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By I. J. Kotzé, R. T. Jones

Conventional PGM matte smelting requires the presence of a certain quantity of base metal sulphides in order to collect the platinum group metals in a molten sulphidic matte phase in the furnace. Furthermore, the quantity of chromium oxide in the feed materials is controlled in order to avoid the build-up of high-melting chromite spinels in the furnace. Mintek has developed a process for smelting difficult PGM-containing feed materials that contain low amounts of sulphur and/or high amounts of chromium oxide. A DC arc furnace is used to provide the appropriate conditions to generate an iron alloy that collects PGMs very effectively, leaving extremely low residual quantities of PGMs in the slag. Various feed materials have been treated successfully in furnace campaigns running at power levels up to 1.5 MW. The longest of these campaigns was run continuously for more than four months, treating more than two thousand tons of materials such as low-grade concentrates, revert tailings, and converter slag. The campaigns demonstrated the robustness and versatility of the process, and proved that it is possible to sustainably produce a PGM-containing alloy and discardable slags containing an average of less than 1.4 g/t of PGMs over the entire campaign. Keywords: DC arc, smelting, furnace, platinum, PGM, revert tailings, converter slag, ConRoast

Jan 1, 2004

By M. Chettibi

The interaction and galena flotation with xanthenes and dexanthogen regularities have been de-fined. So, using thermodynamic method of analysis, the thermodynamic stability of [galena - xanthenes - water] system and the behavior of lead xanthenes surface state in solution were devised. Thus, results of cared out calculations and experimental investigation completely coincide with-out depending on witch product of sulfur oxidation is formed in the solution. In additional, was obtained quantitative physico-chemical models for the necessary xanthenes concentration of lead sul-fide complete flotation in the tuning fork of: at ?? values from 7.0 up to 9.0 (or at the formation of lead carbonate PbCO3 ) and at ?? values from 9.0 up to 12 (or at the formation of lead hydro carbonate Pb3(OH)2(CO3)2 Physico-chemical models derived can be used as the criteria for functional units of automation systems to control and regulate the flotation process in mineral processing plants.

Jan 1, 2014

By W. H. Jang

Although surface chemistry fundamentals of semi-soluble minerals have been studied by many researchers, detailed understanding of these systems is still incomplete. In-situ FT-IR/IRS techniques have recently been used to successfully describe the adsorption of carboxylates at semi-soluble mineral surfaces. However, the wetting characteristics of these adsorbed films require further consideration. In this regard, the hydrophobicity and stability of transferred Langmuir-Blodgett (LB) monolayers of fatty acids at fluorite and calcite surfaces has been studied by contact angle measurements with polar and apolar liquids. Generally, it was found that the transferred LB monolayers of fatty acids at a calcite surface are unstable whereas such monolayers transferred at a fluorite surface are stable, as revealed from advancing and receding contact angle measurements. These results are believed to be due to the incomplete reaction of fatty acid monolayer at the calcite surface. In addition it was found that a closely packed well-ordered stearate monolayer with good hydrophobicity, equivalent to that of a transferred LB monolayer, can be formed at fluorite surfaces by spontaneous adsorption and self-assembly from aqueous solutions.

Jan 1, 1995

By Clélia Ribeiro de Oliveira

Os Aços Inoxidáveis Super Duplex (AISD) constituem sistemas termodinamicamente metaestáveis à temperatura ambiente, de elevada resistência à corrosão por pite em meios contendo cloreto e exibem moderada resistência mecânica. Os AISD possuem diversas aplicações industriais e a principal delas é no setor petroquímico, principalmente nas plataformas offshore. O propósito deste trabalho foi o de analisar a microestrutura e as propriedades mecânicas de juntas soldada por arco elétrico com eletrodo revestido (SMAW) em aços da norma ASTM A890/A890M graus 5A e 6A. As análises foram realizadas sem tratamento térmico pós-soldagem. Procedeu-se ensaios microestruturais (MO e MEV) e ensaios mecânicos (Charpy a -46 e 25 ºC e microdureza) na zona fundida (ZF). Os parâmetros de soldagem foram bem definidos para que não ocorresse fragilidade no material. A microdureza na zona fundida ficou entre 330 e 340 Vickers, o que está de acordo com o valor especificado pela norma Norsok, que é menor que 350 Vickers. No ensaio de impacto Charpy a absorção de energia foi em torno de 86 J para temperatura ambiente e 54 J a -46ºC para ambos os aços. A concentração de fases da austenita na zona fundida ficou em torno de 39%, dentro da faixa estabelecida pela norma ASTM A890/A890M que é de 35 a 65%. As fraturas mostraram-se predominantemente fibrosas, caracterizando elevada plasticidade do material, mesmo em temperaturas negativas.

Jan 16, 2018

By G. K. Nimal Subasinghe

The performance of Knelson Concentrators (KC) used in gravity gold circuits often rely on manufacturers recommendations for selecting operating parameters such as, fluidising water flow rate and cycle time. These parameters are not only dependent on the machine parameters but also on the feed characteristics such as, size distribution of the gold and gangue particles and the composition of its constituent minerals. Particles entering a KC experience a centrifugal acceleration due to the high bowl rotational speeds. The required centripetal force to maintain a circular orbit is provided by the fluid drag force created by inwardly moving fluidising water and the Bagnold?s force arising from the particle/particle collisions. When the fluidising water flow rate is low particles move towards the outer rim of the bowl forming a packed bed within the grooves. On the other hand, if the fluidizing water flowrate is high the bed expands and some particles would move towards the centre of the bowl and gets carried to the tailings stream, thereby reducing the amount of material retained within the grooves of the bowl. Based on a force balance on a particle captured within the KC, a criterion which can be used to predict the amount of material recovered in the bowl has been derived and validated by experimental data. It has been shown that this criterion may be used to demarcate the transition of the bed from a packed-bed state to a fluidised state depending on the fluidizing water flowrate. By identifying the conditions for the optimal expansion of the bed comprising different constituent mineral particles, it is possible to estimate the optimal fluidising water flow rate that would maximise gold recovery while minimising gangue recovery. It was also observed that the accumulation of valuable mineral in the bowl takes place by the displacement of the gangue particles in the bed by the incoming heavy mineral particles. The kinetics of this segregation process was also studied using synthetic mineral mixtures. The experimental data suggests that this process follows first order kinetics and that the build up of heavy mineral reaches a maximum which could be used to identify the optimal cycle time. In this work, the suitability of the above model in optimizing the performance of a KC have been reviewed. Also the necessity and merits of testing an unaltered feed samples in a larger KC as op-posed to the commonly adopted GRG test has been discussed.

Jan 1, 2014

By Luís Carlos da Silva

Apresenta-se uma revisão das características e propriedades do nitreto cúbico de boro (cBN) bem como de diferentes tipos de processamento. A influência da adição de ligantes e a formação de compósitos com outras cerâmicas são também revistas. Finalmente, destaca-se a grande importância prática do cBN como cerâmica de elevada dureza na substituição do diamante em ferramentas de corte.

Oct 30, 2017

By Craig J. Brown

Despite its great potential utility, ion exchange has only achieved limited application in hydrometallurgy. To a significant extent this is due to the limitations of conventional ion exchange process design as well as the properties of the ion exchange resins themselves. Over the past decade several new ion exchange resins have been introduced with properties that make them potentially very useful for various hydrometallurgical separations. In addition, a novel ion exchange process called Reciprocating Flow Ion Exchange or Recoflo, which has been employed in the metal finishing industry for the last dozen or so years for chemical recovery and effluent treatment, has been shown to offer a number of unique and significant advantages over conventional I.X. technology.

Jan 1, 1984

By A. J. Ouellet, A. Coulombe, B. Salmon

The no. 7 vein system cuts the Ventures gabbro which has undergone folding and fracturing; the latter, in response to movement on the nearby Campbell Lake fault. It fills a shear fracture which pinches and swells in the upper mine levels but has a more uniform width in the lower levels. The best copper and gold grades in the upper levels occur in the widest parts of this structure. The vein is richer in quartz on upper mine levels and in carbonate on lower levels. The north wall of the vein is more affected by major and minor element wallrock alteration than the south wall. The isocumulative ci;rves for gold and copper show a direct correlation between the two metals in the upper levels and their increased concentration in the wider parts of the vein. Gold grade decreases in lower levels. A proposed structural model identifies the no. 3 and no. 7 veins as second order conjugate fractures, related to the Campbell Lake fault. The fractures pattern suggests that a conjugate system developed between these two parallel veins as a consequence of rock competence and a relatively low confining pressure.

Jan 1, 1984

By B. C. Jago, H. Derbuch

"The Freightrain kimberlite is located on the Brodeur Peninsula, Baffin Island, Nunavut. Twin Mining is exploring the pipe and adjacent land (79 claims/655 km2) using a combination of airborne geophysics, soil sampling, diamond drilling, trenching and bulk sample processing. The pipe originally was discovered by Cominco Limited in 1975, re-evaluated in 1993 by Lumina Investment Corporation, when it was staked as the Zulu pipe, and subsequently covered by three claims in 1998 by Helix Resources who called it Freightrain.The Freightrain pipe coincides with a strong, ovoid-shaped aeromagnetic anomaly. It is the only surface exposure of kimberlite within a 30 km long linear trend of fourteen aeromagnetic anomalies that are up to 600 m in diameter.The pipe is exposed in the crater facies, near the transition into diatreme facies as indicated by the occurrence of pyroclastic kimberlite characterized by abundant olivine macrocrysts, juvenile lapilli and kimberlite autoliths set in a serpentine-calcite matrix. Olivine, Cr-pyrope garnet and chromite are the most abundant macrocrysts; clinopyroxene, ilmenite and phlogopite mica occur in minor to trace amounts. Garnet and chromite harzburgite, garnet lherzolite, garnet-spinel lherzolite and rare eclogite dominate the xenolith population.Garnet and chromite mineral chemistry indicate encouraging diamond prospectivity and that potentially diamondiferous garnet and chromite harzburgite were the principal sources of diamond in the mantle at the time of kimberlite eruption.Single clinopyroxene grains define an ~42 mW/m2 sub-continental geotherm that is rooted in the diamond stability field. This compares to a slightly hotter geotherm (~48 mW/m2) for adjacent Somerset Island kimberlites with an origin in the graphite stability field. This data accords with the general lack of sub-calcic Cr-pyrope garnet, diamond inclusion chromite and diamond in Somerset Island kimberlites."

Jan 1, 2002

By L. Chanderman, C. E. Dohm

"Mineral Resource estimation (MRE) and classification are highly dependent on the confidence in the model of the orebody geometry, known as the geological model, within which the estimates are constrained. An understanding of the geology of a deposit is thus fundamental to the Mineral Resource evaluation process. The geological model is a function of the structural and depositional complexity of the geology captured by drilling information, which is limited in the early stages of a project. The information effect has a significant impact in terms of the interpretation of the geology as well as the estimation of grade continuity and the resultant risk associated with the Mineral Resource estimate and classification.Therefore, as new drilling information becomes available, it is necessary to update and refine the geological model to appropriately constrain the resource estimates. The grade information is also updated, including statistics and the spatial correlation characteristics. This refinement is based on geological interpretations derived from the drillhole information that becomes available throughout the life of the mine; orebody knowledge that comes from working experience of the deposit, as well as familiarity with the software package used for modelling, is also important.In updating, the potential to identify new resources in previously unknown areas may be realized. The opposite may also occur where previous interpretations of ore continuity are refuted. Both scenarios could result from a better understanding of the geology of the deposit and thus a more realistic MRE, which reduces geological risk. This paper describes how newly drilled advanced grade-control holes for a gold deposit in Mali were used to refine the 3D geological model for the deposit in an attempt to identify the potential for additional oxide ore using conventional geostatistical evaluation techniques."

Jan 1, 2017

By Lim Thi Duong, Du Duy Bui, Thuat Ngoc Pham, Chuc Ngoc Pham, Que Anh Nguyen, Hoa Anh Bui, Chi Thi Ha Nguyen, Hoan Thanh Nguyen, Bac Quang Nguyen, Kien Trung Nguyen, Dung Trung Doan, Nhiem Ngoc Dao

The microstructures and kinetics of a rich iron ore ( TFe = 65.84%) of Na Rua mine, Vietnam, used for the iron production were investigated in this study. Thermal behaviors of iron ores were well-examined by heating microscopy, thermogravimetric analysis, and differential thermal analysis. After being pelletized and then oxidatively fired at 500–1200 °C for 2 h, the pellets fired at 1200 °C (P1200) displayed a hard and dense structure with a decent compressive strength of 317.9 kg/pellet whereas those fired at 500 °C (P500) had a soft and spongy structure. The reduction of iron pellets conducted in a flow of a 60–100% CO2/ Ar gas mixture at 900–1100 °C showed significantly higher efficiency than the reduction using coal. The spongy pellets showed superior performance for the reduction in the CO/Ar gas mixture compared to the dense ones, compatible with the production of sponge iron. When mixed with an amount of coal, P1200 designed for iron production in the blast furnace demonstrated an impressive reduction activity compared to P500 and previous studies. The kinetics of pellet reduction was determined by the diffusion of substances through the solid product layers having the mathematical model of 1 − 2 3 f − (1 − f )2∕3 = kt . The microstructures of pellets during the oxidative firing and reduction were also examined by X-ray diffractometry; scanning electronic microscopy; energy-dispersive X-ray spectroscopy; and Brunauer, Emmet, and Teller method.

Jun 7, 2022

By Harrison R. Cooper

Approximately 40 concentrators throughout the world have successfully adopted computer control for flotation circuit operation since 1969. Successful use of flotation control, gaining up to 2% efficiencies, has largely derived from effective employment of on-stream slurry analyzers and integration of key measurement data through digital processors. Requirements for reliable measurement have also led to improved functional reliability in magnetic flow meters, pH, reagent feed, and other key elements. Methods used in computer control of flotation will be reviewed and variations in operating philosophies will be described with reference to the approaches taken to flotation automation.

Jan 1, 1979

Briefly, an open stope is one in which the ore is taken out and no filling is put in; the only support for the walls may be posts or pillars of ore. Such a method is limited to orebodies with strong walls and ore strong enough to stand unsupported over the back of the stope. Details vary and depend on the dip of the vein, mode of breaking ground, method of handling broken ore, and so forth. The examples given are the Beat-son, Birmingham district, Mineville district, and Cornucopia.

Jan 1, 1925

By Camila Oliveira Colares

Após serem usadas como isolante térmico, as lãs de vidro descartadas pelas indústrias apresentam características constitucionais propícias para a utilização como matéria-prima para a obtenção de materiais cerâmicos. A constituição deste resíduo é baseada em uma mistura de óxidos sendo SiO2 e Na2O majoritários e vários outros em menores teores que podem agir como fundentes. Dentro deste contexto, neste projeto, buscou-se caracterizar física e quimicamente o resíduo de lã de vidro através de fluorescência de raios-X, análise térmica diferencial e difração de raios-X. A partir da composição química definiu-se a formulação mais adequada a ser utilizada para obtenção de materiais vitrocerâmicos com predominância da fase neflina. Al2O3 e Na2CO3 foram utilizados para corrigir a formulação e TiO2 foi utilizado como agente nucleante. Depois de formuladas as amostras foram fundidas para obtenção dos vidros base e submetidas a tratamentos térmicos de nucleação e cristalização, os quais serão definidos por ensaios de análise térmica a serem realizadas em cada formulação para obtenção dos vitrocerâmicos propriamente ditos. Espera-se que as formulações desenvolvidas apresentem nefelina como fase cristalina majoritária.

Aug 8, 2018

By Donald Carlisle

"IntroductionTHE OPINION is held by many persons outside the mining industry, and by some within it, that mine •operators customarily find it advantageous to mine •only the richer parts of orebodies and to leave behind, perhaps permanently, leaner material which could be mined only at a lesser profit. This opinion and the inference which might be drawn from it that 'gutting' of mineral resources is a common feruture• of the mining industry are prejudicial to the intertsts of the industry and deserve careful scrutiny. Oddly enough, a theory of mine economics which gives much support for the opinion was advanced first by members of the mining profession itself, has been repeated •several times in mining literature, and to my knowledge has never been adequately refoted.According to the theory, selective mining of the rich ore first on a large scale will yield substantial gains and these gains do not merely reflect the desire of 'money minded investors' for a quick return but derive from the logical application of compound interest rates and the concept of ;present value. W. O. Hotchkiss and R. D. Parks (1) illustrate the reasoning with a hypothetical example in which an orebody of 4,000,000 tons may be mined either in its entirety in forty years at $1.00 per ton profit or selectively with the recovery of only the richest half in twenty years at $1.50 per ton profit. They show that, with Hoskold rates of 4 and 8 per cent, the present value of profits from mining only the richer 2,000,000 tons exceeds the present value of profits :from mining the whole orebody by about 20 per cent."

Jan 1, 1953

By G. S. Hume

Research thrives on ideas, and the theoretical considerations of today are either the discarded notions or the proven facts of tomorrow. The progress made in the past fifty years in the acquisition of knowledge of petroleum geology is no less astounding than is the tremendous increase in the production of oil on the North American continent from 61 million barrels in 1897 to 1,917 million barrels in 1947, an increase of 3,300 per cent, with production of natural gas expanding from less than 400,000 Mcf in 1897 to approximately 4,500,000,000 Mcf, or an increase of 11,000 fold in the same period. In the search for and discovery of the oil and gas fields that have yielded such prolific wealth, no idea has had a more profound effect than has the ?anticlinal? theory of oil accumulation, propounded in 1844 by Sir William Logan, the founder of the Geological Survey of Canada, after noting the position of oil seepages on the crests of anticlines in Gaspe peninsula. Sir William apparently was not much impressed with his own idea at this time, but after the Drake well discovery in 1859 and the publication by Henry D. Rogers, of Glasgow University, formerly of the Pennsylvania Geological Survey, of a paper in which he pointed out that the seepages in Pennsylvania were on anticlines, T. Sterry Hunt, an associate of Sir William Logan on the Geological Survey of Canada, published a reasonably comprehensive statement of the anticlina theory in the Montreal Gazette on March 1st, 1861. Hunt recognized the fact that the oil ?being lighter than the water which everywhere penetrates the rocks below the water level, naturally rises and accumulates along the crown of these anticlines". This was a recognition of the fact that gas, oil, and water in an anticlinal structure separate according to buoyancy or specific gravity. For some years the anticlinal theory does not seem to have attracted much attention, but when I. C. White in 1883 revived it and put it to practical use by prospecting for 'anticlinal' oil an gas structures in Pennsylvania, West Virginia, and Kentucky, its real value not as a theory but as a fact became widely recognized. Even today, the search for anticlines as oil and gas structures is being vigorously continued. In the past fifty years, however, it has become widely recognized that petroleum and natural gas collect in many different types of structures, and these have become known by the general name of 'traps'. About 1890, terrace structures were highly regarded because it was thought certain oil fields in Pennsylvania, New York, and Ohio were directly related to them. However, as Wilson (2, p. 437) has pointed out, it is recognized to day that ?'wherever the surface evidence is complete and dependable, other factors (than the terrace structure) are found to be in control'.

Jan 1, 1948

By Arthur W. Ruff

Estimated reserves of high-grade iron ore at Serra dos Carajás total 16 billion metric tons and have an average grade of 66.7 percent iron, 2.2 percent combined silica and alumina, and 0.05 percent phosphorous on a dry basis. Hematite is predominant and no significant sulfur or other deleterious elements are present. Figure 1 illustrates the comparative magnitude of the Carajás reserves. Serra dos Carajás is located in northern Brazil, about 550 kilometers southwest of Belém, Pará. It is six degrees south of the equator between the Xingu and Tocantins Rivers. Both rivers flow northward toward the Amazon River. The greater part of the area is covered by thick jungle, and the most practical means of access is by air. Figures 2 and 3 show the location of Serra dos Carajás. Figure 4 shows the distribution of the major iron-ore deposits.

Jan 1, 1973

By Adriana da Cunha Rocha, Carlos Bruno Eckstein, Gabriela Ribeiro Pereira, Clara Johanna Pacheco, Elaine Felix da Silva, Raphael Silva de Araújo, Laudemiro Nogueira Junior, Luiz Henrique de Almeida

A composição química da camada de óxido formada durante operação em um forno de reforma a vapor por 70000 h em um aço inox resistente ao calor grau HP-Nb, foi analisada através da espectroscopia Raman confocal, com o objetivo de correlacionar as características químicas e morfológicas dos óxidos com os diferentes estados de envelhecimento. Os espectros Raman, adquiridos pontos aleatórios da camada de óxidos, revelam que os óxidos de Fe (-Fe2O3 e Fe3O4), bem como os óxidos mistos NiFe2O4 e NiFeMnO4 são as espécies predominantes no estado de envelhecimento I. Amostras envelhecidas dão origem a espectros característicos de Cr2O3, MnCr2O4, Fe3O4 e NiFe2O4, em consonância com estudos recentes reportados na literatura.

Oct 20, 2019

By Doerner H. A.

From thermodynamic calculations Maier predicted that zinc oxide and methane would react at specified temperatures substantially according to equation (1). (1.) ZnO + CH4 = Zn (gas) + CO + 2H2. Other reactions that may take place are (2.) CH4 = C + 2H2. (3.) ZnO + CO = Zn (gas) + CO2. (4.) ZnO + H2 = Zn (gas) + H2O. Maier predicted that 870°C would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1), at equilibrium, would be substantially complete at or above 927°C. Theoretical considerations indicate that reaction (1) is reversible: this is supported, but not proved, by experimental data. The other reactions are known to be reversible. At low temperatures reaction (2) requires a catalyst and it is slow below 1000°C. Reactions (3) and (4) are rapid, but the equilibrium constants are such that only small concentrations of CO2 or H2O can be produced below 1000°C. Maier calculated that CO2 should not exceed 0.5 per cent at 870°C., and the calculation for water vapor gives a still smaller order of magnitude.

Jan 1, 1931

By Chan. C. L., Zehr. R., M. M. Chen, J. Mazumder

"Two three-dimensional models of a surface tension gradient driven flow during laser surface heating are developed. The first model is based on a perturbation solution. The basic solution corresponds to the stationary axisynwnetric case and perturbation is based on a small scanning velocity. The advantage of seeking a perturbation solution, as it turns out, is that the three-dimensional flow is modeled by two sets of two-dimensional equations which are presumably much more tractable than the original three-dimensional equations. Numerical solutions are obtained and discussed. The second model is a full three-dimensional numerical solution of the Navier-Stokes equations, using a point-by-point partially vectorized iteration scheme. Surface shape is also determined in a self-consistent manner. The effect of the presence of convection on pool geometry, cooling rate and solute redistribution is presented and discussed.IntroductionThe existence of fluid flow and convection and their effects were first reported in the fifties (1,2). The role of convection in controlling pool geometry such as pool shape, undercut and ripples, and defects such as variable penetration, porosity and lack of fusion and weld properties such as weld homogeneity and bead formation is studied by a number of researchers and is reviewed by the authors in a recent paper (3).Recently, surface tension gradient driven flow has been identified as one of the forces responsible for convection within the molten pool (4,5). It is postulated that surface tension gradient driven flow is responsible for the surface ripple formation in the weld pool (6-8). Oreper, et al. (9) developed a two-dimensional convection model. Buoyancy, electromagnetic and surface tension gradient forces were considered. The formulation was based on a specified pool profile. It was found that the surface tension gradient is the dominant force in most cases. However, the solid-liquid interface is not known a priori. In fact, the solid-liquid interface, i.e. the pool shape, is a piece of information that the model should be able to predict. A two-dimensional transient self-consistent (i.e. the solid-liquid interface is solved as part of the solution] model for laser surface melted pool was first developed by Chan, Mazumder, and Chen (3)). This model predicted a non-uniform cooling rate, hence non-uniform microstructure. Depending on the Prandtl number (i.e. material) and surface tension number, the shape of the molten region as well as the cooling rate changes. It was also predicted that the recirculating velocity is of one or two order of magnitude higher than that of the scanning velocity. This model provides the detail of the flow field and heat transfer on a plane perpendicular to the scanning direction. However, the front-to-back motion and its effect on heat transfer also play important roles in the physical process, especially for the fact that the recirculating velocity is so much higher than the scanning velocity. Such a motion cannot be obtained from two-dimensional models."

Jan 1, 1986