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By M. S. Moats

As smelter feeds become more complex, the impurities that ultimately report to electrorefineries are changing. Many of these impurities collect in the electrolyte and must be controlled. As commercial copper electrorefineries look to expand their capacities by increasing their operating current density, the interaction between electrolyte composition and anode passivation can cause operational difficulties. To improve the industry's understanding of the passivation phenomena, the role of electrolyte composition was evaluated using commercial electrorefining anode samples. The electrolyte composition variables examined were copper, acid, nickel, arsenic, chloride, thiourea and glue. Finally, the role of non-commercially utilized additives, such as bromide and polyethylene glycol were studied. From this investigation, electrolyte parameters that inhibit copper dissolution through copper sulfate precipitation, copper oxide stabilization and/or absorbed species lead to accelerated passivation. Species that prevent passivation have the ability to complex cuprous ions. Possible mechanisms for the role of each.

Jan 1, 2007

By T. Cutard, E. Cailleux, F. Nazaret, G. Bernhart

This paper deals with the study of the mechanical behavior in the 20°C-900°C temperature range of refractory concretes reinforced with metallic fibers. Fibers are introduced to improve the damage resistance and to minimize the quasi-brittle behavior of refractory concretes. In some cases, a plastic or ductile like behavior can be obtained. Two approaches are considered in these studies. The first one is based on the micromechanical scale. Main objectives are to understand, quantify and predict the thermomechanical behavior of monofiber microcomposites. Such considerations are helpful to optimize the composite formulation for a better behavior. The second one is based on the macromechanical scale. Main objectives are to characterize and to model the macroscopic thermomechanical behavior of randomly reinforced refractory concretes. A particular attention is firstly paid to the relationships between the microstructural changes and the mechanical properties and secondly to the structural size effects.

Jan 1, 2004

By S. R. Izatt

The use of MRT, a highly selective separations technology, has long been demonstrated to be a cost effective, efficient, and environmentally sound process for extraction of a wide range of anions and cations that are commonly found in copper electro - refining and electro - winning circuits, as well as in environmental treatment operations. This paper provides an update of commercial MRT applications in the copper industry. Several recent installations and test programs are reviewed including recovery of bismuth from tank house electrolyte, and from chloride matrix selenium reduction solution which is generated in the anode slimes treatment process. Recovery and refining of platinum group metals originating in the anode slimes is also discussed. Various other base metal and other target separations of interest to the copper producer are also reviewed. The recovery products are high purity metal salts which can be marketed directly or readily reduced to metal.

Jan 1, 2007

By T. Hartmann

The presence of crud represents a permanent challenge for solvent extraction in the hydro-metal industry. The crud is a stable emulsion which slowly spreads along the phase boundary between the aqueous and organic phase. The crud can significantly impair the efficiency of hydro-metal extraction because the phase boundary between the aqueous and organic phases assumes substantial proportions, and the settlers cannot react flexibly. In a chain reaction, all settlers connected in series become infected with crud. The transfer of organic phase to the electrowining (EW) cell can cause 'cathode burn'. Continuous treatment of the crud is extremely effective and reliable with a 3-phase separating solid bowl centrifuge. All three phases are separated distinctly from one another. All associated process steps exhibit a steady uniform efficiency. First and foremost, they ensure a reliable, continuous extraction process and, second, they recover valuable re-usable organics from the crud.

Jan 1, 2007

By C. Bissue, G. M. Castillo

Newmont’s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By Michel Aubertin

Mining activities can produce large volumes of waste rock, which are typically deposited in piles on the soil surface, above the water table. Such piles can cover areas of several tens of hectares and can reach over a hundred meters in height. For hard rock mines, the waste rock grain size can vary from silty particles to metre-scale blocks. The internal structure of a pile constructed on a relatively flat surface typically includes two main zones. The first zone corresponds to the heart of the pile, and is formed by several sub-horizontal stratifications (with dense and loose layers) due to the heavy mine equipment traffic which induces local compaction and degradation of the waste rock. The second zone corresponds to regions where waste rocks are deposited by push-dumping or end-dumping close to the external flank of the pile, inducing grain size segregation along the slope. Depending on the deposition sequence, grain size distribution and bench height, a gradation may then be observed, with coarser particles (with cobbles and blocks) near the base and finer particles near the crest, together with inclined stratifications due to the advance of the deposition face. These internal features affect the distribution and flow of water (and air) in the pile. To assess the internal distribution of material properties within the pile, a combination of several tools is usually required which can provide information on the hydrogeological and geochemical characteristics of the waste rock. In this regard, geophysical tools are very interesting because they can lead to a threedimensional mapping of property variations. The information gathered from a combination of appropriately selected techniques can be used to construct numerical models to further study unsaturated water flow and reactive transport. Such simulations help better understand the pile response in its actual and future states, which in turn provides input to adjust the deposition sequence, to plan for closure, and to select an in situ groundwater monitoring strategy. The presentation will give an overview of techniques that have been developed to characterise material properties in the laboratory and in the field, and to obtain a general picture of a pile?s internal structure. Additional results on unsaturated reactive transport modelling will also be shown to illustrate how the internal pile structure may influence its hydro-geochemical and environmental response.

Nov 1, 2008

By G. Portillo

Electrospark Deposition (ESD) is a pulsed-arc micro-welding process characterized by using high current electrical pulses, of a short duration, to deposit an electrode material on a metallic substrate. The short duration of the electrical pulse allows for a low heat input over the substrate and an extremely rapid solidification of the deposited material. As a result, the ESD is capable of a wide variety of microstructures like micro-segregationfree solid solutions, nanostructured grains, metastable structures, and amorphous phases. The present work shows a microstructural analysis of rapidly solidified Al-Ni alloys coatings by the ESD process. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD) were performed to present the microstructural evolution as a function of the welding parameters. The phases and non-equilibrium metastable structures present in the alloys, and their distribution, were found to be a sensitive function of the alloy composition; hence its formation is governed primarily by thermodynamic considerations.

Jan 1, 2011

By J. M. Menacho

As usually occurs in technological development, heap leaching knowledge has been built upon two parallel lanes, theory developed on fundamentals but relatively far from industrial applications, and operational know-how generated from empirical trial and error. As a contribution to close the gap between the above-mentioned lanes, the De Re Metallica process consulting group has been developing and applying fundamentalsbased modeling tools for industrial process design and process optimization of existing plants over the last ten years. As result, a library of models is now available with application to the whole production chain from blasting to electro winning. This presentation is centered in heap leaching and several real case studies are developed, showing how paradigms are broken when fundamentals are applied. Cu2007 - Volume IV (Book 1) The John E. Dutrizac International Symposium on Copper Hydrometallurgy Edited by P.A. Riveros, D.G. Dixon, D.B. Dreisinger, M.J. Collins Toronto, Canada,

Jan 1, 2007

By J. M. Shneerson

Gipronickel Institute, Saint-Petersburg will The copper concentrate was extracted from copper and nickel matte after its hydrometallurgical treatment and nickel removal. The concentrate containing 60-74% of copper was represented by two principal copper minerals, digenite and covellite. The oxidising leaching of this kind of concentrate was studied at the Gipronickel Institute. The effect of key parameters, such as temperature, oxygen partial pressure and initial solution compound, on the rate of copper dissolution and transfer of sulphur from sulphide to elemental form was investigated. It was shown that at temperatures about 90DC, the sulphur content of covellite converts to elemental form. Under autoclave conditions at 11ODC, the elemental sulphur dissolves as a sulphate-ion. At the temperature range from 50 to 90DC, the copper dissolution rate is in direct relation with temperature. By increasing the temperature to 130DC, this effect is reversed. Based on the research work, a technological flow sheet for the leaching of the copper concentrate was developed.

Jan 1, 2007

By T. Watanabe, M. Nakagawa, K. Kimapong

Ultrasonic wave was irradiated on metal surface in water to introduce compressive residual stress. The ultrasonic wave that was oscillated with 19.5 kHz ultrasonic transducer and amplified with a step type horn was irradiated. Slight plastic deformation occurred at the surface region of pure metal such as Cu and compressive residual stress was introduced. It seemed that the plastically deformed depth from the metal surface corresponded approximately to the depth of introduced residual stress. The higher compressive residual stress could be introduced into the surface of Cu-Zn brass and SUS304 stainless steel because work-hardening was simultaneously induced to those alloys. Furthermore, since martensitic transformation was induced by the plastic deformation in the case of SUS304, the compressive residual stress could be introduced more deeply into the surface region. The residual stress of SUS304 reached to the maximum value of 574 MPa by irradiating for 5min.

Jan 1, 2004

By G. Kordosky

Leaching aids that result in an increase in leaching rates and overall copper recovery have the potential to be beneficial to copper leach/solvent extraction/electrowinning operations. It is generally accepted that effective leaching aids facilitate the penetration of leach solution into ore by lowering the surface tension of the leach solution. Surfactants are designed to do this, and a leaching aid containing the widely used surfactant class, alkyl phenol ethoxylates, has been suggested. Alkyl phenol ethoxylates were tested to determine how they may affect phase separation, entrainment and degradation in a copper solvent extraction plant. The test results suggest the use of leaching aids at a regular rate, or even for a short time period, may have a long term impact on copper solvent extraction. Several scenarios are evaluated regarding existing operations and future solvent extraction projects and cautionary suggestions related to the use of surfactants as leaching aids are given.

Jan 1, 2007

By A. Yousefpour, M. Hojjati, M. Simard, M. Laramée, M-A. Octeau

The need for effective and reliable joining methods grows as the use of advanced thermoplastic composites becomes widespread in aerospace industry. An experimental investigation of resistance welding of APC-2/AS4 thermoplastic composite laminates is presented. In this method, a heating element is placed between the bond-surfaces then the interface is heated by passing electrical current through the heating element. The polymer at the weld interface is melted due to resistance heating, then diffuses and consolidates under applied pressure, resulting in a weld. APC-2/AS4 prepreg, APC-2/AS4 commingled, and different grades of metal mesh heating elements were considered. A custom made resistance welding rig was designed and developed to perform lap-shear welds. The mechanical performance of the welds was quantified using single lap shear tests. The effects of different heating elements on the mechanical performance of the resistance-welded parts were investigated. Also, quality of the welds was examined under optical microscopy.

Jan 1, 2004

By Q. Dong, S. A. Nightingale

An investigation has been carried out to assess the effects of an applied voltage on the dissolution rate of MgO refractory in a steelmaking like slag. In this study corrosion results obtained from dip tests using a dense direct bonded MgO refractory in a CaO-SiO2-Fe2O3-FeO-MgO slag are presented. These results demonstrate that the application of a voltage across a dense MgO refractory-slag interface can change the rate of refractory dissolution. For the slag composition used and the voltage range tested, it was found that a maximum corrosion rate was obtained at a voltage setting of -0.45V. The results of this investigation have been explained in terms of voltage affects on Marangoni (interfacial tension induced) stirring and its effect on the MgO dissolution reaction that is at least partly controlled by mass transfer in the slag.

Jan 1, 2004

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004

By P. Stantke

Glue, thiourea and chloride are the common reagents which are used in copper electrorefining to achieve fine-grained and smooth copper deposition. While thiourea and chloride are clearly defined chemical substances, glue is a natural product consisting of a mixture of amino acids in different constituent parts. The amino acids are continually degraded in the electrolyte by hydrolysis until they finally become completely inactive. This effect is well-known, largely constant and balanced by the continuous dosing of glue. In contrast, the behaviour of glue in the batch container is not always foreseeable. The glue can become partly or completely inactive by contamination with acid or bacteria, for instance. Usually this is not noticed, and partly or fully inactive glue is added to the electrolyte over a longish period, with the result that the copper growth is significantly impaired. Examples from operational practice show that, with the help of the CollaMat system, partly or fully inactive glue batches can be quickly detected.

Jan 1, 2007

By R. Farhat

Coating systems that yield a thermally grown oxide (TGO) protective layer have been proposed as a potential method for extending the lifecycle of components exposed to high temperature corrosion. This is particularly relevant to the petrochemical industry, where any reduction in corrosion rates can yield substantial cost reductions. The primary goal of this project is to develop a coating repair procedure and to investigate the oxidation performance of the repaired location. Electrospark deposition (ESD) was used to repair spalled segments of TGO grown on MCrA1Y substrates using various electrodes possessing mixed crystal structures. Specifically, electrodes of NiCoCrA1Y (BCC-FCC mixtures) and CoNiCrA1Y (FCCBCC mixtures), were deposited and oxidized to develop the TGO using a heat treatment of 24 hours at 1000°C in air. This presentation will focus on the microstructural evolution of the base metal and ESD repair on damaged area, in both as- deposited and oxidized forms. Results of SEM and XRD analysis will be presented.

Jan 1, 2011

By Robert S. G. Chapman, Kieran M. J. Downes

The Sulphide-Preview Lakes area is located 45 km northeast of La Ronge in northern Saskatchewan. It lies within the southern portion of the Proterozoic La Ronge Volcanic-Sedimentary Belt. Two styles of gold mineralization are present in the Sulphide Lake area , stratabound gold mineralization is intimately associated with a pyrite-pyrrhotite-arsenopyrite-bearing graphitic argillite unit within a sequence of intermediate to felsic volcaniclastics. Past operators established three mineralized zones along this horizon with combined reserves for two of the zones, of about 175,000 tons at 0.22 oz/ton Au. In the Preview Lake area , gold mineralization occurs in variably sheared gabbro/quartz diorite sills within a mixed sedimentary-felsic volcaniclastic sequence. Gold occurs with arsenopyrite, pyrite and minor chalcopyrite associated with quartz veins and stringers. A sulphidebearing graphitic argillite unit occurs in close proximity to the mineralized shears. Past operators delineated seven mineralized shear zones, two of which were drilltested. Average gold grades reported are in the 0.1 to 0.2 oz/ton range with erratic values up to 5.0 oz/ton.

Jan 1, 1986

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

In recent years, China and India have emerged as major players in the copper sector. Over the last decade, around 50% of additional global refined copper usage growth can be attributed to them. The paper provides an overview of the current and future copper supply and demand situation in both countries. Results from two market studies commissioned by the International Copper Study Group (ICSG) are complemented with recent copper statistics on North-East and South-East Asia, as well as further sectoral analysis. Developments and trends in copper mining and metal production, semis production, and major end use areas are highlighted. While providing insights into sectoral patterns and growth trends, the paper provides the basis for comparing structure and output of the copper sectors in some of the major copper-using countries in Asia. Afterwards, the current copper reservoir in use associated with infrastructure, buildings, industrial equipment, transportation systems and households is assessed using the ICSG Copper Flow Model. Finally, the identified copper flows are analyzed regarding the potential impact on the future world supply and demand situation.

Jan 1, 2007

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004