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By Lamar S. Todd

The direct production of metal from a sphalerite concentrate is an attractive route for primary zinc. A series of operations and conditions have been selected to efficiently cause the following overall exothermic reaction. The process uses a continuous circulation of molten copper for material and energy transfer between the unit operations. Sulfide concentrate is reduced with an excess of superheated copper to make a copper alloy and white metal. The alloy is stripped of volatile metals under vacuum and some metals can be separately condensed. The residual copper and the white metal are fed into a copper converter to be blown with oxygen for desulfurizing and the superheated copper is recycled. The paper will include a detailed material flow sheet for the process, discussion of the operating conditions of the individual units, behavior of minor elements, and zinc quality.

Jan 1, 1999

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

By P. A. Lawless

The objective of the research performed A for the Bureau of Mines on this contract was to develop a portable instrument for the detection of carbon monoxide (CO) in a mine environment. The desired characteristics were sensitivity and specificity for CO with a stable calibration. The sensor of the instrument was to be of metal oxide composition, requiring low power for compatibility with the types of batteries presently used in personal equipment in mines. The solid state design was also desired for ruggedness and small size. A key design feature of the instrument was to be provided by adherence to the intrinsic safety design requirements for electrical equipments operated in potentially exposive mine atmosphere. The Research Triangle Institute has prior experience in developing a solid state oxygen sensor using a thin film of zinc-oxide (Ref. 1) and experience in fabricating thin film devices. Solid state sensors utilized by other workers (Refs. 2, 3, 4, 5, 6) have included metal and semiconductor films and crystals of materials like carbon and aluminum oxide for the measurement of water vapor in the air and have relied upon measuring resistance and capacitance changes in the sensor in response to adsorbed vapors or gases. Since the effect of carbon monoxide in changing the resistance of various materials such as molybdenum, platinum, and zinc oxide had been reported (Refs. 7, 8, 9, 10), the requirements appeared to be realisable, although it was recognized even at the inception of the work that specificity to carbon monoxide might require the incorporation of more than one sensor.

Jan 1, 1976

By Jonathan Baggett, Nino Ripepi, Amin Abbasi, Richard Bishop, Juan Monsalve, John Hole

This work focuses on the operational and safety issues associated with karst voids in large opening underground mines. Issues include water inrush, structural instability, and engineering uncertainty in these environments. Coupled with the fracturing prevalent in folded sedimentary rocks, karst voids are complex and challenging ground-control risks. Traditional methods of predicting karst void locations, such as probe drilling, are impeded by the inconsistent spatial distribution and variable sizes of the features as reported by Li et al. (J Rock Mechan Geotech Eng:232–242, 2010) and Hassan et al. (Procedia Chem 19:737–742, 2016). Ground-penetrating radar (GPR) is a geophysical technique that transmits radio waves into a medium and subsequently detects reflected waves via a receiver. The travel time and energy of received signals are then processed and interpreted. The difference in conductivity and dielectric permittivity between limestone and open karst cavities causes strong reflections. GPR is frequently used as a geophysical surveying technique in several industries; however, there is a lack of published research on underground mining GPR applications as reported by Zhao et al. (2015a; Geophys J Int:62–71, 2015b) and Eskelinen and Pellinen (Constr Build Mater:888–898, 2018). The purpose of this work is to demonstrate the use of GPR in an underground stone mine and to discuss the importance of karst void detection ahead of mining.

?Hydrothermal breccias-genetic models ?Deep drilling-underground potential ?Deposit variety-test new ideas Exploration Summary

May 1, 2006

By J. F. Wright

During the last three years prospecting has been active in southeastern Manitoba and a number of interesting gold, nickel and copper deposits have been discovered within an area 90 miles north of the international boundary, and extending about 40 miles westerly from between mileage 60 and 110 on the Manitoba-Ontario boundary. As known at present, two-thirds of this area of 2,000 square miles is underlain by pre Cambrian granite and granite gneiss and is not likely to contain mineral deposits of economic importance. The remaining one-third is underlain by metamorphosed sediments and lavas (greenstones), penetrated by the granite and granite gneiss and, at various localities, cut by bosses, sills, or dykes of gabbro, diorite, granodiorite, and other types of intrusives. The nickel, copper, and gold mineralization accompanied or followed the intrusion of these different rock types. The gold deposits are limited in distribution, so far as known, to the northern part of this prospecting area and occur along Manigotagan and Wanipigow rivers. These deposits have recently been described in some detail, (3) and therefore only the copper and copper-nickel deposits of the southern part of this area, along Oiseau and Maskwa rivers, will be described in this paper.

Jan 1, 1925

By R. E. Heithecker

Zwolle oil field of Sabine Parish, La., is different from most oil producing areas of the State in that the oil is obtained from marl and chalk-rock formations. The thickness of the reservoir rocks averages 500 feet; but production is not continuous throughout this thickness, as the oil apparently is localized in vertical and nearly vertical solution cavities and channelways or in porous zones of limited horizontal extent. The nature of the oil accumulation has caused two outstanding peculiarities of the field: (1) About 60 percent of the tests drilled were dry holes and (2) there were many instances of well interference. Commercial production was discovered in November 1928, after 17 years of prospecting in and around the present limits of the area now developed which has a length of about 22 miles and a maximum width of 4 miles. The field had produced 10,266,896 barrels of oil to January 1, 1934. The oil ranges in gravity from 400 to 420 A.P.I. Although the field is divided into several districts which are more or less clearly defined and separated by unproved territory the term Zwolle field", as used in this report, includes the entire area from Blue Lake on the west side, through Zwolle proper, and eastward, including the Many or Eastern extension.

Jan 1, 1934

By H. Vedrine

A modelling study has been carried out on the flotation of the Moinho (Portugal) polymetallic sulphide ore, based on pilot plant data. It shows that successfully modelling the flotation of such an ore needs to take into account not only the influence of particle size, but also that of the mineral liberation of the ore. The benefits deriving from the research have been twofold in that the study has: 1. Improved the understanding of (a) the response of the ore to froth flotation and (b) the influence of regrinding the zinc middlings; and 2. Provided models for the optimization of the industrial flotation circuits when the plant starts up in 1991.

Jan 1, 1991

By SONGHE WANG, YI XUE, PENG HOU, CAIHUI ZHU, XUANYE JIAO, Feng Gao

The abstract discusses the challenges of coalbed methane development in China due to low coal seam permeability. It highlights protective layer mining as a method to reduce in-situ stress and enhance permeability for improved gas drainage and disaster prevention. The study involves experimental and numerical simulations to analyze gas migration and permeability changes during stress release. It includes a stress-strain-seepage coupled test on coal, development of a mathematical model for coal seepage under mining unloading, and a numerical model based on the Wulan coal mine to explore in-situ stress release, permeability evolution, and gas drainage in an unloaded coal seam. The aim is to demonstrate the effectiveness of combining protective layer mining and gas drainage technology for gas outburst risk elimination.

Mar 14, 2022

By O. Alonso-Gonzalez, F. Nava-Alonso, A. Uribe-Salas, C. Jimenez-Velasco

"Most of the gold produced worldwide is still obtained by cyanidation, in spite of the difficulties encountered in the processing of some gold ores such as the dissolution of copper-bearing minerals in cyanide solutions. The leached copper forms complexes with cyanide and causes several operating problems, which have led to the development of copper removal/recovery processes, among them the industrially accepted SART process (sulfidization, acidification, recycling and thickening). Although the SART process is in use in gold production plants around the world, new challenges are appearing with the continuous varying of the mineralogy of ores (such as higher copper grades, changing the solution composition and complexity). The optimal SART operating conditions for a specific solution are not the same when the composition of the solution changes; consequently, the efficiency of this process can decrease.The present study is a thermodynamic approach, corroborated by laboratory experiments, to explain how the main variables of the process affect the efficiency of copper precipitation as cuprous sulfide (Cu2S). The variables considered were pH value, copper concentration, cyanide/copper molar ratio and sulfur/copper molar ratio, all of which werevaried within the limits encountered in typical cyanidation solutions presenting the problem of copper.It was found that the variable that most affects the efficiency of the process was the pH value, since poor or no control of it can cause cuprous sulfide redissolution. The S/Cu molar ratio is also important: raising this ratio increases copper removal, but high ratios will also cause sulfide and cyanide losses. The effect of changing the CN/Cu molar ratio was negligible between 4 and 8. For a solution containing 300 mg/L copper and 490 mg/L cyanide, copper removal as high as 98.8% can be obtained with the addition of 0.6 moles of sulfide per mole of copper at pH = 6.IntroductionThe main process for gold production is cyanidation, because it is the most economical and efficient process so far. Precious-metal leaching occurs when the ore is placed in contact with a dilute alkaline cyanide solution. The dissociation of cyanide salts provides free cyanide ions, which allow the formation of the aurocyanide complex Au(CN)2 -. This complex can be retrieved from the solution by adsorption on activated carbon or by zinc precipitation. Although the use of cyanide represents an issue to health and the environment, there are technologies for its management and treatment that can be easily applied. Furthermore, it is a low-cost process compared with other methods that are available or under development."

Jan 1, 2015

By A. K. Bhasin

The movement of solid particles in a liquid represents an area of interest in many fields of science and technology. Knowledge of the behavior and characteristics of solid-liquid suspensions is of great importance to many areas of mineral processing. In order to characterize a solid-liquid system, the following factors must usually be considered: a) density of the liquid b) rheological properties of the liquid c) density of the solid particle d) size and shape of the solid particle e) volume fraction of solid particles f) relative motion of solid particles and liquid phase Other variables such as the effect of the containing vessel walls, Brownian movement, inter-particle friction, fluid slip and electrostatic effects, are important in special circumstances. Thus it is evident that a complete theoretical treatment is not possible covering all situations. Studies of the kinematic behavior of solid particles in a liquid have been approached by two methods: 1) Assessing the movement of a single particle and extrapolating to a multi-particle system; 2) Modifying the continuum mechanics of single-phase liquids in such a way as to account for the presence of solid particles. The first approach in general utilizes the method of particle mechanics. Extension to a multi-particle system gives rise to very complicated mathematical computation. The creeping motion equations do, however, furnish a practical, useful basis for achieving a uniform treatment and a better understanding of the phenomena. This approach is useful in the study of sedimentation and hindered settling processes.

Jan 1, 1971

By John W. Thatcher

A demountable X-ray tube vacuum spectrograph was designed by the Bureau of Mines for the determination of long-wavelength X-ray spectra from the light elements. This instrument was operated for both secondary and combined primary-secondary excitation of the aluminum K-series. There was an increased analytical sensitivity for elements in period 3, and an indication that with improved X-ray tubes or direct election excitation of the sample, X-ray determination of elements in period 2 is also possible.

Jan 1, 1965

By Leahy G. J, Moxon N. T, Nicol S. K

Experimental work is described in which extremely dilute aurocyanide liquors are treated with novel surface-active complexing agents to produce a hydrophobic aurocyanide species. Subsequent aeration of these liquors causes accumulation of such species at the air-water interface and the aurocyanide complex is transferred to a froth concentrate. A detailed performance assessment of this process is made and this knowledge used in the design of a pilot plant facility. Early results indicate the feasibility of the selective recovery of aurocyanide ions from reclaimed residue dam water (approximately 0.2ppm Au) with upgrade ratios of the order 180:1. A further study was made applying ion flotation to the recovery of gold from a carbon-in-pulp (CIL) feed liquor (approximately 1.0ppm Au). The probable economics of this process compared to conventional CIL processing is also described. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal process- Ing.

Jan 1, 1991

By C. D. Litton

When methods to prevent the occurrence of fire in underground mines fail, the next line of defense is to rapidly and reliably detect the developing fire, so that subsequent evacuation and control procedures can be safely and successfully implemented. To provide this capability requires an understanding of the operational principles of different types of fire sensors, their merits as well as their limitations, and performance characteristics of the monitoring systems that control and process sensor data; an understanding of how fires develop and the different types of fires that can occur, along with their characteristics and the hazards they present; an understanding of the impact of the mine environment and routine mining activities, not only in terms of these effects on fire sensors but also in terms of the impact of mine ventilation and mine geometry on fire growth, fire characteristics and the detection process. All of these factors are components of the technology of fire detection, and when insufficient knowledge of any of these components exists, the ability to implement adequate mine fire detection systems is diminished. Within the last decade, significant advances have been made in fire detection technology applicable to underground mines. These advances include not only the development of improved sensors and better monitoring systems, but also an expanded understanding of how to deploy sensors, set sensor alert/alarm levels, account for ventilation effects, etc. In addition, there has been an increase in our knowledge of the types of fires that occur, the types of combustibles involved, characteristic times for fire growth and development, the levels of heat, smoke and gas that are produced and the hazards that result. It is the intent of this paper to provide not an overview of current mine fire detection technology and, also, to present data obtained for some smoke sensors that have potential for use in underground mines. The paper will also discuss the data, information and resources that are currently available and seek to identify those areas most in need of further research and development.

Jan 1, 2011

By W. W. Adams

The first full year of the second World War for the United States presented a picture of the metal-and nonmetal-mining 4 industry which, without proper analysis and explanation, would convey a distorted view of achievements during 1942, especially because employment at gold and silver (lode and placer) mines-the largest group-declined to such an extent that the over-all totals for the country were reduced even though increases were made at mines producing copper, lead-zinc, iron, miscellaneous metals, and non-metals. A complete panorama of the metal-and nonmetal-mining industry, exclusive of coal mining, reveals a decrease in the number of men employed, the man-hours of employment, and the accident-frequency rates. Were the gold and silver (lode and placer) mines to be considered as a separate category; it would be seen that the number of men employed at all the other groups of mines increased appreciably over 1941. These other increases must be considered important, since these mines produced the vital war minerals that made valuable contributions to the military successes of the United States and its Allies during the year. A separate analysis of each of the various groups of mines may be found elsewhere in this bulletin. For the purpose of maintaining continuity in this series of bulletins, however, the discussion in this introduction will be confined to the entire metal-and nonmetal-mining industry (excluding coal mining, for which a separate bulletin, No. 462, has been published).

Jan 1, 1945

By Maryam Ghodrat, Bijan Samali

Disposal of waste syringes in a safe and eco-friendly way has been an issue of considerable scale for decades. The generated amount of waste syringes has escalated with the rapid growth in population and wide acceptance towards single-use medical devices. Some hospitals have their own on-site incinerators ,but recent tightening of air quality regulations and landfill levies led to the closure of manyon-site incinerators. The solution to this problem implicates the development of an environmentally-sound method that would employ these waste materials. This work investigates a thermodynamic modelling approach for incineration treatment of waste plastic syringes in Electric Arc Furnace (EAF) steelmaking. Mass balance was obtained from HSC Chemistry thermochemical package. The results indicate that the rate of iron oxide reduction in the slag is higher when coke is partially replaced by waste plastic syringes. Furthermore, the amount of dust and stack gas emission was reduced by around 0.4% and 1.25% respectively by replacing 20%-weight of pure coke with waste plastic syringes. The study demonstrates part of the coke can be successfully replaced by waste plastic syringes in electric arc furnace to provide additional energy from combustion without affecting the main process.

Mar 1, 2018

By R. Agius, A. Nacu

"Cyanide destruction technologies are implemented at gold and silver operations to comply with the International Cyanide Management Code and meet ever more stringent discharge limits. Currently, the most common chemical cyanide destruction processes used in industry are sulfur dioxide/oxygen, hydrogen peroxide, and Caro’s acid. The cyanide destruction process used at an operation must reliably generate streams of acceptable quality at all times, and depends on numerous factors, including permit discharge requirements, tailings chemistry, location, site-specific climatic conditions and size of the operation. Selecting the most appropriate cyanide destruction process and determining the process design criteria requires accurate laboratory testing. This paper presents and discusses the results of a number of cyanide destruction evaluations that have been conducted to reduce cyanide concentration in process solutions or cyanidation tails. Laboratory testing provides important insights into reagent consumption and other factors required to achieve the target residual weak acid dissociable cyanide (CNWAD) levels.INTRODUCTION Process solutions associated with the extraction of gold and silver contain several forms of cyanide. The most toxic form of cyanide is free cyanide, which can be present as a dissociated cyanide anion (CN-) or gaseous or aqueous HCN. Weak or moderately stable cyanide complexes such as those of zinc, copper and nickel are classified as weak acid dissociable (CNWAD). Although less toxic than free cyanide, weak acid dissociable cyanide complexes are considered “ecologically sensitive” forms of cyanide and are regulated in most jurisdictions. In practice, reported WAD cyanide values comprises both free cyanide and weak acid dissociable cyanide complexes. Cyanide complexes with gold, mercury, cobalt and iron are referred to as strong acid dissociable complexes (CNSAD) and are much more stable, even under mildly acidic conditions. Another term commonly used in cyanide chemistry is total cyanide, which represents all cyanide compounds present in solution. Total cyanide levels in solutions are always equal to or higher than WAD cyanide values and the difference between the two usually indicates the presence of iron-cyanide compounds. Typically in Canada, CNTOTAL levels cannot exceed 1 mg/L in solutions discharged to the environment."

Jan 1, 2017

By R. E. Heithecker

The Zwolle oil field of Sabine Parish, La., is different from most oil producing areas of the State in that the oil is obtained from marl and chalkrock formations. The thickness of the reservoir rocks averages 500 feet; but production is not continuous throughout this thickness, as the oil apparently is localized in vertical and nearly vertical solution cavities and channelways or in porous zones of limited horizontal extent. The nature of the oil accumulation has caused two outstanding peculiarities of the field: (1) About 60 percent of the tests drilled were dry holes and (2) there were many instances of well interference. Commercial production was discovered in November 1928, after 17 years of prospecting in and around the present limits of the area now developed which has a length of about 22 miles and a maximum width of 4 miles. The field had produced 10,266,896 barrels of oil to January 1, 1934. The oil ranges in gravity from 400 to 420 A.P.I.

Jan 1, 1934

By Ilija Ilic

Recovery of tin from tinplate and production of good-quality detinned-plate for further processing in ironworks has been the subject of interest for many years. Tinplates are mostly used for production of tin containers for food industry and consumer goods. The research carried out so far included determination of the parameters of dissolution of tin from tinplates by alkaline solution of NaOH and electrochemical recovery of tin from the alkaline solutions. During leaching, NaNO3 and methanitrobenzoic acid (MNBA) as oxidants were studied. By leaching the waste tinplate which contains 0.31 % of tin with a solution of 1.12 mol/dm3 NaOH, 0.26 mol/dm3 Na2CO3 and 0.09 mol/dm3 MNBA at temperature of 70°C for 60 mm, a degree of tin leaching of 97 % was attained. MNBA facilitates oxidation of Sn2+ into Sn4+ suitable for obtaining compact, and not spongy, Sn cathode deposit, as it was the ease earlier. Recovery of tin by electrolysis from solutions obtained by leaching was studied to determine the effect of electrolyte composition on the quality of cathode deposit and the degree of electric current efficiency. Experimental results obtained at a laboratory level were checked on an enlarged laboratory set up where continuos leaching of tin from waste tinplate and its electrolytic recovery from the solution obtained were carried out. The experimental set-up -operated under semi-industrial conditions, and about 500 kg of waste tinplate was processed yielding about 1.160 kg of tin (99 % Sn).

Jan 1, 2000

By W. A. Grosh

In 1951 the Federal Bureau of Mines became interested in the reports of copper-nickel mineralization in northern Minnesota. Several outcrops on the north side of the Duluth gabbro in the Kawishiwi River area were sampled by the Federal Bureau of Mines and George M. Schwartz of the Minnesota Geological Survey. Because these samples showed appreciable amounts of copper and nickel, a 100-pound sample of an un-altered outcrop was obtained for metallurgical testing. Results from this preliminary work were all favorable; therefore, in the fall of 1953 the Bureau of Mines diamond-drilled three holes near the outcrop of the con-tact between the Duluth gabbro and the Algoma granite. A total of 686 feet of NX size hole was drilled, and 100 percent of the core was recovered. Each hole intersected the contact, and the strike and dip for that locality were established. The core was split, and half was used for analyses and further metallurgical tests; the remainder was retained for permanent record in the Bureau of Mines core-storage warehouse.

Jan 1, 1955