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By Elizabeth Edwards, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg, Kurtis Judd

Mineralogical characterization of the tailings showed the deportment of Ni to be similar in the Vale and Glencore tailings, with 60% of the total Ni locked in pyrrhotite, and the balance 40% associated with pentlandite. The overall Ni dissolution was correlated with the individual dissolution extents of pyrrhotite and pentlandite as functions of four leaching regimes: ‘anoxic acid’ (with and without pH control), ‘oxic acid’ (oxygen sparging), ‘oxic acid’ (air sparging), and ‘oxic ferric’ (air sparging). The results showed that the maximum Ni dissolution was obtained during the pH controlled oxic acid leach with oxygen sparging at pH 1.5, while the anoxic acid leach at pH 1.5 resulted in minimum Ni dissolution (10–15%) from pyrrhotite. An overall Ni mass balance showed that pyrrhotite and pentlandite dissolve simultaneously in the presence of Fe(III) and oxygen, in contrast to the preferential dissolution of pyrrhotite in the absence of Fe(III). Sulphur mass balances revealed that the yield of elemental sulphur is maximized (65%) during the oxic Fe(III) leach at pH 0.6. Furthermore, the kinetics of Ni leaching and elemental sulphur formation from pyrrhotite tailings leached with ferric sulphate between 55–80°C was investigated at constant oxidation-reduction potential. Elemental sulphur yield increased with increasing temperature, but no observable trend could be linked to ferric or ferrous ion concentration.

Jan 1, 2017

By Masafumi Maeda

Metal recycling and waste treatment have become common issues in various metal industries, notably, the iron and steelmaking industry and the nonferrous industry. The former tends to treat mass wastes such as municipal wastes or plastics. However, volatile compounds are condensed in dusts of their incineration processes and they should also be treated, likely by the nonferrous industry. Those "end-of-life" products contain heavy metals that might be harmful to mankind and should be handled by the non-ferrous industry. Not only revenue derived from regeneration of metals from the secondary materials but also the revenue generated from the treatment charges is a strong attraction for nonferrous industry to process secondary materials. The present study presents some statistical data of the Japanese corporations in the iron and steelmaking industry as well as the nonferrous industry on their revenues generated from processing of secondary materials. Some of the companies are now concentrating their business resources on new areas of the market. Although the quantity of waste or recyclable material is still small at present, the quantity will increase in the near future, and it is anticipated that international collaboration is required to handle the greater variety and the larger quantity of secondary materials.

Jan 1, 2004

By G. Vibert Douglas

NICKEL minerals are known in New Brunswick but have never been reported from Nova Scotia. The attention of the writers was drawn to an occurrence of pyrrhotite, reported to carry nickel, at the Second Gold brook, Middle river, Cape Breton. The purpose of this paper is to record the occurrence and give an account of the general geological association. In a later paper it may be possible to give greater details? than are available at present. GEOLOGY The area lies at the edge of a plateau of Precambrian rocks which forms the panhandle of Cape Breton island. This plateau has a general elevation of 1,200 feet. Middle river, with its tributaries, the First, Second, and Third Gold brooks drains the area. The lower country to east and southeast of the plateau is underlain by lower Carboniferous sediments. The rocks of the plateau are presumably of Precambrian age but have never been definitely correlated with the Gold-Bearing Series of the mainland. ?There i:s; however, some resemblance, although they have apparently been more intensely mountain-built. They are essentially fine grained, sheared quartzites and slates . The general strike is east and west, with a north dip of 45° to 55°. There are smalllocal drag-folds in the area. The only igneous rock in the immediate vicinity is an intrusive pink porphyry. It has small phenocrysts of quartz and feldspar. It has intruded the sediments generally along the structural planes, but in places crosses the structure . Its intrusive character is further proved by the fact that it contains xenoliths of the quartzite.

Jan 1, 1937

By P. L. Drake

This paper comprises a discussion of the role which mineral resources will play in Canada's future export trade and the growing demand for minerals in Canada.

Jan 1, 1979

By Serge Perreault

Le cuivre est un métal fascinant qui joue un rôle essentiel dans le développement des différentes civilisations depuis 7000 ans. Le cuivre est aussi un métal polyvalent et essentiel qui est très présent dans notre vie quotidienne. L’un des premiers métaux utilisés par les humains, il est un élément chimique qui se trouve à l’état natif, ce qui est rare pour les métaux. Il apparaît principalement dans des minéraux, notamment sous forme de sulfures, en raison de son caractère chalcophile (c’est-à-dire son attraction pour l’élément soufre). Le cuivre se trouve dans la croûte terrestre sous forme de minéraux de cuivre, tels que dans les sulfures dont la chalcopyrite, la bornite, la covellite et la chalcocite. Il est également présent sous sa forme native ou dans des minéraux oxydés comme la cuprite et dans des carbonates hydratés, comme la malachite et l’azurite. La formation de gisements de minerai de cuivre implique des processus géologiques complexes, notamment l’activité hydrothermale, les intrusions magmatiques et l’altération des roches. Les gisements de minerai de cuivre se trouvent dans divers types d’environnements géologiques, dont les gisements porphyriques, les gisements de cuivre encaissés dans des roches sédimentaires, les gisements de type skarn, les gisements de sulfures massifs volcanogènes, les gisements magmatiques de type nickel-cuivre, les gisements de cuivre oxydé, et d’autres [1].

May 2, 2024

By Geoffrey C. Streeton

A continual objective of mine operations is to reduce ground control costs without compromising the overall safety or performance of the installed ground support. Any change in the ground support regime must not result in a less secure or safe workplace. The due diligence required to implement a change in rockbolting practice is extensive, particularly when the new bolting system has not been used at any other mining operation. Factors such as yield, shear strength and embedment strength must all be investigated to gain an understanding of how the rockbolt can be expected to perform. This paper also discusses the substantial cost reductions and efficiency gains which can be achieved through the introduction of the Jumbolt rockbolt.

May 1, 2001

By C. R. Edwards, D. G. Feasby

"Over the last 50 years disposal of uranium mill tailings has evolved from dumping untreated tailings into the nearest depression to depositing chemically-stabilized tailings into highly engineered management facilities. This paper describes the evolution of disposal methods and the criteria which have determined the development path followed. Remediation techniques to bring older and now unacceptable tailings deposits into satisfactory compliance with today's· regulations are reviewed.With the closure of the uranium mines in Elliot Lake, Ontario, considerable effort is being made on decommissioning the tailings areas by developing long term maintenance of water covers. The innovative methods being used to develop these water covers are detailed. Methods now under development in Saskatchewan for subaqueous deposition of high density or paste tailings for permanent disposal in mined out open pits are described.SummaryThe technology for uranium mill tailings disposal in Canada has evolved considerably over the past 51 years. This evolution has been driven by an improving understanding of how best to safely and permanently store tailings, in conjunction with stricter environmental protection regulations. Old sites are being decommissioned in situ, but may require long term care and maintenance. The use of water covers is an important technique in eastern Canada to prevent intrusion, radon evolution and, for the Elliot Lake tailings, acid generation. The major drawback of water covers in any above ground disposal method is the requirement that a long term maintenance and monitoring plan be put into effect for each site.New higher grade mines in Saskatchewan will increasingly use disposal in mined-out pits using the pervious surround method and/or paste tailings technology as a method to permanently dispose of these wastes and to permit “walkaway” after a few years of monitoring."

Jan 1, 1996

By Bing Li, Kai Liu, Yongcheng. Zhao

With the ongoing development of copper smelting technology, the improvement of environmental emission control and achieving an automated continuous copper pyrometallurgical process have become the key development goals for copper smelting. The double bottom blowing continuous copper smelting process combine bottom blowing smelting (SKS) and bottom blowing converting (BCC) process and fire refining as “three-connected furnaces” arrangement is a pyrometallurgical process independently developed by China’s ENFI which can continuously produce copper from raw material through to anodes. This technology can improve energy efficiency and reduce environmental emissions for the overall copper smelting and converting process. This paper discusses the engineering characteristics and production practice of the SDIC Jincheng Metallurgical Project, which operates SKS smelting and BCC converting process with “three-connected furnace” arrangement for the first time in the world. Advanced engineering concepts and tools were used to optimize the configuration during the project engineering stage. The operation shows that the process has good environmental performance, reduced energy consumption and high level of automation, which is a new choice for copper continuous smelting process. INTRODUCTION One of the most important developing trends for the overall copper smelting process is to develop a continuous operation. Continuous copper smelting can maximise energy efficiency in copper concentrate and make full use of the rich heat treatment system. Cold charge and a part of low-heat-generating materials, which are processing with additional equipment in traditional copper smelting process, can be processed with rich reaction heat in continuous copper smelting and converting process to achieve good economic benefits. Yuan and Wang (2017) noted that SKS+BCC copper smelting process can reduce the secondary SO2 emissions compared with discontinuous copper smelting process, which required transportation of melted matte by matte ladle and may cause secondary pollution. The continuous copper smelting process can also reduce the generation of intermediate cold materials.

Jan 1, 2019

By L. Torres, C. S. R. Rondestvedt, M. Bustos

In February 2010, Teck’s newest Concentrator at Mina Carmen de Andacollo (CDA), Andacollo, Chile was commissioned. The Concentrator is a single line configuration, comprising of one 36 ft diameter x 20 ft long SAG mill driven by an 18,000 hp gearless drive. The SAG mill feeds two ball mills each 25 ft in diameter x 40.5 ft long, each driven by a total of 19,000 hp through dual pinion drives. A series of four phases will be reviewed from operational readiness, mechanical completion, commissioning, and ramp-up. Also, now after 6 months of operation, this paper will review the significant steps taken during ramp-up enabling the announcement of commercial production, in October 2010.

Jan 1, 2012

By M. Azzaz

In this paper, we report on new mechanical tests, at high temperatures, performed with a supposed better aluminium nitride (A1N) material, containing fewer oxygen. Our purpose was twofold: (i) check whether creep resistance is modified and hopefully enhanced and (ii) determine the elementary mechanisms controlling plastic deformation through transmission electron microscopy (TEM) observations of deformed samples up 10% strain in compression at elevated temperatures (1823-1923 K) under constant stress in the range 150¬250 MPa. Stationary rates are lower by an order magnitude than those previously measured in MN with higher oxygen content. All dislocations imaged by TEM look undissociated, which clearly relates the formerly observed wide dissociation to oxygen in excess.

Jan 1, 2004

By Fathi Habashi

Teaching mining, metallurgy, and geology preceded that of the other engineering disciplines. The first School of Mines was founded in 1756 in Potosi (Fig. 1) in New Spain (now Bolivia), 38 years before the first Polytechnic School (École Polytechnique) was founded in Paris. The schools of mines were also pioneers in the teaching of chem- istry. The teaching staff at these schools cre- ated the basic literature on metallurgy, mining, and geology. They analyzed and dis- covered numerous minerals and discovered the metals tungsten, beryllium, chromium, uranium, zirconium, vanadium, indium, and germanium. The history of some of the first schools is given together with biographies of some of their distinguished teaching staff.

Nov 1, 1997

By C. Okay Aksoy

In Turkey, the increasing demand for lignite has necessitated an increased emphasis on both lignite production and recovery. This emphasis has resulted in a gradual increase in the application of the retreat longwall mining method for both its product recovery and productivity benefits. Also, in order to maximize the recovery of the natural resources and to increase total production, it is necessary to take advantage of underground reserve before abandoning the mine. This means that at the end of the life of the mine, the main drift safety pillar and the shaft pillar will generally be extracted. This investigation a preliminary study of the stability of the main drift and the shaft at the Hustas Mine as the safety pillars are extracted. In this study, field surveys belonging to the underground colliery of Hustas Co. in Soma have been investigated with the help of LAMODEL working under the Laminated Displacement Discontinuity principle for the models calibrated as a results of physical model and finite element analyses. The convenience of Laminated Displacement Discontinuity Analysis has been researched in such studies. The results out of the models have been coherent with the previous studies.

May 1, 2004

By Gerardo Fuentes

Arsenic extraction from Chilean copper concentrates up to nearly 99% was achieved, using hydrothermal reactions. Arsenic appears in nature in more than 200 mineral species, being arsenopyrite (FeAsS), enargite (Cu3AsS4), and tennantite (Cu12As4S13) the most common species. In addition, arsenic is present in a large amount of copper concentrates, produced in northern Chile. Medical statistics show that in northern Chile, the amount of cancer to the lung, skin and bladder are the highest in the country. The latter situation, demonstrates the importance of studying metallurgical processes that do not generate atmospheric pollution. The hydrometallurgical processes such as hydrothermal treatment in autoclave reactors, do not produce gaseous emissions. On the other hand, the arsenic remains in solution from where it can be transformed in scorodite by widely known methods. Previous works about hydrothermal treatment of enargite have shown the feasibility of transforming the enargite of the copper concentrates into chalcocite or mineral species of the chalcocite family such as djurleite, digenite and for this reason enrich the concentrate in copper and pass the arsenic to solution. For this research, two Chilean copper concentrates were used, concentrate 1 with 5.5% arsenic and concentrate 3 with 1.8% arsenic. These concentrates were subjected to a complete chemical and mineralogical characterization. Later these concentrates were carry out to batch tests of hydrothermal treatment. Also, these concentrates were subjected to grinding to have different particle sizes. For the hydrothermal tests, a liter capacity Autoclave Engineer reactor was used. Characteristic of this reactor was the maximum temperature 350°C, 5000 PSI pressure, and 900 rpm agitation speed. Kinetic tests were carried out with the two concentrates maintaining the same solid: liquid relationship, the same agitation velocity and the variables studied were treatment temperature, time of reaction, concentration of copper in the solution and grain size of the concentrates. The conclusions of the study indicated arsenic extraction of the order of 93.98% from the concentrate 1 and arsenic extraction of the order of 98.74% from concentrate 3. After the hydrothermal treatment, the solids and solutions were characterized chemically, by electron microscopy and X ray diffraction. Also the solids were characterized by grainsize through a particle size analyzer (MICROTRAC). Results of batch treatment shows that arsenic can be release almost completely from real copper concentrates using this hydrothermal process and the next stage will be a scale up process in order obtain results for pilot plant design. INTRODUCTION Arsenic is an impurity that appears associated with copper minerals forming enargite, tennantite, tetrahedrite, and that due to the pyrometallurgical treatment either in conversion or roasting furnaces, it goes into the atmosphere together with the sulfur dioxide. A great quantity of literature can be found to eliminate arsenic or try to separate arsenic from copper. The methods used are mainly leaching processes with or without pressure (Padilla, Jerez & Ruiz, 2015) with different reagents like chloride media (Herreros, Fuentes, Quiroz & Viñals, 2003) or chloride media with sulphuric acid (Riveros & Dutrizac, 2008) or sodium hypochlorite (Mihajlovic, Strbac, Zivkovic, Kovacevic & Stehernik, 2007). It is known too that Chile is the first copper producer in the world and a great quantity of its minerals are in the north of the country, in Antofagasta.

Jan 1, 2019

By L. C. Hsu, M. O. Desilets, P. J. Lechler, Jr. Bonham, J. G. Price, L. J. Garside

Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoicsiliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back-ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive-margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995

By Bergh. L. C.

On line monitoring and diagnosis systems of process operating performance are becoming an important part of industrial programs, leading to improve process operation and therefore product quality over time. In processes, such as the contact section of a sulphuric acid plant, a large number of input variables, highly correlated, are presented. These characteristics usually pose more difficulties in modelling the process for monitoring and diagnosis purposes. Multivariate statistical projection methods, such as Main Component Analysis, have been proposed to effectively deal with these situations. The application of these ideas to a section of a 2350 MTD sulphuric acid plant, located at the Caletones Smelter, including dry tower, gas blowers, catalytic reactor and S03 absorber processes, is discussed here. A PCA model with eight main components is used for monitoring and diagnosis of more than seventy operating variables. Hottelling's T2 and Q residuals test were used for detecting measurement problems in relevant variables, and for identifying which set of variables were responsible for driving the process outside its normal operating region. Furthermore, considerable information for the correction of the tested operating problems was given by the use of these techniques.

Jan 1, 2007

By Nima Nabavi

Shovels and excavators have significant blind spots due to their large sizes, increasing the chances of collision with other surrounding equipment such as haul trucks, loaders, and dozers. While a camera surveillance system is very useful in preventing collision, it can benefit from two additional features: (i) the ability to display the distance of the closest object within the view, and more importantly (ii) the ability to warn the operator if objects are getting too close. After a comparison between few different technologies, it is explained how these features can be provided by integrating rugged pulsar radar sensors with a camera system. The specific radar technology is already field proven in the harsh mining environments. Motion Metrics International Corp. has developed this exact product, which combines its 4-camera surveillance system (ViewMetricsTM) with a series of rugged radar sensor elements, named ViewMetricsTM-Radar. The radar system employs intelligent CAN bus communication to reduce wiring, hence improving hardware reliability with built-in troubleshooting features. A USB connection is the only hardware bridge between the radar sensors and the embedded computer. As such, an existing ViewMetricsTM system can be easily upgraded to ViewMetricsTM-Radar. As addition of new interfaces to the cab could result in operator distraction, this paper explains how ViewMetricsTM-Radar reduces distraction compared to other radar collision prevention systems.

Oct 1, 2009

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By Marcel Vallée

"This text consists of two parts, comments on "Classification and Reporting of Mineral Resources for High-Nugget Effect Gold Vein Deposits," by S.C. Dominy, P.R. Stephenson and A.E. Annels, Volume 10, No. 3, pp. 215-233, and related comments on some features of the JORC Code.This paper is, in many respects, a very elaborate and valuable account of the problems encountered in the estimation and classification of high-nugget gold deposits. However, in some key areas, it appears to fall short of its objective to help "resolve satisfactorily most issues" and "contribute to improved estimation and classification" (abstract). One must realize that high-nugget effect gold deposits constitute a very narrow field, despite the occasional bonanzas. This is a field of mostly smaller sized deposits, where limited success and a significantly higher rate of failure occur relative to larger deposits of mostly lower grade. This is shown by the six deposits described in the paper. Thanks for contributing to greater understanding of these complex and nevertheless challenging deposits."

Jan 1, 2002

By Jr. Santos, T. V. Pignaton, R. B. Gomides, W. Phillips, M. P. D. Gomes

Kinross Paracatu started the operation of the new gold processing plant in the end of 2008, being composed by one SAG mill and two ball mills. During the first year of operation the plant had several problems related to stability and throughput capacity, mainly due to low grinding efficiency of the ball mills. In this period many actions were taken to maximize the throughput rate. Among the actions are reducing the size of balls in the mills, increasing the ball charge in the SAG mill, changing cyclone configuration and return of circulating load to SAG mill. With better stability of the circuit, the second stage of improvements has begun with the objective of increasing throughput rate and also reducing operation costs. Among the actions are the optimization of ball charge in the mills and a better operational control of cyclone parts. After two years of operation was obtained a significant increase in plant capacity, but still requires the addition of a third ball mill in order to maximize the use of SAG mill, which has spare capacity.

Jan 1, 2012

The hydrometallurgical treatment of copper ores and concentrates continues to be an active field of innovation. The direct extraction of copper from ores containing chalcopyrite is an important development to provide an alternative to flotation-smelting and refining. Jetti Resources (with the University of British Columbia) and the JX Nippon Group have developed process options for chalcopyrite heap leaching. Biological heap leaching developments for chalcopyrite are also continuing in parallel. These direct leaching technologies are also very attractive for arsenical ores. The atmospheric leaching of copper concentrates is an attractive option along with autoclave processing. The Galvanox™ Process is the focus of commercialization by InCoR Galvanox Holdings under exclusive license by the University of British Columbia. The Galvanox™ Process can be used to treat chalcopyrite or enargite containing concentrates to high copper extraction with simultaneous precipitation of arsenic as atmospheric scorodite. FLSmidth has continued development of the Rapid Oxidative Leach (ROL) and associated technologies for chalcopyrite leaching. The Glencore Albion Copper Process using ultra fine grinding of copper concentrates and atmospheric leaching has found application in central Africa. The pressure leaching of copper concentrates continues to be attractive for rapid, complete oxidation of sulfide minerals with high copper extraction and arsenic stabilization of iron-arsenate minerals and precipitates. The Ecometales PLCC project is designed to use high temperature total pressure oxidation for treatment of an arsenical copper concentrate with use of existing copper SX-EW facilities for copper cathode production. The excess acid from the autoclave process will be used to make up the acid demand for associated copper ore heap and dump leaching operations. INTRODUCTION The recovery of copper from ores is dominated by the flotation of copper concentrates followed by smelting—converting and electrorefining. This process has been enabled by the development of froth flotation and progressively made more efficient by advances in smelting and converting technologies.

Jan 1, 2019