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By E. Fried

Cemented paste backfill (CPB) is an innovative tailings management method that consists in returning considerable amounts of mine tailings into the underground mine openings. The filled stopes thus participate to the ground support that allows maximizing orebody extraction and a safer environment for the mine workers. There are also significant environmental advantages of using CPB. Indeed, up to 50% of the concentrator tailings can be backfilled, leading to a smaller volume of problematic waste materials to be managed at the surface. Once the CPB is placed, or when the mine is flooded at its end-life, the backfill is subjected to underground water flows that may leach and spread the pollutants (mainly metals, sulphates, and acidity) which can contaminate the underground waters. The aim of this study is to characterize the leaching properties of CPB material and to identify the cement phases that ensure the metal fixation. A laboratory procedure was implemented consisting in the preparation of various paste backfill mixtures using sulphide-rich and sulphide-free materials, different types of binder, and mixing waters having various sulphates, copper and zinc concentrations. After 90-days curing time, the samples were submitted to column leaching tests. The CPB materials were flushed each day with 100 ml of deionised water during 100 days. The collected leachates were then analyzed for pH, Eh, electric conductivity and chemical composition. For some samples, a differential acid neutralisation test was carried out. The objective of this experiment is to dissolve selectively the hydrated phases by adding incremental acid concentrations. By analyzing punctually the equilibrated solutions, the composition of the dissolved phases and their metal content can be estimated. The leaching test results showed that the pH of the leachates remains alkaline during the test period. When the pH decreases under 10 (after 30 days), different behaviours in terms of chemical element release (especially for zinc) were observed. During the test, the oxidation of pyrite seems to slow down, probably due to passivating phenomena. Moreover, the differential acid neutralisation test results allowed a better understanding of the CPB mineralogy and the Zn-bearing cement phases. Zinc and the other metals seem to be fixed within a calcium-magnesium silicate.

May 1, 2007

By Robert B. Parsons

"Exploration and development of mineral resources in developing countries by Canadian-based multinational mining companies is becoming increasingly common. One problem being encountered is that the objectives of the governments of developing countries can differ from those of developed countries. These objectives are not always consistent with maximizing returns from the projects, which can create conflicts between the mining company's responsibility to its shareholders and the desire to be a good corporate citizen. This article discusses how a mining tax regime can be designed to make the social goals of a government consistent with the economic goals of the company.IntroductionAt the recent International Seminar on Mining Taxation organized by CIM and the United Nations there was considerable discussion about the role of international mining companies operating in developing countries. Not surprisingly, given the diversity of backgrounds of individuals attending the Seminar, there were different opinions about what this role should be.Government PositionRepresentatives of governments pointed out the strong desires of their countries for technology, high-level technical training of their workforce, increased employment, and development of social infrastructure. They pointed out that, to a large extent, these objectives could be more efficiently met by mining companies operating in the country than by the governments themselves. For example, a multinational mining company (""MMC"") would have extensive knowledge of the various technologies available, and would have performed a detailed evaluation of the mineral resources before choosing the most cost-efficient technology for that project. They would, therefore be in an ideal position to assist the country in importing and developing such technology. Similarly, the company could provide opportunities for hands-on training, both at the technical and managerial levels, which would otherwise be unavailable to the government."

Jan 1, 1991

By J. A. Meech, G. R. Baiden

"A dynamic simulation of a mine-mill complex has been conducted using networked microcomputers (IBM PC/AT and IBM PC/XT). These models allow simultaneous operation of an open pit using shovels and trucks, a primary crusher, and a secondary crushing plant. Each process transmits information via the network, linking all operations together. The effects of blasting, ore quality, equipment utilization and configuration on productivity can be studied either interactively or from a report listing at the end of each shift. Programs are menu driven leading the user through the decisions required in day to day operations. The mine-mill simulator is currently being used as a teaching tool at Queen's University to provide senior mining and mineral processing engineering students with an experience and appreciation for the operating problems across the mine-mill interface. The need for coordination and close communication between the mine and mill can be aptly demonstrated using these models. The simulator could be used to contribute to the training of operating personnel in a real mining operation. INTRODUCTIONThis paper describes a computer simulator that is capable of showing the interactions and operating strategies between a mine and a secondary crushing plant. The simulator uses two models developed at Queen's University; one for open pit mining and the second for secondary crushing. PITSIM is a dynamic shovel/truck haulage model origin2lly developed by P.D.D. Chick (1) and K.G. Fytas (2) to solve shovel/truck scheduling problems. CRUSHSOFT is a dynamic secondary crushing plant model developed by R.J. Tucker (3) and C.A. Harris (4) to study alternative operating and control strategies in a crushing plant."

Jan 1, 1987

By G. A. Mallory

"The South Bay Division of Selco Mining is located fifty-four miles northeast of Ear Falls Ontario on Confederation Lake. The concentrator operates five days a week and processes six hundred tons per day of copper zinc silver sulphide ore. The concentrator is comprised of crushing, grinding, differential flotation, thickening and drying circuits. The major constituents of the concentrator feed are: chalcopyrite 7%, sphalerite 20%, pyrrhotite 3%, pyrite 25 - 30% and felsitic volcanics 40 - 50%. The mine went into production in March 1971 with an anticipated three year life and is now scheduled for closure in the summer of 1981. Recent mine production has been limited to three cut and fill stopes which have widely varying ore grades, therefore mill feeds vary from 0.25 to 4% copper, 3.5 to 27% zinc, 0 to 0.4% lead and 15 to 30% iron.In mid 1977 Selco negotiated a six month rental purchase agreement with Outokumpu Instruments Canada Limited for a five stream analyser system. The Minexan 202 probes were the first Outokumpu probe type analysers installed in Canada although Outokumpus' Courier systems are well known. Installation of the system took place in April 1978 and after numerous hardware faults the six month evaluation began in August. By December it was obvious that the Minexan 202 probes with proportional detectors did not have adequate resolution to determine low copper values in either of the tailings streams. Outokumpu offered to replace the tailings analysers with a new prototype solid state detector probe the following summer. The evaluation on the five Minexan 202 probes continued until August 1979 when the new solid probe was installed. The Minexan S (solid state) probe was evaluated with the three remaining Minexan 202 probes until December 1979 when Selco elected to purchase the system."

Jan 1, 1981

By Robert K. Jonas

"Minerals processors can improve production by using the best available control technology to control their operations. Many mines use expert systems that can provide improved results over manual or basic control, but better results can be achieved using multivariable predictive control. Over the past few years, the application of multivariable predictive control has gained acceptance in many mining processes and has recently proven to be suitable for some of the most challenging processes. This advanced control technology has been successfully applied to a wide variety of processes; alumina digestion, ball mills, CCD/thickeners, kilns/calciners/roasters, heat exchangers/evaporators, and more demanding processes like SAG mills and flash smelters.This paper discusses the needs of advance control technologies in the mining industry, including the impact of these technologies on best practices for implementation and long term sustainability. Results of the multivariable predictive control applications in mineral processing are discussed, and in particular the application to the SAG mill. In addition, an example of the benefits improvement that can be achieved with this technology is presented.INTRODUCTIONThere has been a long term perception in the mainstream mineral processing industry that best advanced control solution is an expert system. There a numerous instances of expert systems used for control of SAG mills, as well as kilns or roasters, thickeners and more recently flotation circuits. Many of theses expert systems have been installed by small, independent companies or by OEMs of processing equipment. Undoubtedly these expert systems have provided millions in benefits to the owners of mineral processing plants.It is this author’s proposition that it is a misconception to believe that expert systems are the best solution for mineral processors, and that in many cases the best solution is Multivariable Predictive Control (MPC). Better control and optimal operations can be achieved through the use of MPC. Another important consideration when considering advanced control technologies is the implementation and support effort. These types of applications have been known to deteriorate, even to disuse, when they are not kept up to date with changes to the process or equipment. The audience is invited to listen to discussion and draw their own opinion. The author has been involved in installing control systems for over 20 years, advanced solutions for over 15 years, and has had privilege to consult with many miners concerning the selection and application of advanced controls over the past 6 years."

Jan 1, 2008

By J. C. Johnson

Underhand mining with cemented mill tailings for backfill has proven to be a safe and effective alternative to conventional overhand mining for rockburst prone mines. The ability of the cemented sandfill to survive a rockburst shock wave without failing has been observed at mines in the Coeur d?Alene Mining District many times in the last twenty years. To better understand the dynamic loading of this commonly used support material the National Institute for Occupational Safety and Health (NIOSH) performed laboratory experiments using a split Hopkinson Pressure Bar (SHPB) to quantify the maximum stress and energy absorption of cemented mill tailings from the Galena mine. Cylindrically shaped cemented backfill specimens aged 28 days were placed in the split Hopkinson pressure bar testing apparatus and a dynamic load was applied. The measured peak dynamic compressive strength of the cemented sandfill was 10.6 MPa (1540 psi) and is approximately twice the static unconfined compressive strength (UCS) of 5.5 MPa (800 psi). These test data showed about 95% of the initial energy was reflected away from the backfill and only 5% of the energy was absorbed. This may help to explain why backfilled stopes could withstand seismic events up to 3.5 Richter magnitude (Ml). When a compressive rockburst wave impacts a stope a large amount of the stress and energy is reflected away. The reflected wave is a tensile wave which creates tensile cracks and spalling in the entire wall of the stope. The backfill supports the damaged wall rock and holds it in place. Some of the stress and energy of the rockburst is transmitted into the backfill and because the backfill is being dynamically loaded it has a strength that is twice its static value and absorbs a substantial amount of rockburst energy. Although mining in deep underground mines is an extremely hazardous occupation, the use of underhand mining with cemented backfill for static and dynamic ground control increases the safety of the workers.

May 1, 2007

By H. E. Frimmel

Abstract - Most of the gold in the Late Archean Witwatersrand Basin is of detrital origin but, in its present form, it is metamorphosed. The only relict detrital features preserved are the morpho­logical characteristics of some placer gold particles. Regional burial metamorphism in the shallower and deeper levels of the Witwatersrand Supergroup reached temperatures around 300°C and 350°C at pressures between 2 kbar and 3 kbar, respectively , estimated from phase relations, chlorite-chloritoid exchange thermometry and chlorite thermometry . Metamorphism of the gold involved compositional homogenization of individual gold particles and partial recrystallization. Various infiltration events caused the partial mobilization of the gold at slightly lower temperatures, between 240°C and 300°C. These infiltrations can be related to crustal extension during the deposition of massive carbonate sequences of the Transvaal Supergroup (around 2.5 Ga), and later to the emplacement of the Bushveld Complex, and to the Vredefort event around 2.0 Ga ago. The mobility of the gold was dependent on the sulfur fugacity prevailing in a particular horizon which, in turn, was deter­ mined by the amount of pyrite (and other sulfides) present in that horizon. With the sulfur fugacity being controlled by stratigraphy, low fluid:rock ratios in a pyrite-rich horizon were most conducive for the mobilization of the gold. Thus, long-range gold mobilization in the Witwatersrand Basin can be expected to be the exception rather than the rule.

Jan 1, 1994

By Tiziana Apuani

The study refers to an area of about 70 km2, extended in the Italian Central Alps along the the San Giacomo Valley where different civil and mining works are present The regional geological setting is related to the Pennidic Nappe arrangement, characterized by the emplacement of sub-horizontal gneissic bodies resulting from the Mesoalpine isoclinalic folding of crystalline basements, emplaced throw East, and separated by matasedimentary cover units. The investigated geological rocks, belong to the ?Tambò?Unit, overlapped by its meta-sedimentary cover and by the ?Suretta? Unit. The tectonic contact gently dips to the E?NE. The valley, furrowed by the Liro Torrent, follows a N?S striking tectonic lineament, almost parallel to the nappe contact. A number of more then 70 sites, distributed in the studied area, were chosen and detailed structural and geomechanical field surveys were performed to characterize the rock masses, its intact rock and discontinuities. The procedure identifies the number of joint sets, their representative orientation, the set spacing, the type of movement, the amount of dilatation, the degree of alteration, the roughness coefficient, the presence and nature of infill. Rock mass quality indexes, such as the Rock Mass Rating (Bieniawski, 1989) or the Geological Strength Index (Hoek et al. 2002) have been evaluated in each surveyed site. The work is a contribute in assessing how the geometrical and geomechanical properties of the rock masses can be regarded as regionalized variables. The spatial distribution of these properties is a function of the geological and structural phenomena at which the rock masses have been subjected. The presented geostatistical analysis regards the spatial variation of the orientation of the most representative joint set.

May 1, 2009

By P. P. Sinha, D. N. Bhatia, B. R. Ghosh, R. K. Gupta

Medium carbon, low alloy, high-strength steels containing Ni, Cr, and Mo are used for the fabrication of various types of high-strength fasteners required for launch vehicle structures. Cold heading properties and response to hardening and tempering are the essential requirements of the material for fabrication and application, respectively. Combining these two requirements is essentially warranted in high-strength fastener-grade steels. Cold heading properties require ductility, which can be achieved through spheroidizing treatments. In the absence of a suitable spheroidizing cycle for medium carbon 3.8 Ni, 1.8 Cr, 0.3 Mo steel, experiments were carried out with a theoretical understanding of the alloy system. This paper presents the experiments and results obtained after a spheroidizing treatment, which was carried out to optimize the process. Hardness measurements were carried out and microstructural studies were conducted to assess the spheroidization process and to determine the optimal spheroidization parameters.

Jan 1, 2007

By Jacob Masliyah, Zhiang Zhou, Dharamdat Christendat, Tshitende Kasongo, Kevin Hyland, Zhenghe Xu, Ted Kizior, Douglas Cox

"A novel on-line visualization system, previously developed at Syncrude Canada Ltd., has been modified to characterize rising bubbles, particles and particle-bubble aggregates in a flotation process. With this system, the bubble size and rise velocity in a laboratory flotation cell can be determined. The technique allows the loading of solids on bubbles to be visualized, thereby providing an in-depth understanding of sub-processes of flotation. A step-by-step data processing procedure is presented. The applicability of the developed system to mineral flotation and bitumen extraction is discussed. Under batch flotation conditions in a laboratory Denver cell, three main bubble-particle attachment patterns are observed. They are: i) single particles attached to single bubbles, ii) particle aggregates loaded on single bubbles; and iii) a group of particles aggregated with a group of bubbles. The results demonstrate that the on-line visualization system is a powerful tool for understanding and diagnosing flotation processes.INTRODUCTIONAir (Gas) bubbles are an indispensable component in a flotation system. Both industrial practice and theoretical analysis indicate (Yoon, 1993; Diaz-penafiel and Dobby, 1994) that the size and population of bubbles are two important process parameters in modeling flotation. More recent investigations (Finch, et al., 1999; Gorain, et al., 1997) suggest that for a given flotation system, bubble surface area flux, defined as the air liquid interfacial area per unit time and unit cross-sectional area of flotation cell, showed a better correlation with the flotation rate constant. As a result, the bubble surface area flux is now being considered as a key parameter to account for the combined effect of bubble size and population in evaluating the performance of flotation machines and modeling flotation processes. However, the success of using bubble surface area flux in flotation process modeling largely depends on how accurate it can be determined or estimated (Finch, et al., 1999)."

Jan 1, 2000

By Jack Zhang, Chuck Edwards

"The versatility and specificity of rare earth elements (REEs) have led to their use in an ever increasing variety of applications in new technologies. Consequently, demand for REEs has increased significantly. However, to separate REEs safely and effectively is a complex and expensive process. While China has consistently invested in R&D of REE processing technologies, there have been only sporadic activities in REE mineral processing in North America in the past 20 years. This paper presents a review of REE mineral processing technology, providing an update on current capabilities in REE mineral processing. This paper reviews REE extraction from the major commercially valuable REE-bearing minerals such as bastnaesite, monazite, and xenotime, and also from the ion-absorption type of REE deposits. Currently, there are four major REE mining areas in China, one in the United Sates, and one in Australia. A review of the REE extraction processes in these major REE mining areas closes out the paper.INTRODUCTION The rare earth elements (REEs) include the 15 lanthanide elements, plus yttrium and scandium. The lanthanide elements are normally categorized in two groups: the light rare earth elements (LREEs), i.e. lanthanum through europium (atomic number (Z) = 57 through 63); and the heavy rare earth elements (HREEs), i.e. gadolinium through lutetium (Z = 64 through 71). Yttrium is usually grouped with the HREEs due to similarity in physical and chemical properties. Table 1 lists the REEs, atomic numbers, and abundances in earth’s crust (Taylor and McCleannan, 1985). Promethium is the rarest due to lack of stable isotopes. REEs with low atomic numbers are more abundant than those with high atomic numbers. More interesting is that the REEs with even atomic numbers are much more abundant than adjacent lanthanide elements with odd atomic numbers as shown in Table 1."

Jan 1, 2012

By John Kazakoff, Andrew Mortimore

"Production at the remote Kumtor Gold Mine in Kyrgyzstan commenced on schedule in December 1996.The ore mined during the first few months of 1997 from the upper benches of the pit did not produce the results predicted by the feasibility study. Low metallurgical recoveries experienced at the time were cause for great concern.It soon became clear the recovery difficulties centred around the preg robbing nature of the ore.Procedures were developed to selectively stockpile highly carbonaceous low recovery ore types. Testing methods were developed in the mill to quante the preg robbing activity of the ore. Preg robbing masking agents were added to the process to reduce the preg robbing activity of the ore.The importance of coconut carbon activity relative to the preg robbing activity of the ore was realized. Every aspect of the performance of coconut carbon in circuit was evaluated and optimized to improve carbon activity.Mineralogical analyses were completed defining the deportment of gold in ore and process tailingsBy year end the recovery difficulties had been overcome and plant design production had been achieved. Process improvements continue through 1998."

Jan 1, 1999

By B. K. Gorain, A. W. Stradling

"The traditional metallurgical scale-up techniques for flotation plants are based on lumped flotation rate constants, dimensionless hydrodynamic numbers and the use of safety factors. Once the plant has been designed, the flotation principles that govern scale-up play almost no role in the optimization of the circuit to meet its metallurgical targets. This deficiency can potentially lead to a plant design incapable of meeting its targets, especially when circuits incorporate large flotation cells. This paper demonstrates the application of the k = PSbRf model in providing a suitable framework for flotation modelling, scale-up and circuit optimization, thus presenting an integrated approach to the problem. Studies were conducted at Teck Cominco’s Red Dog concentrator to characterize cell hydrodynamics, gas dispersion properties, froth flow behaviour, entrainment and ore floatability to obtain the key data necessary to develop a model for the flotation circuit. The findings of these studies are presented in this paper, which provide valuable insights into the modelling and optimization of the Red Dog flotation circuit. IntroductionThe traditional methodology for flotation scale-up and plant design is based on the ruleof- thumb with safety factors and dimensionless hydrodynamic group similitude considerations. With the recent trend toward larger flotation cells with volumes of 150 m3 and greater in concentrators, the problem of scale-up has become even more acute. The scale-up factors that may have been tolerated on smaller cells are not applicable to larger cells. The transportation of froth in these large cells adds further complexity to the problem. Arbiter et al. (1980) foresaw this problem and pointed out that if scale-up were attempted by rule-ofthumb and trial-and-error, the probability of failure would then increase with scale. This problem is confounded by the fact that the design and scale-up considerations used for a new flotation circuit play almost no role in optimization of the circuit to meet its metallurgical target. This results in a plant design, which may be incapable of meeting its metallurgical targets. There have been several instances where new concentrators have required significant circuit modifications and additional capacity to achieve design targets."

Jan 1, 2003

By R. A. Hill, J. D. Pitts

"Long distance slurry pipeline systems have been successfully trans-porting steam coal, iron concentrates, copper concentrates and limestone for an aggregate of nearly 60 years and nearly three billion ton-miles annually. A phosphate concentrate pipeline is nearing start-up and systems for coking coal, lead/zinc concentrates and fly ash are planned. The solids pipeline concept, first patented in the early 1900's and commercialized in the 1950's, is now a proven technology providing an economic, environmentally pleasing and safe method for long distance bulk transport.The challenge for larger tonnage and longer distance movements of solids, for traversing increasingly rugged terrain in grass roots mineral developments, for transporting untried materials and for shipping more economic forms of proven materials still remains. This has necessitated continued refinements and optimization of the technology. The economic and environmental incentives for slurry pipelines when compared to other transport alternatives has justified substantial activity in this area. The scope of planned systems in coal, iron and other minerals is indicative of the firm place slurry pipelines will have in worldwide mineral development.In this presentation, the state-of-the-art in long distance slurry pipelines is reviewed with a focus on major systems of interest to the mineral processing industry. An overview of new developments in the application of this concept is presented, and finally, a projection of the future of pipelines in mineral development both worldwide and in Canada is discussed."

Jan 1, 1978

By J. A. López-Molina, S. García, V. Castellanos-Pedroza

"Grouting aims to reduce the permeability of rock mass below a predetermined value and has been widely used in rock engineering field for a long time. However, the injection procedure needs several empirical decision makings and it is rather difficult to reliably confirm the achievement of improvement, because the grout penetration process is not sufficiently clarified. This investigation proposes a neuronal method of defining spatial distribution of rock hydraulic properties and a fuzzy scheme for estimating their relation with the grout penetration (consumption, localization and filling material). The intelligent method stands as a tool for helping in harmonizing the sealing activities and the medium conditions. The virtual simulation of grouting strategies embraces geology, hydraulic and rock characteristics and the filling process. Important aspects as different pressure injection levels and fracturing systems can be holistically studied using the intelligent environment, resulting in an advantageous, economic, flexible and interactive tool for planning better this critical activity.INTRODUCTION Grouting is a very common method of sealing rock and repairing concrete structures (Butron et al., 2010) and its use in engineering of dam-foundation and tunneling has been documented as very successful (Yang, 2004). Generally speaking, to achieve the closing purpose, boreholes are drilled into the rock mass and grout is injected (under pre-selected pressure) until the fractures around the borehole are filled. The complete filling of these fractures is possible if they are connected to each other in such a way that the remaining water and air can be displaced outside the designed grouting zone (Houlsby, 1990; Kutzner, 1996). Water testing is necessary for evaluating seepage potential and for determining whether grouting is necessary or practical. Regardless of the main reason for the investigations, design of a program for water testing for grouting should consider the type of structure to be built, the geologic conditions at the site and the level of seepage control desired. As information gathered the report must content the fracture openness, number and connectivity, exploratory drill holes orientations, materials situation and a panorama of rock-mass state (quality)."

Jan 1, 2015

By G. Danha, D. Glasser, D. Hildebrandt, N. Hlabangana

"In this work, we apply a method known as the attainable region (AR) technique in order to optimize the milling and leaching process of a low grade gold ore. No work on the application of the AR optimization technique has been done yet on a joint milling and leaching process. The advantage of the AR approach lies in its ability to simplify the optimization problem, as searching over a defined set for the maximum of an objective function is a fairly standard procedure. The objective function we selected was that of optimizing a linear function of the value of the recovered material minus the cost of both milling and leaching. Using the three variables (milling time, leaching time and recovery), we constructed a 3D plot and used it to obtain all the possible recoveries from the different milling and leaching times. The optimum for our chosen objective was then found by overlaying a contour plot of the objective function on the 3D plot. Our results show that the optimum was obtained at 90 % recovery with a profit value of 600, milling time of 30 minutes and leaching time of 1750 minutes.INTRODUCTIONAfrican countries are facing a general increase in demand for electrical power. In South Africa, the demand is now surpassing the supply from ESKOM, the main electric power provider of the country. This has resulted in load shedding strategies being implemented in many local communities in an attempt by ESKOM to cope with the high demand. A potentially better approach is to propose use of energy efficient technologies in the country’s largest power consuming industry; the mineral processing sector.In mineral processing, milling is the highest consumer of energy. The objective of carrying out milling is not merely to reduce the particle size of the feed material, but also to liberate the constituent minerals that make up an ore. This is done so that valuable minerals can be separated from the gangue, in downstream processes, such as leaching. However, the milling process is generally performed relatively poorly, and at a considerable expense in terms of electrical power utilization. Tomanec and Milovanovic (1994) estimated that milling accounts for more than 50 % of the total power used in the concentration process, but this can rise to as high as 70 % for hard or finely dispersed and inter-grown ores. Apart from being relatively wasteful of energy, the milling process is also inefficient with regard to mineral liberation because of the indiscriminate nature of the grinding force."

Jan 1, 2016

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019

An Atomic Force Microscope (AFM) was used to measure the surface forces between glass sphere and silica plate in CnTAC1 (n=12, 14, 16, 18) solutions. The results showed the presence of long-range attractive forces that can be fitted to single exponential functions. With a given surfactant, the attractive force increased with increasing concentration, and reached a maximum at the point of charge neutralization (p.c.n.). The decrease in the attractive force above the p.c.n. is probably due to the inverse orientation of the surfactant molecules. A plot of the log (p.c.n.) vs. the number of carbons in the hydrocarbon chains of the Cn TACI homologues showed a linear relationship with a slope of -0.37, indicating that the surfactant adsorption entails a decrease in free energy by -0.85 kT per mole of CH2 (or CH3) group. These results suggest that the adsorption of long-chain surfactants is controlled by hydrocarbon chain association during the process of forming surface hemi-micelles (or domains). Possible origins of the long-range attractions are discussed on the basis of the results presented in this communication.

Jan 1, 2006

By Michael Godard, Peter Cleyle

"Suncor Energy’s Project Millennium increased oilsands production capacity by an additional 95,000 barrels per day to its present level of 225,000 barrels per day. This massive venture included an expanded Mine, new Extraction and Upgrading facilities, as well as, steam and utilities infrastructuresIn the Primary Extraction process, removal of the bitumen from the oil sand begins with slurry preparation and is followed by primary , secondary and tertiary separation processes. The final cleaning step of the bitumen froth is the Secondary Extraction process, that removes residual water, mineral and solids to produce a clean diluted bitumen suitable for Upgrader feedstock.This paper will review the flowsheet of the Millennium Primary Extraction facility, from its recent commissioning through the ramp up to design production rates. In addition, new technologies in the Primary Extraction flowsheet will be reviewed.INTRODUCTIONAs conventional supplies of oil and gas are depleted in Canada, the Athabasca oil sands industry of Alberta becomes an increasingly important source of energy. Today, high quality crude from Alberta’s oil sands accounts for roughly 30% of Canada’s daily petroleum production. According to government projections, over the next 7 years, oil sands production is expected to more then double, and by 2010 more than half of Canada’s crude oil is expected to come from the oil sands.Oil sands deposits consist of a layer of sand saturated with bitumen covered by a muskeg overburden and underlain by silt and clay. The oil sand is mined where the overburden is economical to remove, typically less than thirty meters thick. The Athabasca oil sand deposits around Fort McMurrray is ideal for mining. Bitumen can be described as a diverse collection of hydrocarbons, organosulfur, and nitrogen compounds."

Jan 1, 2004

By F. E. du Plessis

"The distinction between data suitable for process control and data subject to aliasing only becomes quantifiable with the availability of rapid real-time measurements. Expecting the dynamics of flotation to vary for different ore types, process flows and equipment types; a study was conducted to compare the dynamics of different flotation processes. The results shed light on the critical sampling intervals required for process control which in turn allows process stabilization and optimization. The technology used for the in-line measurements is based on diffuse reflective spectroscopy and has been introduced into the mineral processing industry over the past ten years. It has been widely implemented in the sulphide flotation industry in South Africa for the real-time measurement of grade.BACKGROUND AND OBJECTIVE A study was conducted by Du Plessis and Keet (2010) to quantify the minimum sample frequency required for grade and/or impurity control. The study was based on chromite data collected at 15 second intervals from the concentrate line of a flash float cell in the Platinum industry. The data captured the natural process variation of the entrained chromite through water recovery due to changes in feed parameters and flotation performance. It was found that the minimum rate of sampling required from the studied flash float concentrate was 2 minutes. This sampling interval time accounted for 90% of the variance in the process data. It was further found that a sampling interval time of longer than 4 minutes produced data with no significant correlation to reality. The dynamics of the flotation process has been misjudged in the past but can be quantified with the availability of real-time grade measurement based on diffuse reflective spectroscopy. The objective of the study was to compare the dynamics of different sulphide flotation processes through the comparison of maximum sampling interval times required to combat aliasing. All data were collected from single stream analyzers that are currently installed at mineral concentrators. The technology used is based on diffuse reflective spectroscopy."

Jan 1, 2012