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By Alden Greninger

TWINNED metal crystals are usually designated as either deformation twins or annealing twins. If twins are to be classified according to the treatment the metal has undergone just prior to the obser vation of the twins, there are two other possible groups: (1) solidification twins,? when observed in the as-solidified or as-cast condition, and (2) transformation twins, ? when observed in a metal which has been cooled from above an allotropic transformation temperature. McKeehan has demonstrated that ferrite does, occasionally at least, contain twinned structures2. The twins, which he studied by optical methods, were obtained during the preparation of iron single crystals by very slow cooling through A3. He proved that the twin relation was actually that which previous investigators had predicted; namely, twinning along three planes of the form {112}. Since McKeehan's discovery, little or no attention has-been given to this transformation twinning of alpha iron, or to the possibility that it might occur at all speeds of cooling from above A3 instead of merely during the prepara-tion of single crystals. McKeehan's twins were evidently regarded as interesting only in proving that a body-centered cubic metal could form twinned structures-at least under certain conditions. It is generally believed that iron seldom if ever forms annealing twins. Certainly the straight-line banding which is so abundant in annealed face-centered cubic metals is characteristically absent in iron annealed below A3. However, O'Neill3. has studied "twin-like" crystals in annealed alpha iron and concludes that the specimen he studied actually

Jan 1, 1936

By Tony B. Szwilski

A short study has been made of the underground mining potential in the Plains region, the Province of Alberta, Canada. Particular reference is made to the possible application of longwall mining: Presently underground mining is limited to small scale room-and- pillar methods. The problems anticipated with large scale mining at shallow depths (30 m) are examined. Production factors based upon longwall retreat mining utilizing shield supports are also considered.

Jan 1, 1981

By S. G. Valentine

Blast-furnace blowing engines are broadly of two main types: either steam - or gas-driven reciprocating engines, or turbine-driven rotary engines.

Jan 1, 1915

By H. Conrad, K. Janowski, G. Stone

The available data on the dynamics of plastic flow of sapphire indicate that the deformation rate in the temperature range .from 900° to 1700°C can be expressed either as A number of investigators1-10 have established that sapphire deforms plastically above 900°C, the most common mode of deformation being slip on the basal plane in the [1120] direction. Under certain conditions and at temperatures above 1500°C, slip

Jan 1, 1965

By K. Osseo-Asare

LIX63 In combination with DNNS selectively extracts nickel and/or cobalt from acidic leach liquors with pH values as low as 10 Nickel/cobalt and cobalt/nickel selectivities are achieved by varying the relative concentrations of LIX 63 and DNNS Increasing LIX63 concentration retards both extraction and stripping rates while DNNS has the opposite effect. Slope analyses of equilibrium data Indicate that both LIX63 and DNNS are present in the extracted complexes. Examples of possible flowsheets are presented.

Jan 1, 1981

By B. M. Larsen

In endeavoring to put the art of the steelmaker on a more scientific basis, as a means of securing closer control of the product, we must be severely critical of the basis of any theory we use. In particular, we must be careful to distinguish between factors that are primary and those of only secondary impartance. The concentration relations that determine the slag-metal equilibria, which are usually more or less closely attained, are of course of primary significance, but a, dear picture of the whole process requires that the actual rates of the several reactions be taken properly into account. At the high temperature of the steelmaking furnace, all reactions might be thought to be very rapid, but some of them in fact are not; the essential causes of this condition are important to a proper understanding of the process. This paper aims to present, and to justify, the viewpoint that the most significant reaction is the oxidation of carhon in the metal, the progress of which determines the oxygen pressure levels in slag and metal and produces stirring effects, all of which influence the course of the process as a whole. Reaction Rates at Steelmaking Temperatures General experience in reaction rates makes it almost certain that at steelmaking temperatures equilibrium is attained practically instantaneously when the reactants are well distributed in a single liquid phase —that is, in the so-called homogeneous reactions. The actual slowness of some of the reactions in the open-hearth furnace must therefore be attributed to a relatively slow rate of diffusion within the slag or metal phase, which limits the rate at which the reactants can meet each other in the liquid steel or at its surface. That the reactions can be made to go with great rapidity, by proper mixing and stirring of the reacting phases, is indicated by the following illustrations: 1. In the Bessemer process there is intimate contact between air and the whole mass of metal, and the reactions are complete in a few minutes. 2. Perrinl has demonstrated that by pouring liquid steel into slag contained in a deep ladle, and thereby producing almost a slag-metal emulsion, the phosphorus or oxygen content of the steel is adjustcd immediately. 3. Barret, Holbrook and Wood2 observed a quite rapid rate of desulphurization when powdered calcium carbide was stirred vigorously into liquid iron. 4. When a spoonful of liquid steel is poured into a. mold containing aluminum wire, the formation and precipitation of alumina occurs in the fraction of a second required to freeze the surface layer of the tiny ingot. The first three examples all show that any means of increasing the effective surface between slag and metal and promoting intimate mixture of the reacting phases, thereby obviating the limitation imposed by diffusion, will enhance the speed of the steelmaking process.

Jan 1, 1941

By B. M. Larsen

In endeavoring to put the art of the steelmaker on a more scientific basis, as a means of securing closer control of the product, we must be severely critical of the basis of any theory we use. In particular, we must be careful to distinguish between factors that are primary and those of only secondary impartance. The concentration relations that determine the slag-metal equilibria, which are usually more or less closely attained, are of course of primary significance, but a, dear picture of the whole process requires that the actual rates of the several reactions be taken properly into account. At the high temperature of the steelmaking furnace, all reactions might be thought to be very rapid, but some of them in fact are not; the essential causes of this condition are important to a proper understanding of the process. This paper aims to present, and to justify, the viewpoint that the most significant reaction is the oxidation of carhon in the metal, the progress of which determines the oxygen pressure levels in slag and metal and produces stirring effects, all of which influence the course of the process as a whole. Reaction Rates at Steelmaking Temperatures General experience in reaction rates makes it almost certain that at steelmaking temperatures equilibrium is attained practically instantaneously when the reactants are well distributed in a single liquid phase —that is, in the so-called homogeneous reactions. The actual slowness of some of the reactions in the open-hearth furnace must therefore be attributed to a relatively slow rate of diffusion within the slag or metal phase, which limits the rate at which the reactants can meet each other in the liquid steel or at its surface. That the reactions can be made to go with great rapidity, by proper mixing and stirring of the reacting phases, is indicated by the following illustrations: 1. In the Bessemer process there is intimate contact between air and the whole mass of metal, and the reactions are complete in a few minutes. 2. Perrinl has demonstrated that by pouring liquid steel into slag contained in a deep ladle, and thereby producing almost a slag-metal emulsion, the phosphorus or oxygen content of the steel is adjustcd immediately. 3. Barret, Holbrook and Wood2 observed a quite rapid rate of desulphurization when powdered calcium carbide was stirred vigorously into liquid iron. 4. When a spoonful of liquid steel is poured into a. mold containing aluminum wire, the formation and precipitation of alumina occurs in the fraction of a second required to freeze the surface layer of the tiny ingot. The first three examples all show that any means of increasing the effective surface between slag and metal and promoting intimate mixture of the reacting phases, thereby obviating the limitation imposed by diffusion, will enhance the speed of the steelmaking process.

Jan 1, 1941

Jan 1, 1902

By I. Stapf

Systematic investigations on silver-rare earth metal systems have been extended on the Ag-Ce system in order to clarify the discrepancies reported in literature. The phase diagram has been reinvestigated on the base of thermal analyses and of microstructure examination on cast and annealed specimen. All intermetallic phases Ag4Ce, Ag3Ce, Ag2Ce and AgCe show no extended range of homogeneity, they melt congruently fm), or decompose peritectically (d) at 815 °C (d), 1030 °C (m), 855 °C (d) and 855 °C (m), respectively. The system shows eutectics at 793 °C/10 at.%, 780 °C/42 at.%, and about 505 °C/81 at.% Ce. d-Ce dissolves up to 2 at .% Ag and decomposes metatectically at 710 °C. Furthermore, the phase transformation of the intermetallics would be clarified. The phases Ag5Ce and Ag51Ce14 reported in literature could not be verified.

Jan 1, 1984

Wabush Mines is the largest single supplier of iron ore to the Canadian steel industry, with 42% of its 6 million tpy of iron ore production going to the company's two Canadian owners-The Steel Co. of Canada and Dominion Foundries and Steel Ltd. Six other companies hold interests in Wabush Iron Co. Ltd. These are Lykes-Youngstown, Inland Steel Co., Intrerlake Steel Corp., Wheeling-Pittsburgh Steel Co., Finsider of Italy and Pickands Mather & Co. Field work on Wabush began in mid-1957 when a long-range program of economic, geologic, and metallurgical investigations started. This work was followed in 1959 by the construction of a temporary camp and a 700-tpd pilot plant. At the same time, work was also started on a 38-mi railway connection to Ross Bay, Newfoundland.

Jan 1, 1970

By Abbas Ali Daneshy

A study of the mechanics of hydraulic fracturing shows the fracture initiation pressure to be a function of the in-situ principal stresses, the formation and fluid properties, and how the wellbore has been completed. The orientation of the hydraulic fracture is perpendicular to the least in-situ principal stress. The geometry of the induced fracture depends on the treatment fluid properties, the injection rate and volume, fluid leak-off and formation properties.

Jan 1, 1974

By Allan T. Fisk, Carl R. Peterson, Richard E. Brooks, James J. Olson

Development of a continuous drill-and-blast excavation capability in mining and high-speed tunneling has been a long recognized goal. Ideally, a machine to meet the challenge should simultaneously perform drilling, explosive loading, initiation, mucking, ventilation, and other functions while remaining at the face, since the elimination or modification of the cyclic nature of the system would significantly improve the advance rate and economy of drill-and-blast tunneling. The Rapidex continuous spiral drill-and-blast concept, one of the continuous excavation schemes presently under evaluation in the US Bureau of Mines' Bedded Deposits subprogram, utilizes an unusual blasting pattern that provides effective fragmentation and involves a partially self-shielding geometry that permits a lightly shielded machine to remain at the face during blasting.

Jan 6, 1977

By I. Plaskin

Interaction of sulfide minerals and native metals I with reagents in flotation is largely determined by particle-surface changes resulting from action of the medium and dissolved gases. A number of early studies were devoted to the selective action of various gases on minerals.' Mc-Lachlan' paid attention to oxygen as the most active gas affecting flotation properties of sulfide minerals. Opposing views were expressed concerning the influence of sulfide oxidation on xanthate flotation: Taggart3 recognized the positive influence of oxygen, and I. W. Wark4 rejected it. Shvedovh ffered the hypothesis of partial oxidation. As to the influence of such gases as hydrogen" and carbon dioxide on mineral floatability, opinions also differed. Effect of Oxygen on Sulfide Mineral Flotation: Research on the influence of oxygen and other gases on the floatability of sulfide minerals and native metals has been carried out at the Institute of Mining of the USSR Academy of Sciences in

Jan 1, 1960

By G. T. Murray

The aging behavior of a Cu-Ti (3.2 at. pct Ti) alloy has been followed by electrical resistivity, hardness, and metallographic changes. The resistivity data indicate two principal processes, the first causing a sharp decrease in resistivity, and the second, which occurs over a long period of time, a much smaller rate of decrease. Lamellar nodules, Widmanstätten platelets, and homogeneous continuous precipitation was observed. The Widmanstätten platelets grow at the expense of the latter. When this study was initiated, little information was available on the aging behavior of copper-base titanium alloys. Several articles'-3 that appeared in the early 1930's showed that these alloys could be strengthened by precipitation, but a detailed study was not made. Within the past year, however, two other more comprehensive studies4'5 have been reported in the literature, one consisting primarily of an investigation of mechanical properties, the other

Jan 1, 1961

By O. Lietard, J. Yvon, R. Mercier, J. F. Delon, J. M. Cases

INTRODUCTION Fineness is one of the main characteristics of powders and this parameter is the object of several definitions based on criteria connected with their uses as well as their determination methods. In trying to obtain the best reaction surface, fineness is characterized by the determination of the specific surface, but in other cases, particle size analysis is used. These two main methods are not, in fact, entirely independent and their complementary nature provides information concerning the morphology of the particles. In the case of a product formed by isodimensional spheres, the relationship between the specific surface and the diameter is well known: [S = 6 spd] where p is the specific weight of the material and d the diameter of the spheres. With no monodimensional spheres, but rather a granulometric distribution whose occurrences follow a mathematical law (1), the relationship is more complicated. The relationship between the specific surface measured by gas adsorption and the data of the particle size analysis is much more difficult to predict in the case of asymmetric porous particles, whose particle size distribution curves do not correspond to a known statistical law.

Jan 1, 1980

By J. F. Kemp

CONTENTS. [ ] I. INTRODUCTION. 1. Situation.-From Monterey in the State of Nuevo Leon, the Sierra Madre mountains stretch away to the southeast and present a steep front to the northeast. The Monterey and Mexican Gulf railway, which connects Monterey with Tampico, follows their general line with its road-bed a few miles out from the foothills. At a distance of 100 miles from Monterey it passes through the town of Linares, and from Linares one can see far away to the southeast the peaks of another group of mountains

Jan 1, 1913

By B. A. Chomyn, P. Lapointe

Current work within the Magnetic Properties Task of the Canadian Nuclear Fuel Waste Management Program has indicated that a relation exists between the measured bulk magnetic susceptibility and fracture and lithological characteristics of granitic cores from the Lac du Bonnet batholith in Manitoba. Susceptibility minima correspond to fractured and associated altered rock; uniform background levels coincide with unaltered, non-fractured homogeneous rock; and susceptibility maxima denote the presence of xenoliths and intervals of core containing large and coarse-grained magnetic minerals. The observed variation in bulk susceptibility is largely controlled by the gram size and the relative abundance of iron-titanium oxide minerals of which magnetite is the most important. The magnetic minerals occur as monomineralic grains of magnetite and hematite, as aggregates of magnetite and ilmenite, hematite and ilmenite and as examples of either of these two categories but exhibiting evidence of oxidation and alteration. The degree of alteration of the oxides is commensurate with the alteration of the enclosing rocks. Susceptibility minima characteristic of fractured rock reflect decreases in oxide gram size and abundance, as a result of the oxidation of magnetite to hematite and the development of titanium-rich phases. Correlations between boreholes indicate the possibility of continuous fracture zones at 80 m and 150 m from the surface and another one at a greater depth.

Jan 1, 1984

By R. L. Frantz, R. W. Bouman

The authors investigated the comminution of quartz and limestone mixtures in a ball mill, showing that the distribution modulus of a comminuted material is the same whether it is ground separately or as part of a mixture. Analysis of the ground products indicates that quartz and limestone consume energy during ball milling in proportion to their mass fraction in the mixtures. Recently Schuhmann' made a significant contribution to comminution theory by proposing that complex comminution operations comprise the summation of many individual comminution events. By means of the single comminution event hypothesis, Schuhmann derived the Charles energy-size reduction relationship by considering that fragments of every particle crushed during a single impact have a size distribution characterized by the Schuhmann size distribution. In this paper, the size reduction of mixtures of solids in ball mills is analyzed by considering that size reduction occurs as many single comminution events. If a mixture of two materials is being ground in a ball mill, each successful impact of a ball with a particle of one material should yield an assembly of particles whose size distribution is characteristic of that material. Considering both materials to follow the Schuhmann size distribution equation, the size distribution of material 1 in the product is

Jan 1, 1962

By Harold H. Haman

In view of Twentieth Century advances in mineral dressing technology, most modern metallurgists would be inclined to class jigging as an early, somewhat primitive, representation of their art. The practice of metallic sulfide concentration by jigging is becoming rare. This is so, in part, because the type of ore amenable to the process is becoming rare. It is appropriate, however, that this symposium recognize that a significant contribution of domestic zinc remains dependent upon coarse preconcentration by jigging, and that the state of the art be described even though the theory and applications are already well delineated in technical literature. One of the few areas still using jigging as a major concentrating process is The Upper Mississippi Valley. AREA HISTORY AND JIGGING The Upper Mississippi Valley (UMV) has produced one billion dollars worth of zinc and lead at current prices. The district includes the southwest part of Wisconsin, the northwest corner of Illinois and an adjoining narrow strip of Iowa. Within a total area of 4,000 square miles, important sub-districts cover about 400 square miles. As is widely known, early mining in this district involved shallow lead---crevice deposits of galena that were very selectively mined, hand sorted and cleaned, and then smelted at or near the site. The district has produced almost a million short tons of metallic lead, a very large part of this during the fifty- year period following 1830. Zinc mining began at the end of the civil war, but at a very low rate until about 1905.

Jan 1, 1970

By Hallan N. Marsh, Bruce H. Robinson

It is now generally recognized that to secure the greatest ultimate recovery of petroleum from a field it is necessary to maintain at all times the lowest possible ratio of gas to oil production. The numerous ways of securing low ratios are not so generally understood or practiced. To many operators, reduction of gas-oil ratio simply means "beaning back" wells, with resultant reduced production rate. This postponement of production is often considered and spoken of as "lost" production, with the result that control of gas-oil ratio is in disfavor with some operators. Various methods are herein discussed by which gas-oil ratio may be reduced, some of which invoLve no curtailment of current production, while others are accompanied by an actual increase of daily production. It is further shown that in cases where rate of production is reduced to conserve gas, the indicated ultimate recovery is generally increased. Principles involved are discussed, and conclusions are illustrated by data from the operation of wells. General Principles The rate and ratio in which oil and gas enter a well are solely dependent, so far as the operation of that well is concerned, upon the pressures maintained in the well opposite the producing strata at various times and at various depths. The method of getting the oil out of the hole, whether by natural flow, gas-lift, or pumping, has no effect upon either rate of production or ultimate recovery except through its effect upon pressures. Oil apparently enters wells according to some such equation as the following: R = KC(Pf - Pw)n Where R = rate of production. K = well coefficient, depending upon thickness of sand, and size and number of pores in the sand. C = fluid coefficient, depending upon viscosity, surface tension, etc.

Jan 1, 1929