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By B. Z. Zhong, T. Ong, W. E. Wallace, W. Z. Whong, Z. W. Gu, M. J. Keane

"Abstract-Diesel emission particles (DEP) from an engine operating on the Federal Test Procedure VDC were dispersed in an aqueous mixture of dipalmitoyl lecithin (DPL). a major component of pulmonary surfactant and saline and were tested for genotoxicity using the unscheduled DNA synthesis (UDS) assay with autoradiography techniques in cultured Chinese hamster lung cells. A DEP sample from the same source was dispersed in dimethyl sulphoxide (DMSO) and subjected to the same assay. Both dispersions (in DPL and DMSO) were found to induce UDS in a dose-related manner. After separation of the sample into supernatant and sediment fractions. the activity of the DEP sample was found to reside in the supernatant fraction for the DMSO-dispersed sample; and in the sedimentary fraction for the surfactant-dispersed sample. These findings further indicate that genotoxic activity associated with DEP inhaled into the lung may become bioavailable through the dispersion properties of pulmonary surfactant components.INTRODUCTIONTHE mutagenicity of diesel emission particles (DEP) has been studied intensively (LEWTAS and WILLIAMS, 1986). Carcinogenic effects of diesel exhaust in exposed animals have been reviewed (NIOSH, 1988) and an evaluation of carcinogenic risks to humans from diesel engine exhausts has been published (IARC, 1989). Using components of pulmonary surfactant such as dipalmitoyl lecithin (D PL), dipalmitoyl phosphatidylethanolamine (DPPE) or dipalmitoyl phosphatidic acid (DPPA) dispersed in physiological saline, we have previously shown that diesel soots express mutagenic activities in the Salmonella histidine reversion assay system and in the sister chromatid exchange assay using the cultured Chinese hamster lung (V79) cells. Mutagenic activity of diesel soots dispersed in DPL, DPPE and DPPA was quantitatively comparable to and in some cases greater than, the activity expressed by an equal mass of soot extracted by dichloromethane-dimethyl sulphoxide (DCM-DMSO) (WALLACE et al., 1989).Unscheduled DNA synthesis (UDS) is accepted and frequently included, as one of the tests in the battery of assays used to assess carcinogenic-mutagenic potential -of chemicals (MITCHELL et al., 1983). In this study, induction of UDS in V79 cells by DEP, dispersed in the major component of pulmonary surfactant DPL, was carried out. The purpose of this study is to validate the suggestion generated from our previous work that mutagens associated with inhaled particles may be dispersed or solubilized in the phospholipid component of pulmonary surfactant and become active in such a phase (WALLACE er al., 1989) and to test the fractionated DEP sample using UDS assay for a more complete evaluation of its genotoxicity."

Dec 1, 1995

By Bradley V. Johnson

The Bureau of Mines constructed a microminer--a scaled-down (5-by 5- by 11-foot) continuous-mining machine of the drum type with a unique triaxially controlled head--for use in a research program to study the effects of continuous-mining-machine parameters on the generation of respirable dust. This report describes field research with the microminer at the Bureau's Experimental Mine at Bruceton, Pa. Experiments were conducted to determine the effects of depth of cut, rotational speed, and sump and shear rates on the generation of respirable dust. The cutting forces were also monitored and compared with depth of cut. There appears to be a reduction in the amount of respirable dust generated when the depth of cut is increased or rotational is speed lowered, Variation of other machine parameters seems to have little effect on dust generation.

Jan 1, 1975

By A. B. Hooker

A list of permissible mine equipment, tested and approved by the Bureau r. Mines previous to January l, i-)4, , was published in Bureau c Moines In ornation Circular 7207.3/ The l ,.t c -. that dote was complete as to equipmentthen available and in current Information Circular 7210,?+/ published as a supplement thereto, listed equipment approved during; the calendar 1942. Information Circular72x'3,_/ published as a second supplement thereto, ! listed equipment approved during the calendar year 1943. The present listis. Another supplement covering approvals issued during the calendar year 1c)44. The items are numbered crud to indicate the consecutive order in which each typo of machine or device was approved _.c?. in its particular classification. Thus Information Circular 7207 gave 1,t drills and drilling much fines on the Bureau'sactive.. d active list Ih: additional anal approval: were given in 1942 the three issued in 19 and one issued :n 1944- bring the total to `3. Item 111, under. Loading Machines and conveying appeared in lnformation Circular 7207. It is repeated ',tore to _how that on j,,l was granted Curia 1the optional of this loader when modified .'or 2 0. alt ciruits .]

Jan 1, 1945

By James V. Kelly

During the spring and summer of 1947, the Bureau of Mines conducted an investigation and core-drilling program in the vicinity of the Rodham mine, approximately 4 miles north of Shullsburg, Wis. This work was undertaken as a part of a general study of the zinc and lead-producing area of southwestern Wisconsin. Work in the Rodham-mine area was done to investigate further a mineralized area frilled in part by the Puritan Exploration Co., a Delaware corporation, with offices in Galena, Ill. Some significant lead-bearing samples were obtained, but no continuous ore body was disclosed as a result of the Bureau of Mines work.

Jan 1, 1949

By J. D. Davis

From the chemist's point of view it would be ideal if specifications for coke for any stated purpose could be written on the basis of chemical composition and burning characteristics. Unfortunately this is not possible. In fact, the physical properties of a coke are often of such major importance as to render any specified chemical requirements totally inadequate to show the quality of coke desired. For example, a furnace coke may admirably fill all chemical requirements, such as for low phosphorus, sulphur, moisture, and high fixed carbon, and still be too soft to support the burden of the furnace without excessive crushing. Again, a domestic coke though a good fuel as judged from Chemical analysis, may be of unmarketable size. Thus one can not define the quality of a coke for a specified purpose without taking into account both its chemical and physical characteristics even when this has been done the specification may fail because neither coke user nor producer can accurately define by quantitative tests the qualities most desired. In other words, there is need of accurate test methods for measuring the properties of coke and, what is equally important, for correlating the results with the behavior of the coke in use. Coke quality is determined by the kind of coal used, the coking process, and the type of equipment used in the coking process. Chemical analysis of the coals, together with small-scale coking tests, will give a good indication of their suitability; but, in general, coke must be produced on an industrial scale and tested in the equipment for which it is intended before conclusive information as to its quality is obtained.

Jan 1, 1928

By A. T. Iannacchione, D. G. Puglio

This Bureau of Mines study covers 25 underground mines that were active in the Upper and Lower Freeport and Lower Kittanning coalbeds in 1976. The coal ranges from low to medium volatile in rank; its primary use is for steam generation. Seven mines emit more than 100,000 cfd of methane gas; those mines are the deepest and largest producers. The methane gas content of three core samples of the Lower Kittanning coalbed was estimated by the direct method. A sample from a depth of 320 feet contained 0.5 cu cm of gas per gram, at 620 feet there was 0.8 cu cm of gas per gram, and at 1,060 feet there was 11 cu cm of gas per gram. These results suggest that methane control problems will be encountered in the future as deeper coal is mined.

Jan 1, 1979

By R. Barany

The heats of formation of goethite, ferrous vanadate, and manganese molybdate at 298.15° K were determined by solution calorimetry. For formation from the elements, the heat values were -133.7 ±0.3 kcal/mole for goethite, -453.8 ±0.5 kcal/mole for ferrous vanadate, and -284.8 ±0.2 kcal/mole for manganese molybdate. For formation from the oxides, the heat values were -0.9 ±0.1 kca1/mole for goethite, -19.4 ±0.3 kca1/mole for ferrous vanadate, and -14.6 ±O.l kcal/mole for manganese molybdate.

Jan 1, 1965

By D. Harrington

Research in connection with occupational diseases, including silicosis or, more definitely, pneumoconiosis, has been prosecuted much more actively in North American countries during the past 5 or 10 years than in any other known period. This applies particularly to the United States, owing largely to the fact that in recent years compensation for ill health presumed to be caused by industrial work of certain kinds is being paid to a far greater extent in this country than previously. Most other countries have had occupational-disease laws for many years. Court rulings in the United States, which started 5 or 6 years ago, have given a few heavy verdicts in connection with ill health or death caused, or alleged to have been caused, by some phase of occupational work other than traumatic injury, and these have called attention to the fact that ill health and even incapacitation can be caused by some kinds of employment. With the onset of the world-wide financial depression, which resulted in permanent abandonment of many business or industrial enterprises (among them mines) in the United States, the workers frequently believed that they could expect nothing in the future from their former employers, hence they felt free to demand monetary benefits or damages because of ill health which they suffered, or thought they suffered, because of their previous employment. The result was a flood of lawsuits and. compensation claims for occupational disease, particularly where dust was involved.

Jan 1, 1938

By B. W. Jong

The U.S. Bureau of Mines investigated anhydrous chlorination and caustic-acid leaching processes to recover Ni, Co, Mo, and W from waste hydroprocessing catalysts. In batch laboratory-scale equipment, the chlorination process extracted 61 to 99 pet of the metals. Final recovery was 65 to 99 pct. The caustic-acid leaching process extracted 81 to 98 pct of the metals. Final recovery was 36 to 99 pct. Chlorination processing included roasting, chlorination, hydrolysis of metal chlorides for recovering Mo or W, water leaching of Ni or Co from the spent charge, purification, and solvent extraction or precipitation of Ni or Co from the purified solutions. Caustic-acid leach processing included NaOH leaching, solvent extraction of Mo or W from the NaOH leach liquor, H2S04 leaching of the NaOH leach residue, purification, and solvent extraction or precipitation of Ni or Co from the purified solution. The estimated fixed capital cost for a commercial-scale plant processing 39,000 Ibid of waste Ni-Mo-AI catalyst was $8 million for the chlorination process and $9.6 million for the caustic-acid leaching process. The estimated operating cost was about $0.20 and $0.40 per pound of the waste catalyst, respectively, for the two processes.

Jan 1, 1989

Heavy liquids have come into use in ore-dressing investigations, as they make possible the separation of an ore into its specific-gravity components. A paper containing a general dissertation on heavy liquids has been written by John D. Sullivan,4 and the practical application of heavy liquids is explained by Box and Crabtree5. Some heavy liquids become discolored after continued use, and the lack of transparency impairs their value. Since they are fairly expensive, reclaiming is desirable. This paper briefly discusses the preparation and care of some of the more common heavy liquids.

Jan 1, 1928

By C. K. Lee

This Bureau of Mines report presents results from experimental studies on wood fires in a laboratory-scale tunnel network. Experimental measurements include ignition delay time, flame spread rate, ventilation air and gas flow rates, wood temperature, gas temperature, pressure and composition, thermal flux, and smoke particulates. These measurements form a data base for fire-scaling studies and provide information on various fire processes, such as flow interaction between ventilation air and fire, fire throttling and reverse flow, and duct fire energetics. Results show how hazards of duct fires relate to the development of (1) asphyxiating and toxic fumes, (2) explosive gas mixtures, (3) throttling of ventilation air, and (4) high-temperature combustion products. Such fire hazards should be carefully considered when testing flammabilities of materials used in a confined underground mine environment.

Jan 1, 1980

One of the major unknowns in the use of iron and copper is the quantity of various low level impurities, particularly hydrogen, that may be introduced during the deoxidizing process prior to casting. Introduction of hydrogen results in the embrittlement of components made from these metals. In addition, hydrogen bubbles in castings of copper result in the formation of blisters and swelling of the casting. During the last year, a significant effort has been made at the University of Missouri-Rolla to understand the permeation of hydrogen in galvanized automotive steel components and the hydrogen absorption during the electrodeposition of copper. The galvanized steel components consisted of automotive upholstery clips, seat belt holders and brake clips. Although the process of galvanization protects the steel from corrosion the process invariably causes the steel to pick up enough hydrogen to make it susceptible to brittle fracture.

Jan 1, 1992

By W. A. Haley

This is the second of a series of publications that describes the progress of mechanical longwall coal mining in the United States in which a German coal planer was employed.3/ Details of the equipment, a description of its operation, and the results obtained in mining the experimental panel were published in the preceding report. Experimental mining with the planer in the first panel showed an improvement in performance over conventional mining methods at the coal company's Stotesbury 11 mine. The work, which was begun on an experimental basis, soon proved successful, and the coal company purchased the equipment for continued use. Two panels, adjacent to the first, were developed and mined with the planer. Each of these panels was shorter than the preceding one because water seepage from a surface creek limited development. On completion of mining in the third panel, the planer equipment was moved by the cooperating company to a nearby mine operated in the same coal bed where a large area of coal suitable for planer mining is available.

Jan 1, 1954

By J. E. Tress

The Bureau of Mines has developed a process to utilize waste heat from electric arc steelmaking furnace gases to preheat the ferrous material charged to the furnace. Four heat exchangers were designed, tested, and operated successfully on 1-ton electric arc furnaces. Briquets and pellets were charged continuously, both countercurrent to the hot furnace offgasses and at ambient temperatures. A comparison of the electrical energy consumed in each situation showed that preheating can lower energy requirements as much as 15.6 percent.

Jan 1, 1975

By John C. Franklin

A radon survey was made at five different locations in the Twilight mine near Uravan, Colo., to determine chances in radon concentrations in an inactive mine. Data were taken with a continuous monitor set for 1-minute count periods and readings were taken 24 hours a day for 9 days. The 12 readings per station each hour accurately showed how t w radon concentration varied during the day. From the data collected from the intake portal to station 4, the average radon emanation rate was estimated at 18 picocuries per second per square foot (pCi/sec/ft3). A daily cycle in radon concentration was detected that apparently was related to barometric pressure change.

Jan 1, 1976

By J. J. Forbes

The Coal Mine Inspection Branch of the Health and Safety Division, Bureau of Mines, was established to carry out the provisions in Public Law 49, 77th Congress, H. R. 2082, approved May 7, 1941. The series of major disasters that beset the coal-mining industry in 1940 aroused public interest in mine-safety measures, and the act 18 the direct result of this rekindled interest. Under the provisions of the act, the Secretary of the Interior, acting through the Federal Bureau of Mines, is authorized and empowered to make, or cause to be made, annual or necessary inspections and investigations in coal mines, the products of which regularly enter commerce or the operations of which substantially affect commerce. The principal functions of the Federal coal-mine inspectors are to determine the causes of accidents and occupational diseases in coal mines and then endeavor to eliminate or ameliorate them (1) by revealing, through personal conferences with mine personnel, correspondence, and published reports, the unhealthful and unsafe conditions and practices existing in the mines and (2) by recommending practical means for correcting the conditions observed. The act does not provide any enforcement powers, and therefore compliance with the inspectors' recommendations is not mandatory; it does give Federal coal-mine inspectors the right to enter coal mines for inspection purposes.

Jan 1, 1951

By P. W. Jerant

The methane emissions from an advancing coal mine section were continuously monitored for 120 days. During this time, the section advanced 2,000 feet into virgin Pittsburgh coalbed producing 54,565 tons of coal with a total methane emission of 91 million ft3. Analysis of the data gathered showed that daily methane emissions did not correlate with overburden thickness and daily coal production. A good correlation was found between the daily methane emission and the average length of rib exposed to virgin coal.

Jan 1, 1976

By Chas. F. Jackson

This paper is a tabular compilation of data contained in a series of information circulars dealing with mining methods and costs at a large number of mines in the United States and some foreign countries. There circulars have been published from time to time during the years 1929 to 1934 inclusive. From time to time, as enough data became available in these circulars, other circulars and. bulletins have been published in which the data bearing upon different phases of nine operation were summarized, discussed, and analyzed. The present paper is a compilation of data on costs of drifting and crosscutting contained in earlier circulars, .designed to assemble this information in a convenient form for reference without attempting lengthy discussion of details of drifting and crosscutting practice. For such details the reader is referred to the circulars on individual mines.

Jan 1, 1935

By B. J. Scheiner

As part of the goal to maximize minerals and metals recovery from primary domestic resources, design factors associated with minimizing current leakage in bipolar cell configurations were studied by the Bureau of Mines as a means of improving the efficiency of bipolar e1ectrooxidation cells. Initial studies that were conducted in a small bipolar cell operating at 140 to 145 volts and 15.4 amp indicated how design factors could be employed to minimize cur-rent leakage around adjacent electrodes during cell operation. Based on these results, a 40-electrode, 108-kva prototype of an industrial-sized cell was constructed and tested for extracting metal values from offgrade molybdenite concentrates. The feasibility of recovering molybdenum and rhenium from the oxidized pulp also was determined. Feed to the process sequence consisted of flotation concentrates containing 16 to 35 pet Mo as molybdenite and 6 to 15 pct Cu. E1ectrooxidation in the prototype cell resulted in 84 to 97 pct Mo and Re extraction with a corresponding energy consumption of 9 to 13 kwhr/1b Mo extracted.

Jan 1, 1979

By John A. Organiscak

Laboratory and underground studies were conducted by the Bureau of Mines to evaluate the effectiveness of a water-powered scrubber and a brattice partition to create a clean split of air for longwall workers at the tailgate. In simulated laboratory tests, the system was very effective in creating a clean split of air. Observed system efficiencies were 74 and 84 pct with induced airflows of approximately 2,000 and 2,500 cfm, respectively. Underground evaluations indicated that the system was capable of reducing respirable dust at the tailgate. The first underground evaluation resulted in protection efficiencies of 30.7 and 42.5 pct at scrubber water pressures of 150 and 450 psig, respectively. A 33.7-pct protection efficiency was observed in the second underground evaluation with a modified partition and the scrubber operating at 250-psig water pressure. To be most effective, the system should have the scrubber operating at a flowrate of 10 gpm at 500 psig to deliver a maximum quantity of cleaned air behind a well-sealed partition.

Jan 1, 1983