Search Documents

Christmas Island "C"-grade phosphate consists essentially of the minerals crandallite and millisite. Although containing over 25% P205, this material is not suitable for the manufacture of water-soluble phosphate fertilizers by conventional processes, because of its high iron and aluminium content Cover 25% total R203). In order to produce a water-soluble fertilizer from such material it is necessary to separate the iron and aluminium from the phosphate, which must report in a product acceptable as a fertilizer. Several processes were studied in detail. The first used ion exchange for dissolution and separation and yielded diammonium phosphate; processing costs were high compared with conven- tional processes based on apatite. The latter processes have basically simple flowsheets and cost of processing is low when compared with the costs of the raw materials. The need to separate iron and aluminium from the phosphate introduces additional complexity into the treatment of the C-grade material. The higher processing costs might be justified, however, if alumina could be produced as a byproduct. Two proposed processes have been developed in which: 1. hydrochloric acid is used for dissolution, and solvent extrac- tion for the separation of ferric chloride from phosphoric acid. Aluminium chloride is precipitated and hydrolysed to recover alumina and hydrochloric acid. 2. sulphuric acid is used for dissolution and aluminium is crystallized as ammonium alum. The phosphate is produced as an ammonium phosphate-sulphate fertilizer. High purity alumina can be obtained by treatment of the recrystallized alum. The technology of these processes is described, and their broad economics discussed briefly.\

Jan 1, 1971

In the course of an investigation of the influence of bismuth on copper carried out some years ago, (1) the author found that phosphorus exerted a beneficial effect on bismuth-copper alloys of low bismuth and oxygen content by neutralizing the embrittling effect of the bismuth. In the intervening years, a further examination of bismuth-phosphorus-copper alloys has been canied out and the influence of other elements and combinations of elements on copper containing bismuth has been studied.The results recorded in the present paper are part of this investigation.MATERIALSAll the alloys were made from high-grade copper (KS.A. wire-bar) of the following composition: copper 99·95%, oxygen 0,040'%, iron 0·0015%, sulphur less than 0-001%, bismuth less than (j>'OOl%, other elements each less than O· 0010/<-. The bar was hot rolled and cold drawn to strip which was cut into short lengths and cleaned in nitric acid ready for melting.A piece of this 'strip was drawn to wire 0·08 in. diam., annealed at 5000 C, and measured for electrical conductivity as a check on purity. The result was 101·5% of the I.E'.C. standard.In making the alloys, phosphorus was added as 14% phosphor-copper, bismuth as 17% bismuth-copper, and the other constituents either as copper alloys or as elements of a high degree of purity.PREPARATIQN OF STRIPSThe charges were melted in plumbago crucibles (Morgan salamander brand) in an oil-fired furnace, Le;, in the manner commonly adopted in industrial practice. The copper was first melted under charcoal, well stirred with a chaned stick, and the necessary alloying elements added and stirred in with the stick. The weight of a charge varied according to requirements but generally was about 4 lb. The charges were poured into slightly tapered brass moulds heated to about 1000 C and dressed with a mixture of mineral oil and tallow. They were not only poured under charcoal through the burning mould dressing but also- through a ring of flame produced by burning kerosene on asbestos cord wrapped round the top of the mould. Experiments carried out with plain copper proved that by this means oxygen could be excluded from the stream of metal. The billets were 7·5 in. long x O·83 in. diam. x 1·3 lb. weight.The billets were cropped about 1 in. from the top, cleaned in nitric acid, and measured for density by the usual method of weighing in air and -in water. As these measurements were required only as a check on casting, technique a high degree of accuracy was not essential (accuracy = -+ 0·2%).

Jan 1, 1942

The metallogenic belts of the Central Andes (iron, porphyry copper, polymetallic and tin) are genetically related to an eastward migrating magmatic arc. The polymetallic belt of the Bolivian Altiplano formed during Miocene arc broadening and lies in a critical position for understanding the genesis of this zonation. It is penecontemporaneous with parts of the copper and tin belts, and shares many characteristics with them. The differences between the belts result from contrasting volcanic and feeder stock geometry, depth of erosion and country rocks, and are not due to variations in magma chemistry, age or Benioff Zone depth. Polymetallic mineralisation in the Altiplano is epithermal in style and mostly related to flow-dome volcanism. The intermontane basinal setting precludes deep erosion to expose the epizonal feeder stocks and predicted porphyry copper mineralisation. In contrast, erosion of the less abundant stratovolcanoes of the Altiplano-Puna and Pampean Massif may expose contemporaneous Miocene porphyry copper mineralisation in subvolcanic stocks. The tin belt is coincident with the Paleozoic fold belt of the Eastern Cordillera. The occurrence of minor tin in Altiplano epithermal deposits hosted by Paleozoic sediments, and the persistence of tin mineralisation in the tin belt over 350Ma, suggests that Paleozoic sediments are the source of the tin.

Jan 1, 1987

By G, F Beach, D Jazzini, R Rounsley

Over the past 20 years within Australia, there have been a number of incidents at mine sites where ammonium nitrate-based explosives have reacted with certain rock types containing sulfide minerals. These rocks have commonly been referred to as æreactive groundÆ. These reactions have frequently led to fires (particularly in ground susceptible to spontaneous combustion) or premature detonation of the ammonium nitrate-based explosives. Clearly, this introduces an element of risk when using ammonium nitrate-based explosives in these areas. Dyno Nobel has been proactive in developing ammonium nitrate-based explosive products that can be used in these types of æreactive groundÆ environments that minimise the risk of premature detonations occurring. A system for assessing æreactivityÆ of sulfide containing rocks has been developed that can be used in the field. Previous literature has been reviewed, identifying Differential Thermal Analysis (DTA) as the most common method for determining the æreactivityÆ of the ground. In the present investigation, DTA has been rejected as a suitable technique for determining ground reactivity, since it measures thermal reactions at higher temperatures over short time periods, conditions that are unlike those in the field. For example, ground at ambient temperature has been found to react with ammonium nitrate-based explosives over long time periods, reactions that are unable to be evaluated using DTA. Other more suitable techniques have been developed to monitor rock conditions that can be measured in the field and give a good indication of potential ground æreactivityÆ with ammonium nitrate-based explosives. Dyno Nobel is currently investigating the reaction mechanisms of spontaneous combustion in reactive ground, the decomposition mechanisms of ammonium nitrate and the role of inhibitors in ammonium nitrate-based explosives. Once complete, this fundamental research will lead to the further development of even lower risk ammonium nitrate-based explosive products for use in æreactive groundsÆ in a variety of mine environments.

Jan 1, 2003

By M E. Pierce

Recent advances in comminution and heap leach technology have resulted in the development of many large-scale, low-grade open pit mines that coincide with areas of historical underground workings. Twoand three-dimensional numerical modelling has been conducted to assess the interaction between open pit slope stability and remnant underground voids. Most design analyses for open pit slopes assume a two-dimensional problem geometry. This is not the condition encountered in practice ù particularly when remnant underground voids interact with a large-scale open pit slope. Three-dimensional numerical models have been shown to provide a more realistic representation of the interaction between overall open pit slope stability and remnant underground voids.

Jan 1, 2003

By W L. Lane, T R. Yanske

The Doe Run Company and its predecessors have been mining for over 130 years utilising the room and pillar mining method. This method has left approximately 20 per cent of the orebody in the remaining pillars. The original design and planning for the mines did not include extensive pillar extraction. This paper summarises the introduction of the pillar extraction and backfill techniques which have been implemented since 1991. These techniques include the use of low cost fill walls up to 20 m in height and the use of slinger trucks for topping off the fill. In conjunction with these accomplishments, much experience and confidence has been gained in the use of numerical modelling as a method of predicting pillar stability as the mining of pillars progresses. These advances have led to pillar extraction becoming a major portion of the overall production and have added to the mine life of Doe RunÆs six operating mines.

Jan 1, 1998

The AJ Parker Cooperative Research Centre for Hydrometallurgy is the focus of a world-class effort in providing technical solutions to the minerals industry. The 85 FTE staff are drawn from the CentreÆs five joint venture research partners comprising universities (Curtin, Murdoch and Qld) and government research agencies (CSIRO and WA Dept of Industry and Resources). There are also 12 industry partners, representing most of the leading mining companies in the world. Around 45 postgraduate students, mainly PhDs, make a significant contribution to the research effort. Total annual expenditure on R&D is around $17 million.Hydrometallurgy activities encompass both fundamental and applied research across the alumina, gold and base metal sectors. The Centre is now growing its client base into overseas markets, particularly North America, South Africa and Europe. Quality, strategic R&D by the Parker Centre is seen by the industry as an attractive investment. A recent survey of the industry revealed an estimated ten-fold return based on direct costs of research to the client. In addition, the Parker Centre has a strong commitment to education of postgraduate students wishing to enter the mining industry as well as providing specialist courses for those technical professionals already employed in the industry. The wide range of employment opportunities in the mining industry is reflected in the diversity of the disciplines amongst the CentreÆs research team, eg extractive metallurgy, chemistry, biotechnology, physics, engineering, molecular modelling, microscopy, geology and computational fluid dynamics. How does an atomic force microscope and molecular modelling improve our ability to control gypsum scaling or understand crystallisation of alumina in a Bayer plant? Can a biologist contribute to the problem of the slow leaching of copper from chalcopyrite? Why are computational fluid dynamics and lasers the basis of understanding how to make thickeners work more efficiently. Can you combine a PhD or Honours degree with industry experience? What is crud and why is nickel stressed? These are typical examples of the CentreÆs research activities and demonstrate the contributions of its multi-disciplinary teams which keep the Australian mining industry at the cutting edge of advanced global technology.

Jan 1, 2003

By Zamel GI

The utilisation of fossil fuels, including coal (of which Australia is a large producer and exporter) is a significant contributor to the emission of greenhouse gases. Methane gas, formed during the coalification process, is present in coal seams to varying levels depending on the rank and depth of the deposit. This gas usually escapes to the atmosphere during mining operations without prior conversion to C02 or utilisation as fuel. The quantity of methane released can represent from less than one percent to more than five percent of the carbon content of the coal mined. Per unit of carbon, methane has a greenhouse impact many times that of C02. The emission of uncombusted methane to the atmosphere can therefore represent a greenhouse impact of similar porportions to that of the CO2 formed by combusting the mined coal. However, greenhouse emissions from coal can be minimised by collecting the coal seam methane and converting it to water vapour and the less damaging form, CO2. If such conversion is carried out while performing useful work, the methane can further reduce greenhouse emissions by displacing other fossil fuels. Technology has been developed to allow coal seam methane gas to be economically collected in a pure form, uncontaminated with air. This pure methane can be used to supplement natural gas supplies, to generate power or for the production of chemicals or substitute transport fuels. By collecting and utilising coal seam methane, the greenhouse impact from the mining and use of coal can be minimised, with significant reductions possible in the case of gassy deposits.

Jan 1, 1989

The Fiji islands are the world's most ac- cessible Cenozoic remnant arc. They provide occasional subaerial exposures of an arc frag- ment some 750 km long and 80 km wide, or about the size of the NE Japan volcanic arc. The fragment is one part of the former Vitiaz Arc which once connected Fiji to Vanuatu and Tonga. The Fijian portion has the most completely stu- died Tertiary section which contains a history of arc volcanism from the late Eocene to late Miocene (the Early and Mature Arc stages), a rich diversity of subsequent magmatic responses to the most recent episode of arc rifting (Ear- ly Rifting stage), and an example of transition from arc to intraplate volcanism as this rift- ing proceeded (Late Rifting stage). The arc fragment is surrounded by younger backarc ba- sins. The chemical composition of magmas in both the arc and backarc changed with time, but in opposite directions. In the arc, magmas be- came enriched in sialic components from the Early Arc to Early Rifting stages, whereas in the basins the magmas became more similar to mid-ocean ridge basalts (MORBs) with time. In southwest Fiji, the oldest backarc basin has subducted obliquely beneath the remnant arc du- ring the last 3 Ma, resulting in chemically ex- otic calcalkaline volcanism. During the last decade over 150 radiome- tric age measurements and 650 rock analyses, many with trace element and isotopic measure- ments, have been obtained for samples from Fi- ji, Tonga, and the surrounding seafloor (Figs. 1 and 2). These data are summarized, drawing from the publications of Colley and Hindle (1984), Gill et al. (1984), Hawkins and Melchi- or (1985), Kroencke (1984), Malahoff et al. (1984), Scholl et al. (1985) and Whelan et al. (1985), from the specific research papers refe- renced therein, and from the half dozen or so manuscripts currently in preparation by these people and others.

Jan 1, 1987

By M Roper, M Lovitt

WMC Resources Olympic Dam Operation located in South Australia, is a poly metallic underground sublevel open stoping (SLOS) mining operation with a current annual production rate in excess of 9.0 Mt. Stope size, geometries, geotechnical considerations, drilling and blasting are critical components in stope performance. These factors are further influenced by stringent ventilation requirements due to the presence of airborne radioactive contaminants from uranium mineralisation. Stope planning is complex and mass blasting methodologies have been trialled at Olympic Dam with the view to reducing the frequency of stope blasts, improving stope stability, productivity and ultimately improving overall stope performance. A key aspect in the ability to undertake underground mass blasts of this scale is the application of i-konTM electronic initiation technology by Orica. In the past two years in excess of three million tonnes has been initiated utilising this electronic technology, with an average blast of 250 000 t ranging to the largest to date being 580 000 t. By providing flexibility in blast designs, the use of electronic detonators has allowed mass firings over multiple sublevels. This has resulted in a significant reduction in stope extraction steps compared to conventional pyrotechnic firings. The benefits of this reduction in the number of stope blasts are wide ranging from improved stability of interim stope voids between blasts, reduced blasthole damage, improved blast vibration management and reduction of complex changes to ventilation systems for blasting.

Jan 1, 2004

The Transportable Moisture Limits, as ,measured by the procedures laid down in The IMCO Code of Safe Practices for Bulk Cargoes, determine the target moisture contents for the concentrates produced at the West Coast Mines of Electrolytic Zinc Company of Australasia Limited at Rosebery. Filtration of these concentrates gives moisture contents considered to be low in comparison with those achieved for similar sulphide concentrates, but which are very close to these Transportable Moisture Limits. The filtering techniques used are outlined and the problems associated with-maintaining concentrate moistures below the required limits, together with the methods used to solve these problems are discussed.

Jan 1, 1978

The exploration and mining risks are investigated and compared to the risks of smelting, secondary processing and other normal industrial activities. This study concentrates on the risk before, or at the investment decision. Internal and external risks are distinguished. Internal risks are the risks inherent in every engineering design and common to all projects. The main external risks are the financial risk, changes in prices, location problems and geological factors. Financial risks concern every capital-intensive and export-oriented project and cannot be considered as typical mining risks. Changes in prices, i.e. the market risk, concern every industry using raw materials, but the market risk is especially accentuated in the mining industry. Problems of location and infrastructure are normally more significant in mining than in other projects, and geological risks are unique to mining. All these risks associated with mining projects combine to form a risk at least twice as high as that for other normal industrial activities. Within the range of profitability of mines, which on average is the same as in the manufacturing industry, only a few highly profitable mines exist. These few mines are the sole reward for the high risks taken.

Jan 1, 1986

By P T. Hick, T J. Cudahy, M S. Caccetta

Dust derived from mining and handling of ore has been identified as a major concern for the mining industry in Australia and may be critical to the future viability of some resource industries (CSIRO, 1999). Operational techniques to derive accurate measurements of anthropogenic dust on vegetation and infrastructure are necessary for the long-term management and monitoring of the environment surrounding mining operations. Airborne hyperspectral VNIR-SWIR systems can potentially provide these monitoring data. This paper outlines a method developed for deriving quantitative measurements of dust quantity on mangroves using remotely-sensed airborne hyperspectral data. The results show that it is possible to detect and quantitatively map iron oxide dust distribution using properly calibrated airborne visible to short wave infrared (VNIR-SWIR) data.

Jan 1, 2002

The development of the SECV brown coal open cut at Loy Yang will require depressurisation of aquifers both within and below the coal seam sequence in order to maintain open cut stability. Prediction of future open cut dewatering requirements at Loy Yang Open Cut and evaluation of the regional consequences of dewatering has required development of a detailed hydrogeological model of the Loy Yang area. The complex stratigraphy of the coal seam and aquifer/aquitard sequences at Loy Yang have been analysed and integrated with the hydrogeological concepts developed from regional groundwater studies to formulate a realistic hydrogeological model as a basis for finite-element flow modelling.

Jan 1, 1988

By Hutton A. C

Quantitative X-ray diffraction (XRD) analyses using the Rietveld method, a standardless technique for full XRD pattern fitting, showed the mineralogy of the eastern Queensland Tertiary lacustrine oil shale deposits is dominated by detrital cla

Jan 1, 1994

By Biao Q, Mizuta Y

Thermal constants such as thermal con- ductivity and thermal diffusivity of rock and coefficient of heat transfer of airway wall are the most important characteristic values which decide accuracy of prediction calcula- tion. However, quality of rock is not homoge- neous and water content in rock varies with location and so, a method for in-situ measure- ment of thermal constants must be taken in. The method developed by us is to measure in- situ rock temperatures at two different depths from airway wall. It is simple and we found its accuracy is good enough in the engineering Sense.

Jan 1, 1988

The Government Mining Engineer of South Africa has decided to legislate that Self Contained Self Rescuers (S.C.S.R.) become a mandatory piece of equipment for all those persons proceeding underground. It is envisaged that: * employees in underground coal mines will be fully equipped with S.C.S.R.s during 1988; * those persons employed in gold mines during 1988/89; and * personnel in all other mines by the end of 1990. It is the intention of this paper to discuss the introduction of these auxiliary life support systems, and to give an update on current market developments.

Jan 1, 1988

By Bronson B

The geotechnical and environmental aspects of heap leaching are very closely tied during design, operations and closure. Potential environmental impacts from heap leaching are mostly due to land disturbance and water quality issues, including both groundwater and surface water. Water quality issues are mostly related to containment design, which is primarily a function of proper sizing of the facilities and site specific liner design. Geotechnical analyses is the dominant discipline in providing cost efficient, operationally effective and environmentally sound heap leach facility designs. Much has been published on geotechnical aspects of heap leach design, for example Van Zyl, Hutchison and Kiel (1988) and Van Zyl (1987). This paper will emphasize a few specific aspects related to the geotechnical and environmental consideration for heap leach projects. These aspects are: ò site investigation; ò containment design; ò slope stability; ò heap flow dynamics; and ò closure design. Design of a heap leach project must consider not only the operating life but also closure and post-closure considerations. As a matter of standard practice, designing for closure is an extremely important concept. Not only is it important for environmental aspects, but experience also shows that projects designed for closure will be overall more economical for the total life cycle of the project. Closure considerations are also important during project feasibility evaluations to ensure that total life cycle costs are evaluated.

Jan 1, 1994

By Anderson J. M, Gillies A. D S, Jones N

There are a number of current theories in relation to methane migration and emission into workings following underground coal mining activity and some controversies do exist. Mining causes changes in the stress regimes in surrounding strata and results in fracturing. Permeability increases and methane flows into workings under a pressure gradient. The effects of stress on permeability depend on the physical properties of the coal and surrounding strata. Methane emission also depends on the original methane content and the proportion which will be liberated. There are several methods for determining in situ methane content and desorption characteristics of coal samples and several methane prediction methods but clearly more research is necessary to achieve an adequate predictive model.

Jan 1, 1992

The Department of Resource Industries regulates and oversees safety and environmental standards for the mining and related industries in Queensland, and provides scientific support through its effort in the geosciences.The geoscientific data base accumulated over more than 120 years is very large. Therefore, accessibility to and utilisation of the data base in the most effective manner is an issue to be addressed in terms of modern information technology. The Department has developed a strategy whose implementation is progressing rapidly.

Jan 1, 1990