgy-contains the 24 papers presented under this general heading at the Congress. Also included are discussion, authors' replies, name and subject indexes, and plenary addresses by Sir Val Duncan, O.B.E. and Sir Ronald L. Prain, O.B.E.

ORANGE FREE STATE BRANCH MINUTES OF THE COMMITTEE MEETING HELD IN THE WELKOM CLUB ON WEDNESDAY, 8th NOVEMBER, 1972 Present: C. J. Isaac (in the Chair), E. T. Wilson, J. M. Meyer, C. Mostert, P. L. Nathan, D. A. Smith, R. Sutherland. Apologies: G. Young. MINUTES OF THE PREVIOUS COMMITTEE MEETING The minutes of the Committee Meeting held on the 19th January, 1972 were taken as read and thei r adoption was proposed by Mr J. M. Meyer and seconded by Mr E. T. Wilson. There were no matters arising from these minutes.

By S. M. H. Ahmadi, K. Barani, F. Moradpouri, R. Ghaedrahmati

As exploration is time-consuming, costly, and risky, determination of the erosion surface of a metalliferous deposit before geophysical surveying and exploration drilling might be very helpful. Geochemical haloes can be used to determine whether the erosion surface is supra-ore or sub-ore and thus reduce the risk of exploration operations. The aim of this investigation is to determine the erosion surface of the North ROK porphyry deposit (NRPD) in northwestern British Columbia in Canada using linear productivity (LP), which is the content of an element defining the halo multiplied by the width of the halo. A total of 2045 soil samples from the B horizon were analysed using ICP-MS for 36 elements, including Cu, Mo, Pb, Zn, Au, As, Ag, Ni, Co, Fe, and Mn. The data-set was snalysed to obtain the statistical parameters and the elements Cu, Mo, Pb, and Zn were chosen to calculate the linear productivity and the total linear productivity. These four elements were modelled using probability plots to identify and separate subpopulations in terms of anomalous haloes and background, including the threshold values of each subpopulation. The results of the probability plot modelling and thresholds values were then used to map the distribution of each element in a GIS to calculate the linear productivity. The total linear productivity indicated that the erosion surface is supra-ore. Finally, a 3D orebody model of the Cu, Mo, Pb, and Zn distributions was constructed using borehole data and used to validate the results.

Feb 6, 2023

By J. Petersen, S. W. Robertson

Heap leaching is used extensively for the processing of low-grade copper, gold, and uranium ores. The hydrodynamics is often the most important factor that limits the rate of metal recovery. Over the past decades the author has performed physical and hydraulic testing of a large number of ore samples considered for heap leaching. The data were reviewed to investigate the effect of physical properties such as particle size distribution (PSD) and bulk density on the hydrology. The unsaturated flow through the bed is traditionally modelled with soil science models such as Brooks-Corey (BC) and Van Genuchten-Mualem (VGM), which relate the hydraulic conductivity to the degree of saturation, also known as the hydraulic conductivity function (HCF). However, most authors found a disconnect between the saturated hydraulic conductivity (KS) and the rest of the HCF, which is explained as resulting from a transition from capillary-to gravity-controlled flow. However, the author found no such transition, and found the flow to be governed by capillary flow throughout. Traditional BC or VGM fits were found to be appropriate, however it was necessary to modify the model to include a point of inflection, above which the hydraulic conductivity remains constant while the moisture content keeps on increasing. It was proposed that this is the result of unconnected or poorly connected pores, which fill with solution but do not create additional flow channels. The point of discontinuity was also found to correspond with the air entry point, measured independently from the air conductivity curves. On average, the air entry point corresponds to the experiential rule that the void saturation should remain below 65% for aerated heaps.

Dec 11, 2024

By R. Van Deventer

The BIOX® process was developed for the biological pre-treatment of refractory gold ores and concentrates ahead of conventional cyanide leach gold recovery. Rights to the process are currently with BIOMIN Technologies SA, a subsidiary of Gold Fields Limited. There are currently eight operating installations worldwide employing the process on a commercial scale. EKATO is a company specializing in developing new or optimizing existing mixing applications. EKATO has acquired a vast amount of expertise in agitation over its 75 year history. In a joint research project the reactors of the BIOX® process were characterized from the aspect of their mixing performance. BIOMIN is constantly testing new mixing solutions and reviewing potential vendors to increase the efficiency of the BIOX® process. EKATO?s intention was to qualify as an approved vendor for supplying agitation equipment to the BIOX® process. A two step approach was planned: In phase one of the project EKATO would develop an alternative agitation solution to the established option, exhibiting at least similar performance levels. In phase two potential possibilities to improve the overall design would be developed. This paper focuses on phase one and addresses the systematic approach applied by EKATO in characterizing the mixing processes. Mixing tasks were assessed individually applying basic theory and scale-up and -down rules to the individual tasks. Testing with model systems was done at the EKATO technology center in Schopfheim, Germany, on scales of 50 liters and 1 m³. The results showed that the ISOJET-B impeller design showed promising performance under BIOX® reactor conditions. Scale-up with the ISOJET-B was done in order to apply it in the 21 m³ live volume test reactor at Fairview mine in South Africa. At Fairview tests were performed using model systems and eventually under real plant conditions with BIOX® slurries. The results were a success and confirmed that the scale-up factors determined during the testing at EKATO?s technology center could be substantiated in the ?model scale? 25 m³ reactor. Testing under the actual process conditions showed that all design parameters were within the desired range to be considered an excellent leaching performance. This successful joint development shows the importance of a close cooperation of technology licensors or end-users and equipment suppliers. It is vital for understanding all factors influencing the mixing performance of processes. Exercises such as this will provide equipment suppliers and plant operators more confidence in managing further scale ups at ever larger engineered plants.

Jan 1, 2009

NEW BOOKLET FOR POTENTIAL ENGINEERS A new booklet "Professional Careers in Engineering" for issue to high school students who are considering engineering as a profession has been prepared for general distribution. The booklet is intended to help high school students to decide whether a career as a professional engineer would appeal to them, and to tell them how to set about becoming a professional engineer. Copies of the booklet may be obtained free of charge by writing to: The Federation of Societies of Professional Engineers, P.O. Box 5907, Johannesburg.

By Roger A. Blais, Michel David

"Matheron's geoslalislical method for the estimation of ore reserves has been developed to the point at which real-life problem may be handled effectively. The steps involved in the method are:(i) obtalning the variogram,(ii) fitting a model, and(iii) producing block estimates.All three steps may cause difficulty, and would-be users need a deep understanding of the theory if failure is to be avoided.To illustrate these points, specific cause are considered:(i) two almost equidimensional porpbyry deposits, one drilled randomly and the other regularly; and(ii) two iron formation, one drilled extensively and being mined, while the other is still at the stage of early estimation."

Jan 1, 2014

By P. M. Solozhenkin, O. I. Solozhenkin

Currently lead nitrate is used as the recommended activator in Au-Sb flotation. However, due to high levels of hazard, the application of lead nitrate constitutes a potential risk for human health and ecosystems. To mitigate the harmful impact of activators on the environment, further research on activation by alternative reagents has been launched to promote the efficiency of antimony ores. In the present study, adsorption of lead, copper and zinc cations has been investigated by nuclear quadrupole resonance (NQR), which has revealed copper and zinc cations penetration into the mineral lattice, although lead cations remain adsorbed on the mineral surface. However, the combination of zinc and copper cations leads to preferential volumetric adsorption of zinc in the mineral lattice and further surface adsorption of copper which positively affects the activation process. It has been established that activation of stibnite can be achieved effectively with the mixture of Cu2+:Zn2+=1:1 as much as with lead cations in antimony ore flotation. As a part of this work, the computational modelling has been used in prognosis of reagent activity evaluation (PRAE) for stibnite and aurostibite flotation by sulfhydryl collectors. The lower PRAE value the stronger the ability of a collector to form a stable complex with a mineral. PRAE has shown a strong negative trend to complex formation on the mineral surface of aurostibite and stibnite. Based on these studies, several collectors have been proposed for effective flotation. To verify the feasibility of proposed collectors tetramethyl (ethyl) thiuram disulfides (TMTD and TETD) have been used for flotation of stibnite, sphalerite, pyrite and arsenopyrite. Flotation performance has been improved significantly with TMTD that allows the avoidance of lead nitrate application and increases the recovery of antimony by 8,16%. Keywords: Stibnite, aurostibite, activation, lead, copper, flotation reagents

Jan 1, 2020

By Xiang-nan Zhu, Hao Zhang, Lin Li, Jun Qiu, Yue-xian Yu, Chun-chen Nie, Xian-jun Lyua

Waste printed circuit boards (WPCBs) are excellent metal resources. Mineralogical characteristics of different components in WPCBs were analysed in this study. Organic-enriched particles, fibreglass-enriched particles, associated particles and metal-enriched particles were obtained by density gradient method. Subsequently, the elemental composition, morphology, dissociation characteristics, functional group composition and phase composition of different components were analysed by X-ray fluorescence spectrometer (XRF), scanning electron microscopy and energy dispersive spectrometer (SEM+EDS), infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Elemental analysis results show that Cu is mainly contained in metal-enriched particles. SEM+EDS analysis results demonstrate that ideal dissociation can be achieved when the WPCBs are broken to -1 mm. Organic matter particles are enriched with carbon and oxygen elements, while fibreglass particles and associated particles mainly contain Al and Si elements, verified by XRD analysis. FT-IR results show that hydrophilic and hydrophobic groups exist widely in all components, caused by widespread organic matter. This study reveals the important properties of different components in WPCBs, which is of great significance for the subsequent separation process. Key words: Waste printed circuit boards, mineralogical analysis, elemental composition, dissociation; phase analysis, functional group composition

Jan 1, 2020

By M. Izadi Yazdan-Abadi, S. H. Amiri, M. Ramezanizadeh, M. Bazmandeh

Iron ore concentrate is used as the fresh feed of pelletising plants. The green pellet properties depend on iron concentrate characteristics such as particle size distribution (PSD), specific surface area (Blaine value), iron grade, moisture content and grinding methods. The grinding methods affects particle size distribution and Blaine value. To find out the effects of grinding methods on pelletising process, green pellets were produced with concentrates that were reground by means of HPGR (high pressure grinding rolls) and ball mill. The Blaine values of ground concentrates in both types of milling were approximately 1400, 1600 and 1800 cm2/gr. The results of green pelletising tests on a pilot plant scale showed that at the same Blaine values, drop numbers of green pellets produced by ground concentrate inside HPGR were higher than the green pellets produced by ground concentrate inside a ball mill. Also, reground concentrates by means of HPGR, in comparison with ball mill, caused the production of green pellets, at higher wet and dry compression strengths. As a result, it was found that preparing the pelletising feed by means of HPGR led to more positive effects on the properties of green pellets. Keywords: Ball mill, HPGR, green pellet, drop number, wet and dry compression strengths

Jan 1, 2020

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

2nd CONGRESS OF THE INTERNATIONAL SOCIETY FOR ROCK MECHANICS The 2nd Congress of the International Society for Rock Mechanics will be held in Belgrade, 21-26 September, 1970. The Congress will include: working sessions, study tours, receptions, excursions introduced in the working sessions and post-congress excursions and special programme for accompanying persons. Anyone interested in rock mechanics and its applicarion may take part in the 2nd Congress. Official languages of the Congress are: English, French and German. Simultaneous translation service will be provided during the Congress. All the correspondence concerning the 2nd Congress of the International Society for Rock Mechanics should be addressed to: Sekretarijat 2. kongresa Medjunarodnog drustva za mehaniku stena Institut za vodoprivredu "Jaroslav Cerni" Bulevar vojvode Misica 43, Postanski fah 530 Beograd - Jugoslavija NINTH INTERNATIONAL SYMPOSIUM TECHNIQUES FOR DECISION MAKING IN THE MINERAL INDUSTRY The Symposium which is to be held in Montreal during the week of June 14-19, 1970, follows the Computer Symposium held in Salt Lake City this year. The purpose of the Symposium is to define the role of decision making techniques within the mineral industry and to stimulate the development of specific applications. The subject of the Symposium-mathematics, operations research and computers as applied to the mineral industry-allows a complete picture of the mineral industry in its public policy, corporate, financial and technological environment to emerge. This is another of the series of symposia on this and related subjects started in the early 1960's at the University of Arizona. Sponsorship has included a number of Universities and the Society of Mining Engineers of the American Institute of Mining. This 1970 symposium is the first to be held outside of America, and is being sponsored by the Canadian Institute of Mining, McGill University and Ecole Polytechnique. A number of delegates from South Africa have participated in these symposia and several have already arranged to attend this symposium in Montreal. Enquiries should be directed to: Secretariat, The 9th International Symposium, Department of Mining Engineering, Ecole Polytechnique, P.O. Box 50l, Snowden, Montreal 248, Quebec, Canada. 24th INTERNATIONAL GEOLOGICAL CONGRESS This Congress is to be held in Montreal, Canada, from August 21 to 30, 1972. A very detailed and extensive programme has been proposed, and includes a number of excursions. Copies of the first circular are obtainable from: The Organizing Committee, 24th International Geological Congress, 601 Booth Street, Ottawa 4, Ontario, CANADA. SYMPOSIUM ON THE RECOVERY OF PYRITE The proceedings of the Symposium on the Recovery of Pyrite, held in Johannesburg on 12th to 13th June 1969 are now available. Copies may be ordered from the Secretary, S.A.I.M.M., P.O. Box 61019, Marshalltown, Transvaal at a cost of R10.00. Papers and addresses presented at the Symposium were: Opening Address by Mr J. K. E. Douglas (President). 'The world sulphur position,' by W. C. J. van Rensburg (Member). 'The South African sulphur position,' by D. L. Taylor (Member). 'The recovery of pyrite at Government Gold Mining Areas Limited,' by R. J. Westwood (Member), G. S. Stander (Affiliate) and H. R. Carlisle (Member). 'Recovery of pyrite concentrates from colliery-waste discards-A preliminary assessment,' by W. A. Gilbert (Visitor) and E. A. Nugent (Member). 'The role of pyrite in upgrading the uranium content of Witwatersrand conglomerate ores by means of the heavy-medium separation process,' by D. J. Tutt (Associate Member). 'Pyrite recovery by jigs at Durban Roodepoort Deep Limited,' by E. J. Dominy (Affiliate), F. Diamond (Affiliate) and A. D. Graham (Affiliate). 'The storage of pyrite concentrates,' by Joan C. Campkin (Visitor) and P. J. Lloyd (Member). 'The flotation plants of the Anglo- Transvaal Group,' by L. A. Bushell (Member). 'Pyrite flotation with amines and cyanidation of the products,' by E. H. D. Carman (Member). 'Gold recovery by cyanidation from mill products obtained after pyrite flotation,' by P. G. Mrkusic (Graduate), M. Sciarone (Visitor) and H. E. Simonsen (Visitor). 'The influence of sulphydral and cationic flotation reagents on cyanidation of native gold,' by K. G. Ashurst (Visitor) and W. P. Finkelstein (Member). 'Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collector,' by J. Levin (Member), and M. L. Veitch (Visitor). Closing Address, by Dr R. E. Robinson (Director, National Institute for Metallurgy).

By Brian W. Mackenzie

The mineral exploration environment has observable economic characteristics, the assessment of which provides guidelines for exploration planning in the mining company. The long-term survival of the mining company is directly dependent on successful exploration. Exploration planning contributes to successful exploration through the development of exploration strategies. The objective of exploration planning is to select exploration environments which will enable the mining company to realize best possible profit and corporate risk conditions. Thus, the formulation of exploration strategies is based on profit and corporate risk criteria. Strategic considerations include the selection of commodities as exploration targets, geographic concentration of exploration effort, the realization of acceptable survival conditions, and the structuring of an exploration programme to optimize the economic benefits of the exploration investment process.

Jan 1, 2014

By L. Thomas, A. Argyn, B. Mbao, G. Longo Banza

Since the first application of solvent extraction as part of the hydrometallurgical processing of copper, several studies have been carried out to optimize extractant formulations. In 2006, Solvay developed the ACORGA® OPT series of solvent-extraction reagents to optimize copper transfer by use of a blended formulation containing both aldoxime and ketoxime as well as selected modifiers. The incorporation of selected modifiers in these blended reagents resulted in increased copper transfer, due to the interaction between the modifier and oximes within the blend. By changing the ketoxime concentration and ratio of modifier to aldoxime, the strength of the formulation was optimized to enhance copper transfer and improve Cu:Fe selectivity. This formulation is well known in the African region under the ACORGA® OPT5540 name and provides the best performance at the conditions of agitated leach plants with pregnant leach solutions that fluctuate in Cu grade and pH. This paper discusses advantages of using ACORGA® OPT5540 in the Copperbelt

Jan 1, 2023

By O. Fenn

Earlier work had shown that the use of water jets at moderate pressure enhances mechanical cutting in hard rock. To assess the potential of this technique for use in conjunction with free-rolling cutters, a series of laboratory tests was conducted with disc and button cutters to determine the effect of variations in the jet and cutting parameters on the cuter performance. In these tests it was found that the use of water jets at pressure in the range 5 to 40 MPa can reduce the forces on a free-rolling cuter by 40 per cent, which represents a significant improvement in cutting performance. The reduction in thrust force was found to be dependent on jet pressure: the greater the pressure, the greater the reduction. The reduction in rolling force was independent of jet pressure over the range investigated. The results indicate that no additional improvements in cutting performance of any significance are to be gained by an increase in jet pressure above 40 MPa. The most effective jet configuration for the reduction of cuter forces was found to be four coherent water jets, two lateraly disposed on each side of the cuter and directed at the arc of contact between the cutting edge and the rock.

Jan 1, 1987

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

By G. M. Dunn

Pressure leach autoclave circuits are employed in the leaching of ores, concentrates, mattes, alloys and intermediates for the recovery of metals into solution. Once the metals are extracted into solution, the value metals can be recovered by hydrometallurgical means such as by purification followed by electrowinning, hydrogen reduction, pyrohydrolysis, crystallization and other unit operations. In many of these integrated flowsheets the pressure leach step is pivotal to the recovery of the value metals from the host material. Furthermore, the autoclave circuit invariably is a high capital cost component of the plant and an area that is carefully scrutinized when debottlenecking and capacity increases are being considered. This paper identifies a unique proven way of increasing the capacity of existing or new exothermic pressure oxidative leach autoclave circuits by as much as two or three times.

Jan 1, 2009

By E. M. W. Skinner

Various models of near-surface kimberlite pipe emplacement have been proposed over the years. These include a top-down, phreatomagmatic model, a bottom-up, embryonic pipe model and three top-down explosive dyke models. AU of these models consider kimberlites as essentially the same rock type. However, different kimberlites have different pipe shapes and contain different rock types with very specific mineral assemblages and textures and therefore are likely to have been emplaced by different processes. Some authors have considered local geological differences as the principal reason for the contrasting geology but others argue that, while geological differences might contribute locally the petrographic peculiarities of particular kimberlites may be due mainly to inherent compositional differences specifically in the ratios of juvenile CO2 and H2O.

Jan 1, 2010