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By Roland B. Hoag, Roger G. Webber

Sulphate concentration in groundwater is a good measure of the extent of oxidation of sulphides, provided that sulphide minerals are the primary source of the sulphate. A study was conducted near the Eustis Mine in Quebec to determine where and how the sulphate in groundwaters originated. Atmospheric precipitation is the only source of sulphate other than oxidation of sulphides, and in this study area it is equal to 0.01,. millimole per litre. The oxidation of sulphides can be divided into subsurface oxidation (mainly inorganic processes) and surface oxidation (including both organic and inorganic processes) . The maximum sulphate concentration due to subsurface oxidation of sulphides depends on the solubility of 0 2 in water and is 0.25 millimole per litre. Surface oxidation is, therefore, responsible for any amount greater than atmospheric plus subsurface contributions (0.29 millimole per litre). Surface inorganic oxidation occurs in waters with a pH greater than 15 and is controlled by the kinetics of the oxidation processes. Organic (bacterial) surface oxidation is dominant only in acid (pH< 1.5) waters. The bacterial action accelerates the oxidation of sulphides, and large quanttties of sulphate may be introduced into solution.

Jan 1, 1976

By Jerry Dolph

In September 1855, 55-year-old Noah Spencer Kellogg and his $3 jackass named Bill discovered what was known at the time as a “blow out” of high-grade lead and silver ore. The deposit was located on the side of a North Idaho mountain high above the South Fork of the Coeur d’Alene River. The ore was later assayed at 41,141 g/t (1,200 oz/st) silver. Kellogg named his discovery the Bunker Hill Lode, after the June 17, 1775 Revolutionary War battle of Bunker Hill. A thriving pioneer settlement sprang into existence around the resulting mine’s workings and was eventually— and appropriately — named Kellogg. The peak rising hundreds of feet above the mine’s adit was named “Jack-ass Peak” after Noah Kellogg’s hairy companion.

Jan 1, 1996

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grindablity index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions3 issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor; if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous of coal as delivered is a check on the practical results obtained in the coal.

Jan 1, 1967

By L. E. Schultze

Experiments were conducted by the U.S. Bureau of Mines to verify enhancements due to chloride and surfactant additions in the leaching system of chalcopyrite with ferric sulfate and sulfuric acid. A statistical experimental design was used and equipment was designed to eliminate contributions from changes in solution electrochemical potential during the course of the measurements. Results confirmed that chloride additions increased chalcopyrite leaching by as much as 94 pct over the electrochemical potential versus hydrogen electrode range of 630 to 750 mV at pH 1.7 and 50°C. Total iron concentration had no effect over the range of 1 to 5 g/L. The effect of surfactant addition was less well defined. While additions of LA 790 (a polyoxyethylene lauryl ether) resulted in increased copper leaching in several of the tests, the differences were too small to be statistically significant. No interaction effect could be verified.

Jan 1, 2010

By Tacio Ferreira

How state-of-the-art software, data analysis and communication applied to drilling and blasting techniques have have allowed quarries in the Midwest of the United States to improve results downstream

Feb 1, 2020

By W. H. Hamilton

The Kokomo (Tenmile) mining district has had an output valued between $20 and $30 million, mostly from production of silver, lead, and zinc, since 1878. For many years before World War II, there was little production, as the complex nature of the ores made them unattractive at existing metal prices. Under the stimulus of the war, the Geological Survey and the Bureau of Mines studied they district, and in October 1944 the Bureau of Mines began an exploration project, which included dia¬mond drilling, bulldozer trenching, and geophysical surveying. Project work was continued until March 1949, except for short recesses during 1945, 1947, and 1948. Forty-five diamond-drill holes, totaling about 13,000 feet, were drilled from underground and surface stations on the various properties in the district. Eleven bulldozer trenches, abut 2,400 linear feet, were excavated in an attempt to uncover the outcrop of the middle Quail limestone. These trenches ranged from 100 to 485 feet in length and reached a maximum depth of 15 feet. A limited geophysical investigation was made during the summer of 1946. The length of the traverses were: Magnetic, 990 feet; resistivity, 6,250 feet; and self-potential, 69,780 feet.

Jan 1, 1955

"10.1. IntroductionAs discussed by Westland (1981), the six platinum-group elements (PGE) belong to the Group VIII transition metals, to which iron, nickel and cobalt also belong. The chemical similarity between these nine metals accounts for the fact that they tend to be concentrated together as a result of geological processes. These processes started to effect the distribution of these metals at the very beginning of the earth's history.The first line in Table 1 gives the concentration of nickel and certain other Group VIII transition metals in carbonaceous chondrites, those meteorites with a composition that is believed to reflect best the composition of our planetary system apart from hydrogen and helium. The second line is the estimated concentration of the same elements in the earth as a whole. It is seen that these two estimates are quite similar, the earth being perhaps 2 to 3 times richer in these particular metals than the planetary system as a whole. The reason for this is not fully understood, but it may be due to the earth being formed by the accumulation and capture of a greater proportion of iron (and therefore siderophile-rich) than stoney (and therefore siderophile-poor) planetesimals than the planetary system itself.The third line in Table 1 is the average composition of the crust of the earth. With the exception of iron, all of the Group VIII transition elements are rare in the crust, present at concentrations of It tOO to Itt ,000 of that of the bulk earth. This is because the outstanding chemical characteristic of this group of elements is their siderophile nature; that is, their tendency to alloy with metallic iron. Because of this, once the earth became molten very early in its life history, these elements dissolved in the molten iron present at this stage and were removed from the outer accessible parts as this dense liquid sank to the centre of the earth to form the core. Although iron was the main instrument of concentration of the Group VIII metals, its much greater over-all abundance and its ability to combine with oxygen more easily than the others in the group means that significant amounts still remain in the oxidized portions of the earth.The fact that most of the Group VIII metals are available to use in workable concentrations at all is that they are 5 to 30 times more concentrated in the earth's mantle than the crust, as shown in line 4 of Table I. There has been a constant, if slow, interchange of matter between the mantle and the overlying crust throughout most of the earth's history and, under certain circumstances, this interchange has given rise to economic concentrations of metals."

Jan 1, 1979

By Richard L. Ash

In many instances, blasting exerts the dominant control over the economics and safety of excavation, where the materials involved are too hard and tough to be fragmented efficiently by other means. However, associated with the fragmentation process other effects very often result that are not desirable and may even be hazardous, such as fly rock, air blast, excessive overbreak, and damaging ground virbrations. It has always been the desire of those concerned with blasting to better control the forces involved so as to improve the breakage of materials, but at the same time reduce, or eliminate if possible, the unwanted side effects. Until the last decade or two, little was known of the phenomena concerned with blasting. However, since that time many investigators have studied blast mechanisms produced from both chemical and nuclear explosions, with the result that general concepts of the principles have been developed. But, in general, it is assumed that the energy from the explosion would be propagated spherically throughout the material, the latter of which for convenience of analyses is considered homogeneous and isotropic, i.e., the properties are the same in all directions, However, rocks are not isotropic as a rule, and evidence clearly indicates blasting forces rarely function uniformly or in spherical form as theorized.

Jan 1, 1965

By Kari Niiranen

LKAB (Luossavaara-Kiirunavaara AB) is operating iron ore mines, concentration plants and pelletizing plants in Northern Sweden. The largest of the apatite magnetite deposits and the mines are Kiirunavaara with annual production rate of approximately 27 Mt crude ore underground. LKAB produces two varieties of pellets: blast furnace pellets and direct reduction pellets (LKAB DR Oxide Pellets). Meanwhile the concentration process in a sequence of the low intensity magnetic separation (LIMS) and flotation at the concentration plant. In spring 2007 there were noticed great fluctuations of SiO2 grade in the crude ore. The high SiO2 grade is particularly problematic in the case of direct reduction pellets. In consequence, a project was started (called Silica in the Mine) to define exactly the problem related with silica and to find out, if possible, the reason for the great fluctuation of SiO2 grade in the crude ore going to the processing plant. A further target of this project was to develop a simplified method at the laboratory scale, to predict SiO2 grade in the magnetite concentrate in the future, but also predict the physical properties of the ore with respect to mineral processing. The essential stage of systematic characterization of the ore body for mineral processing properties is the estimation and simulation of different parameters from the laboratory scale to the large scale at the concentration plants using empirical data collected at the mineral processing by LKAB in Kiruna. Further a target was also to find useful physical parameters for mineral processing and implant those parameters into the existing geological 3D-model of the deposit. This information will be used for making prognosis of the future mining and the quality of the crude ore. It will also give better control and improve the production planning in the mine and the performance at the concentration plant in Kiruna concerning the decrease of the SiO2 grade of the magnetite concentrate.

Sep 1, 2012

By Janet Torma-Krajewski, Pauline Lewis, Paul Gust, Lisa Steiner, Kean Johnson

Ergonomics processes described in the literature have been associated mostly with manufacturing, financial, electronics, and office settings where working conditions tend to be rather constant and repetitive. The information presented in this document demonstrates, however, that an ergonomics process can also be implemented in a setting such as mining where working conditions frequently change and workers are periodically exposed to extreme weather conditions. This document describes how Bridger Coal Company implemented an ergonomics process at its Jim Bridger Mine from 2001 through 2004. The process developed by the Ergonomics Committee, the promotion of the process to management and employees, and the impacts of the process on working conditions at the mine are reviewed. Barriers overcome and lessons learned are also described. Quotes from Bridger Coal Company employees are included in the document to add a personal perspective. Other industries with working conditions similar to mining, such as construction and agriculture, may find this information useful.

Jan 9, 2006

By C. A. Young, J. D. Miller

Adsorption isotherms previously determined by in-situ Fourier transform infrared/internal reflection spectroscopy (FT-IR/IRS) for oleate adsorption at calcite and fluorite surfaces near pH 9 and at various temperatures are compared. Results indicate that, at both mineral surfaces, chemisorption occurs at equilibrium concentrations below approximately l x l0-5 M oleate while calcium dioleate surface precipitation occurs at higher equilibrium oleate concentrations. The extent of chemisorption at the calcite surface is 3 to 5 times less than that at the fluorite surface while the extent of calcium dioleate surface precipitation on calcite is nearly a magnitude larger than that on fluorite. However, for both minerals, surface precipitation decreases with increasing chemisorption. Contact angle measurements and flotation recoveries show the hydrophobicity of fluorite to be greater than that of calcite at each of the temperatures and oleate concentrations studied. Significant differences are noted only in the chemisorption region. Unlike calcite, the hydrophobicity of fluorite was sensitive to the presence of oxygen in the system. Multichannel Laser Raman Spectroscopy (MLRS) showed this behavior was caused by the double-bond reactivity of adjacent chemisorbed oleate molecules and subsequent formation of an epoxide/polyether complex at the fluorite surface. Such a reaction product could not be detected at the calcite surface. These differences in adsorption density, hydrophobicity, and polymerization behavior are discussed in terms of the intrinsic surface properties of the minerals.

Jan 1, 1999

By Clinton C. Knox

During the latter part of 1943, a magnetometric survey was conducted by the Geophysical Division of the Bureau of Mines at the Mahopac magnetite mine, Putnam County, N. Y., in an endeavor to locate a segment of the ore body that reports state was cut off by a fault. The Mahopac mine was abandoned about 1895 after producing nearly 1,000,000 tons of high-grade magnetite iron ore. The results of the investigation indicate the termination of the ore body by "pinching", or a displacement of such magnitude as to place any extension at a considerable distance from the original are body. This report describes the work done on the project and presents the data obtained.

Jan 1, 1948

By H. R. Shell

To obtain a better understanding of the crystallization of fluoride containing amphiboles from melts, an investigation of the range of stability between fluoramphi-boles and other minerals was conducted by the Bureau of Mines. This study has shown that the stability of fluoramphiboles is strongly influenced by both fluoride concentration and isomorphic replacement. Over 150 reactions were made with different compositions and reaction conditions. substitutions attempted and the phases that formed when the composition was crystallized by cooling from the melt are discussed. The attainment of equilibrium in these multicomponent systems is not claimed. Many ions that would be expected to enter the amphibole structure instead resulted in crystallization of phases other than amphibole. Those compositions that resulted in a high yield of acicular fluoramphibole by crystallization from the melts are shown in table 2. The fluoramphiboles obtained from melts typically had an acicular crystal habit and a hardness of 6 to 7 on the Mohs&apos; scale. Although many had relatively high length to cross section ratios, none were fibrous; it was concluded that the possibility of synthesizing a fibrous fluoramphibole from a melt was low. However, many compositions can be crystallized into a tough, hard, impact-resistant mass of interlocking acicular crystals.

Jan 1, 1958

By J. B. Dilworth

OUTCROPS of coal have bees discovered is many localities is the Philippine archipelago, and practically all of the larger islands contain deposits of this mineral. Very little prospecting has been done to determine the value of the various coal-bearing areas, but so far as known, the largest and most promising fields are found : (1) is northern Cebu; (2) is the small island of Batan, a part of the province of Albay is southeasten Luzon; (3) is the somewhat larger island of Polillo, off the east coast of Luzon, and (4) is southern Mindoro, sear the small coast tows of Bulalacao. Northern Panay, south-central Cebu, and various localities is southern Luzon, Masbate, Negros, and Mindanao also afford evidences of the existence of coal-beds, the extent and value of which have not yet bees proved. The general position of these islands and districts is shows on the map of a portion of the Philippine Islands, Fig. 1. Some of these coal-fields have been known for many years (coal was discovered is Cebu 1827 and is Batas is 1842),1 and several futile attempts were made by the Spaniards to operate mines is these districts. But owing to many circumstances, chief among which were indifferent management, the political unrest of the islands, natural difficulties of transportation, and those inherent in the mining of steeply-inclined and somewhat irregular seams, no considerable output was ever obtained from any of these mines, and the fuel required is the many departments of industrial and political life has continued to be drawn largely from Australia and Japan. These conditions exist to a great degree at present, and though much interest is the coal-deposits of the Philippines

Jan 1, 1909

By P. M. Sullivan

The principles and application of amalgam electrolysis to the recovery of zinc and tin from secondary products were studied; this Bureau of Mines project was one phase of investigating the development of more efficient methods for processing iron-bearing zinc and tin to produce both base metals of high purity. Zinc of 99-99-percent purity was recovered from galvanizer&apos;s dross with recovery efficiency of 98 percent. Tin of 99.9-to 99.99-percent purity was recovered from hardhead with recovery efficiency of 81 percent. Both materials were treated by the same method in separate systems. Mercury was used to leach zinc from dross and tin from hardhead to form amalgams of each metal, both of which were subsequently refined electrolytically to produce high-purity metal. Impurities that were contained in both secondary products behaved as theoretically predicted; impurities that were insoluble in mercury remained as sludge in the leaching column. Except for lead, the readily amalgamated impurities were prevented from fouling the electrolyte by the blocking action of the amalgam electrode. Lead impurity in the tin-refining system dissolved and immediately precipitated as the sulfate. The primary advantage of the amalgam refining method lies in direct recovery of the extremely pure base metal from highly contaminated secondary material.

Jan 1, 1961

By Khaled M. Mohamed, Michael M. Murphy, Ted M. Klemetti, Heather E. Lawson

"The design of rib support systems in U.S. coal mines is based primarily on local practices and experience. A better understanding of current rib support practices in U.S. coal mines is crucial for developing a sound engineering rib support design tool.The objective of this paper is to analyze the current practices of rib control in US coal mines. Twenty (20) underground coal mines were studied representing various coal basins, coal seams, geology, loading conditions, and rib control strategies.The key findings are: (1) any rib design guideline or tool should take into account external rib support as well as internal bolting; (2) rib bolts on their own cannot contain rib spall, especially in soft ribs subjected to significant load—external rib control devices such as mesh are required in such cases to contain rib sloughing; (3) the majority of the studied mines follow the overburden depth and entry height thresholds recommended by the Program Information Bulletin (PIB) 11-29; (4) potential rib instability occurred when certain geological features prevailed—these include draw slate and/or bone coal near the rib/roof line, claystone partings, and soft coal bench overlain by rock strata; (5) 47% of the studied rib spall was classified as blocky—this could indicate a high potential of rib hazards; and (6) rib injury rates of the studied mines for the last three years emphasize the need for more rib control management for mines operating at overburden depths between 500 ft and 1,000 ft.IntroductionEfforts to improve the stability of underground mine ribs have continued for decades. These efforts by mining professionals around the world persisted throughout the 1990s and 2000s as well, though much of this work focused on rib support methodology and selection of proper support for a specific location. Despite these efforts, it is unfortunate that there has been a continual occurrence of rib-related fatalities in underground coal mines. While overall improvements in rib safety have been achieved, the average fatality rate is still about 1.3 fatalities per year over the last 18 years (Jones, 2014).To manage and control the rib hazard, rib support is used in U.S. coal mines. The current rib support methods for U.S. mines fall into two main categories: rib control based on intrinsic support systems and those based on external support systems. Intrinsic or rib-bolt support requires a roof bolting machine that can install a bolt fixture into the rib. Furthermore, the appropriate level of support needed to control the ribs with an intrinsic-based support system as well as the design parameters for those support systems for various mine conditions have not been established in U.S. coal mines. Furthermore, surface control systems are often an integral part of these support systems and must be considered in the system design."

Jan 1, 2015

By J. Jorge, J. Mariño-Salguero, B. Álvarez-Rodriguez, J. M. Menéndez-Aguado, J. J. de Felipe

"This work focuses on the characterization of heat generation during dry fracture by direct impact of a tantalum ore. Moreover, an attempt was made to quantify the heat energy loss to the environment during the grinding process of a ball mill. The study was carried out using mineral samples from a Spanish mine that were characterized by measuring their density and specific heat. During the experiments, increases of temperature ranging from 5.9 to 7.3 °C after the fracturing process were observed. A numerical model was then applied to calculate temperature distributions through the mill wall. Three possible combinations of heat transfer coefficients were analyzed, from (1) Kapakyulu and Moys, (2) Duda and (3) the heat transfer laboratory of Universitat Politècnica de Catalunya. The models with the coefficients from Kapakyulu and Moys and the heat transfer laboratory of Universitat Politècnica de Catalunya were found to provide results that were in best agreement with the experimental data. IntroductionEvery year, several billion tons of metallic ores, minerals, cement and other solids used in the ceramic and chemical industries are subjected to size reduction in ball mills around the world. The U.S. Department of Energy (2005) reported that in the United States about 29 percent of the total energy used by the mining industry, or 0.4 percent of total U.S. energy consumption, is used in comminution. In Canada and Australia, comminution is responsible for about 2 percent and 1.5 percent of total energy use, respectively. In nonindustrialized countries where mining constitutes higher fractions of their industrial sectors, comminution costs represent a significant contribution to mine operating costs. The specific energy consumption values for the grinding of these materials typically range from 5 to 50 kWh/t. Thus, a significant amount of electrical energy is consumed in the ball mill grinding operation (Aguado et al., 2006; Gupta and Sharma, 2014). Grinding can represent up to 50 percent of the direct operating cost in a mineral processing plant, especially as comminution devices operate in highly inefficient ranges of 4 to 8 percent (Wang, Yang and Yu, 2012)."

Jan 1, 2017

By G. S. Scott. R. L. Grant

Ammonium nitrate (NH4NO3), a white crystalline chemical compound composed of 35 percent nitrogen, 60 percent oxygen, and 5 percent hydrogen, has again attracted attention, due largely to the recent catastrophe on April 16 and 17, 1947, at Texas City, Tex. The fire and subsequent explosion on the steamship Ocean Liberty, outside the harbor of Brest, France, on July 28, 1947, has fur- ther increased the interest in the properties of ammonium nitrate. As a result of the Texas City disaster, several laboratories have undertaken research to determine more certainly what causes ammonium nitrate to detonate and under what circumstances. This is not the first time that ammonium nitrate has been involved in a disaster, and its properties reviewed from the standpoint of safety. The disaster at Oppau, Germany, in 1921, which involved an equimolec- ular mixture of ammonium nitrate and ammonium sulfate, prompted an intensive study in Europe and in America. In the United States the properties of am- monium nitrate are now of especial concern because very large quantites are being manufactured and shipped in interstate commerce and abroad. Many an- monium nitrate factories, which were built during the war, will manufacture increasing amounts of this compound for use as a fertilizer. It is the purpose of this report to present a brief summary and biblio- graphy of the published experimental facts about the properties and behavior of ammonium nitrate. The reader is referred to original publications for greater details of the investigative work, and for theoretical discussions. This report also includes a survey of ammonium nitrate fertilizer of the type involved in the Texas City explosions. In the past, authorities have not always agreed on the degree of hazard involved in the manufacture and handling of ammonium nitrate, as the following quotations from the literature indicate: Munroe (82) quoted the following from Turner's Chemistry (a book pub- lished in 1835): "When this salt is exposed to fire, it liquefies, emits aqueous vapor, dries and detonates." Berthelot (14) in his book, Explosives and Their Power, 1983, wrote: "Ammonium nitrate from the point of view of its volatility, and cn account of many considerations, may be regarded as a typical explosive substance."

Jun 1, 1948

By G. Kolosay, J. Rajala, G. Deschênes, A. Romanov

ABSTRACT: The Kupol project, located in Far East Russia, treats a high-grade, free-milling ore containing 25.5 g/t Au, 298.3 g/t Ag, and 0.5% pyrite,with a P70of 53 microns. Most of the gold occurs as elec-trum and the silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite, andproustite. The mill reached the design throughput of 3,000 tpd six months after start-up. AKnelson con-centratorrecovers10.4% gold and 0.5% silver. Leaching (14.5 hours pre-treatment and 116 hours cyanidation)of gravity tailings is performed with the CANMET Enhanced Leach Process (CELP),using only 490 ppm NaCN (cyanide consumption of 1.1 kg/t). The precious metals are recovered by counter-current decantation and the Merrill-Crowe process. Calcium hypochlorite destroyscyanide and thiocyanate. Overall, gold and silver recoveries for 2008 were 95.4% and 85.6%,respectively (2.8% and7.5% higher than targets). In the first eight months of 2009, gold and silver recoveries were 95.0% and82.6%, respectively. By August 2009, the mill processed 1.42 million tons of ore with production of 1.1 million ounces of gold and 11.3 million ounces of silver. CELP performance was not affected by changes in feed grade and ore mineralogy. Additional modifications to the leaching strategy allowed further reduction in cyanide consumption and effluent treatment costs.

Jan 1, 2011

By P. R. Bradley

NO thought had been given to deep level mining at the Alaska Juneau mine prior to 1930, but in that year a prospect winze was started and continued for 1000 ft. vertically below the main haulage or adit level. The point at which this winze was started was selected entirely by the prevailing physical conditions, such as proximity to established workings, convenience, and the presence overhead of a substantial pillar of dimensions sufficient to lo¬cate the sheave wheel and loading pocket. It was, therefore, with some surprise that the unusually high-grade ore found just below the collar of the winze persisted, with certain vari¬ations, to a full depth of 1000 ft. vertically. Likewise this unusually high-grade ore was found to persist on the various crosscuts driven on levels at 200-ft. vertical intervals. To be brief, this deep level work found richer ore than any yet found in the mine over like areas, and inasmuch as the area was sufficient to plan for extensive deep level mining, plans for such work were given extended consideration.

Jan 1, 1936