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By A. Cummings

This paper reports two aspects of reactivity of complex Ni-Cu sulphide ores: variations that result from stockpiling of a nickel-copper sulphide ore in the Sudbury area and its consequences on flotation behaviour, especially in terms of metal losses to scavenger tails. In relation to the first aspect, self-heating characteristics of the stockpile were carried out by monitoring the internal temperatures of the stockpile. Six heat sensors were installed with respect to external conditions in local weather during a 7-month period. Stockpile temperatures were mainly influenced by ambient temperature with some retardation effects. The maximum temperature recorded in the stockpile was 44 °C. Samples taken at the beginning and at the end of stockpiling were tested to assess variations in behaviour of the rougher-scavenger flotation. Relative to the fresh ore, nickel and copper losses in flotation of the stockpile fines were 5.0 and 3.6 %, respectively. The fresh ore yields concentrates with higher nickel grades due to differential flotation behaviour of pentlandite and pyrrhotite relative to the stockpile fines, which exhibit a truly bulk flotation behaviour at least during the first 3 stages.

Aug 1, 2013

By Shatwell DO, Hayward SB, Leach TM

Following acquisition of the Woodlark Island tenement by Highlands Gold Limited, an exploration programme using extensive diamond drilling has confirmed that the style of gold mineralisation is similar to other SW Pacific Rim carbonate base metal gold systems. The two centres of gold mineralisation at Kulumadau and Boniavat-Busai are inferred to be related. to buried porphyry centres localised on NE trending major horst bounding structures. Individual prospects are localised on NW trending cross structures peripheral to the porphyry centres.Gold mineralisation has been derived from the mixing of hot saline magmatic fluids with cool dilute meteoric waters. While the bulk of mineralisation occurs in dilational tensional gash fractures, bonanza grades resulted from fluid quenching in feeder structures. Pre-mineralisation breccias created plumbing systems for hydrothermal fluids and similar paragenetic sequences are defined for Busai and the Kulumadau areas. These include early, distal porphyry, low sulphidation mineralisation, followed by base metal gold and carbonate deposition.

Jan 1, 1994

By S. Jagdish

India ranks fourth in the world of iron ore production and exported 55% of the total iron ore production of 180.9 million tons in 2006-07. As per United Nations Framework Classification (UNFC), the total iron ore reserves in India is 25249 mt. This consists of about 14630 mt of Hematite ore and 10619 mt of Magnetite ore. While the deposits of magnetite iron ore are limited to the states of Karnataka, Andhra Pradesh and Tamil Nadu, hematite ore is available in abundance in Jharkhand, Orissa, Chhattisgarh, Karnataka and Goa. National Steel Policy, declared by government of India in 2005 envisages 110 million tons of steel production by 2020. This is likely to be revised upwards. Massive exploration work in iron ore is needed to convert the available resources of iron ore into reserve category. Steel Authority of India Limited (SAIL) produced more than 24.5 million tons of iron ore during 2006-07 and plans to produce 42.0 million tons per year by the year 2010-11 to meet the requirement for a hot metal production of 26.2 million tons. While processing iron ore, the challenge faced would be the reduction of the gangue materials ? alumina and silica. It is proposed to bring down alumina and silica in the iron ore to less than 2% each from the current level of 2.5%~3.5% each. Appropriate beneficiation schemes are being developed depending upon the mineralogical characteristics of iron ores at different mines in the country. The state-of-art beneficiation technologies like Hydro-cyclone, jigging, magnetic separation etc. will be incorporated. SAIL?s corporate plan envisages blast furnace burden of 15% iron ore lumps, 15% pellets and 70% sinter by 2010. This strategy opens up the opportunity of utilization of micro fines generated in the mining and beneficiation processes for pellet making. This also directs towards all together new technological approach to the beneficiation process. SAIL is planning to set-up three pelletisation plants of 2~3 mtpa capacity. Environmental issues like reduction in slime loss and utilization of dumped low-grade iron ore are very important. R&D Centre for Iron and Steel, SAIL has carried out extensive laboratory investigations in the above area. This will help in reducing the loss of valuable iron through slimes and also increase the iron ore resource base. Laboratory investigations indicate that low grade dumped ore fines with Fe: 55.5% can be upgraded to a product with Fe: 66.2% with about 48% recovery.

Jan 1, 2014

By Leonardo Zuchi Guio

A ArcelorMittal Tubarão vem trabalhando continuamente no aumento de produção de seu Laminador de Tiras a Quente (LTQ). Com o aumento da produção, o risco de colisão de material ao longo do LTQ, com maior possibilidade de ocorrência na mesa de resfriamento de tiras, se elevou. De forma a permitir aumento de produção e evitar colisão de material, desde o início de 2016 iniciou-se um trabalho de ajuste no modelo. Dado que o modelo consiste na determinação do ritmo de laminação a partir da liberação de extração de placas dos fornos, início do processo de laminação, o trabalho envolveu a criação de um ponto de controle de ritmo no meio da linha do laminador. Para suportar um controle adequado nesse ponto, foram necessários ajustes de parâmetros e cálculos para aumento da precisão do modelo. Esse trabalho apresenta os ajustes realizados para utilização do novo ponto de controle, bem como os ajustes realizados para aumento da precisão do modelo e os ganhos de produtividade obtidos a partir desses ajustes.

Oct 30, 2017

By Sean Warren, JOSEF BOURGEOIS

The potential of rockfall at open-pit mines presents a continuous hazard to mine workers and is typically mitigated by designing catch benches at empirically determined widths. The National Institute for Occupational Safety and Health (NIOSH) is working in conjunction with industry and academia to revisit and update current catch bench guidelines to better match acceptable risk tolerances for modern mining practices. To begin this process, a rockfall testing program was designed to gather empirical runout and bench catchment data at partnering mine sites in the Western United States. This paper presents a detailed description of each component of the rockfall testing program, including scouting and safety plan development, equipment requirements, synthetic rock development for uniform testing across varying bench configurations, local rock collection for testing of mine-specific geology, data acquisition during testing, and data processing. Additionally, this paper describes how the program has been updated over time according to lessons learned during initial rockfall testing.

Feb 1, 2024

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By N. L. Richards

In manufacturing for the 21st century, the first company to market often leads the pack in product development and sales. In this respect, manufacturing processes play an important role in transforming “raw materials” into a product(s) for sale to a customer. Thus it can be seen that upfront modelling of a design concept, or modelling of manufacturing processes in a plant, can play an important role in effectively ensuring the overall design and manufacturing route is carried out in an expeditious manner. In the paper various scenarios are considered with respect to modelling the microstructure and/or process, in various manufacturing processes. Also considered are the effects of service condition on the manufactured product in terms of creep and fatigue.

Jan 1, 2010

By J Herrmann, J Richards, B Hutchison

An extensive trial of laser-based survey and monitoring systems at Hillgrove Resources Kanmantoo Copper Mine in the Adelaide Hills, South Australia, has proved the capabilities of the system in monitoring rock movements on open pit walls. Initially, the trial involved deploying a Maptek I-Site 8820 laser scanner and the proof-of-concept Maptek Sentry software in the Nugent Pit to monitor ductile rock movements located up to 260 m away. The system was proven to be capable of monitoring various rock movements from 1.5 tonne rockfalls up to a 40 m high toppling wall failure. Data collected from smaller rockfalls was used to help build a database for Hillgrove’s rockfall management program. As part of the trial, the laser scanner was deployed to monitor a ramp movement event, as well as the toppling failure, adjacent to an IBIS slope stability radar. Both devices monitored the slump and the slowly developing toppling movements, with similar results. Although the radar was used as the successful ‘critical alarm’ device for the toppling failure, post-failure analysis showed the laser-based system to be capable of performing a similar role in the ductile rock regime; albeit over much shorter distances than the radar capability. A second laser scanner was deployed to monitor Kanmantoo’s Emily Pit in early December 2014, where it successfully provided critical alarm warnings for a block topple event. Sentry software, which takes advantage of Maptek I-Site 3D spatial imaging technology, was first released in November 2014 to meet industry demand for a cost effective, flexible system to detect movement. Sentry has now been re-launched as a fully transportable monitoring system. Deployed in a custom trailer, the system offers a power and communications module, cellular and Wi-Fi networking and a stable bollard for the I-Site laser scanner and Sentry software. This paper will present rock wall movement data from the Sentry trial and a subsequent two years of monitoring of the open pit walls at the Kanmantoo Copper Mine, at distances out to 750m. In addition, examples of remote geological mapping and small rockfall detection, using the laser scans, will be described. The Sentry system has proven to be beneficial for the continual improvement of slope monitoring and risk management at hard rock mines. CITATION:Hutchison, B, Richards, J, Richards, J and Herrmann, J, 2018. Mine rockfall and rock wall failures – proven digital laser-based approach for monitoring slopes at the Kanmantoo Copper Mine, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 463–472 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By David B. Brooks

I gratefully acknowledge the help of a number of American and Canadian geologists, in both federal surveys and in private firms, who took the time to discuss this problem with me. Hans Landsberg and Bruce Netschert also followed the study with interest and encouragement. In their 1961 monograph, THE FUTURE SUPPLY OF THE MAJOR METALS, Bruce Netschert and Hans Landsberg noted that identified potential resources (that is, known but submarginal resources) of lead and zinc were much lower relative to reserves (that is, known and supermarginal resources) than was the same ratio for other metals.1/ Put another way, it seemed that for such metals as iron, manganese, copper, and aluminum, slightly more favorable economic conditions or modest advances in technology would greatly increase reserves by permitting the exploitation of vest quantities of leaner or deeper or otherwise less valuable mineral deposits. But for lead and zinc, Netschert and Landsberg concluded that either: "(1) there is relatively little material below present cutoff grades; [or] (2) such material exists, but for some reason there are no data.? 2/ This situation, which they called "the lead-zinc anomaly" has been subsequently discussed by other authors. The purpose of this paper is to carry the discussion further by examining the evidence in favor of (1) and (2) and by advancing a third alternative.

Jan 1, 1967

Abbey. Robert Graham, District Mgr.. The W. W. Sly Mfg. Co., 50 Church St., New York, N. Y. '21 Abbott, Clarence E., V.P., Charge of Raw Materials, Tenn. Coal, Iron & R. R. Co., 1242 Brown-Marx Bldg., Birmingham, Ala. '04 Abbott, Louis Benjamin, Chief Engr., Consolidation Coal Co., Watson Bldg., Fairmont, W. Va. '15 Abeel, George H., Jr., Cons. Min. Engr 12S1, S. Canon Dr., Beverly Hills, Cal. '18 4 -Abel, Raymond L., Asst. Prof., Dept. of Pet. Refin.. Univ. of Pittsburgh. Pittsburgh, Pa. '28 Abel, Walter D., Cons. Engr 650 S. Grand Ave., Los Angeles, Cal. '82 Abele. Louis T., Min, & Met. Engr., Supt., Texas Hill Mine Coulterville, Cal. '31 Abell, Leo M Sullivan Concentrator, Chapman Camp, B. C., Canada '31 Abernathy, George Elmer, Prof. of Geol. & Min., Kansas State Teachers College. Pittsburg, Kan. '20 Aborn, Robert H., Asst. Met., Research Lab., U. S. Steel Corp., Lincoln Highway, Kearny, N. J. '19 Abraham, W. E. V., Member, Geological Staff of Burmah Oil Co., Ltd., Nyaunghla, Upper Burma, India. '28 Abstein, Henry T., Engr. & Mgr., Profile-Tamarack Mines Co Yellow Pine, Idaho '27 Acker, E. O'C., Met 128 East Washington Lane, Germantown, Philadelphia, Pa. '86 Ackerman, D. E., Met., Research Lab., International Nickel Co., Inc Bayonne, N: J. '24 Ackerman, George F., Engr., Real del Monte y Pachuca Min. Co., Apt. 3, Pachuca, Hgo., Mexico '29 *Acres. T. H.. Geol. Dept., Valuation & Pet. Engrg., Richfield Oil Co., 555 S. Flower St., Los Angeles, Cal. '29 Adachi, Jinzoo Address Wanted '88

Jan 1, 1934

By César Augusto Martín Hilser Vicuña

El "Punto de fluencia” es el contenido de humedad crítico a partir del cual un mineral concentrado sufre “liquefacción”, es decir, libera la humedad como agua libre al ser sometido a las sacudidas propias de una travesía por mar. En esta perspectiva, el presente texto correlaciona la influencia que tiene el proceso de producción de los concentrados en el punto de fluencia a través de los siguientes factores: granulometría, efecto de los reactivos de flotación y la mineralogía. De forma que al conocer los factores que influyen notablemente en el valor de la humedad límite de transporte, se evita los riesgos de que la carga sufra licuefacción durante su transporte por mar.

Sep 14, 2009

By H. R. Manouchehri

"Pyrrhotite (Po) is one of the most abundant sulfide minerals in processing industry and must be rejected in most cases. Particularly, Po rejection and its selectivity against pentlandite (Pn) have long been a challenge due to similarities in the mineral composition of the two minerals and the collectorless flotation characteristics of Po. Xanthates have been widely used to promote sulfide mineral flotation; however, in the presence of xanthates, the redox potential established at the mineral/solution interface is most important, determining the flotation performance. In this paper, the importance of electrochemistry in Po and Pn flotation has been demonstrated and a comprehensive study was conducted on two different feed streams (i.e., magnetic concentrate and scavenger cleaner streams, containing magnetic and nonmagnetic forms of Po, respectively), from Vale’s Clarabelle Mill in Sudbury, Ontario, with an objective to determine if improvements in Po rejection and Pn recovery could be achieved by controlling pulp electrochemistry. By conducting a series of flotation tests under different Eh conditions and reagent usage schemes, it was revealed that higher Po content in the magnetic stream may protect Pn from being oxidized, improving Pn recovery. The results indicated that at low oxidizing pulp chemistry, the rest potential for the Pn is still high enough to allow the formation of dixanthogen to promote its flotation. Using a Pt electrode, it was found that by controlling pulp potential at -50<Eh< +50 mV, the Pn recovery and Po depression would be satisfactory. The results, using mineral electrodes (Outotec Chena analyzer), indicated that selective separation can be achieved if low-to-moderate oxidation potentials (0 to 100 mV) or reduction (0 to -100 mV) potentials are monitored using Pn and Po electrodes. Mixing two streams at 50:50 wt % would be possibly beneficial in selective separation.IntroductionPyrrhotite (Po), Fe1-xS, is one of the most abundant sulfide minerals in the processing industry. It is an iron-deficient sulfide that occurs either in monoclinic or hexagonal form. The monoclinic one is richer in sulfur and is ferromagnetic, whereas the hexagonal Po is poorer in sulfur and has no magnetic properties. In general, the ferromagnetic properties of natural Po increase with increasing sulfur content. Although Po holds significant iron content, it is not used as a feedstock for the iron and steel industry due to the difficulty in achieving complete removal of sulfur. The common availability of iron oxide ores makes the iron sulfides irrelevant for the steel industry."

Jan 1, 2015

By S B. Richardson, D Mead, N T. Moxon

The use of air-decks to reduce explosive costs has become very topical in recent years. The majority of the research in this area has been arried out between the Soviet Union where reductions in explosive consumption of between 10-30% have been claimed with apparent benefits being gained in both fragmentation and movement. Work carried out by the University of Maryland using thick plexiglass blocks has supported these findings and indicated that air-decks in measetbe duration of action of the shock wave on the surrounding material by a factor of 2 to 5 (see Figure 1). Although the fracture network resulting from this mechanism is not as intense as that produced adjacent to the explosive charge it does appear to act over a larger volume of material. Although the mechanism attributed to air-decking has been studied in some detail the effect of this mechanism on the size distribution of material produced during a blast does not appear tot have attracted much attention.

Jan 1, 1991

By AIME AIME

READERS of a technical paper, or the audience if the paper is presented orally, judge the paper on several counts. The September 1940 issue of MINING AND METALLURGY contained an excellent short article by S. Marion Tucker en- titled "Are You Going to Present a Paper," which considered the general subject of presentation. In it Dr. Tucker referred to the large number of poorly prepared and badly delivered papers that are presented annually before the large number of technical and other societies that meet regularly, and he stressed the point that good delivery, length of paper, content, and composition are of great importance. All of Dr. Tucker&apos;s points were well taken; however, good illustrations are equally important in explaining certain phases of some papers.

Jan 1, 1941

By M. H. Thomas

El presente trabajo describe tres ejemplos de empresas en Australia que utilizaron carbones provenientes de fuentes locales para el encendido de sus hornos. Así también se muestra los principios generales de la operación de los hornos rotatorios, la quema de combustible pulverizado, el encendido directo e indirecto, la contaminación de cenizas y los problemas derivados de la eliminación de azufre.

Nov 1, 1984

By Raymond Sandiford, Kenneth Xu, Taehyun Moon

Tunnel approach structures situated in slow moving earth flows are subjected to significant earth pressures. The authors have developed a system, utilizing collapsible concrete columns, that limits such loading. The system uses an array of collapsible concrete columns in front of the structure to absorb downslope movement and limit-imposed loads. This concept has been modelled using 3D FEM analyses and a rudimental lab test. For implementation, the collapsible columns would be prefabricated in strengths to mimic the soil strength profile. This concept has merit, and analytical results demonstrate that collapsible columns are a viable means to limit loading.

Jun 23, 2024

The November General Meeting of the Branch was held in the St. Helena Club at 8.00 p.m. on the 17th November, 1970. Mr J. N. Saunders (Chairman) was in the chair. There were also present six fellows, N. A. Honnet, C. J. Isaac, J. G. Kirchner, (Committee Members), J. M. Meyer, S. L. S. Swart and J. W. Wilson; seven members, D. V. Baum, M. de Lange, A. H. Edwards, G. J. G. Emere, E. R. Penny, G. P. Rundle, C. G. J. Vermeulen; six graduates, N. Mayer, H. Miller, E. J. Shillaber, P. J. H. Short, M. H. Smith, T. R. Stromsoe; five associates, M. Andriesse, A. E. Hooper, A. Paschalides, R. L. Solms, W. M. Todd; one student, J. C. Simms and 14 visitors. Apologies for absence were received from Messrs L. O. W. Leimer and G. Y. Nisbet. MINUTES OF THE ANNUAL GENERALMEETING The Minutes of the Annual General Meeting held on the 27th August, 1970, were taken as read. Their adoption, which was proposed by Mr N. A. Honnet and seconded by Mr J. G. Kirchner, was carried unanimously. MINUTES OF THE JULY GENERALMEETING The minutes of the General Meeting held on the 8th July, 1970, were taken as read. Their adoption, which was proposed by Mr C. J. Isaac and seconded by Mr J. G. Kirchner, was carried unanimously. GENERAL BUSINESS Members were advised that no more applications could be entertained for the visit to Western Holdings; they could, however, still apply to visit Welkom Mine and Harmony. TALK The Chairman invited Mr A. Paschalides to deliver his talk on &apos;Controlled blasting in stopes and new explosives developments&apos;. The presentation proved to be of great interest to the meeting and lively discussion followed the talk. Mr N. A. Honnet proposed a vote of thanks to Mr Paschalides on behalf of all members of the O.F.S. Branch. CLOSURE The Chairman thanked Mr Paschalides for his talk and all present for their attendance, and as this was the last meeting for 1970 he wished all members a Merry Christmas and a Happy New Year. He declared the meeting closed at 9.30 p.m.

By John Ward Smith

Dawsonite bearing oil shale of Colorado&apos;s Green River Formation offers a unique and vast (6.5 billion tons of Al2O3) resource of easily extractable alumina. The processing methods required by the thermal reactions dawsonite and its oil shale carrier also require production of shale oil, soda ash, and nahcolite as marketable coproducts. These production methods are presented. The alumina production process is contrasted with the Bayer process to describe technical advantages of extraction of alumina from oil shale which may offset the problems associated with processing a relatively lean ore. While alumina production from oil shale requires development of new technology, the technical problems appear solvable. Only the political problems arising from the now onerous and completely unnecessary Federal oil-shale withdrawal appear less solvable.

Jan 1, 1980

By Michael Shedlosky, Sonia Sorabella Swift, Nina Carney, David Tarasovic

Rigid inclusions were used to support roadway fills and mechanically stabilized earth (MSE) walls for the South Capitol Street Corridor project. The first phase of this two-phase, nearly $1 billion project will include the replacement of the Frederick Douglass Memorial Bridge, including two approach ovals east and west of the Anacostia River, the replacement of the I-295/Suitland Parkway Interchange, and the construction of several traffic ramps. The bridge itself carries over 70,000 drivers daily and is expected to open in 2021. Ground improvement is required over a portion of the project footprint. Within the ground improvement area, the construction includes MSE walls up to 35 feet high and embankment fills up to 28 feet for which CMC rigid inclusions (RIs) were used to mitigate settlement and stability. The proposed construction runs over multiple old, in-service utilities that the project requirements indicate could not tolerate any stress or settlement due to the construction. As such, solutions that spanned the utilities were required. A concrete slab of varying thickness was used to span a fragile 108-inch-diameter sewer pipeline and 48- inch-square-precast-concrete box beams were used to span twin utilities that were buried just a few feet below current working grades on site. Unreinforced RIs were used to support these structures. The center to center spacing of the RIs perpendicular to the pipe run was 26.5 ft for the concrete slab and 62 feet for the precast--concrete box beams. The axial forces on the RIs were up to 267 kips. The RIs were not structurally connected to the slab or box beams. A single-element load test was performed to confirm the load-carrying capacity of the RIs. This paper will focus on the utility protection slab over the twin utilities and provide an overview of the design of the structural and geotechnical solutions and will present the results of the load test performed. INTRODUCTION The new Frederick Douglass Memorial Bridge (FDM Bridge) and reconstruction of the Suitland Parkway/ I-295 interchange (South Capitol Project) is a part of the Anacostia Waterfront Initiative (AWI) Program, whose goal is to transform the shores of the Anacostia River. The existing FDM Bridge is approximately 70-years old and has been classified as “functionally obsolete”. The completed South Capitol Project will improve the multi-modal transportation options, increase pedestrian and vehicular safety and provide additional green space. The proposed FDM Bridge, a rendering of which is shown in Fig. 1, is designed to become a landmark bridge in the Washington, D.C. area.

Jan 1, 2019

By John L. H. Patterson

Handheld XRF has become the favorite way of measuring the content and identity of alloys in the field. This is because of the very portable nature of the instrumentation and its simple operation. However, these analyzers have been unable to determine the concentration of the light elements like Mg and Si due to the very low energy of the x-rays produced by these elements. In the past accessories such as vacuum and He flush have given some analyzers the ability to determine these light elements with modest detection limits. The introduction of the Silicon Drift Detector (SDD) into this class of instrumentation has added a new level of analysis capability to portable XRF instrumentation. X-ray fluorescence is achieved by exciting a sample with a beam of x-rays, which in recent portable equipment are generated by a small tube. This results in the emission of characteristic x-rays from the sample under test. By measuring the energy of each x-ray it is possible to determine what element generated it. By counting the number of x-rays at each energy it is possible to determine the concentration of each element. The detection limit for each element is dependent upon the number of x-rays which reach the detector. As the number of x-rays increases the detection limit will improve. One of the major factors in an x-ray reaching the detector is the energy of the x-ray. As the energy of an x-ray increases the probability of that x-ray reaching the detector increases. The energy of an x-ray is inversely proportional to the atomic number (AN) of the element generating the x-ray. For example, an iron x-ray (AN=26) is 6.40 keV while an aluminum x-ray (AN=13) is 1.49 keV. As the energy decreases, the detection of the x-ray becomes less and less probable because the x-ray may be absorbed by the windows which are part of the instrument and detector or the air in the path between the sample and detector. In SiPIN based portable XRF analyzers, the lowest element which is detected with acceptable detection limits is normally considered to be Ti (AN=22). The detection limits for 60 second measurements on typical SiPIN XRF analyzer are given in Table I. Thus, portable analyzers have not been useful for measurement of aluminum and titanium alloys as major components of these alloys are Mg (AN=12), Al (AN=13) and Si (AN=14).

Jan 1, 2009