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By Rajashekhar Marthi

Lithium is a key component for future electric vehicle batteries and energy storage. The future availability of lithium to meet the growing demands remains in question. Around 60% of lithium resources exist in the form of continental brines. Traditional methods to recover lithium from brines use solar concentration with precipitation and have found limitations in lithium extraction due to interference of Mg in high Mg/Li brines. Thus, there is a need for highly selective adsorbents. Recently, spinel structured delithiated lithium manganese oxides have demonstrated promising results. However, due to the small particle sizes, it is economically difficult to recover the adsorbents and thereby limits industrial applications. In our work, LiMn2O4 ion sieve was synthesized and immobilized on diatomaceous earth. Fundamental adsorption studies were carried out in lithium buffer solutions to understand the nature of adsorption and kinetics. The adsorbents were also tested for recycle stability, as well as recovery of lithium from Great Salt Lake water samples.

By Patrick R. Taylor

Glass is used for immobilization of radioactive and hazardous wastes due to its durability and ability to accept a variety of waste constituents into its network structure. Alternative high temperature vitrification techniques have the advantage of increased throughput, increased waste loading and being applicable to variable and heterogeneous waste streams. However, the increased processing temperature places further concerns on the increased volatilization of contaminants, and increased corrosion and erosion of me Iter components. A database of melt properties at higher temperatures, such as partitioning, viscosity, density and electrical conductivity, in the temperature range of 1400-20000 K are being developed.

Jan 1, 2000

By Jos. R. Guiteras

This paper is one of a series describing; mining and milling methods and costs being published by the Bureau of Mines. It deals with the mineral resources of western South Dakota and describes the mining and milling of tantalite and associated amblygonite by the Black Hills Tin Co. and the Fansteel Mining Corporation. ACKNOWLEDMENTS Acknowledgment is made to Earl C. Schultz and Arthur I. Johnson, respectively superintendent and engineer for both the Black Hills Tin Co. and the Fansteel Mining Corporation, who contributed the information on mining and milling operations.

Jan 1, 1939

By Danilson Gonçalves de Melo e Silva

O balanço de energia realizado em um forno de aquecimento de tarugos apresentou rendimento de 53%. A maior perda energética estava relacionada ao sistema de refrigeração dos skids, cujo valor calculado foi de 18%. Objetivando minimizar tais perdas, estudou-se a utilização de um novo tipo de revestimento refratário para esta região. O fabricante de refratários apresentou uma estimativa de ganho de 62%. Desta forma, a VBR planejou um teste para validar a eficiência do refratário proposto. Neste teste, o produto foi instalado em uma viga auxiliar. Esta viga foi instrumentada, e foram registrados dados de vazão, pressão e temperatura do fluido de refrigeração (água). Objetivando comparar estes valores com o material convencional anteriormente instalado, outra viga com as mesmas características (dimensões e posição no forno) também foi instrumentada. Posteriormente, foram feitos os balanços de energia em cada viga para quantificação das perdas de energia térmica. Os resultados encontrados mostram uma redução de 92% da perda térmica relacionada ao sistema de refrigeração dos skids. Considerando a eficiência do forno de 53% e a redução de 92% da perda térmica, estima-se uma economia de R$ 1.200.000 por ano.

Sep 25, 2017

By J. Zollinger, J. R. Kennedy, J. H. Park, D. Daloz

"In order to improve the properties of cast Ti-Al alloys to replace Ni-based superalloys past the low pressure stages of aircraft engines investigations into inoculation for grain refinement were carried out. Previous work showed isomorphic self-inoculation using Ti-Al-Nb particles was effective for grain refinement, however the relatively fast diffusion of Nb in Ti-Al make it difficult to observe the mechanism of nucleation. An alternative alloy was developed in the Ti-Ta system for isomorphic self-inoculation, maximizing the Ta content to improve the particles survivability in the melt. The powder processing produced comparatively small inoculant particles which dissolved, however larger particles were seen to survive solidification. The density difference between the inoculant particles and melt resulted in an inhomogeneous mixing of the particles and the melt with larger particles found near the outer edges of the ingots. Variations on particle size and interaction time between the inoculants and the melt resulted in the Ti-Ta inoculant reducing the as-cast equiaxed grain size by a factor of two compared to non-inoculated samples as well as increasing the equiaxed fraction in the ingot.INTRODUCTION Lightweight metals are of particular interest in aerospace applications. The hot sections of turbines are dominated by blades made of nickel based superalloys. Recently the GEnx turbine introduced TiAl blades in the last low pressure stage of the turbine to reduce weight and improve fuel efficiency (Kim & Dimiduk, 1991). In order to carry these benefits deeper into the turbine the high temperature (>800oC) properties of the alloys must be improved. Current grain refinement methods to improve properties rely on boron additions which may not be applicable for all blades as brittle precipitates may be formed during processing (McCullough, Levi, Mehrabian, & Hyman, 1991). A novel grain refinement process was previously introduced called “isomorphic self-inoculation” using Ti-Al-Nb particles to successfully grain refine TiAl (Kennedy, Zollinger, Bouzy, & Daloz, 2016). In order to better understand the mechanism of this process an investigation was carried out using the same process but with a Ti-Ta alloy which is more stable in the TiAl melt than the Ti-Al-Nb."

Jan 1, 2017

By Fouad Faraj

For every blast pattern, zones of unique material types need to be classified before mining. Most material types can be summarized into different kinds of ore and waste. Blocks generated from blasthole assays are too small to be selectively mined so areas with a single material classification meeting the mine’s selective mining unit must be defined. Current industry standard practices are to manually draw ore/waste dig limits but this process is subjective and results in quantities of dilution and ore loss which can be improved upon to enhance the profitability of mining operations. Two weeks production data from a homogeneous Cu porphyry and heterogeneous Manto-type Cu deposit are used to assess the variability in the hand-drawn dig limits for 20 geologists, mining engineers, or ore control specialists and are compared with the optimal ore/waste delineation. The profit for 20 distinct hand-drawn dig limits for the homogeneous mine ranged by 3.7% from $10.5 million to $10.9 million averaging at $10.8 million. The percent range nearly doubled for the more heterogeneous mine at 5.9% from $17.9 million to $19.0 million averaging at $18.6 million. Using the optimal ore waste delineation, the profit increased to $11.0 million (1.9% increase) and $19.3 million (7.0% increase) for the homogeneous and heterogeneous deposits respectively. The natural variability, diggability requirement, and selectivity are identified as the main drivers of ore loss and dilution. Recommendations are provided for reducing the subjectivity in manual hand-drawn dig limits by integrating dig limit optimization algorithms as a tool to assist practitioners.

Feb 23, 2024

A shrinkage stope is an overhand stope in which the broken ore accumulates until the stope is completed to, or near, the level above. As broken ore generally occupies at least 60 per cent. more space than ore in place, about a third of this must be drawn out as the stope advances to leave a working space under the back. The ore remaining supports the miners and gives temporary support to walls, and is all withdrawn when the stope is finished. The shrinkage-stope method is applicable to steep-dipping deposits of strong ore with strong walls. It may be applied to narrow or wide veins, and is simple and cheap. Five examples, which include important and varied types of deposits, are given: namely, Kennecott, Homestake, Jarbidge district, Mogollon district, and Cripple Creek district.

Jan 1, 1925

By Vestre J, Kure K, Bergqvist I

Existing practical laboratory tests for comparative strength determination of commercial explosives consist of the lead block test, the ballistic mortar test, the bubble test etc. These tests are carried out in material with quite different properties compared to rock. The theoretical performance potentials of commercial explosives are traditionally described by weight-strength (WS). Some explosive producers use the Langefors formula for weight-strength calculation, where also the gas volume is considered. Neither the theoretical nor the practical methods for determination of explosive performance such as the above, give good enough prediction of fragmentation and heave in rock blasting. For these reasons a project was started for the purpose of finding a small scale test method which predicts how different explosive parameters affect fragmentation and heave. Small scale tests were carried out by using 50 cm cubical blocks, mainly of concrete, but a few also of rock. All blocks were blasted in a steel cylinder with a diameter of 1.2 meters. The velocity of detonation was monitored, and the velocity of fragments was derived from their time of arrival at the steel wall, which was registered by accelerometers. After blasting all fragments were screened. The charge diameter was 22 mm and the amount of explosive 78 grammes, resulting in a specific charge of 0.62 kg/m3. Explosive properties such as energy, gas, VOD and density were systematically changed.The results presented in this paper show how fragmentation and heave systematically change when the explosive properties like energy, gas, VOD and density are systematically changed. The results from the small scale tests are compared to full scale tests carried out in tunnel blasting, and during summer 1990 also in bench blasting.

Jan 1, 1990

By Robert A. Bosschart, Harold O. Seigel

"Most electromagnetic methods presently used in mining exploration are of the moving source type; i.e., the primary field source is moved simultaneously and in a fixed configuration with the receiver. Of the fixed-source methods, which employ a stationary primary field and a moving receiver, the Turam method is the most effective and has marked advantages over alternative electromagnetic methods. The results are little affected by topographic relief, and a high degree of resolution can be obtained because of the constant relation between source field and investigation area. Another inherent advantage of the Turam configuration is that it provides more favourable dimensional relations. Thus, the primary field attenuates at a much lower rate than in moving-source configurations and, secondly, the method is size sensitive; i.e., conductor size affects the strength of the response, which is not the case with moving-source methods. These factors result in a considerably better potential depth penetration."

Jan 1, 1966

By Maria José Santos Lima

A pesquisa e o desenvolvimento de Materiais nanoestruturados vêm crescendo significativamente nos últimos anos. Estes materiais apresentam propriedades significativamente modificadas em comparação às dos materiais convencionais, devido às dimensões extremamente reduzidas dos cristalitos. O carbeto de Tântalo (TaC) é um material extremamente duro, apresentando elevada dureza, elevado ponto de fusão, elevada estabilidade química, boa resistência ao ataque químico e choque térmico e excelente resistência à oxidação e corrosão. Desta forma este trabalho teve como objetivo a obtenção de TaC nanoestruturado a partir do precursor tris(oxalato)oxitantalato de amônio hidratado, através de reação gás-sólido a baixa temperatura (1.000°C) e curto tempo de reação. Os materiais obtidos foram caracterizados através de difração de Raios-X (DRX), Refinamento Rietveld, Microscopia Eletrônica de Varredura (MEV), Espectroscopia de Infravermelho (espectroscopia IV), Termogravimétrica (TG). Através das analises de DRX e do refinamento Reitiveld para o TaC com S = 1,1584 observou-se a formação do carbeto de tântalo puro com estrutura cúbica e tamanho médio de cristalitos na ordem de 12,5 nanômetros.

Aug 7, 2018

By Rodrigo Costa dos Santos

O objetivo deste artigo é apresentar uma proposta de metodologia para auxílio na fase de planejamento de um projeto de manutenção, objetivando a redução de falhas no mesmo. Tal estudo possui relevância, pois quando se trata de manutenção preventiva o custo é sempre considerável para qualquer empresa, uma vez que para realização as máquinas devem ser paradas e recursos humanos e materiais devem ser disponibilizados, desta forma o planejamento deve ser feito de maneira que sejam utilizados apenas os recursos necessários e suficientes para manter a qualidade dos equipamentos. A metodologia se embasa na teoria geral de projetos e utiliza de maneira sequenciada e estratégica ferramentas já aplicadas no mundo da manutenção para determinar as oito fases personalizadas para um evento de manutenção. A aplicação da metodologia facilita o trabalho do planejador o que consequentemente viabiliza a sua entrada no meio industrial, posto que a metodologia é altamente simples e sequenciada, o planejador não precisa conhecer com detalhes a teoria de projetos para utiliza-la. Portanto, com objetivo de facilitar e sequenciar o planejamento da manutenção afim de reduzir falhas, a metodologia trabalha de maneira forte a análise e gestão de riscos e definição de cronogramas em projetos.

Oct 30, 2017

By Kai Koosmen, Mehdi Serati, Tengzhou Wang

Spalling and rockburst are unwanted brittle failures at the boundaries of underground excavations that are commonly observed in hard rock and high-stress environments at significant depths, although, spalling has also been observed in comparatively shallow soft rocks. The crack initiation (CI) stress threshold (representing the stress level at which new micro cracks begin to form in an intact rock) is widely used to establish the in-situ spalling strength, and is generally regarded as the lower limit of the long-term rock strength. This study analyses the evolution of CI and other mechanical properties for a high-porosity sandstone with an average UCS of 38 MPa under unconfined cyclic compressive loading. The results indicate that rock properties are variably affected by cyclic loading with; no significant effect on Youngs Modulus; a moderate increase in Poisson’s ratio and fracture angle; a moderate decrease in UCS; and a major reduction in the CI stress threshold. All of these changes were generally amplified by cyclic loading at higher stresses. From the results, it is concluded that rockburst and spalling limit in underground structures may reduce over time if the rock is subject to repetitive cyclic loading, and that the reductions will be greater for higher cyclic stresses. This may be a significant factor in the design and operation of some deep underground structures.

Apr 26, 2022

By H. Vincent Wallace

ALTHOUGH it is universally accepted that free oxygen is A necessary in a cyanide solution for the dissolution of gold and silver-in accordance with Elsner's equation that 2Au + 4KCN + 0 + H20 = 2KAu (CN), + 2KOH- little has been written and insufficient attention paid to the drop in extraction due apparently to loss of dissolved oxygen in mill solutions. Aeration or oxygenation of cyanide solutions has been more or less successfully accomplished by various types of agitators such as the Dorr (with or without air lifts), Pachuca tanks and more recently "Turbo-mixers" and Denver "Super- agitators"; also by the introduction of chemical oxidizing agents such as Solozone (Na,O,) . At the Wright-Hargreaves and other mines in the Kirkland Lake camp, the introduction of this reagent at the rate of about 1.25 oz. per ton of ore applied to the feed of the ball mills has certainly been beneficial.

Jan 1, 1932

By Jr. Foot

The Bureau of Mines, U.S. Department of the Interior, investigated flotation methods for recovering fluorite and byproduct beryllium from the Fish Creek deposit of Nevada. The preferred method includes (l) fluorite rougher and cleaner flotation, (2) de sliming at 20 micrometers, (3) muscovite flotation, (4) silicate flotation, (5) hypochlorite wash of silicate concentrate, and (6) beryllium rougher and cleaner flotation from the silicate concentrate, Laboratory results showed that over 94 pct of. the fluorite was recovered in a concentrate containing 96 pct CaFz. Beryllium flotation produced .concentrates .containing in excess of 5 pct BeO with recoveries over 70 pct. A 1.00-lb/h continuous flotation unit was constructed to demonstrate this procedure,

Jan 1, 1985

By Arthur F. Taggart

The following notes represent significant excerpts from a mass of records of experimental work done in the ore-dressing laborattory at the Columbia School of Mines during the years 1926 to 1928 inclusive. Classification of Experimental Work The experiments performed may be grouped for purposes of description under the following general headings: I. Collecting agents. a. A method for quantifying collecting effect. b. Coating with undissolved collecting agents (oils). c. Action of dissolved collecting agents. II. Frothing agent's. a. A method for quantifying frothing effect. b. Relation between frothing effect and chemical composition. III. Inorganic reagents. a. Methods of studying the effects of these reagents. b. Effect on slime dispersion. c. Effect on sulfides. Summary of the Origins of Present-day Flotation Practice The first practicable, foolproof method of froth flotation was described in U. S. Patent 835120, issued in 1906 to Sulman, Picard and Ballot, and in the equivalent patents in other countries. A number of less simple methods of producing the same result had been described previously in patent publications and otherwise.' The reagents specified in all of these early patents were "oils" and, in addition, some inorganic substance, usually an acid. The quantities of reagents recommended and added were enormous when compared with those used today.

Jan 1, 1930

By D R. Venkatesulu, N K. Nanda

Due to increased production of steel in India, the thrust is now on iron ore producers not only to enhance productivity from existing mines, but to look also into alternative resources, like lean grade iron ores such as banded haematite quartz (BHQ)/banded haematite jasper (BHJ), which are available in abundance but not yet utilised for want of suitable process technology. In this context, BHJ ore from the Bellary-Hospet sector was collected and subjected to detailed physical, chemical and mineralogical characterisation and beneficiation studies. The as-received sample was found to occur physically as alternating layers of haematite and jasper. The chemical analysis of the sample was 41.20 per cent Fe, 39.10 per cent SiO2 and 0.86 per cent Al2O3. Based on the mineralogical observation, haematite was found to be the lone ore mineral and jasper was the major gangue mineral. The microscopic observations revealed that the ore minerals liberate at a top size of 0.150 mm. Guided by the characterisation results, indicative tests were conducted using gravity and magnetic separation equipment, namely, Floatex«, gravity slime table and wet high intensity magnetic separator (WHIMS). The results indicate that it is possible to upgrade the sample by both gravity and magnetic separation techniques. However, the WHIMS results indicate that jasper grains report to the concentrate at higher gauss intensities. Therefore, based on the encouraging gravity separation results and the availability of new design spirals for treating fine particles, the applicability of gravity spirals for beneficiating BHJ in the liberation size range of -0.150 mm was studied. The sample was ground to a top size of 0.150 mm and was subjected to preconcentration using wash waterless spirals. Tests were conducted at different feed rates, pulp densities and splitter positions. The results indicate that it is possible to upgrade the sample from a feed grade of 41.20 per cent Fe to a preconcentrate ranging from 46 per cent to 62 per cent Fe with a yield ranging from 19 per cent to 55 per cent. The obtained preconcentrate was then subjected to a cleaning stage by using a combination of wash water and wash waterless spirals. The test results indicate that it is possible to obtain a final concentrate assaying 65.75 per cent Fe and 4.75 per cent SiO2 with a yield of 25.9 per cent and an iron recovery of 41.31 per cent. It was concluded that further test work is necessary to increase the recovery and improve the product specification.

Jan 1, 2009

By Laszlo Valentyik

The wide scale acceptance of the heavy media separation is due to its simplicity and efficiency. The two most important variables of the process are specific gravity and consistency of the medium. The latter is a function of the settling rate of the media solids. The almost always present clay in the feed and conse¬quently in the medium acts as a stabilizing agent, and its optimum concentration varied between 3-4%.(1,2) Since polymers essentially perform the same function in oil well drilling muds - i.e. to suspend cuttings during drilling - as the fine clay in heavy media separation, this led to the investigation of whether polymers could be used in heavy media separation as supporting agents. During the first phase of the work, it was found that by the controlled addition of polymers, the stability of the heavy media increased without unduly increasing viscosity of the suspensions, thus yielding conditions for more effective and efficient separation. The results of the experiments were reported in a paper at the AIME Centennial Annual Meeting, March 1971.(3) This paper presents the results of the experiment carried out during the second phase of the work.

Jan 1, 1975

By D. Nardini

The need to move towards faster and safer mine development is a key priority in mining houses globally. In addition to this, South Africa faces an array of challenges introduced by labour-intensive operations; hence a study was conducted to look into improving development rates and labour productivity, specifically in the areas where trackbound flat-end development is required. The aim of the study was to propose a method to deliver fit-for-purpose tracked tunnels that advanced at a rate of one blast per end every single working day. A major part of the study was to optimize the selection of an appropriate trackless fleet and mitigate any constraints introduced with the mechanization. This was done by creating scenarios, based on a typical case study, looking into the aspects around safety, mine design, mine activity cycling, men and machine requirements, service installations, and trackless-trackbound interfaces. The case study was based on a deep-level gold mine developing twin headings with connectings; however, with the move to extend and deepen platinum operations it is foreseen that twin end development will become more prevalent due to ventilation, logistical, and other requirements. With the introduction of the trackless mechanized system suggested, development rates of 56 m of system advance are expected (189 m total development), with on an average of three headings and fixed blast times. Scenarios run with multi-blast conditions yield expectations of 75 m/month advance of the system, significantly higher than the conventional performance seen today.

Jan 1, 2012

"In a continuing investigation into the development of uranium alloys for armament applications, some complex base alloy corn positions were modified by varying the amount of alloying elements and by removing one or two of the alloying elements in turn from the base alloys. These uranium-base alloys were specially formulated in a search for heat-treatable, high-strength, ductile, high-density alloys. All alloys studied were ternary, quaternary or more complex alloys of uranium with molybdenum, zirconium, niobium and vanadium. Each cast alloy was studied under three different heat-treatments, and its mechanical and corrosion properties were determined. It was found that although most of the alloys studied had the hardness and strength required, they were extremely brittle and notch-sensitive under tensile stresses."

Jan 1, 1968

By Sathit Tandanand

This Bureau of Mines report describes the method of obtaining a strength index for rock drillability, particularly for percussion drills. The original Protodyakonov method has been slightly modified, essentially to eliminate uncertainties in the measurement of the volume of fines, and to avoid conjecture in selecting the representative value as the strength coefficient. A theoretical consideration of the relevant parameters in the method was extended from a comminution theory, and hence the meaningful value was obtained experimentally by plotting the ratio of the number of drops and the volume of fines against the number of drops. The minimum ratio of the number of drops to the volume of fines in the plot was selected as the coefficient of rock strength. The modified method of obtaining the strength coefficient preserves the original Protodyakonov test apparatus and the merit of simplicity of the test procedure. The modified coefficient of rock strength shows its usefulness in predicting penetration rates with greater reliability than other mechanical properties. Consequently, the drillability curves were drawn using the modified coefficient of rock strength as the parameter for penetration rate prediction in the field.

Jan 1, 1975