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By Stephen A. Swan

Bureau of Mines researchers have collected and evaluated rollover protective structures (ROPS) f or more than 10 yr. ROPS and falling object protective structures (FOPS) are required on specified mining machines under regulations of the Mine Health and Safety Administration (MSHA). Both ROPS and FOPS are required on mining machines used in surface coal mines and surface areas of underground coal mines (30 CFR 77.403 and 7 7.4 13a), and ROPS are required on mining machines used in metal and nonmetal mining operations (30 CFR 55, 56, and 57.9-88). This illustrated manual provides mine safety personnel, MSHA inspectors, and original-equipment manufacturers with guidelines and a check- list for inspecting ROPS being used in the field. The manual discusses specific requirements of the MSHA regulations and minimum inspection and maintenance checks for ensuring compliance with those regulations. An easily reproducible checklist is provided as an aid to the inspection of ROPS.

Jan 1, 1985

By Arnulf P. Hagen

This project was designed to explore the suitability of using fluorinated inorganic materials as solvents for the in situ mining of thin seamed, heavily overburdened coal; to build a data base for the selection of an inorganic solvent for use for coal cleaning; to determine if fluorinated solvents will reduce the organic and inorganic sulfur contents of the coal, as well as to lower the ash content. The coal samples have been combined with pure solvent, as well as with aqueous solutions at atmospheric pressure and at increased pressure. The increased pressure experiments are important since they duplicate the conditions anticipated for an in situ cleaning and mining operation. Trifluoroacetic, difluorphosphoric (phosphorodifluoroidic), and trifluoromethanesulfonic acids have been found to be effective for the cleaning of high sulfur, high ash coal at 300°C and at atmospheric pressure. At pressures up to 20,000 psi the effectiveness of these reagents is not decreased.

Jan 1, 1983

By John W. Finch

The Secretary of the Interior acting through the Bureau of Mines and the Geological Survey is authorized by the Strategic Materials (Public No. 117 - 76th Cong., Chapter 190 1st Sess.) to make investigation concerning essential minerals of which the quantities or grades obtainable from known domestic sources are inadequate. The Bureau of Mines, in carrying out its part of this program, may investigate deposits of such minerals in whatever manner may be necessary, in order to determine (1) the extent and quality of the are, (2) the most suitable method of mining and beneficiating it, and (3) the cost at which it may be produced. The essential objective in doing these things is to determine where and how supplies of minerals and metals of which domestic production is usually inadequate might be obtained in a national emergency, even though at higher cost than usual.

Jan 1, 1939

By W. P. Diamond, John C. LaScola, D. M. Hyman

In 1972, the Bureau of Mines developed a direct-method test for measuring the gas content of virgin coal core samples for coal mine health and safety considerations. Since that time, approximately 1,500 coal samples from more than 250 coalbeds in 17 States have been collected for gas content determination. The gas content data, when combined with geologic and engineering studies, can be used as a basis for a preliminary estimate of mine ventilation requirements, and to determine if methane drainage in advance of mining should be considered. The data are also critical in delineating coalbed methane resources and in utilization feasibility studies. This report makes the Bureau's extensive data base of gas content data more readily available to the coal and gas industries. The data are presented in tabular form, alphabetically by coalbed name and by State. The components of the total gas content (lost, desorbed, and residual gas) are given, Location (State and county), sample depth, coalbed or formation name, and coal rank are included for geographic and geologic identification.

Jan 1, 1986

By Charles W. Huggins

The Bureau of Mines investigated palygorskite, a natural asbestiform material, to accumulate knowledge that might serve as a foundation for future synthesis of a similar material. Unit cell, chemical analysis, DTA, TGA, optical constants, and electron microscopy data were obtained. Selected palygorskite samples of bettor than 97-percent purity were used to obtain this information. Chemical analysis revealed the following formula: (OH2)4 (OH)2 Ca0.01Fe0.02K0 .c3Mg2.10A12.00Si7.93020.3.91 H2O. The optical constants for sodium light are a = 1.522; S = 1.530; ?=1.533; biaxially (-). The following orthorhomibic unit cell constants were determined: ao = 12.690 A, Z = 2, bo = 17.857 A, Dx = 2.327. co = 5.207 A, Identical diffraction patterns resulted from the three palygorskite samples that were studied. X-ray, chemical, DTA, TGA, and optical data were compared with literature values for similar fibrous materials. X-ray diffraction lines were indexed. Several electron micrographs were made to compare the structures of palygorskite and attapulgite with that of chrysotile. The micrographs revealed extremely short laths for attapulgite, very long flexible laths for palygorskite, and tubular structure for chrysotile.

Jan 1, 1962

By R. V. Thurston, Edmund S. Leaver

"During the development of the sulphur dioxide leaching process for the treatment of ""mixed"" copper ores at the Southwest experiment station of the Bureau of Mines*** the pulp from treatment of roasted cupriferous pyrite with sulphur dioxide gases and water showed an unexpected amount of sulphuric acid. After following out several false premises it was found that this was due to iron in the solution, and also that this iron tended to oxidize to the ferric state if the concentration of sulphur dioxide in the roaster gases used did not rise above a certain figure. While the percentage of iron present was email it was enough to cause an entirely different set of conditions from those of the original sulphur dioxide leaching process and to promise a much wider application of the general idea. Sulphurous acid dissolves only certain copper minerals, sulphuric acid solutions certain additional minerals and ferric sulphate solutions certain further additional copper minerals, so this observation was of importance in connection with possibilities in the hydrometallurgy of the so-called ""mixed"" or partly oxidized copper ores.The work has been carried along by a number of experimenters. L. R. Eckman, junior chemist of the Southwest station, contributed largely to the early developments. L. Roberts, W. D. Bonner and C. G. Maier each in turn physical chemists at the Pacific Experiment station, (Berkeley, Calif.) have studied the reactions involved. A complete report of all the work on this process will be prepared later under the direction of O. C. Rolston. The purpose of the present paper is to place a summary of the more practical phases of this seemingly important piece of work before those interested."

Dec 1, 1923

By Jack E. Fraley

Magnesium oxysulfate cement has been specially formulated as a sealant in underground coal mines for reducing sloughing of shale roofs and coal ribs, for reducing air losses through block stoppings, for constructing sprayed stop-pings over approved jute cloth or metal lath, and for reducing combustibility of polyurethane foam. A standard spray machine (Mining Enforcement and Safety Administration (MESA) approved) was used for the underground testing. Our research shows that a 1/2-inch coating reduces shale and coal sloughing, reduces air losses through block stoppings, and prevents fire propagation through a metal tunnel lined with polyurethane foam. During the underground tests, excess mixing water was used to improve pumping the slurry to the spray nozzle. This was later found to increase shrinkage cracks in the cured coatings. Controlling excess water is important to an acceptable coating.

Jan 1, 1976

By Joan C. Biordi

[Composition profiles for atomic, radical, and stable species, as well as temperature and area expansion ratio profiles, have been determined for a nearly stoichiometric CH4-02-Ar flame and one to which 0.3 percent CF5Br inhibitor had been added. Net reaction rate profiles were calculated for all the observed species. For the normal flame, these and the mole fraction profiles gave rate coefficient information about the elementary reactions in the methane flame, for example, CH. + 0 4- H2CO 0 H, k4 = 1.05 X 1014CM3 mole-1sec-1 for 1,550§T 0,725' K; CO + OH 4 C02 + H, k6= 4.7 X 1011 for 1,350{T X1,750° K. Comparison between the inhibited and normal flame showed that A] and [CH3] were significantly reduced at the lower temperatures in the inhibited flame even though in the hot gas region the [E] [OH!, and [0] were essentially the same in both flames. The CF3Br disappears very early in the flame, relative to the fuel, and the reaction primarily responsible for its disappearance is H v CF3Br 4 HBr + CF3, where k7 is found to be 2.2 X 1014 exp(-9460/RT) for 700-1,550° K. Reaction of the inhibitor with methyl radicals provides for the relatively small amounts of CH3Br observed, but CH3 + Br2 - CHs Br + Br must also occur. The HBr formed reacts rapidly with H atoms to form H2 and Br, but the reaction is soon "balanced" in the flame as may be demonstrated by calculation of the equilibrium constant at various temperatures. The fluoro-carbon fragment produced in reaction (7) also reacts rapidly, in part with methyl radicals to give the observed elimination product CH2CF2 Later in the flame, above -1,400' K, F2CO is formed from the reaction CH2CF2 + 0 P F2CO + CH2 and k., -1.5 X 1013 at 1,600° K. The rather slow decay of carbonyl fluoride is attributed to reaction with H atoms according to the sequence F2CO I H - HF + FCO and FCO + H HF + CO.]

Jan 1, 1975

By Richard Havens

Samples of low-grade oxide manganese ores were procured from two southern Utah properties by examining engineers of the Bureau of Mines during an investigation of manganese mineral deposits of continental United States. A 2-ton lot of ore was obtained from the Blackbird group of mining claims in Paiute County, 11 miles southeast of Marysvale, Utah. The deposit was described as an intrusive sheet or sill of altered brecciated rhyolite cemented together by manganese oxide minerals. A 2-ton sample from the Black John property, situated 32 miles northeast of Kanab, Kane County, Utah, was taken from open cuts on the vein. The blanket-type vein deposit consisted of nodules and streaks of manganese imbedded in compact gray clay.

Jan 1, 1949

By F. W. Hoertel

The effects of certain process variables on the grain size, grain type, and microhardness of vapor-deposited tungsten were established, and the near-optimum parameters and the efficacy for the vapor deposition process were determined. No significant change in the grain size or microstructure resulted from ultrasonic vibration of the substrate during deposition, from variations in the hydrogen (H2) to tungsten hexafluoride (WF6) ratio, or from small increases in reaction-chamber pressure. Near-optimum conditions were continuous deposition at atmospheric pressure, a deposition rate of 2-mils thickness/square inch of substrate area/hour, a temperature of 5500 C, and a hydrogen to WF6 ratio of 4:1. The addition, individually, of about 2 volume-percent of butane, 24 volume-percent of carbon dioxide, or 4 volume-percent of propane to the hydrogen and WF6 mixture produced deposits with the finest grain size for each gas. A corresponding increase in microhardness accompanied the decrease in grain size. The addition of gases did not alter the columnar microstructure found in vapor-deposited tungsten.

Jan 1, 1966

By B. S. Covino

The Bureau of Mines has conducted a laboratory and field corrosion test¬ing program to determine materials of construction for the leaching and gas-sparging crystallization environments of the clay-HC1 process in order to more fully utilize the alumina from domestically available kaolinitic clays. Laboratory tests were used to determine the corrosion rates of 22 metals and alloys by weight-loss measurements in these two environments of the process. The results of this laboratory study were used both to suggest metals and alloys for field testing and to determine the effect of the individual solution components on the corrosion behavior of the metals and alloys. Results from the field tests were used to recommend Ta, Ta-2.5W, and Ta-10W for con¬struction of the agitators for the leaching process. The metals and alloys recommended for construction of the gas-sparging crystallizer heat exchangers were Ta, Ta-2.5W, Ta-10W, Nb, Nb-1Zr, Nb-3Zr, Nb-28Ta-10W-1Zr, Nb-10Hf-1Ti, and Zr for the first stage and Ta, Ta-2.5W, Ta-10W, Nb-28Ta-10W-1Zr, Nb, Nb-10Hf-1Ti, and Zr for the second stage.

Jan 1, 1981

By A. F. Colombo

The differences in starch demands that occur between ore types subjected to the anionic flotation of calcium-activated gangue and the range of residual starch contents expected to give the best metallurgical response were evaluated on a batch and pilot plant basis. A phenol-sulfuric acid procedure was used to determine the residual starch contents in the iron ore slurries. Three pilot plant campaigns on samples from a group of orebodies located on the Marquette Range, Michigan, showed that in the rougher flotation pulp, a residual carbohydrate range of 25 to 100 ppm, which is equivalent to a 0.5 lb/short ton spread, yielded optimum results. Concentrates assaying at least 65 percent Fe and less than 6.0 percent Si02 and containing more than 80 per-cent of the recoverable iron were obtained. Both batch and continuous research indicated that starch adsorption is calcium modulated and relatively unaffected by the fatty acid additions employed. Residual starch level is not a critical control factor, but the addition must be adjusted to about 25 to 50 ppm residual starch and kept in this range for most effective utilization of the added tapioca flour.

Jan 1, 1972

By Guy A. Johnson

This Bureau of Mines report summarizes the results of efforts to develop reasonably priced, reliable mine shaft fire and smoke protection hardware for metal and nonmetal mines. The hardware was incorporated into a viable prototype system that would minimize fire and smoke hazards. The design of the system had to be sufficiently flexible to be utilized in a wide variety of metal and nonmetal mine shaft and shaft station configurations. As a result of long-term, rugged field tests, an improved (second generation) system was developed. The hardware is now commercially available.

Jan 1, 1978

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By David R. Hanson

Experimental work performed by the Bureau of Mines in a laboratory environment has shown that the formation of failure zones within certain rock types is accompanied by the emission of significant amounts of radiofrequency (RF) electromagnetic (EM) energy. This radiation was detected using nonresonant, "electrically short," broad-band antennas. Rock types for which emission was observed include granite, quartzite, and taconite; sandstone and marble did not emit measurable radiation. Amplitude spectra of the radiation showed the energy to be concentrated between 10 and 40 kilohertz. These data indicate that emission is directional, but this has not yet been proven. In addition, amplitude of RF emission increases with increasing crack size. Since emission was observed only for brittle quartz-bearing rocks, it appears the formation of piezoelectric fields is a necessary condition for RF radiation. Plausible mechanisms for emission include rapid decay of piezoelectric fields accompanying the sudden stress release at failure and/or the acceleration of an "exoelectron plasma" through the intense local piezoelectric fields. Since emission appears to increase with the scale of failure, and since antennas do not need to be coupled directly to rock surfaces as with conventional geophones, the possibility of developing a portable system to monitor seismically active areas exists.

Jan 1, 1981

By C. M. McCulloch

As part of the Bureau of Mines methane control program, the Pittsburgh coalbed was studied in Washington and Green Counties, Pa., and in Marion and Monongalia Counties, W. Va., where this coalbed is now being mined at its greatest depth. The coalbed thickness appeared to be structurally controlled; the bed was generally thinner near the axes of anticlines and thicker near the axes of synclines. The overburden isopach shows a similar relationship. Most of the clay veins in coal occur in the synclinal troughs, generally under sandstone roof. Cleat orientations measured in 18 underground mines showed that face cleats are perpendicular to the axial trends of the folds, and the butt cleats are parallel to the axial trends, indicating structural control of the cleat. Measurement and analysis of surface joint orientations provide a method for predicting the cleat orientations of the coalbed, but linears measured from infrared photographs and photoindex sheets helped only to determine regional trends. The results of these investigations provide a geologic framework for rational planning for underground mine development to use the best available technology to cope with methane emissions, coalbed discontinuities, and related ground support problems.

Jan 1, 1975

By V. R. Spironello

Operating variables affecting the efficiency of the basic oxygen furnace (BOF) and the level of contaminating elements in the steel product were investigated by the Bureau of Mines. Steel was made in a 400-lb-capacity BOF designed to rotate on its vertical axis to increase the area of hot metal surface subject to oxygen attack. Hot metal for the BOF was made by melting pig iron and scrap in an 18-inch (ID) cupola. The variables were BOF speed of rotation, rate of oxygen flow, number of jets and angle at which they were machined into the oxygen-lance tip, temperature of hot metal, reactivity of lime, and temperature of scrap for the BOF charge. Experiments were arranged according to a two-level fractional-factorial design. The effects of the seven variables were evaluated for 13 responses. The greatest ingot yield occurred while using the larger angle lance tip and jets. The most carbon burned per unit volume of oxygen resulted from rotating the BOF and using the smaller angle lance tip. The largest sulfur transfer to the slag occurred at the higher hot metal temperature levels and higher rate of oxygen flow.

Jan 1, 1970

By W. D. Bryson

This paper is one of a series being prepared by the United States Bureau of Mines on tunnel-driving methods. The practices described are those used at No. 11 mine of the Colony Coal Co., Denver, Colo. No. 11 Mine is situated at Dines, some 14 miles north of Rook Springs, in Sweetwater County, Wyo. It is served by a spur off the Winton branch of the Union Pacific Railroad. The Colony Coal Co.'s mines were opened in 1918, and since that time have been among the largest producers of coal for the railroad and domestic markets in the Rock Springs coal district.

Jan 1, 1932

By James C. Barker

Gold placer deposits along the upper Yukon River, in the region between the river villages of Circle and Eagle, were investigated by the Bureau of Mines. The investigation was conducted intermittently between 1976 and 1985 as part of an evaluation of mineral resources on lands proposed for inclusion in the National Park System. At least 230,000 troy ounces (tr oz) of gold has been produced in the region, principally from Woodchopper, Goal, and Fourth of July Greeks. The placers are underlain by, or occur downstream of, early Tertiary sediments that have been deposited in the Eagle Trough. Strike-slip displacement along the Tintina Fault is responsible for creation of the trough and may have been a factor in the formation of the present placers. Placers were found to have a close spatial correlation to certain altered fault lineaments of the Tintina Fault trench. Placer concentrates contain several different textural forms of gold, suggesting multiple origins. Geological studies and a survey of 162 panned concentrates throughout the region indicated previously unreported sites of placer gold, and potential exists for the discovery of additional placer and lode gold. Because of nearly continuous soil and vegetation cover, further evaluation of the region will require subsurface sampling.

Jan 1, 1986

By John M. Devine

The oxygen bomb-is used extensively for determining sulphur in petroleum, although it has been suspected that the results obtained with this method are somewhat lower than the true varies. In this paper are compared the results given by the oxygen-bomb and Carius methods, the latter being generally accepted as the standard procedure for the determination of sulphur in organic compounds. The Carius determinations given hero were made in connection with a special study of this method.4 Only petroleum oils of the less-volatile type are covered in the present work. Summary and Conclusions. When used with oils containing 2.3 to 0.15 per cent of sulphur the oxygen-bomb method gives results that are consistenly if slightly lower than those obtained with the Carius method. This variation, for the oils used, amounts to 3.1 per cent (on tae basis of sulphur present) for the sample containing 2.47 per cent of sulphur, and gradually increases (as the percentage of sulphur in the oils decreases) to 7.3 per cent for the oil containing 0.15 per cent of sulphur. With the oils studied the presence of ammonium nitrate in the bomb does not influence the results materially.

Jan 1, 1928