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By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By Shamia Hoque, Charles Q. Jia

Smelter slags contain valuable metals such as Co, Ni and Cu in proportions of less than 1 wt% along with about 40 wt% of Fe and 15 wt% of Si. Although aqueous SO2 is a versatile lixiviant for transition metals, dissolving the slag in aqueous SO2 produces solutions in which Co and Ni concentrations are lower than that of Fe due to the low metal/ Fe ratio in the slag. To develop the options for increasing Co and Ni concentrations the solubility of slag in aqueous SO2 was studied experimentally and theoretically using OLI, a software package for simulating electrolytes chemistry. The modeling results correlated well with experimental results. The model suggested that the species dominating the system was FeSO3, which would precipitate out as FeSO3.3H2O when the concentration of Fe+2 reached 1.22 molal and the concentration of S032- was beyond 1.4 molal. In the experiments the influence of pH and solids loading were studied. The leach solution obtained after dissolution of slag at 50% solids loading had a pH of 1.85. On raising the pH to 3, precipitation occurred. Analysis of the solution collected after the addition of alkali showed over 50% reduction of Fe, Co and Ni. XRD analysis revealed the precipitate to be of amorphous nature due to the silica present. The analysis confirmed that the precipitate was mainly FeSO3.3H2O. The paper also discusses the potential impact of the slag on the environment.

Jan 1, 2004

By T. Maruyama

Tamano Refinery started its operation in 1972 with the cathode production capacity of 84,000 tons per year. After several expansions, the production capacity increased to 228,000 tons per year in 2001. In this paper, we are introducing our next expansion projects starting October 2006. The project expands the production capacity of cathode from 228,000 tons to 260,000 tons per year. The main modification of this project is the conversion to the ISA process and the installation of additional seventy-two cells in the No.2 Tankhouse. The No.1 Tankhouse remains the same, using the conventional process. Half of our starting sheet cells are converted to commercial cells. The other expansions are to enlarge our purification plant. And the incidental facilities are enlarged, for example, circulation tanks, heat exchangers, filtration system, etc. Finally, this paper describes those improvements to our refinery performance and preparing for future expansions.

Jan 1, 2007

By T. R. Bieler

"Hot forming and superplasticity in powder metallurgy aluminum alloys and composites is reviewed. The effects of alloy composition, particulate composition, size, and size distribution is summarized. The role of climb distance for recovery is described in connection with the size of strengthening phases. In materials with fine strengthening phases on the order of one micron or less, high strain rate superplastic deformation processes are likely. However, the quality of superplastic deformation depends on the prior processing history, and these effects are reviewed. Very few data describing the effects of hot forming history on post-forming properties exist, but some results emerging in the literature are compared.IntroductionHot deformation in aluminum based materials is done for several technological purposes, such as thermomechanical processing to alter mechanical properties of simple forms, and/or final shaping operations to produce a complex shaped part by means of extrusion, forging, or superplastic forming. In the interest of improving the mechanical properties of aluminum based materials, two microstructural design strategies are commonly used, dispersion strengthening, and composite strengthening. The introduction of fine, stable dispersions is commonly done for high temperature strength, and the dispersions are typically ceramic particles in the range of 10 nm to 1000 nm in volume fractions around 5 vol.% (Higashi et al., 1990; 1991a; 1991b; 1992; Bieler and Mukherjee, 1990; Otsuka et al., 1987; Bieler et al., 1991; Oliver and Nix, 1982). Alternatively, composite strengthening strategies using 10-40 v% of 3 µm to 40 µm ceramic particles provide high modulus and high strength aluminum based materials (Midling and Grong, 1995; Lloyd, 1994; Subramanian et al., 1995)."

Jan 1, 1997

By F. King, R. Sutherby, J. Been

With thousands of kilometers of buried oil and gas pipelines throughout the country, carrying flammable, high-energy hydrocarbons, the integrity and safety of this transportation and distribution network are paramount. The pipeline industry has the primary responsibility for pipeline safety and has in many ways taken the lead in dealing with safety issues. Over recent years, regulatory demands have increased, requiring operators to comprehensively evaluate their pipelines through indirect and direct inspections and to manage risk through integrity programs. Mechanistic and correlative models have been developed that assist in the prediction of pipeline integrity and the determination of reassessment intervals. These lifetime prediction models are based on decades of laboratory research as well as pipeline operating data, material data, and field monitoring data pertaining to soil conditions and CP. An overview is presented of an integrated approach towards the development of such models for the evaluation of external cracking and corrosion of transmission lines.

Jan 1, 2005

By Hani Henein

Most metals and alloys processed undergo a solidification processing step. Increasingly, there is a growing number of solidification processing routes that involve rapid solidification of the alloy. These include strip casting, high pressure die casting, 3D printing, and atomization for the production of powders or spray formed parts. By contrast, there are few experimental techniques developed to study the solidification path of alloys during rapid solidification. Amongst these laser melting and solidification, Electromagnetic Levitation (EML) and Impulse Atomization (IA) are the most prominent. Of relevance is the formulation of the solidification path of an alloy and the resultant identification and quantification of metastable phases and their relationship to processing conditions. This typically involves the understanding of the interplay between undercooling and cooling rate for the various phases that form. This presentation will outline some of the methodologies developed to quantify phase fractions and their solidification path as a function of processing conditions using EML and IA.

Jan 1, 2016

By J. E. Nesset

The past 50 years have been a golden era, not just for the CMP but also for the development and success of Canadian technologies in the field of mineral processing. The CMP has played a critical role of technology transfer agent, and the success of these technologies is also linked to the success of the CMP itself. The presentation will cover, in brief, the growth of the CMP from its origins as the Canadian Gold Metallurgists in 1964, with some 39 attendees, to the present day when the annual meeting sees 500 and more from a dozen countries. Also covered will be selected technology success stories from the 50th anniversary volume to be given to all delegates ‘Canadian Contributions to Mineral Processing Technology 1968-2018’. The volume itself highlights some 40 technologies that have been divided into five categories; process water treatment and minesite environment, technology innovations, innovations in operations, technology providers and university contributions. Some international perspectives will also be shared.

Jan 1, 2018

By Y. C. Kim

This paper discusses Air Liquide's patented SPALTM (Surface Protection Air Liquide) technology and process for the inerting of coreless induction furnaces using cryogenic liquid gas. Air Liquide Canada Inc., in collaboration with Riverside Brass and Aluminum Foundry Limited (Riverside Brass), conducted plant trials to demonstrate the applicability of the SPALTM technology for copper-based alloys. Results showed that with SPALTM, Riverside Brass benefited from a significant increase in metal yield as the level of dross formation was drastically reduced. Together with the many other benefits of this technology, SPALTM demonstrated to be a non-negligible cost-effective solution to reduce metal production costs. In an effort to optimize the argon flow, different flow rates were used and the oxygen level above the metal bath was measured to pinpoint optimal flow. The results of metal yield, charge mix, dross formation, and melt temperature are compared with and without argon. The metal yield improvements are dramatic and calculated net savings are presented hereunder.

Jan 1, 2007

By R. A. L. Drew, J. P. Immarigeon, F. Jalilian, M. Jahazi

In the present work TLP bonding of Inconel 617 is investigated. The influence of the main processing parameters i.e. time and thickness of the interlayer were studied with optical and scanning electron microscopy. Boron containing interlayers with two different thicknesses were used and the influence of various holding times from 5 min to 24 hours on the microstructure of the bond region was investigated. The results indicated that, for the testing temperature of 1065°C and holding times above 2 hours with an interlayer of 25.4 microns thick no liquid phase was observed. The same phenomenon occurred only after 6 hours for a 76.2 microns thick interlayer. Precipitate growth started at grain boundaries and continued inside the grains. The composition, size and morphology of the precipitates were studied using electron microprobe analysis. No noticeable changes were observed in the grain size of the base metal with increasing holding times.

Jan 1, 2004

By W. Beres, Li. J.

The finite element method (FEM) has been applied to investigate the stress fields and deformation of a TiN/Ti-6A1-4V coating/substrate system subjected to nanoindentation. MSC Patran and MSC Marc were used to prepare the three-dimensional finite element models and to perform the simulations of the Vickers nanoindentation experiments. Pure silicon and TiN/Ti-6A1-4V coating/substrate system were analyzed. The properties of the materials were assumed to be homogeneous and isotropic with a linear hardening behavior. The reverse method was used to extract material properties, such as the yield stress and strain hardening coefficient, from the numerical results by comparing the simulated indentation load vs. penetration depth (P-h) curves with those obtained experimentally. Both non-linear elastic and non-linear elastic-plastic analyses were carried out for the coating/substrate system. The results are given for four different coating thicknesses.

Jan 1, 2004

By B. T. Lu, J. L. Luo, H. X. Guo

This paper investigated the synergistic effect in the slurry-erosion process of carbon steel. In line with the mechanisms of material loss, the synergism due to interaction of erosion and corrosion was divided into the corrosion enhanced by erosion and erosion enhanced by corrosion. The erosion-corrosion tests were conducted with A1045 steel in slurries containing silica sand. Experimental results showed that the rotating of the sample in corrosive media raised both OCP and corrosion rate, but the impingement of solid particles did not affect the corrosion current significantly. In the quiescent solutions, the Faraday's law gave a good prediction for the weight loss caused by corrosion but for rotating samples, the weight loss experimentally measured was virtually greater than that predicted by the Faraday's law, indicating that the corrosion-enhanced erosion could occur in corrosive fluids in absence of solid particles. A half-logarithm relationship was observed between the weight loss due to corrosion-enhanced erosion and the anodic current density.

Jan 1, 2004

By R. Mohamad, J. Asfahani

Abstract - Radioactive characteristics of pits drilled in the Al-Sharquieh mine while prospecting for recent phosphatic resources have been investigated. The results indicate that phosphatic layers are characterized generally by high radioactive intensities (more than 800 c.p.s). The lithological section in the study area is very complex sedimentologically, and characterized by high faciological variation in all directions. The Schlumberger geo-electrical configuration with fine separation of AB/2 was successfully applied to determine lithological boundaries, and the resistivities of the layers of the lithological section, especially for thin layers. It was shown that the phosphatic layer resistivities increase or decrease as a function of associated material. As a result, two types of phosphatic layers have been geo-electrically distinguished. The first is characterized by high resistivity and relatively low radioactivity, which could be related to the rock phosphatic layers. The second is characterized by low resistivities and high radioactivity, which could be related to the sandy phosphatic layers.

Jan 1, 2000

By K. Madi, E. Yeugo Fogaing, S. Forest, M. Boussuge, L. Massard, M. Huger, Gaultm C.

This study has been carried out owing to the French research program PROMETHEREF, which aims to improve the knowledge of thermal and mechanical properties of industrial refractories at high temperature. In this frame, this paper relates a collaborative study between Saint-Gobain CREE, R&D Centre for Saint-Gobain Ceramics & Plastics in Europe (Cavaillon), the Materials Center P.M. Fourt of Ecole des Mines de Paris (Evry) and the Research Group on Heterogeneous Materials (GEMH) of ENSCI (Limoges). Data collected at high temperatures by using different means (bending tests, ultrasonic measurements,...) allows the identification of the high temperature behavior of two fused cast materials, produced by Saint-Gobain group for the glass manufacturing industry. The results emphasize the importance of the transformation of zirconia and of the viscosity of the glassy intergranular phase on the mechanical behavior. Damage under the form of microcracking caused by thermal expansion mismatch between the phases is also observed during cooling down at low temperature, when the material is elastic.

Jan 1, 2004

By J. Scalise

The paper covers a wide range of topics relative to filtration for continuous cast copper and aluminum. Subjects include system concepts, filtration concepts, system components, filter types, filter media selection, caster water filtration, coolant disposal, and recommended materials of construction.

Jan 1, 2007

By K. Feindel

The distribution of water in operating fuel cells must be carefully managed to optimize the performance, durability, and functionality of the system. For example, the ionic conductivity of polymer electrolyte membranes decreases as membrane hydration is reduced. Flooding at the cathode inhibits mass transport, and it can lead to failure of materials. Build up of liquid water in the gas flow channels of a fuel cell stack will create a non-uniform distribution of pressure drops across the individual cells. We will discuss the application of 1H NMR microscopy to investigate in situ the production and distribution of water throughout an operating H2/O2 polymer electrolyte membrane fuel cell. Polymer electrolyte direct methanol fuel cells posses high theoretical storage capacities as power systems for portable electronic devices. There are, however, two long-standing hurdles to development of practical methanol fuel cell systems. First, the electro oxidation of methanol at the anode of the fuel cell is poisoned by absorbed carbon monoxide, an intermediate in methanol electro oxidation. Second, methanol readily crosses over from the anode to the cathode of the fuel cell. This methanol crossover wastes fuel, and it poisons the electro reduction of oxygen at the cathode. We are investigating use of 2-propanol as an alternative to methanol as a fuel. 2-Propanol is less toxic than methanol, and it is less prone to crossover from the anode to the cathode. More significant, however, is that the electro oxidation of 2-propanol to acetone is faster than the electro oxidation of methanol because it avoids formation of adsorbed carbon monoxide. We will present active catalyst systems for the electro oxidation of 2¬propanol to acetone in fuel cells. We will also present methods to convert the resulting acetone back into 2-propanol, possibly leading towards rechargeable portable fuel cell systems.

Jan 1, 2005

By Gheorghe Vieru

Security and safety due to environmental impact as well as the radiological consequences during the uranium mining operations, tailings management, uranium processing, disposal of waste in conventional landfill sites are matters of great importance. The Uranium National Company (CNU) from Romania is responsible for all aspects belonging to the management of the entire Romanian uranium industry- the uranium ore extraction, transport and processing of uranium ore, concentrates processing, as well as disposal of sterile ore and waste. The paper will presents specific safety problems related to the identification and evaluation of potential environmental risks, as well as possible radiological consequences associated with the disposal of sterile and the uranium processing waste resulting from processing of the uranium ore. Computer codes will be used, such as IAEA INTERTRAN II and RADTRAN 5. It is also to be noted that this paper considers the main results of the scientific research carried out by the main author as CSI (Chief Scientific Investigator) for Romanian Research Contract on NORM concluded with IAEA Vienna.

Aug 1, 2010

By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By D. Eriksen

Zero Emission Gas power, ZEG, is a novel concept where a high temperature solid oxide fuel cell (SOFC) is integrated with a reforming reactor producing hydrogen from natural gas through Sorption Enhanced Steam Methane Reforming (SESMR). The SOFC is used as a high temperature heat source for regeneration of the CO2-absorbent. Moreover, by using part of the produced hydrogen as fuel for the SOFC, the waste heat of the process is considerably reduced. Thus, the process has a very high thermal efficiency and produces both electricity and hydrogen from natural gas. In addition, a stream of pure CO2 is produced in the regeneration step and can be deposited or used commercially. Initial cost estimates indicate a cost of electricity and a cost of hydrogen well below today&apos;s prices. A small (1kWel + 1kW H2) demonstration set-up is under construction and experimental results and related research will be presented. This set-up comprises one 2.5kWth H2 SESMR-reactor (about 0.85 Nm3/h H2) operating batchwise with dolomite as the CO2-sorbent. The reactor developed is designed like a parallel plate heat exchanger where the mixture of sorbent and reforming catalyst is packed between the heat exchanging plates. The demonstration set-up includes a 1kW SOFC operating in a continuous mode. The set¬up will therefore demonstrate continuous simultaneous hydrogen- and electricity production, but cannot demonstrate simultanuous electricity- and CO2-production. The set?up is well equipped for on-line monitoring of gas composition, flows and temperatures. This important part of the demonstration set-up is developed and provided by Christian Michelsen Research (CMR). A minor part of the project is the development of a continuous circulating fluidized bed SESMR-reactor system and in another related project the focus is on the development of more suitable sorbents. In these two projects co-operation with University of British Columbia and Lousianna State University, respectively, is highly appreciated.

Jan 1, 2005

Everybody would agree that a good roadway leads to more efficient haulages by reducing haul times, smoother and safer operation for operator and less wear and tear on tires and equipment, thus improving availability and overall costs efficiency. There is a number of factors that come into play to achieve this especially when developing a mine. Excavations of Ramps and Headings: Operators should follow surveyors and layouts accurately while driving ramps. To maintain constant grades on ramps, which leads to better design control of water and easier grading of roadways. Dips and dives lead to needless over excavations and unnecessary cost and disposal of waste rock. When dressing a ramp some areas may require 2 to 3 feet of material to correct the dips and perfect to constant grade. You may ask yourself, is this all necessary? A small exercise is to follow a loaded haulage truck up ramp. At the first hump, grade change, notice the down shift and notice how far the truck travels to regain the up shift and his speed. The difference is remarkably noticeable when the grade is constant. All this leads to less driveline shock, less horsepower demand, better fuel efficiency and more productivity. Drill & Blast Patterns to control water for Ramp Headings: The drill pattern needs to allow for a ditch. A slight cross fall to form a ditch can easily be done with the lifters. The preferred side of the ditch is always the inside curve of the ramp as it has less tendency to erode roadbed material. On a level, the ditch is dictated by the sump location. A blasted ditch will eliminate water pounding and keep the roadbed dry. Water trapped in roadbed is the major cause of rollout and de-stability of roadbed. If the water is allowed to drain in the middle of the ramp it will cause erosion, movement and loss of fines and an increase in grading intervals.

Feb 1, 2008

By G. Agar

"E. Joe We have been working for some years on the elimination ofCANMET thiosulphates from solutions as a means of protecting ground water and fish streams. Alot of these thiosulphates result from the mill use of S02. Is there any possibility that thiosulphates will be generated by this process?Reply I don't know the answer to your question. I can speculate that there is no question that when one adds SO2 and air to a sulphide pulp one generates a host of unsaturated poly¬cyanates. I unfortunately cannot remember the reactions which arise in the cyanide destruction scheme. I think that if thiosulphate was generated the process wouldn't work. It is not oxidizing enough to destroy the cyanide.R. Wagner Would you comment on the actual cost/ton at the Scottie goldPamour mine concentrator? Would $2.50/ton be typical or is thisPorcupine just a ball park figure.Reply We wouldn't disclose Scottie's costs even if we knew them. I depends on the amount of cyanide and thiocyanate in the effluent. I have given you a hypothetical case. With the conditions stipulated the figures I Have given are realistic.K. Konigsmann I do not believe the use of S02 adds significantly to the thio Noranda Mines salt problem Certainly we use SO2 in many of our mills and thio-salt levels in a number of them haven't changed whether we use or don't use S02. For instance, Orchan and Matagami mills treating the same ore side by side in which one was using S02 and the other wasn't, the thio-salt level was virtually the same in both pulp streams. In the case of Brunswick where alot of SO2 is used (20 tons/day) there is a thio-salt problem but it is relatively insignificant.Reply Thank you for that comment. It serves to reassure us that we are not polluting the environment."

Jan 1, 1984