Search Documents

By S-E. Vandat

The goal of this work was to select an appropriate electrode for dummy load of diesel engine in fully salt-water in the DESA factory. The electrochemical corrosion rate of general structural steel, commercial pure aluminum and cathode copper calculated as weighting, volumetric and commercial in fully salt-water by city power. After several tests and then applying the fuzzy logic method, it was determined that general structural steel is the best selection for this purpose.

Jan 1, 2005

By JOHN DUNFIELD

Good quality sphagnum peat bogs occur across Canada in areas of ample rainfall and cool, temperate climates. Early peat production techniques were restricted primarily to hand digging blocks of peat and piling them up to be dried by sun and wind. Suburban de velopment in the 1950s and the concomitant spread of home gardening triggered a dramatic growth in peat demand; labour costs rose in the same period. Peat production techniques had to alter accordingly. The three mechanical inno vations attempted were hydraulic mining, mechanical block digging and vacuum harvesting. Of these, the last method pro ved the most successful in Canada and is used to harvest 80% of Canadian peat production. Escalating transportation costs are the most important feature affecting future development of the Canadian peat industry.

Jan 1, 1984

By B. K. Gorain

Barrick' s Buzwagi copper-gold deposit in Tanzania comprises oxide, saprock and sulphide mineralized zones averaging approximately 0.058oz/t gold, 0.13% total copper and 0.03% cyanide-soluble copper. A comparative evaluation of the project based on two potential flowsheet alternatives is presented. The first flowsheet included a gravityconcentration and carbon-in-leach (CIL) plant. The second flowsheet was based on a Gravity-Flotation-CIL plant, which proved to be more economically robust. Selective flotation of copper minerals to produce a saleable copper concentrate proved to be challenging. Detailed characterization of the Buzwagi deposit was carried out through understanding of ore mineralogy, mineral liberation, floatability and selectivity, reagent chemistry and regrinding issues. With this insight, a flotation concentrate of greater than 25% Cu was achieved, recovering a significant amount of copper minerals and tellurides. The overall economics of the project improved significantly with the addition of flotation. Leach tests on gravity and flotation tailings showed an overall increase in gold recovery of approximately 6% for a Gravity-Flotation-CIL plant compared to that for a Gravity-CIL plant.

Jan 1, 2007

By C. Pichler, S. Luidold, C. Wagner, C. Sagadin, D. Kreuzer

Engineers and scientists have been combating the attack upon refractory materials of molten metals/matte and slags for hundreds of years. The details in many cases are still questionable or at least debatable. The corrosion is a major concern for furnace operators as refractory wear or failures inevitably results in reduced production efficiency and furnace reliability. Also the cost to industry is considerable and only a thorough understanding of all the complexities of the process will help to minimize that cost. One of the critical questions to overcome is the correct selection of refractories for the individual process steps to provide long and predictable refractory life together with high furnace availability. To understand the nature of the reactions involved in refractory corrosion, it is crucial to determine the complex thermo- chemical equilibria of the reactions occurring between the refractory materials and the process phases. A simulation model coupled with commercial software like FactSageTM is demonstrated aiming to understand the corrosion mechanisms between refractories and the molten process phases and draw implications for improving the performance of refractories and refractory lifetime. INTRODUCTION The extraction or recycling of valuable materials, e.g. metals, can be done by two main routes, pyro- and/or hydrometallurgical processing, depending on the chemical behavior of the used ore, scrap or pre-treated concentrate. Sometimes it is also necessary to use both process routes for the extraction or the recycling of valuable materials. In the case of a pyrometallurgical treatment, the usage of refractory materials is inevitable. This is mainly caused by high temperatures, prevailing during processing. The interaction between refractory material and slag, metal or matte leads to different reactions and interactions. As a main result corrosion of the furnace lining (refractory material) takes place. Hence, recurring furnace shutdowns occur for renewing the refractories. This leads to reduced production efficiency. Such refractory lifetimes are between some hours and decades, depending on the processes.

Jan 1, 2019

By Juergen Antrekowitsch, Stefan Steinlechner

"Within the last decades, mainly the base metals, like zinc, copper and lead were recycled from different industrial residues without taking into account that accompanied minor side-elements are often also present. A high supply risk for critical raw materials derives mainly due to the high share of the worldwide production in a limited number of countries. Examples include indium and germanium in China, PGM in South Africa and Russia or cobalt and tungsten in the Democratic Republic of Congo. By taking the market of critical metals into account, the recycling of potential residues does not only contribute to an economic treatment but also to the European strategy to decrease the supply risk of certain metals. Depending on the metal discussed, political unrest, decreasing primary resources leading to supply risks in different countries or also simply economic interests moved these mentioned side elements and with this the residues where they are present in, into the focus of the recycling industry.Because of this, the typical routes of lead, zinc and copper production are evaluated concerning generated residues and their typical contents of contained minor elements. Finally, the paper tries to answer the questions how a possible treatment of these wastes could contribute to the overall supply of for example silver but also other minor elements."

Jan 1, 2016

By R. R. Rogers

Abstract The degree of cathodic protection of steel and the anode corrosion rate were determined when anodes and waters of different compositions were used at temperatures similar to those in domestic hot water tanks. Twenty different anode materials, sixteen of them magnesium-zinc-aluminium alloys, were immersed in six different synthetic waters resembling those to be found in various parts of Canada. The results showed that (1) both the degree of cathode protection and the average anode corrosion rate are affected materially by the composition of the anode material and of the water; (2) poor cathode protection is associated with low anode corrosion rate; (3) when the cathode is fully protected, the anode corrosion rate may be comparatively low or comparatively high, depending upon the composttion of the water; (4) an important relationship exists between the magnesium content of the preferred anode and the composition of the water; (5) the degree of protection is increased as the SO4 + Cl concentration of the water is increased and thus as its specific resistance is decreased. Introduction Fairly recently, the use of the active metal magnesium for the cathodic protection of less active metals has received a considerable amount of attention. This interest has been stimulated by the fact that the wartime demand for magnesium was greatly in excess of the present peacetime demand and there is a natural desire to continue operating the large magnesium plants which were built during the war. Information regarding the use of zinc and aluminium for this purpose also has been published. There is a great demand for domestic hot-water tanks which will resist corrosion satisfactorily. This problem is rather complex in view of the fact that the composition of the water used in such tanks varies greatly and depends upon the locality. The present investigation deals with the effect of water composition and anode composition on the cathodic protection of steel under conditions approaching those which exist in hot water tanks.

Jan 1, 1948

By M. Cala

Underground coal gasification is technology which enables energy to be extracted from coal beds where mining by means of classical methods is either impossible or uneconomical. The process of coal gasification itself is a complex phenomenon which includes chemical and physical processes: thermal, hydrological and mechanical. Additionally, the analysis of underground coal gasification is difficult to carry out for environment reasons, this being due to the local characteristics of the areas where it is carried out. This paper deals with interaction of geo-reactor with surrounding rock mass, it omits the chemical processes inside geo-reactor itself. Due to the complexity of the processes proceeding and during underground coal gasification coupled with minimal practical experience in using this technology, it is difficult to estimate its influence on the surrounding rock mass. Within this scope, the use of numerical programs can be useful. This paper presents a trial of modeling the processes accompanying underground coal gasification. The processes proceeding and during the underground coal gasification are characterized, and the significant, specific phenomena are discussed, with respect to the influence on the surrounding rock mass. For the chosen processes, examples of numerical calculations are presented. These enabled conclusions to be drawn and also provided directions for the modeling of the underground coal gasification processes.

Aug 1, 2013

By K. Bachmann, M. Rudolph, U. A. Peuker, H. H. Duong, T. Heinig, T. Leißner, H. Schubert, Helmholtz-Institute Freiberg for Resource Technology, Technische Universität Bergakademie Freiberg

"Minerals can be liberated by random fracture of particles into smaller fragments or by detachment along phase boundaries. These two mechanisms represent borderline cases. When ores get comminuted the liberation of minerals is achieved to some extent by both mechanisms. This article describes a method to determine the extent of transgranular and intergranular fracture on surface exposure of minerals based on 2-dimensional liberation analysis.The approach uses the non-biased surface information like phase specific surface area (PSSA), phase specific free surface (PSFS) and phase specific locked surface (PSLS) of minerals and their change with comminution. The amount of transgranular and intergranular fracture on surface exposure can be calculated using the phase specific surface parameters.A sedimentary rock (apatite ore), an igneous rock (nepheline-syenite) and an artificial material (copper slags) were ground to different fineness. Based on the mineral liberation analysis (MLA) of feed and products, the extent of phase boundary fracture on the surface exposure of the minerals is studied.INTRODUCTIONMinerals can be liberated ether by comminution or by detachment (Gaudin, 1939). Liberation by comminution is a random fracture mechanism, which is not being influenced by ore texture, grain boundaries and mineral features (transgranular fracture). Liberation by detachment represents a fracture along grain boundaries (intergranular fracture). Random fracture often is named as the dominating mechanism for the liberation of ore minerals. This has been the basis to simplify models for liberation modelling (Barbery, 1991; King, 1979; Meloy, 1984) assuming that the probability of cracks moving along grain boundaries is zero. Thus, no interfacial area is lost during comminution."

Jan 1, 2016

By Derek Perkins

"Brenda Mines Ltd. operates an open pit copper and molybdenum mine located in south central British Columbia. The main economic mineralization is chalcopyrite and molybdenite. Pyrite, galena and sphalerite are also present in varying quantities. The mineralization is present in small veins and fractures in a porphyritic quartz diorite host rock.The mill processes approximately 30,000 tonnes of ore daily. The ore is crushed in three stages and then ground in conventional rod mill - ball mill circuits with cyclone classification. The cyclone overflow is fed to the bulk flotation circuit as a pulp with a density of 50% solids. The particle size distribution is approximately 35% plus 65 mesh. Bulk rougher and cleaning flotation produce a concentrate grading approximately 20% copper and 4% molybdenum. This concentrate is fed to the separation circuit, where the copper is depressed with sodium hydrosulphide and the molybdenum is floated. These products are further ground and then upgraded by column flotation. The molybdenum concentrate is pumped to the leach plant to reduce concentration of lead and copper. It is then washed, filtered, dried and packed for shipment to Europe. The copper concentrate is filtered, dried and subsequently shipped to Japan.Prior to November 1977, the mill flotation control was carried out by the assay laboratory using a Philips PW 1540 sequential x-ray spectrograph. The assay set consisted of twelve samples, analysed on a two hourly basis for copper, molybdenum, lead, iron and silica.In order to provide elemental composition information on a much shorter sampling interval and to produce speedier control analysis for automating process control, an Applied Research Laboratories PCXQ on stream analyser was purchased. The installation of this analyser, reduced the turnaround time of the control analyses from (2) hours to (20) minutes. At Brenda, the following assays are used in the mill control strategies."

Jan 1, 1989

By E. Allen

Quebec Cartier Mining Company operates approximately two hundred and fifty pieces of equipment in a climate with a temperature that has averaged 27.5°F during the last seven years. The use of special-purpose lubricants, fuels, antifreeze, rubber compounds, and alloy steels have reduced the cold-weather hazards. In some areas, high-cost cold-weather protective heating devices are being eliminated with experience.

Jan 1, 1966

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By D. R. Murray

"In 2017, Nutrien Allan Potash remediated a portion of the concrete liner in the production shaft. A set of underslung work platforms and collection boxes were used in conjunction with hydraulic splitters, jackleg drills and hand chippers to excavate and remove the broken concrete. New concrete was placed with the original pressure relief design, using a shaft slip form. Shortly after excavating, it was found that the estimated breaking rate and amount of original concrete in-situ was under estimated. Fifteen feet of excavated concrete (2719cu.ft) and ten feet (of replaced concrete was completed on April 28, 2017, and operation of the production shaft was returned to mine operations. During February 2019, Nutrien Allan Potash began remediation of a portion of the concrete liner in the service shaft. The project is different than the 2017 project, as the remediation has occurred during normal running operations and occurred only on night shift. Rather than hydraulic splitters and hand chippers, the new method includes a concrete saw and mechanical excavator from a working platform. The selected method is based on the lessons learned from the 2017 project in the production shaft. The service shaft project was scheduled to be completed in July, 2019. INTRODUCTION Nutrien Allan Potash is located approximated 75 km east of the city of Saskatoon, Saskatchewan, Canada. There are currently two shafts at Nutrien Allan Potash: the Production Shaft and the Service Shaft, transporting people and material from surface to a depth of 3,335 ft. The Production Shaft was completed in 1967, with one section of grey cast iron tubbing installed in the Blairmore formation between the 1605 and 2037 ft Levels. A second set of cast iron tubbing was installed in the Duperow formation between 2203 and 2463 ft Levels in 1999. The remainder of the concrete as of todays standards is designed as a pressure relief liner. The Service Shaft was completed in 1968, with one section of grey cast iron tubbing installed in the Blairmore formation between the 1600 and 2048 ft Levels. A second set of cast iron tubbing was installed in 1981, with 169 ft installed through the Duperow formation. The remainder of the concrete as of todays standards is designed as a pressure relief liner. PRODUCTION SHAFT REMEDIATION During the second quarter of 2015, the Mine Engineering team were notified of an area of concern in the production shaft. The shaft specialists of Golder Associates Ltd (Golder, formerly Alan Auld Canada) were contacted to complete an inspection of the production shaft liner with emphasis on the area of concern. Based on the inspection and documentation review, it was determined that the concrete at the 2804 foot elevation had been broken out for some time and was retained with #8 rebar bolts with resin encapsulation. The broken concrete was encroaching on the clearance to the conveyance."

Jan 1, 2019

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake's McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004

By Horace Freeman

"IN THE writer's opinion, the most important industrial re-search problems in Canada concern development of technology for the treatment and commercial utilization of the recent discoveries of v.ast quantities of easily concentrated iron ores in both eastern and western Canada. They exist in both magnetite and hematite forms. The subject is doubly important because of the lack of metallurgical coking coal in Canada. Methods for utilizing our lower grade eastern and western coals for reduction purposes must be developed. We are fortunate in our supplies of oil and gas, which can supply the heat requirements for processing or for thermal electric plants, which are now competitive with hydro-electric plants in the industrial areas. These are among the reasons which have prompted the writer to continue the development of the co-current rotary kiln direct-reduction process outlined •in his report to this Institute at the 1956 Annual Meeting ( 1) in the face of the scepticism which has surrounded the numerous costly failures in 'sponge' or 'direct' iron production. The work involved in bringing the concentrating ores of Canada to the metallic state involves, firstly, concentration of the ores; secondly, preparing the concentrates for reduction; thirdly, reduction of the 'reconstructed' ore; and finally the steel making process. These briefly will be dealt with in order, giving emphasis to the most important of these steps, the reduction process which is the main subject of this paper."

Jan 1, 1959

By Jacques Ouellet

Outline What is Microwave energy Investigation of transparency of 40 minerals Melting of Andesite in a MW oven Numerical modeling /Computer Simulations o FEM analysis ?? Some laboratory experiments o Particle Modelling Mw Application to Rock Breakage o A MW Rock Drill Prototype Conclusions What is Microwave energy Microwave energy is an electromagnetic wave consisting two electronic & magnetic wave traveling perpendicular to each other and transporting energy with the speed of light.

May 1, 2008

"The Australasian Joint Ore Reserves Committee (JORC), which is sponsored by the Australian mining industry and its professional organisations, developed the JORC Code to provide minimum standards for public reporting. JORC was first published in 1989 and later incorporated into the Listing Rules of the Australian and New Zealand Stock Exchanges making compliance mandatory for listing public companies in Australia and New Zealand."

Jan 1, 2003

By R. L. Every, A. G. Fonseca

"Sulphur deposition on the internal wall of a pipeline is caused by the temperature effect on the solubility of sulphur in the carrier fluid and is not due to particulate sulphur present. Deposition can be completely eliminated by proper insulation of the pipeline to prevent ""cold-spots"" and the resultant temperature gradient necessary for sulphur to precipitate from solution. Friction head losses for sulphur-condensate slurry systems are quite acceptable from a technical and economic standpoint and, in fact, are less than many present commercial slurry systems. Slurry transportation of sulphur in a hydrocarbon pipeline is a viable possibility and promises to have economic advantage over currently accepted transportation modes."

Jan 1, 1972

By M. Kawata, T. Amano, T. Miyamoto, K. Shibayama

"The High Pressure Acid Leach (HPAL) plant of Taganito HPAL Nickel Corporation (THPAL), located in Taganito, Philippines, with a nameplate capacity of 30,000 Ni-t/year started commercial operation on October 2013. The plant load was smoothly ramped up and it achieved monthly production equivalent to 33,000 Ni-t/year in 2016. Partial improvement of the plant capacity for the achievement of 36,000 Ni-t/year, as evaluated from the current operation progress of each system is planned for 2017. In this paper, aside from presenting the progress of the plant ramp-up, research and development activities such as the reduction of nickel loss and the improvement of filtration capacity which was achieved by particle size control of ZnS precipitates in the Zinc Removal system are also discussed.INTRODUCTION Taganito HPAL Plant Project History of THPAL Taganito HPAL Nickel Corporation (THPAL) was incorporated in August 2008, as a joint venture of three (3) companies, namely Mitsui Corporation with 15% share, Nickel Asia Corporation (NAC) with 10% share and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 75%. Aside from its capital share, NAC’s Taganito Mining Corporation (TMC) supplies the ore for the HPAL plant located in Taganito, Claver, Mindanao, Philippines. The objective of THPAL is to produce 30,000 MT of nickel and 2,600 MT of cobalt as mixed (Ni/Co) sulfide by treating nickel laterite ore in the Philippines and exporting to Japan as raw material for SMM’s Niihama Nickel Refinery (NNR) for the next 30 years. In other words, 1.15 wt% of nickel in ore is refined to 99.99 wt% nickel in electrolytic nickel. The mixed (Ni/Co) sulfide is shipped to NNR and SMM provides the technology and management personnel to THPAL plant as well as sulfuric acid which is the main reagent for HPAL process. Figure 1 shows the location of THPAL and current relationship between the stake holders.The Characteristics of THPAL Plant In terms of plant design, a 2-train system is applied for the HPAL circuit considering the reliability of the process, facility and avoidance of whole plant shutdown due to HPAL troubles. The technical data, operation know-how and improvements gained from the successful operation of Coral Bay Nickel Corporation (CBNC) which was established in April 2002 were reflected in THPAL’s plant design. As for the H2S plant, a more economical design was considered which is different from CBNC."

Jan 1, 2017

By T. C. Rao, Deb Kanungo

"The results of tests carried out on a 3-in. hydrocyclone have shown the linear relationships that exist between: (1) the flow-rate of water in the feed to and the overflow product from the cyclone; (2) the flow-rate of solids in the feed to and the underflow product from the cyclone. The underflow size distribution of an operation has been found to be linear and its usefulness in evaluating particle distribution in the cyclone has been discussed. Effects of design and operating variables on the above relationships have been discussed. The performance of this 3-in. hydrocyclone has been compared with that of a 20-in. cyclone, the results for which are available in the literature."

Jan 1, 1973