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By Ann G. Kim

Hydrocarbon gases, primarily methane but also the C2 through C5 paraffins, the C2 and C3 olefins and possibly the C4 and C5 olefins, are byproducts of coal formation. Although it is generally believed that coal formation occurred at temperatures below 200° C, most experimental work on gas formation from coal has been performed at temperatures between 200° and 1,000°C. The objective of this Bureau of Mines experiment was to determine if observable changes in the gases from coal could be produced at temperatures below 200° C in relatively short periods of time. The experiment involved heating coal samples from six coalbeds at constant temperatures and analyzing evolved gases. The composition of the gases at three temperatures was compared. At 35° C, over 99 pct of the gas is methane; at 125° and 150°, methane constitutes approximately half of the hydrocarbon gas. Isobutane and pentane are the predominant higher hydrocarbons at temperatures between 100° and 150° C.

Jan 1, 1974

By Bruna Helena Malovini Loiola

Os aços ligados ao níquel especificados pela norma ASTM A 522 são utilizados na fabricação de válvulas, flanges e conexões de tubos, na indústria automotiva, na construção civil e na área naval. Na indústria de petróleo e gás, o material requer desempenho adequado para resistir às altas pressões, ao ambiente corrosivo e à abrasão. Considerando os efeitos do desgaste nas válvulas e flanges, este trabalho tem como objetivo avaliar o efeito da temperatura de revenimento na microestrutura e dureza do aço. Amostras submetidas à têmpera a 860°C e ao revenimento na faixa de 380 a 630°C proporcionaram resultados que mostram uma microestrutura predominante de bainita após têmpera e redução da dureza com o aumento da temperatura de revenimento devido ao alívio de tensão.

Aug 17, 2017

By Pedro Jorge Walburga Keglevich de Buzin

A produção siderúrgica em usinas semi-integradas gera vários tipos de resíduos dentre os quais as carepas. No presente trabalho estuda-se o comportamento físicoquímico em altas temperaturas de briquetes autorredutores elaborados com carepa e finos de carvão vegetal produzidos no Rio Grande do Sul, objetivando sua introdução no processo produtivo de aciaria elétrica. Ensaios realizados em laboratório com briquetes industriais confeccionados com estes resíduos demonstraram a potencialidade de utilização destes briquetes autorredutores em processos siderúrgicos via forno elétrico a arco (FEA).

Aug 16, 2017

By Federick W. Miller

The Bureau of Mines has investigated the availability of columbium from 19 deposits (3 producers and 16 nonproducers) in 7 market economy countries (MEC?s). Brazil has the largest recoverable columbium resource, posessing approximately 2.39 million metric tons Wmt), or 69 pet of the MEC total (3.47 Mmt). The Western Hemisphere countries of Brazil, Canada and the United States contain 3.14 Mrnt of recoverable columbium or 90 pnt of the MEC total. Columbium recovered as a byproduct of tin mining is not included as part of MEC resources in this study. Currently producing mines are Araxa and Catalao in Brazil, and Niobec in Canada, These three mines have 2.42 Mmt of recoverable resources or approximately 69 pct of the MEC total. It is estimated that these mines, operating at full capacity, could satisfy cumulative MEC demand (based on an annual growth rate of 5.1 pct) for the next 20 yr. The United States is totally dependent upon foreign sources for its columbium supply. The majority of U.S. columbium is imported from Brazil in the form of steelmaking- grade ferrocolumbium. Canada has been the sole source of pyrochlore concentrates since Brazil discontinued exports in 1981. The United States also imports small (but important) quantities of columbium as columbite concentrates from Nigeria and Brazil, as columbite contained in tin slags from Thailand and Malaysia, and as synthetic concentrates from the Federal Republic of Germany.

Jan 1, 1986

By J. E. Rouse, D. L. Buchanan

"During the emplacement of the Bushveld Complex in the Potgietersrus area magma reacted with the original floor rocks— Archaean granite or Malmani dolomite and overlying Penge handed ironstone or sedimentary rocks of the Pretoria Series. The complex sequence of sulphide-rich mafic rocks that formed along the contact is known as the Platreef. Associated with the sul­ phide mineralization are important concentrations of platinum-group metals, copper and nickel. Xenoliths of Malmani dolo­ mite have been incorporated into the Platreef and previous work has suggested that anhydrite is likely to have been present in the dolomite. The sedimentarv-derived sulphur thus introduced into the magma exercised an important control on the forma­ tion of the sulphides.Petrographic studies on the Platreef rocks from the Tweefontein area indicate that the original magma reacted with the banded ironstone to form iron-rich pyroxenites. In the Turfspruit area, to the south, the footwall rocks consist of sediments of the Timeball Hill Series. Original argillaceous rocks have been metamorphosed to cordierite-, corundum- and spinel-bearing hornfelses. Graphite was present in the contact zone in both the Tweefontein and Turfspruit areas. Anhydrite-bearing hornfels rocks are also present on Turfspruit.The Platreef rocks that overlie the corundum- and spinel-bearing hornfelses on Turfspruit are peridotitie, and pyroxenites are present in areas underlain by cordierite-bearing hornfels. The absence of orthopyroxene in the peridotite is probably indicative of low silica activity in the original magma. The pyroxenites have, however, undergone silica contamination from the underlying more siliceous cordierite hornfels.Carbon isotope studies indicate that the graphite in the Tweefontein and Turfspruit samples represents organic material orig­ inally associated with the footwall sediments. Sulphur isotope determinations on the anhydrite-bearing floor rocks indicate that this phase is clearly of sedimentary origin and was probably derived from an evaporitic unit within the carbonate sequence. This provides firm support for a model of ore genesis that involved the introduction of additional sulphur into the Bushveld magma. Isotope studies on sulphides associated with the banded ironstone and graphite indicate that these units were not the source of additional sulphur. Experimental studies predict, however, that a magma contaminated with iron- and carbon-rich material would have a high sulphur-carrying capacity. Where additional sulphur is available the magma would achieve saturation early in its crystallization history and precipitate an immiscible sulphide phase. Experimental work has also shown that sulphide precipi­ tation can be triggered by the introduction of salic material into a magma close to sulphur saturation. This mechanism probably played a role in the control of the sulphide mineralization in the Turfspruit area."

Jan 1, 1984

By J. A. Rowland

Magnesium alloys containing nickel, nickel and manganese, lithium, lithium and manganese, and lithium and aluminum were investigated. Melting, casting, and mechanical working techniques and the heat treatment of various compositions were studied. Amenability to cold and hot working was shown for many compositions. The magnesium-nickel and magnesium-nickel-manganese alloys failed to develop superior mechanical properties and were very low in resistance to corrosion. The magnesium-lithium series, although entirely plastic, had low strength properties. The addition of small amounts of aluminum to the Mg-Li base did not affect greatly either the ductility or the strength; further additions developed increased strength, but only at room temperature, and the alloys became brittle with age. Continued study, concentrating on the ductile lithium-rich beta phase as a base composition for ternary and quaternary systems, is recommended.

Jan 1, 1956

By V. A. Luganov

Methods of treatment of pyrite concentrates differ, depending on the content of pyrite and non-ferrous metals: oxidation roasting, sulphatization roasting, smelting, direct hydrometallurgical treatment and so on. Existing technologies do not provide for high recovery of metals, expenses associated with existing technologies are high, and environmental issues, associated with the existing technologies need serious attention. We have developed universal technology of the activating-dissociating autogenous roasting of pyrite concentrates using air based, or air, enriched with oxygen, blow. The basic process is taking place in accordance with the following reaction: (1-x)FeS2 + (1-2x)O2 = Fe1-xS + (1-2x)SO2 +Q The products of this reaction are pyrrhotinized cinder and roasting gases, rich in SO2 (up to 18 % in case of air blow) and poor in SO3, that contain up to 1 % of elemental sulphur. Cinder contains different forms of pyrrhotite. These forms of pyrrhotite differ by its content (from Fe0.843S to Fe0.945S), thermodynamic, magnetic (from 4.10-1 to 3.6 SI units), flotation properties (with pyrite dissociation the ?-potential of the product is moving towards more electrically positive charge, from 0.95 for pyrite to 0.2 for dissociation products) and other properties that depend on the conditions of roasting. The combination of pyrrhotizing roasting with different methods of cinder treatment allows to increase the level of sulphatization of non-ferrous metals during the roasting; reduce the amount of blow used during the processing; reduce dust losses to the gas phase; reduce the capacity of gas cleaning system and increase resistance to corrosion of the gas-treatment system, used for the production of sulfuric acid from pyrites. This combination of treatments also allows to use magnetic separation and flotation for separation of ferrous and non-ferrous metal compounds during cinder treatment; perform de-arsenation of arsenic containing concentrates and by-products. Pyrrhotinized cinder may be treated by oxidizing and non-oxidizing hydrometallurgical methods. Keywords: Pyrite, polymetallic ores, sulphidization roasting, pyrrhotite, magnetic separation, arsenic sulphide

Sep 1, 2012

By T. G. Joseph, A. Chamanara

ABSTRACT: The chicken and egg scenario — where adverse truck motions cause ground deterioration and poor ground profiles cause adverse truck motions — is a downward deterioration spiral dominating our industry. If we remove one action, the reaction stops. A simple truck to excavator load data analysis and wireless communication system is outlined, which will provide visual assistance to the excavator operator in achieving improved load placement and balance in a truck body. This will reduce subsequent hauler duty cycle adverse motions and g levels that contribute to structural fatigue, higher tkph, reduced tire life, and ongoing maintenance of haul roads.

Jan 1, 2012

By G. Plenge, M. Brittan

"Plant design parameters for gold extraction, leach residence time and cyanide consumption are generally determined from standard bench-scale bottle roll or agitation leach tests. The application of laboratory data to process design has essentially evolved from the testing of oxide or low cyanide-consuming ores. Such scale-up factors may not be appropriate for ores that deplete cyanide and oxygen since this interferes with gold extraction kinetics. High cyanide-consuming ores also exacerbate the differences between the conditions applicable to small batch tests and large continuous operations. Testing a reactive high-sulfide South American ore deposit necessitated the re-evaluation of conventional bench-scale cyanidation procedures. Pulp density can be a major factor affecting the results for plant design purposes and should be treated as a test work variable. As with high clay-bearing ore, where pulp viscosity can hinder mass transfer, minimizing the influence of test equipment on gold extraction kinetics may require low pulp densities. This introduces interpretative complexity since cyanide consumption changes as a function of pulp density. Activated carbon also consumes cyanide, so its effect has to be accounted for in the case of carbon-in-leach (CIL) or carbon-in-pulp (CIP) plant flowsheets. Since cyanide is an expensive reagent, often a major component of plant operating costs, it is important that the scale-up of cyanide consumption from laboratory to plant be representative. The traditional method of reporting cyanide consumption in bench-scale testing is questioned since it takes credit for residual free cyanide in leach tails. The projected plant consumption may be better estimated by using the total cyanide addition in a laboratory test. We propose a test work protocol that categorizes the cyanide consumption into its components but requires more extensive testing to generate design data. The ultimate validation of scale-up factors used by project engineers requires rigorous bench-scale versus commercial plant comparative data. Such data are not readily available.IntroductionMajor factors in the design of a gold processing plant are gold recovery, leach residence time and cyanide consumption. These parameters are important determinants of project revenue and costs and, thereby, potentially of project financial viability. Estimates of the associated design criteria for a commercial plant are normally generated from laboratory cyanidation, carbon-in-leach (CIL) or carbon-in-pulp (CIP) tests using standard procedures (Angove, 2005). The key question is whether the standard laboratory test work procedures developed historically for low reagent consuming ores are appropriate for ores that are highcyanide and oxygen consumers.The present paper examines test procedural factors that can influence the test work results and, therefore, their interpretation for design scale-up purposes. The study refers in particular to a high cyanide-consuming sulfide ore. The ore was being tested to develop scoping level engineering design criteria for a proposed project in South America."

Jan 1, 2015

By J. Makgatho, P. Condori, J. Winnett, Fischerm D.

"Palabora Mining Copper (PMC) has two autogenous mills that have been in operation since 1976. The mills were originally designed to treat 30 000 t/d of open cast copper ore in a closed circuit with cyclones. As the ore body went deeper the open cast method of mining was changed to block caving, a consequence of this was the dolerite content (hardest barren material) increased significantly, increasing the production rate of pebbles and thus reducing the milling capacity. In order to cope with the increased ore hardness and to increase mill capacity, a second ball milling stage and pebble crushing were incorporated to the circuit. The above actions created new challenges to the circuit operation and bottlenecks in different areas of the milling circuit.This paper reports the holistic work performed on the Palabora autogenous milling circuit including the implementation of a mill constraint control scheme, the implementation of a pebble removal system from the circuit and a new circuit configuration."

Jan 1, 2012

By Marcela Dalboni Teixeira Garcia

Neste trabalho foram apresentados com detalhes os estudos necessários para o estabelecimento de uma metodologia capaz de avaliar a espessura de óleo depositado em folhas-de-flandres. A elipsometria é uma técnica poderosa capaz não somente de medir espessura de variados filmes finos, mas também caracterizar propriedades ópticas e elétricas dos mesmos. Foram testados vários procedimentos para acessar o substrato da folha-de-flandres e vários modelos que reproduzissem as características elipsométricas medidas. Escolheu-se então melhor procedimento adequado para acessar as características do substrato e o melhor modelo para caracterização elipsométrica do filme fino de óleo.

Aug 16, 2017

By C. F. Davidson

The Bureau of Mines studied the extraction of lithium from lithium-containing clays by chlorination with hydrogen chloride (HC1). In bench-scale laboratory investigations, HC1-H20 mixtures were used to selectively chlorinate lithium, but not calcium or magnesium, in lithium-containing clays. The addition of calcium carbonate to the clay was found to improve the lithium recovery. Reaction conditions found to affect the lithium recovery were ratio of clay to carbonate, reaction temperature, and HC1 concentration. The best conditions for selective chlorination of the lithium were 2:1 clay-carbonate, 750° C, and 20 wt-pct HC1. The experimental results and trends in lithium extraction are explained using thermodynamic relationships.

Jan 1, 1981

By James E. Hoffmann

Oxidative pressure leaching is gradually supplanting other techniques for the decopperizing of slimes. The reasons for this include: much more rapid reactions, more compact equipment, a reduced environmental burden, and perhaps most important, a much lower final copper concentration in the decopperized slimes. This paper will discuss the reactions occurring during decopperization, the acidity and temperatures encountered and the techniques employed for discharging non condensable gasses. A spreadsheet is provided which allows adjusting the operating conditions depending upon raw (undecopperized) slimes composition, solids concentration and lixiviant composition. A typical process equipment flowsheet is provided along with a process narrative.

Jan 1, 2000

By D. Harrington

ANNUAL or necessary inspections and investigations of coal mines for various purposes were made possible through the Federal Coal Mine Inspection Act of May 7, 1941, which authorized entry to the Secretary of the Interior through the Bureau of Mines. Primary object of these inspections is to obtain information pertaining to health and safety conditions. Among the purposes for which the data are to be used, are annual reports to Congress, the publication of inspection reports, and the compilation and publication of statistics. The act states that inspections and investigations shall be made by employees of the Bureau of Mines, who shall co-operate with other bureaus of the U. S. Department of the Interior, as well as with the official mine-inspection, safety cr health agencies of the several states and territories. The act specifies that a coal-mine inspector shall have "the basic qualifica-

Jan 1, 1946

By J Kinal, P Steinier

A considerable volume of work exists in the literature examining the electrochemical interactions between grinding media and sulfide minerals. Broadly, most sulfide minerals are more noble than forged steel grinding media used during comminution, therefore a galvanic couple between the media and the sulfide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulfide minerals thereby affecting their floatability. This paper explores the science behind these corrosion reactions, and provides an explanation of their impact on the pulp chemistry of sulfide mineral slurries and subsequent flotation behaviour. A number of laboratory and plant case studies are used to illustrate the benefits of changing to a more inert grinding media.

Jan 1, 2005

By C. Birch

"The purpose of this study was to establish the impact of discount rates on cut-off grades for narrow tabular gold deposits as characterized by the goldfields of the Witwatersrand Basin in South Africa. There are various methods available for determining the cut-off grade, from simple breakeven calculations to sophisticated software packages that consider a variety of inputs to optimize the cut-off grade. For this study a simple financial model was created in Microsoft Excel® that links the ore flow, block listing, and the cash flow. This allows the cut-off grade to be optimized considering how the cost of capital and chosen discount rate affect the cash flow.The discounted cash flow (DCF) and resultant net present value (NPV) are a widely used valuation method for production properties according to the South African Code for the Reporting of Mineral Asset Valuation (SAMVAL Code). The financial model in this study utilizes the Solver function, as well as simple Microsoft Excel spreadsheet formulae to optimize the NPV. Solver was chosen as it is a standard feature in Excel and thus no additional software costs are incurred beyond the basic Microsoft Office suite. For the purpose of this study, just narrow tabular gold deposits of the Witwatersrand Basin were considered. An example of a typical ore block listing, as well as the costing figures, was obtained from an operating gold mine. The results obtained from the study financial model were compared to the current cut-off grades obtained from the mine using their proprietary optimizer program, and were found to be comparable. The methodology utilized for this study thus appears valid.The cut-off grade was optimized considering the cash flow, which includes the variable mineral resource royalty tax, the variable gold income tax, as well as the discount rate. By comparing the resultant NPVs using discount rates of zero, 9%, and 12%, the impact of the discount rate on cut-off grades, resultant life of mine, and average mining grades (AMG) could be compared for the example ore block listing. The South African Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (SAMREC Code) does not require operations to state if a discount rate was considered in determining mineable reserves. Mining companies approach the question of applying discount rates in determining their cut-off grades, and thus mine planning strategy, in different ways. Due to the negative impact that optimizing purely on NPV has on the life of mine, some choose to optimize only on profit. Other companies have reverted to utilizing pay limits as their primary grade planning strategy. The calculated cut-off grade is then considered to be another planning indicator rather than a hard determination of mineable reserves."

Jan 1, 2016

By Frank A. Peters

An evaluation is made of a lime-soda sinter process for extracting alumina from clay. In this process, alumina is extracted by sintering clay with soda ash and limestone and then leaching the sinter with a dilute sodium carbonate solution. The sodium aluminate solution formed during leaching is separated from the residue and treated with lime in autoclaves to remove dissolved silica before alumina trihydrate is precipitated with carbon dioxide. The tri-hydrate is then calcined to a-alumina. Two options, dry grinding and wet grinding, are used in the sintering step. The fixed capital costs for plants producing 1,000 tons of alumina per day are $72 million for the dry grinding option and $66 million for the wet grinding option on a Marshall and Stevens chemical equipment index basis of 240.0. Specific geographic locations of plant and raw material sources are not assigned, but, since this process requires large quantities of both lime-stone and clay, the plant site is considered as variable with relation to the clay mine and limestone quarry. A nomograph is given to find operating costs at various delivered costs of clay and limestone. If the plant is located nearer the limestone quarry so that the delivered cost of clay is $2 per ton and the delivered cost of limestone is $1 per ton, the operating costs are $76.47 and $71.61 per ton of alumina for the dry grinding and wet grinding options, respectively. On the other hand, if the plant is located nearer the clay mine so that the delivered cost of clay is $1 per ton and the delivered cost of limestone is $2 per ton, the operating costs are $80.15 for dry grinding and $75.34 for wet grinding.

Jan 1, 1967

By R. G. B. Pickering

Successful management of mining operations depend on the accurate and reliable measurement of performance as a monitoring instrument in a feedback and control loop. However, when changes are being considered, the probable effect of the change on bottom line results requires different measuring techniques incorporating an in depth understanding which can identify hot spots in the operation which exhibit strong sensitivity to change. The CSIR's Division of Mining Technology has therefore been devoting a considerable effort to the establishment of techniques which enable changes to be analysed in terms of their impact on the two key parameters describing mine performance, i.e. profitability and safety. This paper describes these techniques, outlines their application to some example situations and discusses planned enhancements. The first section of the paper addresses the profitability model, and this is followed by a section considering the mine safety model.

Jan 1, 1996

By Sitotaw Y. Fantaye

"The first segment of the Second Avenue Subway extension is approaching construction completion. The new extension will operate along Second Avenue from 96th Street to 63rd Street, where it will divert west along the existing 63rd Street line, stopping at the Lexington Avenue/63rd Street Station. The new line will have stateof-the-art stations at 96th, 86th, 72nd and 63rd streets.Most of the two-track, twin-tunnel subway was constructed using bored tunnel methods (Figure 1), with a tunnel boring machine (TBM). The launch and retrieving box of the TBM was strategically located at the south end of the 96th Street Station where bedrock exists approximately 70 ft (21.3 m) below street level. The TBM launch box and the 96th Street Station (Figure 2), including the ancillary facilities adjacent to the station, were constructed by the cut-and-cover method. The cut-and-cover work required the contractor to design and implement a stiff, tightlybraced retaining wall, approximately 100 ft (30.5 m) long, to tie the existing tunnel constructed in the 1970s to the new station, temporary street decking over the entire excavation, and a wide range of excavation support systems at various locations.The cut-and-cover construction posed significant challenges including: installation of street decking on busy Second Avenue, relocation and suspension of the myriad utilities beneath the streets, and configuration of a lateral support system that would minimize movement of adjacent structures but not slow down excavation activities. This article describes the innovative solutions developed to manage and facilitate safe and efficient construction without disrupting Second Avenue, a major southbound one-way thoroughfare.The work was performed in several phases involving: (1) preconstruction condition survey of existing buildings, (2) installation of instrumentation and monitoring, (3) major utility relocation efforts to move vital utilities from within the alignment of the slurry wall on both the east and west sides of the avenue, (4) implementation of maintenance and protection of traffic plans, (5) installation of temporary street decking across the entire avenue and over the excavation to allow an orderly movement of traffic and pedestrians, (6) staged excavation and installation of an intricate temporary bracing system beneath the decking (7) step-by-step construction of the new subway station’s structure and (8) staged removal of the bracing as the structure gained sufficient strength to resist the lateral loads. The main focus in this article is the design and construction of the temporary street decking and lateral bracing systems; the utility suspension system and the north tie-in that allowed the daunting task of excavation and construction of a new subway station in bustling New York City, with minimal disruption to the community, businesses and everyday traffic."

Jan 1, 2016

By A. Poitras

The Cummings Complex consists of three superposed sills, exhibiting a differentiation pattern: the lowest sill being the most basic and the highest sill, the most acid. Each sill is also characterized by an internal petrographic and geochemical variation which is evidence of differentiation due to fractional crystallization. The REE concentrations in the different units of the complex indicates that the three sills are comagmatic. The interpretation of these results permits the formulation of an emplacement model not previously proposed for this complex.

Jan 1, 1984