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By C. Kim

The integration of three-dimensional (3D) data with infrared thermography has received much attention for its potential use as input data for building energy simulations. Therefore, researchers have proposed methods to integrate 3D data with infrared thermography obtained by different sensors. These studies show the potential of the integration of 3D data and infrared thermography using various systems. However, these studies have ignored property aspects of infrared thermography, such as the low resolution of infrared thermography and external environmental influences. Thus, their proposed methods to integrate 3D data and infrared thermography are inadequate because these problems can affect the resulting building energy simulation. This research proposes a framework that integrates infrared thermography and 3D data while accounting for the resolution and shadow effect of infrared thermography. The proposed framework consists of three steps. In the resolution enhancement step, bi-cubic interpolation is proposed. In thermal data correction from the shadow effect, the shadow area is detected from the visible image, and then the shadow effect is removed from the registered infrared thermography. Finally, enhanced infrared thermography is mapped to the 3D data obtained by a laser scanner. The performance of the proposed framework was evaluated using test images obtained from a building in operation. The experimental results show that the proposed framework provides a 3D thermal model that is useful and accurate in simulating building energy. It is expected that the 3D thermal model can be used for accurate energy simulation of existing buildings. In addition, the proposed framework can be applied in defect detection for buildings. Furthermore, this novel approach enhances infrared thermography using visible images.

Aug 1, 2013

By M. P. Sinha, Rashmi, Tata Steel Ltd., S. Jaiswal, A. Bhatnagar, P. Garg

Reagents form a crucial part of flotation process as they have the power to control the surface properties of minerals. In case of coal flotation, collectors and frothers are two the important and commonly used reagents. But other types of reagents such as promoters, modifiers and depressants are also finding wide applications because of their availability to improve selectivity and increase recovery. Because of these chemicals the scenario has changed from flotation being used mostly for high rank hydrophobic coals to low rank, oxidised or inferior coals. In the present work a case is presented in which two non-ionic surfactants (abbreviated as A & B) known to act as emulsifier have been studied to get a better flotation performance for a preparation plant with varying feed characteristics. Laboratory flotation tests were conducted with both the surfactants using three feed samples of the plant by varying the dosage at three different levels. The highest combustible matter recovery (more than 80%) was obtained for surfactant B at a dosage of 75 ppm (parts per million) for feed 1. But at the same dosage the recovery decreased by 21% and 10.2 % respectively for feed 2 and 3. On the other hand surfactant A showed a consistent result for all the three feed samples giving the highest value at a dosage of 50 ppm followed by a decrease beyond this point. The tests were complemented by contact angle measurements that demonstrated the same trend. In addition to this the reproducibility of data for Surfactant A was checked and found that the standard deviations for both separation efficiency and combustible matter recovery were within the permissible range (less than 5%). Finally an in-plant process optimization study to evaluate the performance and applicability of surfactant A at industrial level was done and has been discussed.

Jan 1, 2016

By M. F. Almeida

"Due to the randomness of all factors influencing the sintering operation, a two-stepped procedure is proposed to find the best way of using stocked fines at a plant producing Fe-Mn alloys for the steelmaking industry. The approach is based on the following: (1) predict the result of the sintering operation by establishing the best multilinear regression model using some of the characteristics of the loaded material; and (2) find the best solution under a minimizing cost criteria by solving a linear optimization problem using the regression equation plus constraints on the feed and product. IntroductionSome tests carried out using 20% to 30% of sinter in the material loaded into a 60 000 KVA Tysland-Hole electric furnace producing Fe-Mn alloys for the steelmaking industry indicated: (1) a meaningful decrease in the off-gas temperature and, consequently, a better energy use due to the material higher porosity; (2) more uniform heat distribution as a consequence of the electrode reaction zone enlargement; (3) an improved furnace control resulting in a smoother operation; and (4) a decrease in gas production facilitating the off-gas treatment. For some years, this plant used only the coarse fraction of the Mn ores, thus stocking all the received and own-generated fine particles. In view of the mentioned results, a strategy for increasing the use of stocked fines was formulated, including a step where it was necessary to decide which components and respective quantities should be used in the blends to be sintered (Almeida, 1984).It is well known that several factors affect productivity and energy consumption in sinter production, also influencing the product quality. Raw materials characteristics, namely chemical and size composition, affect permeability to gases and may or may not allow a deeper bed. In general, finer ores decrease permeability, increasing electricity consumption by fans, but due to their higher specific surface area, react more completely with other components in the mixture. For coke granulometry, a compromise must be obtained in order not to burn it too quickly nor to widen the flame front, therefore decreasing productivity. Decreasing coke in the blend also acts in sinter bonding, decreasing its consistency and increasing crushing and return fines. Moisture addition also influences components mixing, pre-agglomeration, bed permeability and, consequently, sintering productivity. Therefore, optimum conditions must be established for both a given sintering plant and the components in the feed (Dawson, 1993)."

Jan 1, 1998

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By F. Grant

"General *The mining experiences of the coal mining industry in Western Canada have been extremely varied, with the mining companies having to adjust their operations or fail due to the harsh economy of the country in the first part of the century. The bituminous or mountain mines had the railways as main consumers with, at times, optimism that potential steel producers would require metallurgical coal. The prairie and foothills mines mainly provided household fuels, with the fine coal sold to local thermal power plants at discounted prices. In practically all cases fuel competition was very keen, and the less successful mines ceased operations in short-time spans. Knowledge of the parameters that governed the success or failures of the past coal operations should be of value to the present and future mining companies. The initial coal mines were small and were started to supply local demand. These mines had little in the way of capital machinery, engineering, or transportation equipment; therefore the mining methods and mine plans were very simple. The first industrial-sized mines imported most of their management and mining methods from other mining areas, mainly Great Britain. It took time to change the bias of management and mining methods to the requirements of strata characteristics, with rapid closure to those mines that were slow to adapt working methods. The main markets for coal were for household fuel, thermal power plants and railways, with very few other industrial markets developed. The economy of the period was harsh and cyclic and the coal mines were affected more than most industries by these boom and bust periods. It led to the survival of the fittest or the most efficient. Due to the economy, mechanization was introduced to the mines very slowly, with the inability to sell coal fines at a profit being another reason for the delay. Manual labour with hand tools was the main means of production. The work was heavy and arduous, and the pay was based on contract coal tonnage; therefore both men and management paid close attention to details so that nonessential work could be eliminated. Mine openings were dimensioned so that coal could be loaded easily by hand and support requirements were kept to the minimum. Transporting and handling the timber supports required heavy labour; thus the most efficient dimensions were chosen to suit the strata. On the other hand, during the main production seasons the mines tried to make the strata stress work for them so that the pressure was kept on the coal face to keep the coal loose while the strata, a short distance back, was induced to cave to minimize the abutment stresses. This caused mining to be an art, using skills developed by experience with the strata. This led to the development of efficient mine layouts with the openings dimensioned to the strength of the strata and the type of support available. The lack of capital and mechanization, and the manual labour, induced the mines to correlate their service and haulage systems with their mining methods. This caused many innovations that proved very practical."

Jan 1, 1985

By J. Oré

An alternative method for dewatering slurry (tailings) is the use of geocontainers (MacTubes). The practical application of this work was carried out in the concentrator plant of the Raura Mining Company, located in the occidental mountain between Huánuco and Lima in Peru?s central highland. For the development of the research, the MATLAB R2012a software MGeST (v. 1.0) was used (Slurry Geocontainer Maccaferri Treatment). MGeST is used for sizing MacTubes, which allows determination of the most important design parameters, such as height (H), filling residual pressure (P1O ), strength of geosynthetic (T), and dehydration height. Compared with GeoCoPS v. 3.0, there is a maximum difference of 3% between the results obtained. The tailing to be treated in the MacTube have a specific weight of 11.62 kN/m3. After several tests it was determined that a MacTube of an apparent opening size of 0.22 mm was required for this specific weight.

Aug 1, 2013

By M. L. Jeremic

The design of the long-hole sublevel mining method was originally based on the traditional assumption that the principal load was due to the weight of the overlying rock, and that the horizontal stresses are equal to one-third of the vertical stress. However, as mining progressed, the virgin lateral stress was found to be equal to or greater than the vertical stress. The virgin stress in the rock mass is not uniform throughout the folded orebody and adjacent strata. From detailed investigations, three basic patterns of virgin stress in ore panels have been inferred: uniform, bent and twisted. Stresses induced by stoping are up to three times greater than original stresses in the rock mass; they cause heavy ground conditions and make extraction of ore difficult. In the last ten years, the original mining system has been modified several times in order to destress the ground and improve the extraction of ore.

Jan 1, 1978

By van der Meer. F. P.

High Pressure Grinding Roll (?HPGR?) technology is applied in a broadening range of minerals processing applications for relatively wet or moist materials. HPGR grinding of dry material or involving drying and air classification is more common, for example in cement manufacturing. A number of minerals processing plants are also operating with dry material, either due to process reasons, such as considerations of preceding or subsequent process stages, or as dictated by local conditions of arid areas and scarcity of water. The present world-wide expectation of decreasing availability of water supply urges us to look for alternatives that minimize water consumption. Recently established and envisaged future HPGR applications with dry ores have indicated that the technology of dry crushing and classification as practiced in cement and limestone grinding can be applied in minerals processing. Moreover, dry technology could very well be applied for generating a final fine product at sizes near or below 100 microns, as may be required for beneficiation by, for instance, flotation, magnetic separation or tank leaching. Dry HPGR grinding requires special attention in maintaining suitable process economics, when considering power input in grinding, drying and classification. In some cases, HPGR capacity and roll surface wear life may be negatively affected by a lack of moisture in the feed. This publication summarizes some of the features of, and experiences in dry HPGR applications. This includes design aspects of the classification system and discussion of the wear protection of the roll surfaces. The paper also includes examples of operational experiences of dry practices in minerals processing and cement plants.

Jan 1, 2012

By C. -G. Berg, J. T. Tuominen

Since the beginning of the 20th century, energy efficiency in copper smelting has been improved by a factor of 30 as a result of adopting autogenous smelting processes with more and more efficient waste heat recovery systems, increasing use of oxygen enrichment and countless smaller improvements. Nevertheless, energy in the form of electricity and fuels continues to be the biggest contributor to smelter operating cost. Metallurgists around the world are under constant pressure to find ways to save those precious megajoules wherever they can. One area that is often neglected is the removal of water contained in concentrates. Copper flotation concentrates, as delivered to a smelter, typically contain some 8–12% moisture. This moisture must be removed and the only way to do this is by evaporation, which consumes a lot of energy. Several studies have shown that the most efficient way of removing this moisture is to use a steam- heated indirect dryer—the least efficient way being the feeding of wet concentrate directly into a smelting furnace. Even in the most efficient smelters that employ modern steam drying, the energy needed to remove the moisture from the concentrates constitutes over 15% of the total energy consumption of a smelter – acid plant complex. The major steps that have been taken in the past to lower the energy consumption of moisture removal are the use of drying in general and the adoption of steam drying. The energy efficiency of concentrate drying has been improved by 25% over the last 20 years. The latest giant leap in this area, the Kumera Heat Recovery Dryer, is the result of Kumera’s long-term development in improving the efficiency of concentrate drying. The Heat Recovery Dryer is a novel application of steam drying that uses the waste heat from dryer exhaust gas for drying concentrates, thus, cutting the energy consumption by a further 30%. This paper discusses energy consumption in copper smelting in general and analyzes the energy consumption of concentrate drying in detail. Different dryer types are compared especially from the perspectives of energy consumption and environmental emissions. Applicability of different energy sources for drying is evaluated and discussed. The principle of the Kumera Heat Recovery Dryer is presented along with results from extensive continuous pilot plant tests. Potential applications and the feasibility of Kumera Heat Recovery Drying technology are discussed.

Jan 1, 2019

By F. E. Lathe

RECENT events have emphasized with renewed force the well known fact that war greatly intensifies the demand for certain metals, particularly for iron, copper, and zinc. Any increase in the use of iron and steel, whether in war or peace, is also accompanied by increased consumption of those metals which find their chief application as ferro-alloys, such as nickel, chromium, manganese, molybdenum, tungsten, and vanadium. Further, since high temperatures are essential for the production of all these metals, activity in the metal industry is inevitably accompanied by an insistent demand for refractories. For example, in North American practice the consumption of magnesitic hearth refractories is frequently expressed in pounds per ton of steel. This quantity (not including straight dolomite) ranges on individual plants from about 7 to 12 pounds. When the industry is operating at approximately full capacity, the ratio of refractory to steel tends to increase, since the tonnage of steel produced is recognized as of paramount importance, and this leads to the harder driving of furnaces and less regard for the effect on refractories. It should also be observed that the cost of refractories per ton of metal produced is always so low, in comparison with other items, that it may even increase while the cost of metal per ton is being reduced through more continuous operation and the use of higher temperatures. As one prominent Canadian copper metallurgist has tersely expressed it, he is "not in business to save refractories but to smelt ore". The effect of war demands and of general industrial activity upon the production of basic and neutral refractories is clearly shown in Figure 1, which gives the value of chrome ore and magnesitic-dolomite produced in Canada during the period 1907 to 1937. Tonnages have not been shown, as these are not available for the full period; such figures as have been published from time to time are not strictly comparable, since both raw rock and finished products have on occasion been included. The preliminary figures for 1938, which are now available, have been prepared by the Dominion Bureau of Statistics on a different basis from those immediately preceding, and have therefore not been shown.

Jan 1, 1940

By F. Ajersch, A. R. Hekmat

Apparent viscosities of hypo-eutectic (Al-7% Al) and hyper-eutectic (Al-35% Si) binary alloys were measured in the semi-solid state using a Couette type viscometer at variable shear rates. Analysis of the microstructural evolution demonstrates the differences in the rate and degree of attrition of the primary phase particles which are characteristic of the thixotropic nature of the semi-solid alloy. It was observed that the Si primary phase in the hyper-eutectic alloy is much more difficult to fragment than the dendritic a-Al phase in the hypo-eutectic alloy. For the case of the a-Al, the dendritic structure is broken down by attrition and fracture of the dendrite arms whereas the fracture of the Si hexagonal crystals in the hypereutectic alloy occurs along the {100} and {110} cleavage planes. Results are presented for fixed solid fractions of the primary phase at isotherm condition for each type of alloy.

Jan 1, 2006

By A. C. Headon, K. W. Lam, D. P. Dautovich

"Microbiological activities affecting the performance of materials have been encountered in diverse situations within Ontario Hydro. Case histories of bacterial problems which are presented include ground rod corrosion at transformer stations, corrosion of a bare steel cooling water intake structure in Lake Huron and corrosion of steel components in a nuclear generation station vacuum building. Possible microbiological activities which may affect the corrosion behaviour of containers for the disposal of nuclear fuel waste in the future are discussed, as are bacterial actions suspected of causing an odour problem in residential water heaters.IntroductionBacteria are ubiquitous. Except by use of sterilization methods, bacteria -free environments are no t possible to find. Bacteria lie dormant in hostile environments, spread easily through air and water currents and reproduce rapidly under favourable conditions. Although different types of bacteria have different preferable conditions for growth, they are highly adaptive and in general, whenever there is a source of water and carbon (carbon dioxide or organic matter), there will be bacterial activities . These activities often induce or enhance costly metallic corrosion in industries and water odour problems in rural water supplies . Underground structures and systems in contact with natural water or water containing organic matter are most susceptible to bacterial attack.The types of metal-degrading bacteria , their characteristics and the conditions for growth have been reviewed extensively in the literature(1,2,3). There are several often encountered groups of bacteria which, through their metabolic processes, may lead to the degradation of metals. A large variety of bacteria produce corrosive in organic or organic acids as waste, such as the well known formation of sulphuric ac id by aerobic sulphur oxidizers . Anaerobic sulphate reducers produce hydrogen sulphide which is corrosive and has an obnoxious smell, slime-forming bacteria from slime which shelters sulphate reducers and iron bacteria oxidize ferrous to ferric ion which precipitates as hydrated oxides creating oxygen concentration cells . The following are bacterial problems encountered in Ontario Hydro. Although the number of recognized cases has been few, they show the diversity of location and environment where bacterial problems could arise. These include ground rod corrosion at transformer stations, corrosion of bare steel in a water intake structure, corrosion of steel in a nuclear generation station vacuum building and an odour problem in residential hot water tanks. In addition, possible bacterial- enhanced corrosion in containers for future disposal of nuclear fuel wastes are also discussed."

Jan 1, 1984

By L. T. Loe, A. S. Norsk, Mo i. Rana

High production rate and good stability demand the optimization of all phases of electric pig iron smelting. This is important with respect to slag chemistry, which to a large extent regulates the process temperature in electric smelting. Controlled basicity and slag volume. and a satisfactory screen analysis of the reduction material and sinter, are of the utmost importance for smooth furnace operation. Large variations in slag volume and in B/ A and C/Fe ratio will have an influence on the furnace resistance and thus the specific energy development in the furnace, which lead to variable reduction of SiO.. The result will be variable hot -metal quality and un-stable furnace operation.

Jan 1, 1970

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

This work illustrates the potential of two welding processes for joining AA1100-16 vol.% B4C metal matrix composite: laser welding process using a 4 kW Nd:YAG laser and Friction Stir Welding. A comparison is made between these two welding techniques in terms of microstructure and mechanical properties of welded joints. A large amount of brittle needle-like phases, together with some residues of B4C particles were observed in the fusion zone of laser welded joints. The use of Ti filler can improve the microstructure and increase the joint efficiency from 63% to 75%. On the other hand, the friction stir welding process being a solid state welding technique is interesting as it avoids the formation of brittle intermetallic phases. In addition, the breakage of B4C particles and the grain refinement of the matrix were observed in the weld zone. Consequently, FSW joints show much better mechanical properties than laser welded joints. Up to 100% joint efficiency can be achieved by FSW for annealed AA1100-16 vol.% B4C materials.

Jan 1, 2011

By H. H. Bleakney

The merit of reduction-in-area as a criterion of quality in metals is shown to lie in its influence on breaking stress, but the virtue of elongation is not easy to find. In order to assess the value of elongation, either as a measure of quality or as a guide to design, it will be necessary to separate the overall de-formation occurring in tension tests from the localized deformation associated with localized reduction in area. The obstacles to a successful solution of this problem have been shown to be more formidable than is generally appreciated, and a new solution to the problem has been suggested. This solution involves a de-vice by which an electric circuit is broken when the particular value of strain is reached that is to be taken as the point of separation between general and localized deformation. The report presents results from a number of tests on both low-carbon and alloy steels. These results indicate that the selected criterion of separation is accurately identified by the proposed method; that it

Jan 1, 1962

By Carl Lausen

Within recent years several mining companies have sent expeditions co the east end of Great Slave lake co determine the mineral possibilities of that area. Little was known of the geography of the region, and even less of the geology; and, not until Blancher's survey was made and the results published, was an accurate map of the lake available. Early explorers followed the Inconnu channel and the north shore of McLeod bay to Port Reliance, and, just prior to Blancher's survey, Hornby showed that the southern passage was feasible. Apparently, but few geologists have ? travelled through the country, for geological information is meager. In 1900, Robert Bell, of the Geological Survey, made a trip to Fort Reliance by way of the north shore of McLeod bay, and he gives a brief description of the geology. The present paper is the result of an expedition into this little-known region by Mr. Geo. M. Douglas and the writer in the summer of 1928. The south shore of Great Slave lake was followed to the east end of Tochatwi bay, and an extensive exploration was made of Kahochella and Pethei peninsulas. The prime object of the expedition was co determine the presence or absence of the copper-bearing Keweenawan basalts.

Jan 1, 1929

By H. McLeod

Introduction In the period from 1939 to the present, Canada has experienced a remarkable industrial expansion, rising to probably seventh in rank amongst world countries. In the early part of this period, the desperate need for military supplies unloosed tremendous amounts of capital for building new factories and for expanding and converting existing facilities. Mines, factories, and other divisions of the industrial economy bent every energy toward greater and greater output. The result was an 80 per cent increase in the volume of the nation's production within a period of four years, a truly remarkable accomplishment and one in which the mining industry had a very vital part. After the critical year, 1944, the tempo of industry eased off a bit, dropping approximately 20 per cent by 1946. At this time the prospects or post-war industry were clouded by monetary and political chaos in overseas countries, by trade restrictions, and by market uncertainties. There was, of course, a pent-up demand, both at home and abroad, for civilian goods that had been curtailed during the war and for capital equipment that had been destroyed. In the midst of this world-wide uncertainty, if anyone had ventured to predict that by the end of 1950 Canada's industrial output would be back to the 1944 level and humming along at nearly twice the best pre-war pace, he would have been considered rash indeed. Yet this has been the case.

Jan 1, 1951

By C. J. R. Braithwaite, Giancarlo Rizzi

"The Navan zinc-lead ore deposit (70 million tonnes) is hosted principally (97%) by the Meath Formation (Lower Carboniferous, Courceyan, Navan Group), comprising a lower, mainly carbonate mudstone unit, the Stackallan Member, and an upper grainstone-dominated unit. TheStackallan Member, about 60 m thick, comprises about 35 peritidal cycles including an oolitic grain-stone interval. Grainstones forming the upper part of the formation, about 150 m thick, comprise at least six shallowing-upward ramp cycles. Emergence horizons are indicated by subaerial dissolution surfaces, in situ breccias, and a single palaeosol.Most dolomitization at Navan is con?ned to the Meath Formation. The linear dolomite body,trending NE-SW, has a ?attened, laterally limited, tabular geometry in cross-section, suggesting that dolomitizing ?uids initially rose vertically, cross-cutting stratigraphic and sedimentological bound-aries, although ?uid ?ow was subsequently controlled by these features.Three stages of dolomitization are indicated by textural relationships, cathodoluminescence (CL),oxygen isotopes, and ?uid inclusion data. Stage 1 crystals, with generally dully luminescing cores and up to six overlying subsidiary zones, are the main replacive phase. Crystal surfaces are commonly corroded and overlain by bright stage 2 rhombs (which also form new nuclei lining molds and fractures). Three subsets of zones are present in stage 2 crystals: bright, non-luminescent, and dull; these are locally separated by additional corrosion surfaces. Stage 3 comprises relatively large baroque crystals, generally dully luminescent but with up to seven sub-zones. Isotopic and ?uid inclusion data suggest growth of successive stages from waters which became progressively hotter(60°–160°C).The distribution of the ores follows the dolomite trend. Ores were precipitated between Stages1 and 2 of dolomite growth, following Stage 2, and also during the nucleation and growth of Stage3 crystals. Dolomitization and mineralization appear to have been temporally and genetically related. The cyclic sedimentation of the host rocks, which accentuates lithological and petrographical contrasts between depositional units, controlled dolomitization. The relationship between dolomitization and mineralization, which is closely associated with faults, provides powerful exploration criteria. The recognition of these features in limestones elsewhere in the Irish ore ?eld may point toward unrecognized zinc-lead prospects."

Jan 1, 1997

By C. J. R. Braithwaite, Giancarlo Rizzi

"Abstract-The Navan zinc-lead ore deposit (70 million tonnes) is hosted principally (97%) by the Meath Formation (Lower Carboniferous, Courceyan, Navan Group), comprising a lower, mainly carbonate mudstone unit, the Stackallan Member, and an upper grainstone-dominated unit. The Stackallan Member, about 60 m thick, comprises about 35 peritidal cycles including an oolitic grainstone interval. Grainstones forming the upper part of the formation, about 150 m thick, comprise at least six shallowing-upward ramp cycles. Emergence horizons are indicated by subaerial dissolution surfaces, in situ breccias, and a single palaeosol.Most dolomitization at Navan is confined to the Meath Formation. The linear dolomite body, trending NE-SW, has a flattened, laterally limited, tabular geometry in cross-section, suggesting that dolomitizing fluids initially rose vertically, cross-cutting stratigraphic and sedimentological boundaries, although fluid flow was subsequently controlled by these features. Three stages of dolomitization are indicated by textural relationships, cathodoluminescence (CL), oxygen isotopes, and fluid inclusion data. Stage 1 crystals, with generally dully luminescing cores and up to six overlying subsidiary zones, are the main replacive phase. Crystal surfaces are commonly corroded and overlain by bright stage 2 rhombs (which also form new nuclei lining molds and fractures). Three subsets of zones are present in stage 2 crystals: bright, non-luminescent, and dull; these are locally separated by additional corrosion surfaces. Stage 3 comprises relatively large baroque crystals, generally dully luminescent but with up to seven sub-zones. Isotopic and fluid inclusion data suggest growth of successive stages from waters which became progressively hotter (60°-160°C).The distribution of the ores follows the dolomite trend. Ores were precipitated between Stages 1 and 2 of dolomite growth, following Stage 2, and also during the nucleation and growth of Stage 3 crystals. Dolomitization and mineralization appear to have been temporally and genetically related. The cyclic sedimentation of the host rocks, which accentuates lithological and petrographical contrasts between depositional units, controlled dolomitization. The relationship between dolomitization and mineralization, which is closely associated with faults, provides powerful exploration criteria. The recognition of these features in limestones elsewhere in the Irish ore field may point toward unrecognized zinc-lead prospects."

Jan 1, 1997