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By F. K. Shelton, J. C. Stah, Ruth E. Churchward

A study of the hydrometallurgy and electrowinning of cobalt from various domestic ores has been in progress at the Boulder City, Nevada, Experiment Station since February 1940. Previous reports covering certain phases of this investigation have been published. This report covers the research and pilot-plant work on the production of cobalt metal from cobalt-copper ores from the initial experimental work on crude ore through continuous operation. The ore types were from the Blackbird District, Lemhi County, Idaho. The initial tests were made with concentrated ore which was received by air mail and these experiments were expanded both in size and scope. After the laboratory was continued, improved, and extended tests were reported. Sufficiently advanced, a continuously operated plant producing 250 pounds of electrolytic cobalt per day was operated from June 15 through July 15, 1944.

Jan 1, 1948

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By D. F. Malan

This study reviews the concept of squeezing (large time-dependent deformation) in rock and investigates the possibility of this phenomenon becoming more pronounced in the planned ultra-deep mines of the South African gold mining industry. Although squeezing behaviour is not commonly found at the current depths of the gold mining industry, it is observed at Hartebeestfontein Mine due to a combination of weak rock and high stresses. Calculations based on the average strength of the Witwatersrand quartzites and the competency factor used to identify squeezing conditions in civil engineering tunnels, indicate that there is an increased risk of squeezing behaviour in ultra-deep mines. This will adversely affect the profitability of these mines and highlights the need for further research into the time-dependent behaviour of rock. Finally, the current support strategies in squeezing conditions are reviewed.

Jan 1, 1998

By Gregory R. Gorrell

The legal issues surrounding the regulation of subsidence are among the major concerns facing the underground mining industry today. Whether subsidence occurs almost immediately as a result of longwall mining or without warning as a result of room and pillar mining conducted years ago, the resulting disputes are highly controversial and typical of the disputes involving the competing interests of surface and mineral estate owners. Until recently, the law governing these disputes was firmly established under the common law. The passage of the Surface Mining Control and Reclamation Act 1, the utilization of new mining technologies, and the general heightened environmental awareness of our times, however, have interjected new issues into this area of the law. State and Federal court decisions and administrative agency interpretations have helped clarify some of the issues. However, as evidenced by the many recent lawsuits between operators, surface owners, and regulatory agencies, many uncertainties still exist.

Jan 1, 1986

By A Rorke, B Cubitt, R Beeslaar

The recent drop in the value of the South African Rand has resulted in an increased export value for South African coal and has lead to new coal reserves becoming available for mining. Very often these reserves are in close proximity to existing structures and utilities thus calling for stringent blast control measures to keep the risk of vibration, air blast and fly rock damage to a minimum.

Jan 1, 1997

By Kjell Karlsrud

"Abstract New semi-empirical design procedures for the determination of ultimate shaft friction and load-displacement response of axially loaded piles in clay are proposed. Hereunder also prediction of how the capacity will build up with time following the pile installation, primarily as result of reconsolidation. A main basis for developing the new procedures was detailed review and re-assessment of results from a series pile load test programs published over the past 30 years on piles well instrumented to monitor soil- and pore pressures as well as load distribution along the pile shafts. Two new alternative procedures are proposed for predicting the ultimate shaft friction; a-approach using the normalised undrained strength based on direct simple shear tests as a main correlation parameter, and ß-approach using the overconsolidation ratio, OCR. Both approaches include the effects of the plasticity index of the clay, Ip, which is shown to have an especially large impact on the correlations when Ip<25. It is recommended to use both methods in design practice, and select design values for the ultimate shaft friction that represents an average for the two methods. Pile diameter, length or stiffness, or whether the pile is open- or closed-ended seem to have little impact on the shaft friction. However, a moderate effect of pile length or flexibility on the total ultimate pile capacity comes out of the proposed t-z curves, which include some post-peak reduction. The proposed procedure for predicting the time for set-up is based on linear radial consolidation theory. The main input parameters are the insitu permeability and virgin modulus number (or virgin compression index) of the undisturbed clay. The same basic formula and correlations are applicable to both open and closed-ended or partially plugging piles.IntroductionThe design procedures presented herein are primarily based on observations and data collected in connection with “fully instrumented” pile testing programs that the author has been responsible for or has become involved with over the past 40 years, or that have been found in the literature.It was a pre-requisite for the test programs included that there were sufficient high quality soil data available to give a reliable determination of the true in-situ strength and compressibility characteristics of the clay deposits. The soil conditions range from soft NC clays with undrained shear strength down to about 15 kPa, to very stiff clays with undrained shear strength up to about 500 kPa and OCR up to 25. The plasticity index of the clays mostly lies in range 12 to 60 %."

Jan 1, 2014

By G. G. Barbante

The oxidation behaviour of selenide matte with a substantial Cu content and low Ag differs significantly from that of high-Ag matte. Low-Ag selenide mattes display a large oxygen solubility and the upper boundary of the miscibility gap in the Ag-Cu-Se-O system is depressed to quite low Se contents. As a result, the formation of Ag metal is considerably delayed. The oxidised selenide matte, low in Se and with a relatively high oxygen content, has previously been termed oxymelt. With further oxidation, its composition enters the misciblity gap and crude Ag is formed. The sodium silicate slag captures very little of the SeO2 and the dissolved Ag2O(s) content of the slag is relatively small, with a Raoultian activity coefficient of 0.57. This value was found to be independent of the slag's Cu2O content

Jun 19, 1905

By Cesar Sáenz Acosta

El presente texto señala las mediciones de impactos que se han realizado a los programas de responsabilidad social de una empresa minera. Esta medición se realizó a través del cálculo del indicador “Retorno social de la inversión”, aplicando el modelo SROIM o Gestión del Retorno Social de la Inversión. Los proyectos de RS medidos permiten actuar a las empresas de manera responsable con su comunidad y comprenden: salud y nutrición, educación y desarrollo económico. Asimismo, esta medición contribuye a mejorar la comunicación de los impactos generados y desarrolla una gestión adecuada de estos.

Sep 12, 2011

By M. Arlandi, J. C. Monge

In this paper, the finite element method is used to obtain deformations of a rock tunnel. More than 3,000 numerical simulations and calculations were carried out. The analysis of this results has allowed to achieve mathematical formulations and graphs, to obtain in advance support monitored displacements in tunnelling construction, so they can be predicted before excavation and supporting woks. The application of the presented formulations and charts will aid engineers to control tunnel monitoring, reducing decision time when problems occur. The analysis is limited to cases involving elastic behaviour of the terrain for tunnels of average to good quality in rock, and to excavation sections of average or smaller dimensions for road tunnels. The results show that, in all cases, mathematical expressions to obtain induced displacements around tunnel excavations, have similar pattern than Kirsch (1898) expressions for circular excavations. As corollary of the achieved results, a method to estimate in situ natural geostress ratio K0=sh/sv , by means of convergence measurements, is presented. In diesem Beitrag wurden die Verschiebungen eines Tunnels durch die Methode de Finiten Elemente berechnet. Mehr als 3000 numerische Simulationen und Berechnungen wurden ausgeführt. Die Analyse dieser Resultate hat es ermöglicht, mathematische Formeln und Grafiken zu entwickeln, die zur Voraussage der Verschiebungen in Tunnel dienen, auch unter Betrachtung der verschiedenartigen Abstützungen. So können die Verschiebungen vor den Erdarbeiten und dem Bau der Abstützung abgeschätzt werden. Die abgeleiteten Formeln und Grafiken werden vor allem einen grossen Dienst für Ingenieure bei der Mithilfe zu zeitsparenden Entscheidungen im Tunnelbau und bei der Tunnelkontrolle leisten. Die analysierten Fälle sind auf eine elastische Modellierung des Baugrunds beschränkt, sowie auf eine mittlere bis gute Qualität des Felsens und auf die Aushebung von Abtragungsabschnitten mittlerer oder geringer Grösse für den Strassenverkehr. Die Resultate zeigen, dass in allen Fällen die hergeleiteten Formeln zur Berechnung der durch den Tunnelbau verursachten Verschiebungen um den Tunnel die gleiche mathematische Struktur haben wie diejenigen von Kirsch (1898) für kreisförmigen Bodenaushub. Als Korollarium der ausgeführten Berechnungen wird eine Methode zur Abschätzung der vorherrschenden in situ Geospannungs-Verhälniss K0=sh/sv angegeben, die von den Messungen der Verschiebungen im Tunnel ausgeht. Dans cet article, la méthode des éléments finis est utilisée pour obtenir les déformations d’un tunnel creusé dans la roche. Plus de 3000 simulations numériques et calculs ont été effectuées. L’analyse de ces résultats a permis de définir des modèles mathématiques et des abaques afin de prédire, avant l’excavation et les travaux de soutènement, les déplacements auscultés pendant la construction du tunnel. L’application de ces modèles et abaques permettra donc aux ingénieurs de contrôler les déplacements durant l’auscultation du tunnel et de réduire le temps de décision lorsque des problèmes surviennent. L’analyse est limitée au cas du comportement élastique du terrain pour des tunnels creusés dans de la roche de moyenne a bonne qualité, et à de sections d’excavation de petites à moyennes dimensions pour des tunnels routiers. Les résultats montrent que, dans tous les cas, les expressions mathématiques permettant d’obtenir les déplacements induits autour des excavations de tunnel, présentent des similitudes avec celles de Kirsch (1898) pour des excavations circulaires. Comme corollaire aux résultats obtenus, une méthode pour estimer le rapport des

Jan 1, 2003

By H. K. Lin

Deepwater discharges of sulfide flotation tailings have been practiced for several decades. Oxygen penetration and organic matter content in such environments are the two major factors that determine their reduction-oxidation condition and hence the rate of sulfide mineral dissolution under such discharge environments. In this study, the effects of solution redox potential and pH on the dissolution of some heavy metals from sulfide flotation tailings were examined. Zn, Pb and Cu concentrations in solution were all higher at a higher redox potential and lower pH. Dissolved Zn concentrations reached 100 ppm even at a low redox potential of 105 mV and near neutral pH after 33 days. Pb concentrations were below 2 ppm at 105 mV and near neutral pH after 165 days. At 105 mV, the Cu concentrations were below 0.2 ppm at near neutral pH after 165 days. At pH 2.3, the Fe concentrations were higher at 420 mV than at 105 mV. But at pH 6.8, the Fe concentrations were lower at 420 mV than at 105 mV, due to the oxidation of Fe2+ to Fe3+ and the subsequent precipitation of ferric hydroxide. Arsenic concentrations in solution were all less than 0.002 ppm. For Zn, Cu and Fe, no significant differences were observed between the tests in solutions prepared using seawater and those using distilled water. However, Pb concentrations reached higher levels in solutions prepared using seawater.

Jan 1, 2009

By S. L. George

The semi-solid metal casting process results in a unique solidification path. The microstructural features that were identified during the characterization of the as-cast microstructure, were used as evidence of the process history in order to determine the solidification path followed during the evolution of the microstructure. The morphology of the grains was characterized using SEM and the extent and distribution of the elemental segregation within the grain structure was analysed using EDS. Keywords Semi-solid casting, solidification path, segregation.

Jan 1, 2011

By H. J. Sutherland

This paper reviews the results of the subsidence research prop ram at Sandia National Laboratories. The manuscript highlights the following: the application of empirical methods (profile functions) to the subsidence above longwall panels in the U.S.; the use of the "rubble model" to describe the behavior of broken strata as it distends when it falls to the Mine floor (or top of the rubble pile) and then is subsequently compacted as it is loaded by overlying elements of strata; and, the application of physical modeling techniques (centrifuge simulations) and numerical techniques to study the failure mechanisms in highly structured stratigraphy. The capabilities of the latter two are illustrated &apos;)y comparing their predictions to the results of a field case that has complicated stratigraphy.

Jan 1, 1982

By T. Tafi

The Ute-Ulay project area is located approximately five miles west of Lake City, in Hinsdale County, Colorado. The Ute-Ulay Mine site is approximately one mile east of the project area. The elevation of the site is 9,200 feet and is adjacent to Henson Creek (Figure 1) [ ] The Ute-Ulay Mining complex is an inactive gold, silver, and zinc mining/milling operation, that operated from the 1880?s until the 1970?s, and sporadically into the late 1990?s. The mining complex comprises several levels of underground mines, a flotation mill, and an abandoned town site. Due to the narrow, steep sided canyon, milled tailings were pumped upstream one mile in a sluice box to a wider section of the canyon, and deposited into five tailings impoundments and one berm located between the impoundments. An estimated 9,000 cubic yards (yd3) of fine grained tailings were located in the impoundments adjacent to the creek. The Ute-Ulay project area consisted of the mill tailings impoundments located upstream from the historic mine.

Jan 1, 2011

When we are beset with the economic problems the world faces today, we are always inclined to look at the shorter term future. Today I would like to take a long-term view of our industry, project historical demands for our products into the future and discuss opportunities for our members. Perhaps we could firstly look at the long-term demand trends for our metals. If I tend to use non ferrous metals as a basis for my figures it is because this data is more readily available to me. I am sure that most other products of our industry show similar trends.

Jan 1, 1992

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By W. H. Yarroll Discussion by W. A. Griffith

W. A. Griffith (Head, Research Department, Phelps Dodge Corp., Morenci, Ariz.) - It is gratifying to see the increasingly common use of classical statistical procedures by metallurgical researchers. Mr. Yarroll has given excellent illustrations of the utility of multiple correlation analysis of complex metallurgical data. Our experience in applying these procedures to historical plant operating data has differed, however, from that which he suggests. The uninitiated frequently assume that the volumi-

Jan 1, 1969

Economic Sustainable Power for Mineral Processing

Sep 13, 2010

By P Goblet, S A. Séguret, E Cordier, A Galli

In salar-type deposits, lithium grades can be measured by bailers introduced at different elevations in the drill holes at locations where, later, the brine will be pumped out to recover the metal. When they are duplicated, these a priori rudimentary measurements may show large differences without indicating whether this is due to the procedure itself or to some physical causes linked to the dynamic behaviour of the salar (seasonality, rainfall, underground flow etc). In the reservoir presented in the paper, the problem is complicated by the double lack of stationarity of the lithium grades: the grades not only increase importantly with the depth but at the same time their fluctuations decrease, making it necessary to use non-stationary geostatistical techniques to simulate them. Reservoir simulation is developed in two steps: first, geostatistical simulations of the lithium grade create possible realisations of the reservoir; then, each geostatistical simulation is followed by a pumping simulation that calculates, at each drill hole of a given extraction scenario, the lithium produced each year over 40 years. For the set of 100 simulations produced in this way, a scenario reduction is made to choose the five most representative simulations where more complex calculations will be carried out (for example, changing hydrogeological parameters such as porosity and permeability, or the elevation of the filters, the number and the location of the pumping and the reinjection drill holes etc). The paper first presents an analysis of the geostatistical model sensitivity to the grade uncertainty when measured by bailer. Among the 100 measurements at our disposal covering the future production domain, 50 per cent are duplicates measured at the same place but at different times. They are randomly sampled to produce five subsets of 75 values, which will constitute the future 3D conditioning points for the geostatistical analysis and the simulations. For each subset, trend, standard deviation and variogram models are fitted, leading to five sets of 20 geostatistical simulations of grades. In this way, the reliability of the different parameters involved in the procedure is evaluated, as well as its impact on the pumping results. Then, a reconciliation study is conducted between the non-stationary nugget effects encountered in the 3D variograms of the lithium grade and a pure statistical analysis of 25 duplicates measured at different locations and/or different times. The result is that if the nugget effect reaches 20 per cent, which is the case of three conditioning subsets out of five, the reconciliation is good and the nugget effect of the variogram model represents the bailer uncertainty, ie the measurement error. Since the geostatistical simulation incorporates a nugget effect, it handles the bailer uncertainty and the impact on the produced metal is included in the evaluation. The final conclusion is that, after the hydrogeological pumping simulations, the initial differences between the five geostatistical models do not influence the final results: lithium grades measured by bailers can lead to a robust evaluation of the extractable resources, a conclusion that conflicts with conventional wisdom.CITATION:Séguret, S A, Goblet, P, Cordier, E and Galli, A, 2017. Bailer uncertainty evaluation in a lithium salar deposit, in Proceedings Eighth World Conference on Sampling and Blending , pp 395–402 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By P Staples, G Lane, S Morrell

The design of semi-autogenous grinding (SAG) mill based comminution circuits for the treatment of competent ores, similar to those at Geita and Boddington, involves the same process of sample selection, test work, data analysis and data modelling/interpretation as that used for &apos;average&apos; competency ores. However, over the past couple of years a number of issues have arisen that are common to the design of circuits for the comminution of &apos;highly&apos; competent ores. The impact of these issues on project viability is generally more pronounced when treating hard ores than average to soft ores due to the greater impact on capital and operating costs. The issues encountered have included: standard test procedures have been modified; test equipment has worn or been damaged; different procedures yield different data and varying interpretation; and modelling and empirical calculations have been based on poor benchmarks, or used incorrectly in the case of JKSimMet, yielding misleading outcomes. The purpose of this paper is to present, discuss and clarify some of the issues associated with conducting test work and designing comminution circuits for the treatment of &apos;highly&apos; competent ores in order to reduce thelevel of conflict arising from interpretation and application of test work data. Specifically, the issues associated with the bond crushing (impact) and rod work indices measurement, the various SAG mill specific energy tests, and the interpretation of the resulting data will be discussed in the context of case studies.

Jan 1, 2009

By J. R. Ross

A reconnaissance for sources of scandium and a metallurgical investigation of recovery methods for byproduct scandium from uranium mill solutions were conducted by the Bureau of Mines. The work on scandium was undertaken to obtain information on domestic resources and to explore and develop recovery procedures in consonance with the Bureau&apos;s long-range program for conservation and wise utilization of mineral resources. The element scandium is widely distributed in the earth&apos;s crust in trace amounts, but it seldom occurs as an important constituent in any mineral. An exception is thortveitite, (Sc,Y)2 Si207) a rare mineral that contains various amounts of scandium and yttrium and may contain up to 42 percent scandium oxide (SC203). Knowledge of the chemistry of scandium has expanded rapidly in recent years (1, 4, 9)4 but only fragmentary information is available about the metal because it is still largely a laboratory curiosity without established uses (2, 3). A recent study shows some of the physical proper-ties of the metal are (1) density of 3.05 grams per cubic centimeter) (2) melting point of 1,540° C, (3) hexagonal close-packed structure) (4) hardness of about 50 Brinell (500-kilogram load), and (5) an alloy behavior similar to yttrium and rare-earth metals (2). The price of $2,850 a pound for scandium oxide of 99.9 percent purity and $2,700 a pound for oxide of 99 percent purity reflects the scarcity and complex chemistry of the element.

Jan 1, 1962